This study evaluated changes in volatile organic compounds (VOCs) and aerosol particle concentrations following the use of certain spray-type household chemical products in an indoor environment. Four commercially available products in South Korea (including sticker/tar removers, a razor cleaner, and a fabric stain remover) were analyzed using real-time VOC monitoring with proton-transfer-reaction time-of-flight mass spectrometry (PTR-ToF-MS) and particle number concentration measurement with an Optical Particle Sizer. Immediately after spraying 17 grams of each product, VOC concentrations increased sharply, and hazardous substances such as benzene, 1,3-butadiene, formaldehyde, and acrolein remained at elevated levels for a certain period. Additionally, some products exhibited benzene concentrations exceeding levels of potential exposure concern, and the operation of an air purifier reduced VOC levels by 73%. This research provides insight into changes in indoor air quality and associated exposure risks due to household chemical use, and it may serve as a basis for future air quality management and regulatory standards.

2019년 농촌 인구는 전년도보다 7만 명 감소하였으며, 60대 이상이 전체 농촌 인구의 69%를 차지하면서 노동력 부족이 심화되고 있다. 또한 기후 변화로 인한 폭염과 가뭄뿐만 아니라 농업 생산에도 큰 피해가 발생하고 있어, 농업용수 절감과 자원 낭비 감소가 필수적이다. 현재 농가에서는 파종 후 초기 육묘기에 분수 호스를, 성장기에는 점적 테이프를 사용하지만, 두 가지 장치를 함께 설치하면 노동력과 비용이 증가하고 관수 효율이 낮아 용수 낭비와 폐기물이 많아지는 문제가 있다. 본 연구에서는 이러한 문제를 해결하기 위해 원거리 살수 기능을 가진 분수 호스와 직하 점적 기능을 수행하는 점적 테이프의 장점을 결합한 복합형 분수 호스를 개발하였다. 이를 위해 공급 압력만으로 두 가지 기능을 수행할 수 있도록 충돌형 Dripper를 설계하였으며, 내부 유로의 최적 설계를 통해 충돌각, 충돌율, 단면적의 형태 및 크기, 공급 압력 등의 요소를 조절하여 원거리 분사와 직하 점적을 동시에 수행할 수 있도록 하였다. 실험을 통해 충돌각 20° 및 30°에 대한 다양한 Dripper 설계 조건을 평가한 결과, 충돌각 30°에서 중첩율 30.0%(0.50×0.50 mm, 중첩 거리 0.15 mm)의 Dripper가 가장 우수한 성능을 나타냈다. 이 설계는 0.5 bar의 낮은 압력에서는 직하 점적 기능을 수행하고, 1.0~2.0 bar의 높은 압력에서는 원거리 확산 살수가 가능하여 기존의 분수 호스와 점적 테이프를 하나의 장치로 대체할 수 있다. 이 연구를 통해 농업 노동력 절감, 관수 비용 절감, 용수 절약 및 관수 폐기물 감소 등의 효과를 기대할 수 있으며, 복합형 분수 호스의 실용화를 위한 설계 기준을 제시하였다.

Thin films of yttria-stabilized zirconia (YSZ) nanoparticles were prepared using a low-temperature deposition and crystallization process involving successive ionic layer adsorption and reaction (SILAR) or SILAR-Air spray Plus (SILAR-A+) methods, coupled with hydrothermal (175 °C) and furnace (500 °C) post-annealing. The annealed YSZ films resulted in crystalline products, and their phases of monoclinic, tetragonal, and cubic were categorized through X-ray diffraction analysis. The morphologies of the as-prepared films, fabricated by SILAR and SILAR-A+ processes, including hydrothermal dehydration and annealing, were characterized by the degree of surface cracking using scanning electron microscopy images. Additionally, the thicknesses of the YSZ thin films were compared by removing diffusion layers such as spectator anions and water accumulated during the air spray plus process. Crack-free YSZ thin films were successfully fabricated on glass substrates using the SILAR-A+ method, followed by hydrothermal and furnace annealing, making them suitable for application in solid oxide fuel cells.

Fluorine-doped tin oxide (FTO) has been used as a representative transparent conductive oxide (TCO) in various optoelectronic applications, including light emitting diodes, solar cells, photo-detectors, and electrochromic devices. The FTO plays an important role in providing electron transfer between active layers and external circuits while maintaining high transmittance in the devices. Herein, we report the effects of substrate rotation speed on the electrical and optical properties of FTO films during ultrasonic spray pyrolysis deposition (USPD). The substrate rotation speeds were adjusted to 2, 6, 10, and 14 rpm. As the substrate rotation speed increased from 2 to 14 rpm, the FTO films exhibited different film morphologies, including crystallite size, surface roughness, crystal texture, and film thickness. This FTO film engineering can be attributed to the variable nucleation and growth behaviors of FTO crystallites according to substrate rotation speeds during USPD. Among the FTO films with different substrate rotation speeds, the FTO film fabricated at 6 rpm showed the best optimized TCO characteristics when considering both electrical (sheet resistance of 13.73 Ω/□) and optical (average transmittance of 86.76 % at 400~700 nm) properties with a figure of merit (0.018 Ω-1).

충청남도농업기술원 화훼연구소에서 2021년에 개발된 ‘Pinky Lang’은 분홍색 홑꽃 타입의 스프레이 국화 신품종 이다. ‘Pinky Lang’은 2016년 10월에 육종 하우스 내에서 2016년에 순백색의 진한 녹심이 매력적인 품종으로써 선발 된 백색 홑꽃의 ‘Bodre’ 품종을 방임 수분하여 48개의 종자 를 채취했다. 채취한 종자를 2017년 파종한 뒤 우수개체로 선발되어 2017년부터 2020년까지 4년간 촉성, 억제, 자연개 화 작형별 주년생산성 검정을 수행하여 선발된 우수계통을 ‘SP17-425-01’이라 계통명을 부여하였다. 2020년 최종적으 로 우수한 계통으로써 평가 및 심의를 받은 뒤 ‘충남SP-68 호’로 명명하였고, 당해 년도 12월 직무육성 신품종 선정위원 회를 통과하여 품종명은 ‘Pinky Lang’으로 하였다. ‘Pinky Lang’은 고온기에 화색이 변하지 않고 녹심이 매우 진하며 줄 기가 튼튼한 품종이다. 여름철 흰녹병에도 강하여 고온기 수출 품종으로 적합하다고 판단되었다. ‘Pinky Lang’은 연중 3 작기 재배테스트에서 단일처리 후 개화소요일수는 자연개화 작형 52일, 촉성작형 49일, 억제작형 50일이었고, ‘Yes Luna’ 는 각각 51일, 52일, 52일로 전반적으로 개화소요일수가 짧 았다. ‘Pinky Lang’의 절화장과 줄기굵기는 각각 104.5cm, 4.71mm으로 ‘Yes Luna’가 109.5cm, 4.25mm인 것에 비 해 5cm정도 짧았고 줄기굵기는 0.46mm 더 굵었다. ‘Pinky Lang’의 꽃 크기는 5.6cm이고 ‘Yes Luna’는 6.8cm로 1.2cm 작았다. ‘Pinky Lang’의 한 줄기에 달리는 꽃의 수와 한 송이 당 꽃잎수는 각각 27.7개, 30.9매였고, ‘Yes Luna’ 는 각각 18.0개, 37.0매인 것으로 착화수는 9.7개 많았고 꽃 잎수는 6.1매 적었다. 여름철 재배테스트를 통해 확인해본 결 과 흰녹병 저항성이 높은 경향을 확인하지만, 1~10% 정도의 병반을 보여 완전저항성을 가지진 못하는 것으로 사료된다. 자연개화 작형에서 절화수명의 경우는 24.5일로 ‘Yes Luna’ 에 비해 2.1일 길었다. ‘Pinky Lang’은 과습한 경우 줄기가 연약해질 수 있기 때문에 생장억제제인 Daminozide를 처리 하여 줄기를 강건하게 하고 절화 품질의 균일도를 높여 고온 기 재배에 안정적인 생산이 가능하여 수출할 수 있다.

In this study, we examined the effect of orifice diameter on atomization performance such as SMD(Sauter Mean Diameter), MMD(Mass median diameter), particle size distribution, spray distance, and spray angle when water was sprayed through a siphon nozzle. In addition, the behavior characteristics of spray were analyzed using the CFD(Computational Fluid Dynamics) commercial program. In the downstream direction of the flow, the dispersion and diffusion power of the droplets increased, greatly improving atomization performance. The spray spread in the radial direction when the jet velocity of water increased. As a result, atomization performance improved as the jet velocity increased.

Wide-area surface decontamination is essential during the sudden release of radioisotopes to the public, such as nuclear accidents or terrorist attacks. A spray coating composed of a reversible complex between poly (vinyl alcohol) (PVA) and phenylboronic acid-grafted poly (methyl vinyl ether-alt-mono-sodium maleate) (PBA–g–PMVE–SM) was developed to remove radioactive cesium from surfaces. The simultaneous spay of PVA and PBA–g–PMVE–SM aqueous polymer solutions containing Cs adsorbent to contaminated surfaces resulted in the spontaneous formation of a PBA–diol ester bond-based gel-like coating. The Cs adsorbent suspended in the gel-like coating selectively removed Cs-137 from the Cs-contaminated surface. The used gel-like coating were removed from surfaces by simple water rinsing. This recovery way has advantages compared with costly incineration to remove the organic materials for final disposal/storage of the radioactive waste. Thus, our spray coating is suitable for practical wide-area surface decontamination. In radioactive tests, the hydrogel containing Cs-adsorbent showed substantial Cs-137 removal efficiencies of 96.996% for painted cement and 63.404% for cement, which are 2.33 times better than the values for the commercial surface decontamination coating agent DeconGel.

본 연구에서는 Monopile 방식 풍력발전기 강구조물의 부식을 방지하기 위하여 S355 steel의 표면 거칠기에 따른 용사 코팅 상태에 관한 연구를 수행했다. 일차적으로는 시편별 서로 다른 표면거칠기를 부여하기 위해 밀링머신에 페이스 커터를 결합하여 시편별로 다른 조건의 Ra값 기준 표면거칠기를 부여했다. 실험 조건으로는 시편 가공 시 4가지의 회전속도(60, 400, 1200, 2000 rpm), feed rate 150(mm/min) 조건을 선정했다. 2차로는 와이어 용융 방식의 아크 용사 코팅을 실시했다. 코팅 조건으로는 분사 거리 200mm, 전압 24V, 전류 120A, 분사 압력 5bar, 와이어 삽입 속도 30g/mm, 와이어 직경 2mm이다. 용사 코팅 후 FE-SEM으로 표면을 관찰한 결과 모든 시편의 S355 면과 코팅층(아연-알루미늄) 사이에 유격이 발생하지 않고 성공적으로 안착이 되었음을 확인할 수 있었다.

3Y-TZP (3 mol% yttria-stabilized tetragonal zirconia polycrystals) ceramics have excellent mechanical properties including high fracture toughness, good abrasion resistance as well as chemical and biological stability. As a result, they are widely used in mechanical and medical components such as bearings, grinding balls, and hip implants. In addition, they provide excellent light transmittance, biocompatibility, and can match tooth color when used as a dental implant. Recently, given the materials’ resemblance to human teeth, these ceramics have emerged as an alternative to titanium implants. Since the introduction of CAD/CAM in the manufacture of ceramic implants, they’ve been increasingly used for prosthetic restoration where aesthetics and strength are required. In this study, to improve the surface roughness of zirconia implants, we modified the 3YTZP surface with a biocomposite of hydroxyapatite and forsterite using room temperature spray coating methods, and investigated the mixed effect of the two powders on the evolution of surface microstructure, i.e., coating thickness and roughness, and biological interaction during the in vitro test in SBF solution. We compared improvement in bioactivity by observing dissolution and re-precipitation on the specimen surface. From the results of in vitro testing in SBF solution, we confirmed improvement in the bioactivity of the 3Y-TZP substrate after surface modification with a biocomposite of hydroxyapatite and forsterite. Surface dissolution of the coating layer and the precipitation of new hydroxyapatite particles was observed on the modified surface, indicating the improvement in bioactivity of the zirconia substrate.

The purpose of this study was to examine whether galvanic corrosion of copper occurs by inserting a third barrier layer with a higher corrosion potential than copper between copper and cast iron when the copper layer is locally perforated by pitting or partial corrosion. A triple layer composed of copper, inserted metal, and carbon steel was manufactured by cold spray coating of inserting metal powders such as Ag, Ni, and Ti on carbon steel plate followed by Cu coating on it. First, the corrosion properties were evaluated electrochemically for each metal coating. As a result of Tafel plot anaylsis in KURT groundwater condition, the corrosion potential of Fe (-567 mV) was much lower than that of Cu (-91 mV), and the corrosion potential of Ni (-150 mV) was also lower than that of Cu. Therefore, Ni was likely to corrode before Cu. However, the corrosion current of Ni was lower than that of the Cu. In the galvanic specimen where the copper and inserting metal were exposed together, Cu-Fe was much lower corrosion potential of -446 mV, and the corrosion potential of Cu-Ti, Cu-Ni, and Cu-Ag were slightly higher than that of Cu. Therefore, it seemed that Ag, Ni, and Ti all might promote galvanic corrosion of surrounding copper when the copper layer was perforated to the inserted metal layer. If the metal insertion presented in this study operates properly, the disposal container does not need to worry about the partial corrosion or non-uniform corrosion of external copper layer.

Long-term safe storage of spent nuclear fuel (SNF) determines sustainability of the current light water reactor (LWR) fleet. In the U.S., SNF is stored in stainless steel canister in dry cask storage system (DCSS) after spending several years in wet pool storage system while there is no DSCC in Republic of Korea. The SNF storage time in DSCC is expected to be multiple decades since no permanent geological repositories are identified in both countries. One limiting factor for extended storage of SNF in DSCC is chloride-induced stress corrosion cracking (CISCC) in the welded regions of the stainless steel canisters. The propensity for the occurrence of CISCC has warranted the development of the mitigation and repair technologies to ensure the safe and long-term storage for both present and new canister although no CISCC failure was reported yet. This study investigates cold spray deposition coatings of 304 L and 316 L stainless steels on prototypical stainless steel canisters such as sensitized flat and C-ring samples. The cold spray technology has been identified as the most promising approach by Extended Storage Collaboration Program (ESCP) driven by Electric Power Research Institute (EPRI). The talk includes microstructural characterization, adhesion strength measurement, residual stress evaluation, and corrosion behavior of the coated materials in boiling MgCl2 solution and electrochemical corrosion tests in NaCl solution. In addition, the capability of repair of cracks on the canister surface using the coating technology will be presented.

With rising concerns about pesticide spray drift by aerial application, this study attempt to evaluate aerodynamic property and collection efficiency of spray drift according to the leaf area index (LAI) of crop for preventing undesirable pesticide contamination by the spray-drift tunnel experiment. The collection efficiency of the plant with ‘Low’ LAI was measured at 16.13% at a wind speed of 1 m·s-1. As the wind speed increased to 2 m·s-1, the collection efficiency of plant with the same LAI level increased 1.80 times higher to 29.06%. For the ‘Medium’ level LAI, the collection efficiency was 24.42% and 43.06% at wind speed of 1 m·s-1 and 2 m·s-1, respectively. For the ‘High’ level LAI, it also increased 1.24 times higher as the wind speed increased. The measured results indicated that the collection of spray droplets by leaves were increased with LAI and wind speed. This also implied that dense leaves would have more advantages for preventing the drift of airborne spray droplets. Aerodynamic properties also tended to increase as the LAI increased, and the regression analysis of quadric equation and power law equation showed high explanatory of 0.96－0.99.

The purpose of this study is to develop and evaluate amorphous spray-dried microparticles (SDM) containing levosulpiride to increase its solubility. SDM are prepared via solvent evaporation using polyvinylpyrrolidone (PVP) as the water-soluble polymer and Cremophor RH40 as the surfactant. The SDM is prepared by varying the amounts of PVP and Cremophor RH40, and its physicochemical properties, solubility, and dissolution are confirmed. All levosulpiride-loaded SDMs converted the crystalline drug into an amorphous form, significantly improving drug solubility and dissolution compared with the drug alone. SDM consisting of drug/PVP/Cremophor RH40 in a weight ratio of 5:10:3, with increased solubility (720 ± 36 vs. 1822 ± 51 μg/mL) and dissolution rate (10.3 ± 2.2 vs. 92.6 ± 6.0%) compared with drug alone, shows potential as a commercial drug for improved oral bioavailability of levosulpiride.