철근콘크리트는 가장 널리 사용되는 건축자재로 최근 노후 시설물이 증가하면서 노후 구조물에 대한 안전성 검토가 매우 중요한 문제로 대두되고 있다. 본 연구에서는 대표적인 열화 인자인 동결융해와 철근부식 그리고 동결융해와 철근부식의 복합적 열화에 따른 RC 휨 부재의 거동을 실험적으로 평가하였다. 4개의 철근콘크리트 휨 부재를 제작하였으며 각 열화 인자에 따른 RC 휨 부재의 거동을 평가하기 위해 4점 재하법을 이용하여 정적실험을 수행하였다. 동결융해는 총 300 사이클의 급속동 결융해실험을 수행하였으며, 부식은 전위차부식촉진실험을 수행하였다. 실험 결과, 동결융해로 인해 콘크리트의 압축강도가 12% 감소하였으며 RC 보 부재의 상부 압축부의 파쇄 범위가 증가하였고 최대강도가 6% 감소하였다. 철근부식으로 인해 RC 휨 부 재의 항복강도가 1.2%, 최대강도가 7% 감소하였으며, 복합열화로 인해 RC 휨 부재의 항복강도가 2.4%, 최대강도가 9% 감소하 였다.

먼지 필터 막은 인간의 건강, 안전 및 환경 보호의 몇 가지 중요한 측면에 기여하기 때문에 인간의 삶과 다양한 산업에서 중요한 역할을 한다. 이 연구는 고온 조건에 대한 우수한 열안정성과 접착 특성을 가진 polysulfone@polyphenylene sulfide/polytetrafluoroethylene (PSf@PPS/ePTFE) 복합 먼지 필터 막의 개발을 제시한다. FT-IR 분석은 PSF 접착제가 PPS 직 물에 성공적으로 함침되고 ePTFE 지지체와의 상호 작용을 확인한다. FE-SEM 이미지는 향상된 섬유 상호 연결 및 PSf 농도 와 함께 접착력을 보여준다. PSf@PPS/ePTFE-5는 가장 적합한 다공성 구조를 보여준다. 복합 막은 400°C까지 예외적인 열 안정성을 보여준다. 박리 저항 테스트는 먼지 여과에 대한 충분한 접착력을 보여 공기 투과성을 희생시키지 않고 힘든 고온 조건에서 신뢰할 수 있는 성능을 보장한다. 이 막은 산업 응용 분야에서 유망한 잠재력을 제공한다. 더 나아가 최적화 및 응 용 가능성을 탐구할 수 있다.

In this study, a new manufacturing process for a multilayer-clad electrical contact material is suggested. A thin and dense BCuP-5 (Cu-15Ag-5P filler metal) coating layer is fabricated on a Ag plate using a high-velocity oxygen-fuel (HVOF) process. Subsequently, the microstructure and bonding properties of the HVOF BCuP-5 coating layer are evaluated. The thickness of the HVOF BCuP-5 coating layer is determined as 34.8 μm, and the surface fluctuation is measured as approximately 3.2 μm. The microstructure of the coating layer is composed of Cu, Ag, and Cu-Ag-Cu3P ternary eutectic phases, similar to the initial BCuP-5 powder feedstock. The average hardness of the coating layer is 154.6 HV, which is confirmed to be higher than that of the conventional BCuP-5 alloy. The pull-off strength of the Ag/BCup-5 layer is determined as 21.6 MPa. Thus, the possibility of manufacturing a multilayer-clad electrical contact material using the HVOF process is also discussed.

국내 철근콘크리트 구조물은 겨울철 영하의 날씨로 매년 동결융해가 반복된다. 동결융해의 영향으로 철근콘크리트 구조물에 여러 가지 문제가 발생한다. 동결융해에 의해 손상이 된 철근콘크리트 구조물을 보강하기 위하여 다양한 보강공법 중 CFRRP(탄소섬유강화플라스틱)보강공법을 사용하였다. CFRP는 고강도, 고탄성 경량 소재로 시공성이 우수하며 인장강도, 탄성계 수가 뛰어나다. 본 연구에서는 동결융해 환경에 노출된 철근콘크리트 보(FTB), CFRP 플레이트로 보강한 철근콘크리트 보(FPB), CFRP 플레이트로 보강한 후 동결융해 환경에 노출된 철근콘크리트 보(FFP)의 휨 성능 실험을 하였다. 실험결과 FTB는 최대강 도 도달 이후 강도가 급격하게 감소하였다. FPB는 최대강도 도달하기 전에 강도와 강성이 증가하지만 CFRP 플레이트의 조기 파괴 후에는 효과가 없음을 보여준다. 또한 FFP는 FPB보다 최대강도가 낮았다. 이는 동결융해에 의한 콘크리트 표면과 CFRP 플레이트 사이의 계면전단응력의 감소로 판단된다.

Conductive carbon cloths (CCs) have been great attention as a promising current collector for flexible supercapacitors that supply power to portable and wearable electronics. However, the hydrophobic surface and weak adhesion with active materials has limited to be adopted as the binder-free and flexible electrode with mechanical/electrochemical stability. In this work, we demonstrate preparation of binder-free and flexible electrodes based on polyaniline (PANI) on carbon cloth. Polydopamine (PDA) layer are used to impart hydrophilicity, leading to uniform growth of PANI on the hydrophobic surface of carbon. Furthermore, PDA layer improves adhesion strength between PANI and carbon substrates, which allows for superior mechanical stability under ultrasonic condition. PANI-based flexible electrode shows high areal capacitance (160.8 mF cm− 2 at 0.5 mA cm− 2), good rate capability (71.1% even at high current density of 10 mA cm− 2), and long-term cycling stability (82.6% capacitance retention after 1500 cycles). Furthermore, a quasi-solid-state flexible supercapacitor reveals remarkable mechanical flexibility and durability, with superior capacitance retention (~ 100%) in bent state and after repetitive 1000 cycles.

This in vitro study investigated the enhancement of rumen bacterial adhesion on a substrate to increase the digestibility of rice straw in Hanwoo cattle. The rice straw was pretreated with enzymes, probiotics, or ammonia, and the effects on the enhancement of bacterial adhesion and fiber degradation were analyzed using in vitro rumen fermentation. Enzyme treatment included spraying of cellulase and xylanase at 40 and 120 U per g of rice straw, respectively; Saccharomyces cerevisiae culture of 1.0×107 CFU was sprayed as a probiotic treatment per gram of rice straw; ammonia was sprayed at 0.3% per gram of rice straw. Following enzyme treatment, Fibrobacter succinogenes formed a higher adhesion colony than the control group (7.26±0.03 and 8.43±0.20) after 6h and 12h of in vitro culture (p<0.05), respectively. Attachment of Ruminococcus flavefaciens also increased following enzyme treatment (p<0.05) after 6 and 12 h compared to that of the control (5.18±0.06 and 6.60±0.15); and R. albus attachment showed a significant increase compared to that of the control (5.94±0.15) after 6 h of incubation (p<0.05). Probiotic treatment increased attachment of F. succinogenes in comparison with untreated rice straw after 6 h and 12 h of fermentation (p<0.05); R. flavefaciens attachment showed an increase only after 6 h of culture (p<0.05); R. albus was not affected. Attachment of F. succinogenes, R. flavefaciens, and R. albus increased with ammonia treatment after 6 h and 12 h (p<0.05). Dry matter digestibility was higher after the enzyme treatment (3.45±0.21 and 7.04±0.09) than in the control group(1.85±0.08 and 3.94±0.04) after 6 and 12 h of in vitro culture (p<0.05), respectively. It was also higher than that of untreated rice straw after probiotic and ammonia treatments (p<0.05). There was an increase in the enhancement levels of bacterial adhesion depending on the type of fibrolytic bacteria following enzyme, probiotic, and ammonia treatment. These treatments improved digestibility. This enhancement is considered to be greater following enzyme and ammonia treatments than with probiotics.

박리강도와 내수성이 향상된 친환경적인 수성 점착제 제조를 위해 Tg가 상온에 가깝도록 아크릴 모노머인 methyl methacrylate(MMA), butyl acrylate(BA), methacrylic acid(MAA)의 비율을 조절하고 ammonium persulfate를 개시제로 이용하여 아크릴 공중합체(Acrylic copolymer)를 유화 중합하여 아크릴 에멀젼 점착제를 제조하고 평가하였다. MMA:BA:MAA를 55.2:43.5:1.3의 mole 비율로 합성한 결과, GPC와 입도분석으로 아크릴 공중합체 에멀젼이 합성된 것을 확인하였으며 휘발성 유기물(VOCs)도 검출되지 않았다. 이론적 Tg는 18.1℃이며, 피착재로써 폴리우레탄 폼, 폴리프로필렌 폼, 폴리프로필렌을 적용하여 초기, 최종, 침수 후 접착력을 평가한 결과 박리강도가 기존 제품에 비해 향상되었음을 확인하였다.

PURPOSES : The adhesive bonding strength of the grid between asphalt pavements is critical in pavement performance. The study is to compare and evaluate the interlayered bonding strength of asphalt mixture specimens with fiber-glass grid (FG) reinforcement and different tack coating materials based on the test results of the shear bonding test. METHODS : Asphalt mixtures were molded with FG reinforcement using various tack coating materials namely RSC4 and D/B coat. The adhesive shear-bond strength was measured by inducing a monotonic shear loadnig rate of 5 mm/min at 20℃. RESULTS : As expected, the asphalt mixture with non-reinforced FG exhibited the highest adhesive shear-bond strength, followed by that of the FG with D/B coating. The ranking order of superiority is as follows: Control (RSC4) > D/B+FG > RSC4+FG. CONCLUSIONS : The results of this experimental study indicate that FG with RSC4 and D/B tack coats can be successfully used in asphalt concrete overlay construction with superior field performance. Based on the test results and literature review, the field bonding strength should exceed 300kPa in grid reinforced asphalt pavement.

본 연구에서는 CFRP 복합재료 플레이트로 외부 보강된 철근콘크리트 보 구조물의 장기 거동 특성과 CFRP 복합재료 플레이트의 부착거동을 실험을 통하여 검토하였다. 장기 사용성을 고려하기 위하여 동결융해 시험법을 사용하였으며 4절점 휨 실험을 통하여 평가하였다. CFRP 복합재료 플레이트로 보강 후 동결융해를 진행한 시험체(FFCB)와 동결융해 후 CFRP 복합재료 플레이트로 보강한 시험체(LFCB)의 4절점 휨 실험 결과를 비교 분석하였다. LFCB 시험체가 FFCB 시험체 보다 조기에 CFRP 복합재료 플레이트의 박리가 발생하였으며, 파괴형태가 다르게 발생하였다. FFCB의 경우 콘크리트 커버가 탈락되었으며, LFCB의 경우 콘크리트의 표면의 탈락이 발생하였다. 동결융해의 영향을 받은 콘크리트 재료의 성질이 약화된 결과로 판단된다. 동결융해 실험을 통하여 콘크리트 공시체의 압축강도가 약 19% 감소하였으며. 이에 따라 콘크리트 커버부의 인장강도도 감소한 것으로 판단된다. 콘크리트 구조물에 대한 보강의 경우사용기간 및 환경변수 등을 고려하여, 콘크리트 보강표면에 대한 정확한 상태평가가 필요할 것으로 판단된다.

Selectins are cell membrane glycoproteins that recognize specific glycoconjugates expressed on the surface of cells. Then, selectins adjust cell-cell interactions that are important in inflammation, hemostasis and cancer metastasis. Selectins mediate leukocyte calls to move into the site of inflammation through interactions with activated endothelial cells or endogenous selectin ligands expressed in high endothelial venules. Types of selectins are divided into L-selectin, E-selectin and P-selectin, which are called to CD62L, CD62E, and CD62P, respectively. Each selectin is composed of four regions; the C-type lectin region of N-terminal, the epidermal growth factor (EGF) region, the intracellular C-terminal region, and the hydrophobic transmembrane region. They have similar structures but differ in their binding specificities and tissue distributions. The selectin family commonly recognizes the sialyl Lewis X (sLeX) on carbohydrate structures. Although biological ligands bound to each selectin are different from each other, they commonly bind to P-selectin glycoprotein ligand-1 (PSGL-1) ligand. The PSGL-1 ligand is a glycoprotein promoting cell adhesion in inflammatory responses. If the absence of selectins and their ligands in humans and animals are, should lead to persistent infections and diseases. Selectin family must be considered as a key subject for drug discovery since they have various functions depending on the ligand which they bind to.

A coal dust scattered from storage and transfer facilities of coal power plant is led to a air pollution. It is difficult to reduce some scattered coal dust by used filter system such as bag filter and electric precipitator because of being scattered in the large area. The need to cut down coal dust generation has been increased as being reinforced regulation to reduce dust from coal power plant. So this is a experimental basic study which reduces coal dust generation. This study is to reduce scattering rate of the coal dust by collision and interception between fine fog droplet and coal dust particles. The reducing rate of coal dust is evaluated by droplet size of 10㎛ sprayed. It is evaluated that capture efficiency is lower as a coal dust concentration become higher. And also it is increase as droplet size is decrase and droplet density is increase. It is resulted that coal dust coefficient to optimize the fog system design is 25μg/m3/l/hr and capture efficiency of coal dust is about 80%.

A two-level full factorial design 22 with three replications was employed to assess the effect of the incorporation of PSF into the epoxy matrix and the surface treatment of carbon fibers on the work of adhesion (WA) and the interfacial shear strength (IFSS) of carbon fiber–epoxy composites. The IFSS was determined using the microbond (or microdrop) micromechanical test, and the work of adhesion was estimated using two different procedures: (1) using the Owens and Wendt method, and (2) from the Dupre–Young expression using the contact angle θ of a cured epoxy resin on a single carbon fiber and the surface energy of the cured epoxy resin. It was found that the treatment of the carbon fiber with the silane-coupling agent appreciably increases its polar component because of the nitric acid oxidation and the chemisorption of the silane-coupling agent onto the carbon fiber surface. Also, the O=S=O group present in the polysulfone chain resin fairly increases the polar component of the epoxy–PSF blend. The results show that the wetting of the silane-treated carbon fiber by the thermoplastic-modified epoxy resin is better, thus increasing the fiber–matrix adhesion. It was also found that there is a similarity between the trends of both, the IFSS and the WA results. Also, from the ANOVA results it was also seen that both the incorporation of the PSF to the epoxy matrix and the surface treatment of the carbon fibers and their interaction were statistically significant to the IFSS and the WA.

Ice accumulation on Aluminum Conductor Steel Reinforced(ACSR) cable during winter is an important matter in terms of safety, economy, and efficient power supply. In this work, the ice adhesion strengths of ACSR cable oxidized during different periods(7 years oxidized and 15 years oxidized) are evaluated. At first, a plate type dry oxidation standard specimen, whose surface characteristics are similar to those of ACSR cable, is prepared. Dry oxidation standard specimens are heat-treated at 500 °C for 20, 60, and 120 minutes in order to obtain different degrees of oxidation. After the dry oxidation, surface properties are analyzed using contact angle analyzer, atomic force microscopy, spectrophotometer, and gloss meter. The ice adhesion strengths are measured using an ice pull-off tester. Correlations between the surface properties and the ice adhesion strength are obtained through a regression analysis indicating a Boltzmann equation. It is revealed that the ice adhesion strength of 15- year oxidized ACSR cable is approximately 8 times higher than that of ACSR-bare.

In the aerospace field, Carbon/Cork composites have been used for rocket propulsion systems as a light weight structural component with a high bending stiffness and high thermal insulation properties. For the fabrication of a carbon composite with a heat insulation cork part, the bonding properties between them are very important to determine the service life of the Carbon/Cork composite structure. In this study, the changes in the interfacial adhesion and mechanical properties of Carbon/Cork composites under accelerated aging conditions were investigated. The accelerated aging experiments were performed with different temperatures and humidity conditions. The properties of the aged Carbon/Cork composites were evaluated mainly with the interfacial strength. Finally, the lifetime prediction of the Carbon/Cork composites was performed with the long-term property data under accelerated conditions.

With the recent remarkable improvements in the average speeds of contemporary trains, a necessity has arisen for the development of new friction modifiers to improve adhesion characteristics at the wheel-rail interface. The friction modifier must be designed to reduce slippage or sliding of the trains’ wheels on the rails under conditions of rapid acceleration or braking without excessive rolling contact wear. In this study, a novel composite material consisting of metal, ceramic, and polymer is proposed as a friction modifier to improve adhesion between wheels and rails. A blend of Al-6Cu-0.5Mg metallic powder, Al2O3 ceramic powder, and Bakelite-based polymer in various weight-fractions is hot-pressed at 150oC to form a bulk composite material. Variation in the adhesion coefficient is evaluated using a high-speed wheel-rail friction tester, with and without application of the composite friction modifier, under both dry and wet conditions. The effect of varying the weighting fractions of metal and ceramic friction powders is detailed in the paper.