As an approach for estimation of the droplet size in the molten salt-liquid metal extraction process, a droplet formation experiment at room temperature was conducted to evaluate the applicability of the Scheele-Meister model with water-mercury system as a surrogate that is similar to the molten salt-liquid metal system. In the experiment, droplets were formed through the nozzle and the droplet size was measured using a digital camera and image analysis software. As nozzles, commercially available needles with inner diameters (ID) of 0.018 cm and 0.025 cm and self-fabricated nozzles with 3-holes (ID: 0.0135 cm), 4-holes (ID: 0.0135 cm), and 2-holes (ID: 0.0148 cm) were used. The mercury penetration lengths in the nozzles were 1.3 cm for the needles and 0.5 cm for the self-fabricated nozzles. The droplets formed from each nozzle maintained stable spherical shape up to 20 cm below the nozzle. The droplet size measurements were within a 10% error range when compared to the Scheele-Meister model estimates. The experimental results show th

The volume of fluid method is used to investigate the behavior of a liquid water slug in a PEMFC trapezoidal gas channel(GC) with a open angle of 60 degrees. To evaluate the effect of the contact angle of the top and side walls, the gas diffusion layer water coverage ratio(GWCR) and water volume fraction(WVF) in a inspection control volume are analyzed. As the contact angle increases, GWCR increases and WVF decreases. The cases with the GC contact angle of 60 and 80 degrees show the more favorable water removal characteristics compared to the other cases in a GC flooding condition.

In a PEMFC gas channel with a trapezoidal cross-section, the effect of air and water inlet velocities on water removal characteristics is numerically studied via the volume of fluid(VOF) method. When the channel wall contact angle is 60 degrees, the air inlet velocities higher than 2.5 m/s are advantageous to obtain lower GDL surface water coverage ratio(WCR). The WCR increases as the wall contact angle increases to 90 or 120 degrees due to the relatively lower surface tension force. In overall, WCR decreases as the air inlet velocity increases and WCR increases as the water inlet velocity increases.

The water removal characteristics in a PEMFC trapezoidal gas channel are investigated with the volume of fluid (VOF) method. For the case of wall contact angle of 60 degree, liquid water attaches on the top wall and moves toward the exit. In contrast, liquid water moves along the channel side corner or GDL surface irregularly for the higher wall contact angles. The hydrophillic wall contact angle of 60 degrees provides more favorable diffusion of reactants to cathode reaction sites as the GDL surface water coverage ratio approaches zero even if the water flow rate increases.

The effect of PEMFC trapezoidal channel wall contact angle on water removal characteristics is investigated with the volume of fluid (VOF) method. Two different contact angles 60 and 90 degrees are selected. In the case of the side and top wall contact angle of 60 degrees, stable semi-spherical droplets move along the top wall slowly. In contrast, complex shaped droplets move along the lower edge in the case of 90 degrees. Moreover, it is shown that very complex interaction patterns between different droplets which introduced into the channel at different times.

본 연구에서는 건축폐기물로 분류되는 레미콘회수수를 재활용함과 동시에 지구온난화의 주범 인 CO2의 자원화를 위한 시스템의 공정최적화를 진행하였다. 레미콘회수수를 이용한 액상탄산화 반응에 서 가장 중요한 공정은 Ca2+를 용출하는 공정이다. 일정량의 레미콘회수수를 이용해 고순도의 CaCO3을 생성하기 위해 Ca2+ 용출시 질산에 의해 낮아지는 pH 농도를 기준으로 실험을 진행하였으며, CO2는 발전기 배기가스를 이용해 MEA용액에 포집하였다. 본 연구를 통해 1톤의 레미콘회수수에서 최대 11 kg의 CaCO3를 합성할 수 있었다. 생성된 CaCO3 분석결과 제지용으로 사용 가능한 것을 확인하였다.

The Saemangeum watershed is required to manage water pollution effectively but the effect of liquid manure (LM) on soil and water quality in the basin is not clearly identified as yet. This study aims at assessing the effect on soil of a rice field and water quality of water bodies near the rice field during rice-crop time period to find out the effect of LM, the effect of rainfall, and the effect of rice-crop environment on soil and water quality by analyzing data of nitrogen components. As a result of the LM distribution, NO3-N was much higher than other N components in the entire soil layers and it was accelerated by rainfall right after the LM distribution. Compared to chemical fertilizer (CF), LM was slightly affected but still influenced on the surface water quality. During weak rainfall, low nitrogen concentration in topsoil was resulted as NH3-N decreased and Org-N and NO3-N increased. NO3-N concentration in the water of irrigation canals increased with time. During intensive rainfall, NO3-N and Org-N of the soil were measured highly in the submerged condition, while the water quality of the rice field was lower due to flooding into the irrigation canal as well as the growth of the rice plants. Also, total nitrogen was increased more than 7 times and it showed serious water quality deterioration due to LM and excessive fertilizer distribution, and rainfall during all rice-crop processes. The effect of LM on water quality should be studied consistently to provide critical data while considering weather condition, cropping conditions, soil characteristics, and so on.

A simple method for generating pores in a cellulose acetate (CA) polymer matrix was developed using a combination of an ionic liquid and water pressure treatment. A porous CA membrane was successfully prepared using the ionic liquid (BMIM-BF4) and subsequent water pressure treatment. Pores were generated in the CA polymer matrix when the CA/ionic liquid composite was subjected to water pressure. The characteristics of the thus-generated porous membrane were evaluated using porosimetry. FT-IR and Thermogravimetric analysis (TGA) showed that when the CA polymer was subjected to water pressure, most of the BMIM-BF4 incorporated in the polymer during its preparation was removed, thereby generating the observed pores. In addition, it was observed that the flux varied with water pressure, indicating that the pore size was controllable.

침지식 분리막 모듈에서 공기강도에 따른 분리막 위치에 대한 오염을 조사하였다. 분리막의 충진밀도가 낮은 곳에서 높은 유체 유속을 나타내었으며, 유체 속도는 기-액 주입률에 비례하였다. 전단응력은 기-액 주입률 및 유체 유속에 비례하였다. 비가역오염(Rir)은 흡입 압력이 가까운 부분에서 가장 높게 나타났다(position 1). 비가역오염에 대한 저항과 분리막 고유 저항의 비(Rir/Rm) 및 비가역오염에 대한 저항과 가역오염의 저항의 비(Rir/Rr)도 position 1에서 가장 높게 조사되었다. 비가역오염(Rir)은 흡입 압력이 높은 곳인 position 1에 오염물질이 축적되어진 결과이다. 분리막 위치에 따른 오염현상은 모듈 디자인 최적화에 중요한 인자임을 알았다.

In this study, a liquid carbonation method was applied for producing precipitate calcium carbonate by liquid-liquid reaction. We recycled the recycling water of ready-mixed concrete, one of construction waste for use source of carbonate ion. A supernatant separated from the recycling water of ready-mixed concrete, as a result of ICP analysis of a cation, Ca²+ was contained up to 1100 ppm. We used MEA as a CO₂ absorbent for the liquid carbonation. A precipitate CaCO₃ was produced at more than MEA 20 wt%. The precipitate CaCO₃ as a final product was separated and dried. The result of XRD was confirmed the generation of CaCO₃ to calcite structure.

돈분뇨 액비 시용 후 경운처리에 의한 청보리, 호밀, 트리티케일, IRG의 생육과 잡초발생량 차이를 구명하였다. 파종기에 한발이 지속된 포장의 수분함량을 조사한 결과 화학비료 처리구와 무처리구에서는 8.5 ~ 9.1%를 나타냈으나, 액비를 살포한 포장은 20.5 ~ 23.1% 수준이었다. 파종 15일 후에 유묘출현율은 액비 처리구에서는 화학비료 및 무처리구에 비하여 청보리는 2.9배, 호밀과 트리티케일은 각각 2.2배, 2.4배 높게 나타났다. 또한 시험작물 모두 초장이 액비시용구에서 약 2배 이상 증가하였다. 월동 후 최고분얼기에는 모든 작물의 초장이 화학비료 및 무처리구에 비하여 액비처리구가 1.1 ~ 1.3배 길었고 경수도 비슷한 경향을 보였으며, 분얼수는 청보리, 호밀 및 트리티케일이 각각 4.5개, 5개 및 6개/개체로 화학처리구에 비해서 1개체씩의 증가를 보여 한발에 의한 초기 생육차이가 월동 후에도 지속되는 것으로 확인되었다. 한편 잡초발생은 답리작포장이기 때문에 뚝새풀이 주로 발견되었으며, 액비 처리구는 경운으로 m2당 잡초발생수가 5개 수준이었으나, 화학비료 처리구는 무경운으로 145개 발생되어 29배의 잡초발생 차이를 보였다. 월동 후 액비시용하고 경운을 하면 비료효과가 지속되어 화학비료 처리구보다 우수한 생육을 보였으나, 액비시용 후 무경운 처리는 낮은 생육을 보였다. 수확기 생체중 역시 액비처리후 경운처리구가 가장 높았으며, 청보리, 호밀, 트리티케일, IRG 모두 증수되었다. 따라서 한발이 지속될 경우 액비살포 후 경운은 작물의 영양원으로 뿐만 아니라, 수분공급의 효과로 종자의 발아를 촉진시켜 초기생장 및 수량증수에 크게 기여하며 부수적으로 잡초발생도 감소시키는 것으로 판단된다.

가강수량과 구름물량의 시공간적 분포와 특성을 분석하기 위해 청주, 합천, 대관령에서 마이크로웨이브 라디오미터의 관측을 수행하였다. 각 지역에서 관측된 가강수량을 검증하기 위해 고층자료에서 산출된 가강수량과 비교하였으며 그 결과 상관계수가 0.8 이상으로 좋은 상관도를 보인다. 청주, 합천, 대관령 지역의 가강수량의 계절적인 변동과 일변화는 유사하게 나타났으며 일반적으로 1000 LST부터 증가하기 시작하여 1900 LST에 극대 값을 보인다. 반면에 구름물량은 지역적으로 계절적인 차이를 보인다. 이는 평지에 위치한 청주, 소백산맥으로 인한 편서풍 구름 차폐가 발생하기 쉬운 합천, 안개 및 구름이 잦은 대관령(834 m 해발고도) 등 각기 다른 지형 및 지리적 영향에 기인한 것으로 사료된다.

저 농도와 고 농도 돈분 액비의 비료효과를 비교하기 위해 제주대학교 목장에서 2005년 6월부터 9월까지 피의 생산성, 피 재배 토양의 화학적 특성 및 용탈수 특성을 조사하였다. 실험은 난괴법 4처리 (무비구, 200 N kg/ha +150Pkg/ha+150 K kg/ha 화학비료구, 200 N kg/ha 1.8% DM 저농도 돈액비구, 200 N kg/ha DM 7.0% 고농도 돈액비구) 4반복으로 실시하였다. 용탈수는 2005년 8월 21일(1차),

This paper was examined water resistant performance of cementitious composites applying inorganic liquid type core material as part of a basic study for development of inorganic liquid type self-healing capsule. Results of assessment, inorganic liquid type core material have shown that with a water resistance performance.

The analytical method for 16 organophosphorus pesticides was developed in this study. The 16 organophosphorus pesticides were analyzed by liquid chromatography-tandem mass spectrometry (LC/MS/MS) using on-line solid phase extraction (on-line SPE) with PLRP- S cartridge. Analysis of all analytes in the MS/MS was processed in the electrospray ioni-zation (ESI) positive mode. They are Azinphos ethyl, Chlorfenvinphos, Ethion, Famphur, Phosmet, Phosphamidon, Terbufos, Aspon, Chlorpyrifos-methyl, Crotoxyphos, Dichlofenthi-on, Dicrotophos, Fonofos, Thionazin, Dimethoate and Iprobenfos. Limits of detection (LODs) and Limits of quantification(LOQs) were obtained as 0.8~2.0 ng/L and 2.6~6.4 ng/L, respectively. All compounds were not detected at the 8 sampling points of the raw water and clean water.

Recently, it is increase in the processing of organic waste using anaerobic digestion. Therefore, the studies on theprocessing method for increasing the anaerobic digestion waste water. Among them, purification treatment and liquidfertilizer have been issues. But, efficiency of the ways is very insufficient. While increasing the anaerobic digestionprocess, increasing study for the treatment of anaerobic digestion waste water. In this study, It was evaluate thecharacteristic of liquid fertilizer of anaerobic digestion waste water as affected by aeration rate and solid-liquid separation.Also, we review liquid fertilizer degree using maturity assessment indicators of liquid fertilizer by national institute ofanimal science. As a result, insertion of air(3.5L/min) sample after solid-liquid separation appeared was the highest. pHand color was difficult to understanding correlation with liquid fertilizer among maturity assessment indicators(seedgermination, ammonia(NH3), hydrogen sulfide(H2S), electrical conductivity(EC), pH, color, etc).

물/Span 80-Tween 80/긴 사슬 파라핀 오일 계에서 PIC (조성 상전이) 방법을 이용하여 O/W 나노에멀젼을 제조하였다. 제조 온도를 30 ℃에서 80 ℃로 상승시킴에 따라 제조된 나노에멀젼의 입경은 120 nm에서 40 nm로 감소하여 나노에멀젼을 형성하였다. 혼합 계면활성제의 HLB를 변화시킴에 따라 12.0 ~ 13.0 부근에서 가장 작은 입경을 형성하는 최적 HLB가 존재하였다. 나노에멀젼의 점도는 액적의 부피 분율(ϕ)에 따라 현격하게 증가하였으나, 입경의 크기는 약간 증가하였다. 그리고, ϕ ≤ 0.3 조건에서 나노에멀젼의 크기 분포는 2 개월 이상 일정하게 유지 되었다. 이러한 결과는 점성 파라핀 오일의 경우 30 ℃에서는 PIC 방식으로 거의 분산 할 수 없음을 보여주지만, 제조 온도가 증가할 경우 단 분산 나노에멀젼의 제조가 가능하다는 것을 보여준다. 나노에멀젼이 생성되면, Ostwald ripening에 대한 안정성은 연속 상에서 액상 파라핀 오일의 매우 낮은 용해도로 인해 안정하게 되며, 이는 화장품 응용에서 매우 중요하다.