The high-level radioactive waste repository must ensure its performance for a long period of time enough to sufficiently reduce the potential risk of the waste, and for this purpose, multibarrier systems consisting of engineered and natural barrier systems are applied. If waste nuclides leak, the dominating mechanisms facilitating their movement toward human habitats include advection, dispersion and diffusion along groundwater flows. Therefore, it is of great importance to accurately assess the hydrogeological and geochemical characteristics of the host rock because it acts as a flow medium. Normally, borehole investigations were used to evaluate the characteristics and the use of multi-packer system is more efficient and economical compared to standpipes, as it divides a single borehole into multiple sections by installing multiple packers. For effective analyses and groundwater sampling, the entire system is designed by preselecting sections where groundwater flow is clearly remarkable. The selection is based on the analyses of various borehole and rock core logging data. Generally, sections with a high frequency of joints and evident water flow are chosen. Analyzing the logging data, which can be considered continuous, gives several local points where the results exhibit significant local changes. These clear deviations can be considered outliers within the data set, and machine learning algorithms have been frequently applied to classify them. The algorithms applied in this study include DBSCAN (density based spatial clustering of application with noise), OCSVM (one class support vector method), KNN (K nearest neighbor), and isolation forest, of which are widely used in many applications. This paper aims to evaluate the applicability of the aforementioned four algorithms to the design of multi-packer system. The data used for this evaluation were obtained from DB-2 borehole logging data, which is a deep borehole locates near KURT.

The permanent disposal of discharged spent nuclear fuel (SNF) and contaminated radioactive waste generated from the subsequent chemical treatments of SNF has become a serious pending issue in many countries that operate the nuclear power plants. Among the diverse engineering solutions proposed for the disposal of high-level radioactive waste (HLW), deep geological disposal (DGD) has been considered as the most proven and safe option to prevent any significant release of radionuclides into the biosphere and to predictably ensure the long-term performance of disposal system. The DGD system consists of multiple structural components; the bentonite clay-based buffer and tunnel backfills are designed to perform the primary hydrogeochemical functions of 1) inhibiting the ingress of groundwater and reactive substances that could compromise the integrity of canister and 2) retarding the migration of released radionuclides into biosphere by providing the sufficient chemisorption sites. Montmorillonite, which is a 2:1 phyllosilicate mineral belonging to smectite group, constitutes the majority of bentonite, and it mainly predominate the swelling and chemisorption capacities of the clay material. Thus, it is essentially required to thoroughly understand the chemical interactions of major radionuclides and other important substances with montmorillonite in advance to accurately evaluate the long-term retention performance of engineered barriers and to reduce the uncertainties in the safety assessment of a deep geological repository (DGR) ultimately. Thus far, sorption of dissolved species onto mineral adsorbents has been generally described and quantified using the simple sorption-desorption distribution coefficient (Kd) concept; since any specific reaction mechanisms are not considered and reflected in the Kd concept, an empirical Kd value is intrinsically dependent on the aqueous conditions under which it was measured. In this framework, substantial scientific efforts have been made to develop a robust basis for geochemically parametrizing the sorption phenomena more reliably, and the application of thermodynamic sorption modeling (TSM), which is based on the chemical principle of mass action laws, has been studied with the aim of improving overall confidence in the description of radionuclide migration under a wide range of aquatic conditions. The disposal performance demonstration R&D division of KAERI introduced a new reference Ca-bentonite clay called Bentonil-WRK (Clariant Korea) for HLW disposal research in 2021 as the domestic Ca-bentonite sources have being depleted. We successfully separated and purified Ca-montmorillonite from the Bentonil-WRK clay, and its geochemical characteristics were meticulously studied by means of XRD, BET, CEC, FT-IR analyses and controlled acid-base titration. In this work, chemical sorption behaviors of aqueous iodide and benzoate, which are a major fission product in HLW and a model ligand of complex natural organic matters present in the deep geological environment, onto the purified Camontmorillonite were assessed under ambient conditions of S/L = 5 g/L, I = 0.01 M CaCl2, pH = 4- 9, pCO2 = 10-3.4 atm, and T = 25°C. Further, their unique adsorption envelopes and corresponding thermodynamic reaction constants refined from the diffuse double layer model (DDLM)-based inverse modeling of experimental sorption data were discussed.

The WRK (Waste Repository Korea bentonite) compacted bentonite medium has been considered as the appropriate buffer material in the Korean SNF (Spent nuclear fuel) repository site. In this study, hydraulic properties of the WRK compacted bentonite core (4.5 cm in diameter and 1.0 cm in length) as the buffer material were investigated in laboratory experiments. The porosity and the entry pressure of the water saturated core at different confining pressure conditions were measured. The average velocity of water flow in the WRK compacted bentonite core was calculated from results of the breakthrough curves of the CsI aqueous solution and the hydraulic conductivity of the core was also calculated from the continuous flow core experiments. Because various gases could be generated by continuous SNF fission, container corrosion and biochemical reactions in the repository site, the gas migration property in the WRK compacted bentonite core was also investigated in experiments. The gas permeability and the average of gas (H2) in the core at different water saturation conditions were measured. Laboratory experiments with the WRK Compacted bentonite core were performed under conditions simulating the DGR environment (confining pressure: 1.5- 20.0 MPa, injection pressure: 1.0-5.0 MPa, water saturation: 0-100%). The WRK Compacted bentonite core was saturated at various confining pressure conditions and the porosity ranged from 27.5% to 43.75% (average: 36.75%). The calculated hydraulic conductivity (K) of the core using experimental results was 8.69×10-11 cm/s. The gas permeability of the core when the water saturation 0~58 % was ranged of 19.81~3.43×10-16 m2, representing that the gas migration in the buffer depends directly on the water saturation degree of the buffer medium. The average gas velocity in the core at 58% of water saturation was 9.8×10-6 m/s, suggesting that the gas could migrate fast through the buffer medium in the SNF repository site. Identification of the hydraulic property for the buffer medium, acquired through these experimental measurements is very rare and is considered to have high academic values. Experimental results from this study were used as input parameter values for the numerical modeling to simulate the long-term gas migration in the buffer zone and to evaluate the feasibility of the buffer material, controlling the radionuclide-gas migration in the SNF repository site.

In KAERI, the nuclide management technology is currently being developed for the reduction of disposal area required for spent fuel management. Among the all fission products of interest, Cs, I, Kr, Tc are considered to be significantly removed by following mid-temperature and hightemperature treatment, however, a difficulty of real spent-fuel thermal treatment experiment limits the development of such thermal treatment. The test employing SimFuel (Simulated Spent Fuel) can be an alternative for such condition, however, the fabrication of SimFuel containing semivolatile species such as Cs, I and Re (substitute for Tc) was not achieved for conventional sintering method since such species are easily removed during hot temperature treatment. In this study, for the prevention of volatilization of such species and the inclusion of semi-volatile species in fabrication of SimFuel, argon-based high pressurizing up to Max 100 bar was considered to be applied in high temperature treatment. For this, lab-scale hot-isostatic press applicable up to 1,500°C was fabricated and is being waiting for the approval for high-pressure test. After approval of license, UO2 baesd SimFuel containing CsI will be fabricated and its micro-structure and composition will be evaluated through SEM-EDX and XRD

The PRIDE scale mechanical decladder is decladding apparatus for separating and recovering fuel material and cladding hull by horizontally slitting rod-cut. In order to enhance mechanical decladdng efficiency, the main requirements were considered as follows. Decladding of the fuel rods may be performed by rotation of three circular cutting blades inserted among the rollers arranged at 120° portion. In a mechanical decladder, a slitting assembly as a unit for slitting the cladding tube may include cutting blades for slitting and rollers for guiding extrusion of the cladding tube. Rotation of the cutting blades may be caused by the fuel rods being extruded from a plurality of rollers. Slitting intervals of rod-cuts having different diameters may be controlled by adding or removing a spacing plate between the cutting blade and a ranch bolt for fixing the slitting blade to the slitting assembly. An extrusion velocity with respect to the fuel rods may be controlled by a hydraulic pressure applied to the fuel rods. A force for cutting the fuel rods may be adjusted by controlling steel plates. Forces applied to a plurality of rollers may be generated by the hydraulic cylinder. The hydraulic pressure may be controlled by hydraulic pressure controller. The PRIDE scale mechanical decladder mainly consists of auto feeding module, hydraulic cylinder module and blade module. A load cell was installed between the hydraulic cylinder and the extrusion pin to measure the decladding force and slitting velocity, and a data acquisition system capable of obtaining data by using the RSC 232 was constructed. Also, the control panel can control the forward and backward movement of the extrusion pin, the hydraulic flow rate, and the hydraulic velocity. In the mechanical decladding test, 40 pieces of simulated rod-cuts were loaded in two auto feeding basket and slit by utilizing the 3-CUT blade modules in the housing, and hulls and simulated pellets were collected in the collection container. As a result, 80 pieces of simulated rodcut (brass pellets + Zry4 tube) were slit continuously without any problem. About 35 min was required to slit 80 rod-cuts and average decladding force was 260 kg. The decladding force of the ceramic simulated rod-cuts (castable) requires 25 kg less force than the brass pellets. Therefore, it is estimated that the spent fuel rod-cut can be fully split into three pieces using the mechanical decladder.

Dry storage of nuclear fuel is compromised by threats to the cladding integrity, such as creep and hydride reorientation. To predict these phenomena, spent fuel simulation codes have been developed. In spent fuel simulation, temperature information is the most influential factor for creep and hydride formation. Traditional fuel simulation codes required a user-defined temperature history input which is given by separate thermal analysis. Moreover, geometric changes in nuclear fuel, such as creep, can alter the cask’s internal subchannels, thereby changing the thermal analysis. This necessitates the development of a coupled thermal and nuclear fuel analysis code. In this study, we integrated the 2D FDM nuclear fuel code GIFT developed at SNU with COBRA -SFS. Using this, we analyzed spent nuclear stored in TN-24P dry storage cask over several decades and identified conditions posing threats due to phenomena like creep and hydrogen reorientation, represented by the burnup and peak cladding temperature at the start of dry storage. We also investigated the safety zone of spent nuclear fuel based on burnup and wet storage duration using decay heat.

For safe and economical spent fuel management, assessing the integrity of the cladding, which is the first barrier to the escape of radioactive material, is very important. For the sake of risk assessment, it is essential to calculate the probability of failure of the spent fuel rods loaded inside the cask during the transportation or storage. However, due to the large amounts of calculations required, it is not practical to analyze every detail of the spent fuel rods and assemblies. This study presents a methodology to perform a cask-level analysis by sequentially simplifying the fuel rods and spent fuel assemblies for the calculation of fuel rod failure probability. A simplified single fuel rod model was generated by considering the material properties of a high burnup fuel rod stored in dry storage for approximately 5 years and the interfacial bonding conditions of the cladding tube. The simplified model produces the same deflection as the detailed model at the critical moment that produces a fracture plastic strain of 1%. The developed single fuel rod simplified model is assembled in a CE 16×16 configuration, and a methodology is presented in which the CE 16×16 assembly model is once again replaced by a simplified model with a cuboidal shape. Compression analyses were performed on each part of the CE 16×16 model to obtain isotropic property data, and a simplified model was created based on those data and the cross-sectional second moment values of the parts. A cask drop analysis was performed to validate the similarity of the CE 16×16 model and the simplified model by comparing important structural responses such as impact acceleration. The 20 simplified fuel assembly models and one detailed model were loaded into a cask to perform the drop analysis. For the detailed model, the impact acceleration was extracted for different loading positions and the corresponding impact load and pinch load were derived. The spring force and contact force corresponding to the pinch load were extracted by applying a Python script technique to extract the maximum value of them exerted on each fuel rod. The vulnerability of spent fuel rods to bending loads and the failure criteria were considered during the simplification process of a single fuel rod. From the extracted impact and pinch loads, the probability of failure of the spent fuel rods as a function of impact acceleration can be calculated.

In general, systems are developed by repeatedly performing the processes of design, analysis, manufacturing, and performance testing. In particular, systems with temperature, pressure, and flow rate often utilize computational fluid dynamics tools at the design stage. In this paper, we aim to verify the reliability of the analysis results of Solidworks Flow Simulation, which is widely used in heat flow analysis at the design stage. A tube furnace was manufactured, various experiments were performed, and a study was conducted to compare the analysis results. The details of the experiment are as follows. First, an experiment was conducted in which the heater was heated to 900°C without insulating the exposed part of the tube. The detailed contents of the experiment are as follows; - Heating heater and measuring temperature without supplying flow inside the tube, - Tube flow supply (25°C, 15 lpm air) and heater heating/temperature measurement. Second, an experiment was performed in which the exposed part of the tube was insulated (thickness 50 mm) and the heater was heated to 900°C. The detailed contents of the experiment are as follows; - Insulate the outside of the tube except for the flanges at both ends of the tube, and heat the heater and measure the temperature without supplying flow inside the tube. - Insulate the outside of the tube except for the flanges at both ends of the tube, supply flow rate inside the tube (25°C, 15 lpm air) and measure heater heating/temperature. - Insulate the flange of the flow supply section, heat the heater and measure temperature without supplying flow inside the tube. - Insulate the flange of the flow supply section, heat the supply air (277°C, 15 lpm) and measure the temperature using a heating gun without heating the heater. - Insulate the flange of the flow supply section, supply heated air (277°C, 15 lpm) and measure heater heating/temperature. - Insulate the flange of the flow supply section and measure temperature according to heater heating (900°C) and supply temperature (25°C, 277°C 15 lpm). The following results were derived from the experimental and analysis results. - When the exposed part of the tube is insulated, the temperature inside the tube increases and the steady-state power decreases compared to non-insulated. - In areas with insulation, the temperature error between experiment and analysis results is not large. - When flow rate is supplied, there is a large temperature error in experiment and analysis results. - The temperature change after the center of the heater is not large for a temperature change of 15 lpm flow rate. From these results, it can be seen that Solidworks Flow Simulation has a significant difference from the experimental results when there is a flow rate in the tube. This was thought to be because the flow rate acts as a disturbance, and this cannot be sufficiently accounted for in the analysis. In the future, we plan to check whether there is a way to solve this problem.

In KAERI’s previous phosphate precipitation tests, the dispersed powder of lithium phosphate (Li3PO4) as a precipitation agent reacted with various metal chlorides in a simulated LiCl-KCl molten salt. The reaction of metal chlorides composed of actinides such as uranium and three rare earths (Nd, Ce and La) with lithium phosphate is a solid-liquid reaction. A phosphorylation reaction rate is very fast and the metal phosphates as a reaction product precipitated on the bottom of the molten salt crucible. One of the recovery methods of the metal phosphate precipitates is segregation the lower part (precipitates) of the salt ingot using the various cutting tools. Recently, a new phosphorylation experiment using lithium phosphate ingots carried out in order to collect the metal phosphate precipitates into a small recovering vessel, and the test result of this new method was feasible. However, the reaction rate of test using lithium phosphate ingot is extremely slower than that of test using lithium phosphate powder. In this study, the precipitation reactor design (a tapered crucible with polished inner surface) used for phosphorylation reaction showed that the salt ingot with metal phosphate precipitates could be detached from a tapered stainless steel crucible. We propose that the recovery of precipitates from a salt ingot is possible by introducing a dividing plate structure into a molten salt and by positioning it at the interface between salt and precipitated metal phosphate.

Considering the domestic situation where all nuclear power plants are located on seaside, the interim storage site is also likely to be located on coastal site. Maritime transportation is inevitable and the its risk assessment is very important for safety. Currently, there is no independently developed maritime transportation risk assessment code in Korea, and no research has been conducted to evaluate the release of radioactive waste due to the immersion of transport cask. Previous studies show that the release rate of radionuclides contained in a submerged transport cask is significantly affected by the area of flow path generated at the breached containment boundary. Due to the robustness of a cask, the breach is the most likely generated between the lid and body of cask. CRIEPI investigated the effect of cask containment on the release rate of radioactive contents into the ocean and proposed a procedure to calculate the release rate considering the socalled barrier effect. However, the contribution of O-ring on the release rate was not considered in the work. In this study, test and analysis is performed to determine the equivalent flow path gap considering the influence of O-rings. These results will be implemented in the computational model to assess sea water flow through a breached containment boundary using CFD techniques to assess radionuclide release rates. To evaluate the release rate as a function of lid displacement, a small containment vessel is engineered and a metal O-ring of the Helicoflex HN type is installed, which is the most commonly used one in transport and storage casks. The lid of containment vessel is displaced in vertical and horizontal direction and the release rate of the vessel was quantified using the helium leak test and the pressure drop test. Through this work, the relationship between the vertical opening displacement and horizontal sliding displacement of the cask lid and the actual flow path area created is established. This will be implemented in the CFD model for flow rate calculation from a submerged transport cask in the deep sea. In addition, the compression of the O-ring causes very small gaps, such as capillaries. In these cases, Poiseuille’s law is used to calculate the capillary flow rate.

Currently, the Korea Atomic Energy Research Institute is conducting research on the development of technology to reduce the disposal area for SF (Spent nuclear Fuel). If the main radionuclides contained in SF can be separated and recovered according to their characteristics (long half-life, high mobility and high heat load) and uranium oxide which is expected to be the final residue, can be made into solids, the burden of the permanent disposal area of the SF will be greatly reduced. The waste form that end up in the repository must be verified for ease of manufacture and stability of the block. And, in order to increase the loading efficiency, a large block manufacturing technology is needed. This study describes the background of introducing PSA (Particle Size Analyzer) which is one of the necessary equipment for manufacturing UO2 blocks using slip casting, the method of using the equipment and performance verification of the equipment using standard samples. The particle size affects the sintering quality by the way the particles rearrange themselves during sintering. Powders of small particles are generally less free flowing and more difficult to compress, they form thin pores between the particles and sinter to higher density. In contrast, larger particle has a lower sintered density. Therefore, accurate particle size measurement and the selection of a suitable particle size are important. For this purpose, a PSA was installed in nuclear cycle experiment research center. To verify the performance of the equipment, a standard sample of 1.025 μm was analyzed. We got an average particle size of 1.0293 μm and standard deviation of 0.0668 μm. This value was within the uncertainty(±0.018 μm) of the sample’s certificate. In the future, this equipment will measure the size of UO2 (depleted uranium) powder and to produce large scale uranium oxide blocks.

Pyroprocessing technology has emerged as a viable alternative for the treatment of metal/oxide used fuel within the nuclear fuel cycle. This innovative approach involves an oxide reduction process wherein spent fuel in oxide form is placed within a cathode basket immersed in a molten LiCl-Li2O salt operating at 923 K. The chemical reduction of these oxide materials into their metallic counterparts occurs through a reaction with Li metal, which is electrochemically deposited onto the cathode. However, during process, the generation of Li2O within the fuel basket is inevitable, and due to the limited reduction efficiency, a significant portion of rare earth oxides (REOx) remains in their oxide state. The presence of these impurities, specifically Li2O and REOx, necessitates their transfer into the electrorefining system, leading to several challenges. Both Li2O and REOx exhibit reactivity with UCl3, the primary electrolyte within the electrorefining system, causing a continuous reduction in UCl3 concentration throughout the process. Furthermore, the formation of fine UO2 powder within the salt system, resulting from chemical reactions, poses a potential long-term operational and safety concern within the electrorefining process.Various techniques have been developed to address the issue of UO2 fine particle removal from the salt, utilizing both chemical and mechanical methods. However, it is crucial that these methods do not interfere with the core pyroprocessing procedure. This study aims to investigate the impact of Li2O and REOx introduced from the electrolytic reduction process on the electrorefining system. Additionally, we propose a method to effectively eliminate the generated UO2 fine powder, thereby enhancing the long-term operational stability of the electrorefining process. The efficiency of this proposed solution in removing oxidized powder has been confirmed through laboratory-scale testing, and we will provide a comprehensive discussion of the detailed results.

It is known that ZrCl4 can be used in the chlorination process of spent nuclear fuel. However, its solubility in high temperature molten salt is very small, making it difficult to dissolve a large amount of ZrCl4. Therefore, in this study, a flange-type sealed reactor was manufactured to observe the reaction characteristics of LiCl-KCl salt and ZrCl4. LiCl-KCl salt and ZrCl4 were placed in each alumina crucible, the reactor was sealed, and heated. The temperature at the reactor surface was above 500°C and maintained at that temperature for 48 hours. After completion of the reaction, the reactor was opened and the reaction products were recovered from each alumina crucible. The crystal structure of the reaction product was identified through XRD analysis, and the concentration of Zr was analyzed using ICP. Reaction characteristics were observed according to the molar ratio of ZrCl4 added to the number of moles of KCl in LiCl-KCl salt. The molar ratios of ZrCl4 to KCl were 0.5, 1, 2, and 3, respectively. As a result of each experiment, more than 95% of the injected ZrCl4 was vaporized and there was almost no residue in the ZrCl4 crucible. In the LiCl- KCl crucible, the weight increased in proportion to the amount of ZrCl4 added. As a result of XRD analysis, K2ZrCl6 was confirmed in all LiCl-KCl salt product. When the ZrCl4/KCl molar ratio was 2 and 3, LiCl-KCl could not be confirmed. Additionally, when the ZrCl4/KCl molar ratio was 1, LiCl was identified, but KCl was not found. Almost all of the KCl appears to have reacted with ZrCl4. ICP analysis results showed that the Zr concentration was proportional to the amount of ZrCl4 added in each LiCl-KCl salt, and exceeding the number of moles of reaction with KCl in the LiCl-KCl salt was observed. Therefore, these experimental results showed that ZrCl4 can be dissolved in LiCl-KCl salt at a maximum concentration higher than its solubility.

The separation efficiency of nuclides in molten salt systems was investigated, with a focus on the influence of apparatus configuration and experimental conditions. A prior study revealed that achieving effective Sr separation from simulated oxide fuel required up to 96 hours, reaching a separation efficiency of approximately 90% using a static dissolution reaction in a porous alumina basket. In this study, we explored the impact of agitation on improving Sr separation efficiency and dissolution rates. The simulated oxide fuel composition consisted of 2wt% Sr, 3wt% Ba, 2wt% Ce, 3wt% Nd, 3wt% Zr, 2wt% Mo, and 89wt% U. To quantify the Sr concentration in the salt, we utilized ICP analysis after salt sampling via a dip-stick technique. Furthermore, we conducted ICPOES analysis over a 55-hour duration to assess the separated nuclides. Complementing these analyses, SEM and XRD investigations were performed to validate the crystal structure and morphology of the oxide products.

Molten salt reactor (MSR) uses fluoride or chloride based molten salt as a coolant of the system, and fuel materials are dissolved in the molten salt, therefore it can be act as both coolant and nuclear fuel. A few issues have arisen from early-stage research and development program of MSR from Oak Ridge National Laboratory, including corrosion of structural materials and fission product management. For investigating the effect of additives on corrosion of structural materials, Mg(OH)2 and MgCl2*6H2O are added into the NaCl-MgCl2 eutectic salt. Prepared chloride salt is injected into the autoclave in the glove box, as well as corrosion coupons for candidate structural materials for molten chloride salt reactor, SS316, Alloy 600, and C-276 are also prepared. The temperature is set as 700°C. After 500 h corrosion experiment, the samples are taken out from the autoclave, and they are analyzed with scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS). SS316 samples show weight loss with all salt conditions, while Alloy 600 and C-276 show weight gain after the corrosion experiment.

Various disposal methods for spent nuclear fuels (SNFs) are being researched, and one of these methods involves separating high heat-generating nuclear isotopes such as Strontium-90 (90Sr) and Cesium-137 (137Cs) for deep disposal. These isotopes has relatively short half-lives and substantial decay energies. Especially, 90Sr undergoes decay through Yttrium-90 to Zirconium-90, emitting intense heat with beta radiation. Therefore, the removal of these high heat-generating isotopes will significantly contribute to reducing disposal site area. To remove 90Sr from SNFs, molten salt was utilized in KAERI. During this process, it was discovered that 90Sr dissolves in the molten salt in the form of SrCl2 and/or Sr4OCl6. Afterwards, it is crucial to recover 90Sr in the form of oxide from the salt to create immobilized forms for disposal. This can be achieved by reactive distillation with K2CO3. However, the amount of 90Sr within the SNFs is only 0.121wt%, and even if all the 90Sr in the SNFs were to leach into the molten salt, the quantity of 90Sr in the molten slat would still be very small. Therefore, adding K2CO3 to the molten salt for reactive distillation could result in significant possibilities of side reactions occurring. In this study, a two-step process was employed to mitigate the side reactions: the 1st step involves evaporating the all molten salts and the 2nd step includes adding K2CO3 to make oxides through solid-solid reaction. Eutectic LiCl-KCl, which is the most commonly used salt, was employed. The eutectic LiCl-KCl with SrCl2 was heated at 850°C for 2 h to evaporate the salts under a vacuum (> 0.02 torr). However, after examining the distillation product before the solid-solid reaction, it was observed that SrCl2 reacted with KCl in the salt, resulting in the formation of KSr2Cl5. It means that salts containing KCl are not suitable candidates for reactive distillation aimed at producing immobilized forms. As an alternative, MgCl2 could be a highly promising candidate because it is inert to SrCl2 and according to a recent study in KAERI, MgCl2 exhibited the most efficient separation of Sr among various salts. Therefore, we plan to proceed with the two-step reactive distillation using MgCl2 for the future work.

It has been investigated on the management of Strontium-90 in KAERI. It is needed to separate the solute from the salt solution for the recovery of strontium after the chlorination of the strontium oxide in molten salt. A vacuum distillation technology was used for the separation of strontium from the molten salt in our previous study. Strontium chloride was successfully carbonated by reactive distillation of SrCl2 – K2CO3 – LiCl – KCl system. In this study, it was tried to develop another route to recover strontium from the salt solution by a solid-solid reaction for avoiding the entrainment of product and the salt-K2CO3 reaction. Reactive distillation experiments were carried out for SrCl2 - K2CO3 – LiCl – KCl system. The carbonation temperature and pressure were 520°C and 0.8 bar. After the carbonation reaction, the temperature was elevated to 820°C to remove KCl from the reaction product. SrCO3 and KCl peaks were found in the XRD analysis of the residual product. It could be concluded that SrCl2 can be successfully carbonated after salt removal by the solid-solid reaction.

Korea Hydro & Nuclear Power (KHNP) is currently developing a vertical concrete dry storage module for the dry storage of used nuclear fuel within nuclear power plants. This module is designed with a structure consisting of cylinders, which can block the ingress of external air, thereby preventing Chloride-Induced Stress Corrosion Cracking (CISCC). However, due to the presence of these cylinder structures, unlike conventional dry storage systems, it cannot directly dissipate heat to the external atmosphere, making thermal evaluation an important issue. The SF dry storage module being developed by KHNP is a massive concrete structure of approximately 20 m × 10 m × 7 m in size, employing a vertical storage system. To demonstrate the safety of such a large structure, there is no alternative to conducting experiments with scaled-down models. Furthermore, according to NUREG-2215 Section 5.5.4, it is explicitly mentioned that design-verification testing can be performed using scaled-down models. In this paper, a 1/4 scaled-down model was constructed to perform thermal performance verification experiments, and the effectiveness of this model was analyzed using Computational Fluid Dynamics (CFD) methods. The analysis results indicated that there was not a significant difference in terms of maximum concrete temperature and air outlet temperature. However, a considerable difference was observed in the canister surface temperature. Therefore, it is concluded that careful consideration of natural convection heat transfer is necessary for the full application of the scaled-down model.

The Spent Nuclear Fuel (SNF) cladding serves as the first barrier that prevents the release of radioactive materials. It is very important to maintain cladding integrity in SNF management. It is known that the pinch load applied to the cladding can lead to Mode-3 failure and the cladding becomes more vulnerable to this failure mode with the existence of radial hydrides and other forms of mechanical defects. In this study, a numerical analysis process was proposed to scientifically and systematically evaluate the fracture resistance of cladding with reoriented hydrides under pinch load. The mechanical behavior and fracture of the irradiated cladding under pinch load can be evaluated by Ring Compression Test (RCT). Under the stress field generated by RCT, the cracks propagate more easily through radial hydrides than circumferential hydrides. The δ-hydride which form within the α-zirconium matrix causes a large expansion strain due to the volume difference and voids form at the interface between the hydride and the zirconium matrix. Chan demonstrated that the load needed to form voids and separate the hard hydride precipitates from the Zr matrix is considerably lower than that which initiates brittle fracture of hydrides using a micro-cantilever test. Therefore, we propose a microstructure crack propagation analysis method based on Continuum Damage Mechanics (CDM) that can simulate fracture of hydride, zirconium matrix, and Zr/hydride interface. CDM is possible to simulate the hydride, zirconium matrix, and interface cracking in a continuum model based on cladding deformation. The RCT simulation model was constructed from the microscopic images of irradiated cladding. A pixel-based finite element model was created by separating the hydride, zirconium matrix, and interface using the image segmentation method on a morphology operation basis. The appropriate element size was selected for the efficiency of the analysis and crack propagation using CDM. The force-displacement curves and strain energy from RCT were compared and analyzed with the simulation results of different element sizes. The finalized RCT simulation model can be used to evaluate the fracture resistance of the irradiated cladding under the quantified pinch load and to establish the failure criterion of fuel rods under pinch load. The advantages and limitations of the proposed process are discussed.

Hydride reorientation is widely known as one of the major degradation mechanisms in Zirconium cladding during dry storage. Some previous theoretical models for hydride reorientation used assumption of an ideal radial basal pole orientation for HCP structure of Zirconium cladding. Under this assumption, circumferential hydride was considered to precipitate in the basal plane while radial hydride was considered to precipitate in the prismatic plane, thereby giving energetical penalty on thermodynamical precipitation of radial hydrides. However, in reality, reactor-grade Zirconium cladding exhibits average 30° tilted texture, adding complexity to the hydride precipitation mechanism. In this study, reactor-grade Zirconium cladding was charged with hydrogen and hydride reorientation -treated specimens were fabricated. Microstructural characterization of hydrides was conducted via following three methods in terms of interface and stored energy. And this study aimed to compare these characteristics between circumferential and radial hydrides. Using Electron Back Scattered Diffraction (EBSD), the interface was investigated assuming that interface lies parallel to the axial axis of the tube. These were further validated with Transmission Electron Microscope (TEM). In addition, Differential Scanning Calorimetry (DSC) analysis was conducted to calculate the stored energy. This investigation is expected to establish fundamental understanding of how hydrides precipitate in Zirconium cladding with different orientations. And it will also increase the predictability of radial hydride formation and help understanding the mechanical behavior of Zirconium cladding with radial hydrides.