기존의 해상교량 기둥의 외부보강에 따른 연구들은 현재까지 주로 중앙점 재하에 따른 성능을 평가하였다. 하지만, 장대교량의 기둥은 정확한 중심축을 기준으로 축하중을 받는 경우와 편심으로 인한 큰 모멘트가 동시에 작용하는 경우가 많이 발생한다. 이 연구에서는 해상장대교량의 고강도 철근콘크리트 기둥의 하중재하 위치와 2가지의 보강 재료인 탄소섬유 및 고성능 유리섬유를 각각 보강하여 그 효과를 분석하였다. 실험에 사용된 12개의 기둥 실험체는 모두 같은 크기로 제작 및 실험을 하였다. 그 중 6개 실험체의 횡보강 철끈은 띠철근으로 배근하였으며, 그 외 6개의 실험체는 나선철근으로 매끈하였다. 그리고 각각 3겹의 탄소섬유 및 고성능 유리섬유를 적용하여 감싸기 방법으로 보강하였다. 실험변수는 하중재하 위치에 따른 철근의 보강행태 및 보강재료가 고려되었다. 실험결과, 편심축에 따른 하중재하 기둥부재는 중심축 하중재하에 비해 최대 파괴하중이 감소하였지만 고성능 유리섬유를 보강한 기둥부재는 축하중 및 편심하중에서 탄소섬유를 보강한 경우보다 내력과 연성이 우수하였다.

C-Reactive protein (CRP), which is an 118 kDa pentameric protein, was secreted by the liver is an important biomarker for coronary disease, hypertension and inflammation. In this study, a method for CRP detection exploiting quantum dot (Qdot)-antibody conjugate was developed according to an indirect-competitive immunosensing protocol. For this purpose, a streptavidin-bound Qdot605 was linked with a separately prepared biotinylated monoclonal antirat CRP antibody to produce a Qdot-antibody conjugate. The immunosensing was performed at 0.1 and 20 nM of the coating antigen and conjugate, respectively. The current method was found very sensitive in CRP detection, judging from the concentration-dependent fluorescence emission.

Glass-ceramics were fabricated by heat-treatment of glass obtained by melting a coal bottom ash with Li2O addition. The main crystal grown in the glass-ceramics, containing 10 wt% Li2O, was β-spodumene solid solution, while in Li2O 20 wt% specimen was mullite, identified using XRD. The activation energy and Avrami constant for crystallization were calculated and showed that bulk crystallization behavior will be predominant, and this expectation agreed with the microstructural observations. The crystal phase grown in Li2O 10 wt% glass-ceramics had a dendrite-like shaped whereas the shape was flake-like in the 20 wt% case. The thermal expansion coefficient of the Li2O 10 wt% glass-ceramics was lower than that of the glass having the same composition, owing to the formation of a β-spodumene phase. For example, the thermal expansion coefficient of Li2O 10 wt% glass-ceramics was 20×10-7, which is enough for application in various heat-resistance fields. But above 20 wt% Li2O, the thermal coefficient expansion of glass-ceramics, on the contrary, was higher than that of the same composition glass, due to formation of mullite.

The effects of thermal properties on the crystallization behavior of CaMgSi2O6 glass-ceramics were investigated as a function of sintering temperature from 800˚C to 900˚C. The crystallization behavior of the specimens depended on the sintering temperature, which could be evaluated from the differential thermal analysis, X-ray diffraction and Fourier transform infrared spectroscopy. With increasing sintering temperature, the thermal conductivity of the sintered specimens increased, while the coefficient of thermal expansion (CTE) of the sintered specimens decreased. These results could be attributed to the increase of crystallization, confirmed from the estimation by density measurements. Also, the thermal diffusivity and specific heat capacity of the sintered specimens were discussed with relation to the sintering temperature. Typically, a thermal conductivity of 3.084 W/m˚C, CTE of 8.049 ppm/˚C, thermal diffusivity of 1.389 mm2/s and specific heat capacity of 0.752 J/g˚C were obtained for CaMgSi2O6 specimens sintered at 900˚C for 5 h.

Optical characteristics and structural changes depending on CuO content in phosphate glasses that are used in near-infrared (near-IR) filters were investigated. With phosphate glasses that contain 1-9 mol% CuO, changes in optical transmittance, optical absorption, and color coordinate were measured with a UV-VIS spectrophotometer. An XPS (X-ray photoelectron spectroscopy) analysis was performed to determine valence of copper ion that influences optical characteristics in near-IR filter glasses. Structural changes in glasses depending on CuO content were also analyzed by FT-IR (Fourier transform infrared) and Raman spectrophotometers. From the UV-VIS spectrophotometer results, strong absorption peaks at 220 & 900 nm were found and transmittance was decreased. The color coordinates of the glasses were shifted to the green color direction with CuO addition for increasing absorption of long wavelength range spectra, in spite of the amount of Cu2+, which gives a blue color to glasses, and which was increased in XPS results. Also, structural de-polymerization of glasses with CuO addition were found by FT-IR and Raman results.

본 연구에서는 기존의 중량법과 광산란법과는 원리와 기술이 다른 입도별 부유물질 측정용 분리막 모듈 및 장치를 개발하기 위한 원리를 수립하기 위한 기초 자료를 확립하고자 하였다. 이러한 목적을 위하여, 이산화규소 및 덱스트란(dextran), 카올린(kaolin), PEG (polyethylene glycol) 부유용액을 대상으로 유리섬유 여과지 GF/C와 GF/A를 분리막 모듈에 장착하여 여과시키면서, 디지털 압력계를 사용하여 막간압력차(TMP, Trans-membrane pressure) 변화를 측정하였다. 모사용액의 농도와 TMP 변화율 기울기의 상관관계식을 TMP 변화 실험 결과로부터 구하여, TMP 변화 기울기로부터 시료의 농도를 예측할 수 있도록 하였다.

본 연구에서는 국내 LTPP 구간에서 수행된 FWD 시험의 결과를 바탕으로 섬유보강, 폴리머 개질, 일반 아스팔트 포장의 구조적 성능을 비교 평가하였다. FWD 시험 결과, 표층 하단부의 인장변형량이 섬유보강 아스팔트는 29%, 폴리머 개질 아스팔트는 21% 저감되는 것을 확인하였다. 또한 FWD 처짐량을 역산하여 각 층의 탄성계수를 추정한 후 이를 바탕으로 AASHTO 설계방법, 구조적 해석 방법 및 생애주기비용분석을 통해 섬유보강 및 폴리머 개질 아스팔트 포장의 비용 효과를 분석하였다. 분석 결과, 섬유보강은 약 5cm, 폴리머 개질은 약 3cm의 아스팔트 층 두께 감소 효과를 보여주었다. 그러나 섬유보강 및 폴리머 개질 아스팔트의 고가격으로 인하여 전체 시공재료비는 일반 아스팔트 포장에 비해 상승하는 결과를 보여주었다. 생애주기비용 결과는 초기 공사비는 섬유보강 및 폴리머 개질 아스팔트 포장이 높지만, 유지관리비용 및 사용자비용은 감소하는 것으로 나타났다.

본 연구는 도로안전 시설물의 풍하중에 의한 손상발생 사례를 토대로 현행 도로안전 시설물의 구조적 휨 성능을 평가하고 이에 대한 부재별 휨 성능개선을 위한 연구이다. 본 연구의 대상구조물로는 대표적인 도로안전시설물이며 풍하중에 대한 선행 피해사례가 밝혀진 방음벽 지주프레임을 대상으로 고려하였으며 이들 지주프레임의 휨 구조성능 및 형상설계에 대한 평가를 우선적으로 수행하였다. 본 연구평가 결과에서 나타난 현행 보강재의 구조적 성능을 토대로 중량 대비 구조적 강성이 우수한 유리섬유 강화플라스틱 (GFRP)을 활용하여 다양한 보강 형태에 따른 성능개선방법을 해석 및 실험적 연구를 통하여 수행하였다. 그 결과 효율적 성능개선을 위한 GFRP 적용방법의 경우 구조적, 시공적 측면에서 효율적인 것으로 평가되었고 자체적인 형상단면 최적설계를 통한 개선방법도 성능보강에 효과적인 것으로 해석적으로 평가되었다. 본 연구에서 적용된 GFRP 단면보강 및 최적형상설계 연구는 향후 노후 도로안전 시설물의 풍하중 또는 태풍으로 인한 피해예방을 위한 기초자료로서 효율적으로 활용될 수 있을 것으로 판단된다.

The Zr-based bulk metallic glass matrix composites of a mixture of gas-atomized metallic glass powders and Fe-based nanostructured powders were fabricated by spark plasma sintering. The Fe-based nanostructured powders adopted for the enhancement of plasticity were well distributed in the matrix after consolidation, and the matrix remains as a fully amorphous phase. The successful consolidation of metallic glass matrix composite with high density was attributed to viscous flow in the supercooled liquid state during spark plasma sintering. Unlike other amorphous matrix composites, in which improved ductility could be obtained at the expense of their strength, the developed composite exhibited improvement both in strength and ductility. The ductility improvement in the composite was considered to be due to the formation of multiple shear bands under the presence of the Fe-based nanostructured particles.

Reflection properties, such as specular reflection and diffuse reflection, are very important optical properties for the reflector, which has high reflectance in the display and architecture industry. Calcite is lowcost, nontoxic, and stable over a wide temperature range. Therefore, it is one of the most widely using fillers in many industries and has some advantages over titania as a filler to improve reflectance. However, optical properties, especially those of ceramic-filled composites, have not been analyzed. We studied the reflectance of calcite composites with their surface roughness. The reflectance of the composites was determined using a UV-visible spectrometer. The surface morphology and the micro-structure of the composites were investigated by atomic force microscope. The reflectance of the composites was improved by increasing the content of calcite in the calcite-frit composite. The reflectance is related with the surface roughness in the composites. However, the reflectance depends on the calcite contents in materials with similar surface roughness.

In the present study, Zr-base metallic glass(MG)/diamond composites are fabricated using a combination of gas-atomization and spark plasma sintering (SPS). The densification behaviors of mixtures of soft MG and hard diamond powders during consolidation process are investigated. The influence of mixture characteristics on the densification is discussed and several mechanism explaining the influence of diamond particles on consolidation behaviour are proposed. The experimental results show that consolidation is enhanced with increasing diamond/Metallic Glass(MG) size ratio, while the diamond fraction is fixed.

Glass ceramics were made from coal bottom ash by adding CaO and Li2O as glass modifiers and TiO2 as a nucleating agent in a process of melting and quenching followed by a thermal treatment. The surface of the glass ceramics has 1.6 times more Li2O compared to the inner matrix. When TiO2 was not added or when only 2 wt% was added, the surface parts of the glass ceramics were crystalline with a thickness close to 130μm. In addition, the matrixes showed only the glass phase and not the crystalline phase. However, doping of TiO2 from 4 wt% to 10 wt% began to create small crystalline phases in the matrix with an increase in the quantity of the crystalline. The matrix microstructure of glass ceramics containing TiO2 in excess of 8 wt% was a mixture of dark-gray crystalline and white crystalline parts. These two parts had no considerable difference in terms of composition. It was thought that the crystallization mechanism affects the crystal growth, direction and shape and rather than the existence of two types of crystals.

This study investigates Bi2O3-B2O3-BaO-ZnO glass with variations of the Co3O4 content (0.25,0.5,1,and 2wt%) and the interaction between transparent dielectric and Ag electrodes heat-treated at 500-560oC for30min. The glass transition temperature, softening temperature and thermal expansion coefficient were432oC, 460oC and 81.4×10-7/oC, respectively. The transmittance of 0.25wt% Co3O4 to which dielectric wasadded was highest and was decreased due to coloration with the addition of more than 0.25wt%. However,without Co3O4, the transmittance of the transparent layer was decreased due to the formation of Ba5Bi3;however, the occurrence of the crystal phase decreased as a result of the addition of Co3O4. The amount ofCo2+ ions increased as the Co3O4 increased. With a maximum of Co3+ ions, the highest transmittance wasobserved.

An insulator is widely used for automobile parts to protect the thermal damage and noise from the engine. In this paper, the heat shield performance of insulator in the automobile parts has been investigated experimentally. Also, the experimental results are compared with the numerical analysis. It was tested for the effects of heating temperature and insulator material on heat shield performance. As a results, in the range of heating temperature 95℃∼175℃, the heat shield performance is enhanced with increasing heating temperature. Furthermore, glass wool and Formed mat have similar heat shield performance. So, it is very effective to use the glass wool as insulator in the range of 95℃∼175.

The purpose of this study is to distinguish the causes of broken glass on doors or windows when it is originally kept among the remains on the floor in fire site - whether it was broken due to heating or outer power-through test and characteristics of the broken plane including the pattern on the plane. Addition to it, the study tries to find characteristics to judge the point and direction of breakdown through the analysis of glass broken by outer power. With two assumed causes - a) breakdown due to heating and b) breakdown due to outer power-3 pieces of glass plates (30cm×30cm×5mm) were tested for each case, getting the results as following: First, for the glass broken due to the change of temperature, the broken plane is of slow and smooth curve without any pattern. Second, for the glass broken due to outer power, with the impact point as the center, the glass shows breakdown of radial type and the side shows breakdown of near-perpendicular type. The far the broken piece is from the impact point, the bigger the size is. The broken piece at the impact point is of long triangle type and the two long planes of the triangle shows semi-arc with the center of breakdown point and the other plane shows opposite pattern. Third, when glass that is damaged by outer power is heated, damaged forms and side patterns of the glass that is damaged by outer power are heated and disappeared.

국내 LTPP(Long Term Pavement Performance) 연구에서 섬유보강 아스팔트 포장의 성능을 평가하기 위해, 국도 1호선 구간에 일반 아스팔트 포장과 섬유보강 아스팔트 포장을 각각 시공하였으며, 각각의 단면에 포장체 구조적 거동을 측정할 수 있는 계측센서를 매설하였다. 본 연구에서는 국내 LTPP구간에서 수행된 차량재하시험과 FWD시험의 결과를 바탕으로 섬유보강 아스팔트 포장의 구조적 성능을 평가하였다. 본 연구결과, 차량재하시험에서 섬유보강재를 사용할 경우 표층하단부의 변형률이 크게 저감되는 것을 확인하였다. 또한 일반 아스팔트 포장보다 응력중립축이 상승하여 일반 아스팔트포장은 중간층 하단에서 압축변형이 발생하는 반면에, 섬유보강 아스팔트포장은 중간층 하단에서 인장변형이 발생하였다. 반면 기층 하단부에서의 인장변형률은 두 포장형식 모두 큰 차이를 나타내지 않았다. FWD 시험에서도 섬유보강재를 사용할 경우 약 24% 정도 표면 처짐 량이 저감되는 것을 확인하였다. 이와 같은 결과를 종합하여 볼 때, 섬유보강 아스팔트 포장이 소성변형에 대한 저항성을 증진시킬 수 있다고 판단되며, 향후에 포장상태조사를 통해 장기포장공용성에 대한 연구가 수반되어야 할 것이다.

In this study, the additivity factors of compositions to density and glass transition point (Tg) in a xLi2O-(1-x)[(1-y)TeO2-yZnO] (0<x<20, 0<y<20) glass system were analyzed by using mixture design, and the change of ionic conductivity with density and Tg was discussed. As a method for predicting the relation between glass structure and ionic conductivity, density was measured by the Archimedes method. The glass transition point was analyzed to predict the relation between ionic conductivity and the bonding energy between alkali ions and non-bridge oxygen (NBO). The relation equations showing the additivity factor of each composition to the two properties are as follows: Density(g/cm3) = 2.441x1 ＋ 5.559x2 ＋ 4.863x3 Tg(˚C) = 319x1 ＋ 247x2 ＋ 609x3 － 1950x1x3 (x1 : fraction of Li2O, x2 : fraction of TeO2, x3 : fraction of ZnO) The density decreased as Li2O content increased. This was attributed to change of the TeO2 structure. From this structural result, the electric conductivity of the glass samples was predicted following the ionic conduction mechanism. Finally, it is expected that electric conductivity will increase as the activation energy for ion movement decreases.

The Ni-based bulk metallic glass matrix composites were fabricated by spark plasma sintering of mixture of gas-atomized metallic glass powders and ductile brass powders. The successful consolidation of metallic glass matrix composite was achieved by strong bonding between metallic glass powders due to viscous flow deformation and lower stress of ductile brass powders in the supercooled liquid state during spark plasma sintering. The composite shows some macroscopic plasticity after yielding, which was obtained by introducing a ductile second brass phase in the Ni-based metallic glass matrix.

In this work, we employed an electroless nickel plating on glass fibers in order to enhance the electric conductivity of fibers. And the effects of metal content and plating time on the conductivity of fibers were investigated. From the results, island-like metal clusters were found on the fiber surfaces in initial plating state, and perfect metallic layers were observed after 10 min of plating time. The thickness of metallic layers on fiber surfaces was proportion to plating time, and the electric conductivity showed similar trends. The nickel cluster sizes on fibers decreased with increasing plating time, indicating that surface energetics of the fibers could become more homogeneous and make well-packed metallic layers, resulting in the high conductivity of Ni/glass fibers.