수소투과금속인 tantalum과 세라믹 지지체로 Y2O3-stabilized ZrO2 (YSZ)를 이용하여 cermet 수소분리막을 제조하였다. Ta/YSZ cermet 분리막은 헬륨분위기에서의 예비소결과 고진공 하에서의 본소결을 통해 제조하였으며, 소결 및 밀봉 과정에서 발생하는 불순물은 연마를 통해 제거 가능하였다. 이렇게 제조된 분리막은 tantalum의 연속상이 잘 발달된 치밀구조를 보였다. 수소 해리를 위해 팔라듐 코팅을 한 Ta/YSZ 분리막을 이용하여 200∼350°C의 범위에서 수소투과실험을 수행하였다. 300°C에서 분리막에 균열이 형성되었고 Pd 코팅층은 몇 곳이 박리되었다. XRD 결과는 tantalum이 수소와 반응하여 Ta2H가 생성되는 것을 보여주며, Ta2H에 인한 격자 팽창이 분리막의 결함을 초래하였다.

On cold start operation of an SI engine, a catalyst shows poor performance before it reaches activation temperature. Therefore, fast warmup of the catalyst is very crucial to reduce harmful emissions. In this study, an appropriate control strategy is investigated to increase exhaust gas temperature through changes of spark timing and exhaust valve timing. Combustion stability is also considered at the same time. Experiments showed that retarded spark timing promotes the combustion at the end of expansion stroke and increases exhaust gas temperature during cold start.An advance of exhaust valve timing decreases residual gas in cylinders due to decrease of valve overlap period. It helps improvement combustion stability by virtue of reduced residual gas. A control strategy of proper valve timing and spark timing is suggested in order to achieve fast light-off of the catalyst and stable operation of the engine in a cold start and idle operation

Cermet 분리막 제조를 위한 혼합 분말은 60 vol.% vanadium과 Y2O3-stabilized ZrO2 (YSZ)를 기계적으로 혼합하여 준비하였다. 혼합 분말을 원판으로 압축한 후 진공 분위기에서 1600°C로 2시간동안 소결하였다. 소결 분리막은 치밀하였고, 브레이징 필러를 이용하여 스테인레스 링에 장착되었다. V/YSZ 분리막의 수소 투과량은 100% 수소를 흘려 200∼ 350°C 범위에서 측정되었다. 350°C, 0.5 bar압력에서 분리막의 양 표면에 균열이 형성되었다. 투과실험 동안에 V/YSZ 분리막의 vanadium은 수소와 반응하여 V2H를 생성하였으며, 이로 인해 분리막이 균열되는 것을 알 수 있었다.

생식 첨가량을 3.7-11.7%로 조절한 생식음료의 분산안정성을 터비스캔을 사용하여 광학적 방법으로 측정하였다. 생식음료는 제조 후 시간이 경과함에 따라 음료 하부에서는 침전이 생성되어 후방산란광플럭스(이후 후광플럭스로 약칭)가 강해진 반면, 중간부에서는 청징현상에 의해 약해졌으며, 최상층부에서는 거품이 생성되어 다시 강해졌다. 생식 첨가량이 증가할수록 침전이 서서히 진행되었으며 전체 침전층은 두텁게 형성되었다. 침전에 의한 후광플럭스의 퍼센트변화율의 시간에 따른 변화는 로그 모델이 적용되었으며 결정계수는 0.979-0.988로 높은 값을 보였다. 생식 첨가량은 생식음료의 상층부에 형성되는 청징층과 하층부의 침전층의 경계면, 즉 청징층 선단의 이동속도 뿐 만 아니라 분리된 층의 수에도 영향을 미쳤다. 생식 첨가량 3.7%의 경우는 2층으로, 5.7-9.7%의 경우는 3개 층으로, 11.7%는 4개 층으로 분리되었다. 생식음료 제조 후 17-29분 사이에 1차 청징층 발생이 시작되었고 22-53분간 지속되었으며, 생식첨가량이 낮을수록 청징층 두께는 증가하였다. 청징층 발생은 생식 첨가량 7.7%인 음료에서 가장 늦게 나타나 최대 분산안정성을 보였다.

Metal(Zinc) soap and mixed metal(Zn/Ba) soap were synthesized with good structures and characterized by IR and H-NMR. The H-NMR spectrums of the synthesized soaps were in very good accordance with the structures proposed by earlier workers. The mixed metal soaps with various costabilizers(acid or metal content effect), which added in order to investigate the thermal stabilization effect at low and high temperature, were investigated the thermal stabilization effect. The temperature effect is relation to the metal content effect than acid effect. In case of mixed metal soap, the high thermal stabilization effect improved with increasing Barium content. As the Zinc content increase the low temperature thermal stabilization effect improved, but the high temperature thermal stabilization effect showed an opposite tendency.

본 연구는 전자 및 반도체 산업의 각종 에칭공정에서 발생되는 중금속 함유 산성 폐에칭액을 NF 막분리법을 이용하여 에칭액 회수와 중금속 처리를 효율적으로 수행하기 위한 NF 막공정의 운전조건을 설정하기 위한 기본 자료를 확보하는데 있다. 이를 위해 3가지 종류의 상용 NF 막(General Electric Co. Duraslick NF-4040 막, Dow Co. Filmtec LP-4040 막 및 Koch Co. SelRO MPS-34 4040 막)을 대상으로 Pb+2 중금속을 함유한 모의 질산 폐에칭액의 회분식(dead-end) 막여과 실험을 수행하여 폐에칭액의 투과 플럭스와 Pb+2 중금속 이온의 총괄 배제도를 측정하여 폐에칭액 처리에 우수한 NF 막을 선정하였다. 실험결과 질산용액에의 막 보관기간이 길수록, 질산용액의 pH가 낮을수록 산에 의한 막의 손상이 심해졌으며, 질산에 의한 막의 손상은 SelRO MPS-34 4040 < Duraslick NF-4040 < Filmtec LP-4040 막의 순서로 심하게 일어났다. 또한 질산용액에의 막 보관기간이 길수록, 질산용액의 pH가 낮을수록 Pb+2 이온의 배제도가 낮아졌으며, 배제도 값은 Duraslick NF-4040 막의 경우에는 95% 수준의 초기 배제도 값에서 질산용액에의 4달 보관 후에는 20% 수준으로, SelRO MPS-34 4040 막의 경우에는 초기 85% 수준에서 4달 후 65% 수준으로, Filmtec LP-4040 막의 경우에는 초기 90% 수준에서 4달 후 10% 이하 수준으로까지 감소하였다. 3종류의 상용 NF 막 중 내산성 용도로 개발된 SelRO MPS-34 4040 막이 중금속 함유 산성 폐에칭액의 재생에 가장 적합하였다.

According to the recent statistics of marine casualties in Korea, fishing boats are more likely to be ended in the casualties, and small fishing boats especially cause much more accidents in sinking and capsizing than any other big vessels. These casualties were mainly produced from the ignorance on the lack of own ship stability. From this view, this study aims to analyze the characteristics of stability on the crab trap fishing boat receiving transverse wave by means of carrying out the water tank test. The rolling angle of the model ship was affected largely with the displacement and the wave period of it, and the trends were shown that the magnitude of the angle was proportional to the displacement, but inversely to the wave period. And the wave height had effect on the rolling angle just in the specific range of the wave period. The force of steady wind didn't have influence on the rolling variation significantly.

Core stability exercises for patients with hemiplegia have become increasingly important and a variety of exercises have been developed over the years to give the hemiplegic patients more stable postural control. This study examined the therapeutic effects of the core stability exercises on the ability of static and dynamic postural control. Fifteen hemiplegic patients (7 males, 8 females, age ranging from 46 to 76 years) hospitalized in a Daejoen rehabilitation hospital were enrolled in this study. Nine and 6 patients had a cerebral infarction and cerebral hemorrhage, respectively. The subjects participated in a core stability exercise program consisting of a total of 12 sessions 3 times each week over a 4-week period with each exercise lasting approximately 15 minutes. The ability of static and dynamic postural control by Berg Balance Scale (BBS) and Timed Up and Go (TUG), respectively, were measured before and after the core stability exercise. A Wilcoxon signed ranks test was used to compare the effects of the ability of static and dynamic postural control before and after core stability exercise in patients with hemiplegia. The =.05 level of significance was used for the statistical tests. Core stability exercises were effective in improving the ability of static postural control; BBS (p<.05). Core stability exercises were also effective in improving the ability of dynamic postural control; TUG (p<.05). Overall, core stability exercise is believed to be an important therapeutic method in rehabilitation programs for hemiplegic patients.

The field emitters were fabricated by screen-printing of carbon nanotube paste, and their emission stabilities were evaluated. It was found that the emission stability measured in a sealed device is much higher than that measured in a vacuum chamber in spite of similar pressure. This was because oxygen gas was scarcely remained in the sealed device, while the gas is continuously supplied into the vacuum chamber during the stability measurement. It was found that the plasma treatment etched the protruded CNTs, resulting in the uniform height of CNT tips. As a result, the stability was increased remarkably. It was also found that the stability of CNT paste emitter was improved by electrical aging and that the optimum condition for the aging was varied with the size of emitter.

The authors have demonstrated white oraganic light-emitting diodes (WOLED) using 1,4-bis[2-(4'-diphenylaminobiphenyl-4-yl)vinyl]benzene as fluorescent blue emitter and iridium(III) bis(5-acetyl-2-phenylpyridinato-N,C2') acetylacetonate as phosphorescent red emitter. The optimized WOLED using red host material as bis(2-methyl-8-quinolinato) -4-phenylphenolate exhibited proper color stability in comparison with the control device using 4,4'-N,N'-dicarbazole-biphenyl as red host. The white device showed a maximum luminance of 21100 cd/m2 at 14 V, luminous efficiency of 9.7 cd/A at 20 mA/cm2, and Commission Internationale de I'Eclairage (CIEx,y)coordinates of (0.32, 0.34) at 1000 cd/m2. The devices also exhibited the color shift with δCIEx,y coordinates of ± (0.01,0.01) from 100 to 20000 cd/m2.

The purpose of this study was to investigate the storage stability of mayonnaise containing a different emulsifier and various levels of soybean paste powder. The mayonnaise with egg yolk as an emulsifier is E group according to the amount of soybean paste powder addition of 0%(E1), 3%(E2), 6%(E3) and mayonnaise with soy milk as an emulsifier is S group with soybean paste powder addition of 0%(S1), 3%(S2), 6%(S3). Storage stability of mayonnaise was determined during storage at 30 ± 5℃ for 8 weeks. The peroxide value, TBA value, acid value of mayonnaise with addition of 6% soybean paste powder was significantly lower than that of 0% and 3% addition. The turbidity decreased according to storage period. The viscosity of mayonnaise was increased with increasing amount of soybean paste powder. Base on these results, addition of soybean paste powder in the mayonnaise improved oxidation stability during storage period.

The Heat Transport system loop stability of CANDU-6 reactor as Wolsong-1 with the CANFLEX fuel bundle has been studied. The SOPHT modelling of the CANFLEX fuel bundle and the ROH interconnection line was made and the stability analysis response of Wolsong-1 reactor with CANFLEX fuel bundle was obtained. The mechanics of the flow instability caused by two phase flow was reviewed. Without the ROH interconnection line the Heat Transport system loop is unstable while the Heat Transport system is stable within ±1 % of nominal flow with the ROH interconnection line

약과 반죽시 참기름 대용으로 쇼트닝을 이용할 목적으로 쇼트닝의 혼합비율을 달리하여(참기름 100%, 참기름 75%+쇼트닝 25%, 참기름 50%+쇼트닝 50%, 쇼트닝 100%) 약과를 제조하고, 약과 유지의 지방산 조성, 유지함량, 원료유지의 잔존율, 저장 중의 유지산패도(산가, 과산화물가, 카르보닐가)를 측정하여 쇼트닝 약과의 유지안정성을 비교 분석한 결과 다음과 같았다. 1. 약과 반죽의 유지 함량은 9.33%였으나, 튀김 후 시료 구별 약과의 유지함량은 25.20-29.12%로서 아주 높았다. 이들 약과의 유지 구성은 반죽에 첨가되었던 원료유지와 튀김에 사용된 튀김유(대두유)의 비율이 각각 16-10%와 84-90%로서 튀김유가 대부분을 차지하였다. 2. 모든 약과의 지방산 조성은 쇼트닝의 첨가수준에 관계 없이 시료구간에 거의 유사하여 linoleic acid 49.71-51.27%, oleic acid 26.05-26.77%, palmitic acid 10.07-11.71%, linolenic acid 5.51-5.72% stearic acid 4.51-4.68%였으며, 이것은 튀김유(대두유)의 지방산 조성과 유사하였다. 3. 쇼트닝 첨가에 따른 약과의 저장중 산가, 과산화물가, 카르보닐가의 변화는 쇼트닝 첨가가 산가의 증가를 다소 지연시켰으나 과산화물가와 카르보닐가는 시료구간에 차이를 나타내지 않았다. 약과 제조시에 반죽에 첨가되는 유지의 지방산 조성이 크게 다르더라도 약과의 유지 산패도는 큰 차이를 보이지 않았다. 이것은 튀김 과정 중 튀김유가 약과내로 다량 흡유되어 약과반죽의 원료유지보다도 큰 영향을 준 것으로 생각된다. 따라서 쇼트닝은 약과 반죽에 참기름 대용으로 사용될경우 약과의 유지 산패 면에서는 참기름 100% 약과와 차이가 없어 약과 제조시 참기름 대체효과가 있을 것으로 기대된다.

The effects of Quenching and Partitioning (Q&P) and Annealed Martensite (AM) heat treatment on the microstructure and tensile properties were investigated for 0.24C-0.5Si-1.5Mn-1Al steels. The Q&P steels were annealed at a single phase (γ) or a dual phase (γ+α), followed by quenching to a temperature between Ms and Mf. Then, enriching carbon was conducted to stabilize the austenite through the partitioning, followed by water quenching. The AM steels were intercritically annealed at a dual phase (γ+α) temperature and austempered at Ms and Ms±50˚C, followed by cooling in oil quenching. The dual phase Q&P steels showed lower tensile strength and yieldyield strength than those of the single phase Q&P steels, and tThe elongation for the dual phase Q&P steel was partitioning 100s higher than that of that for the single phase Q&P steels as the partitioning time was less than 100s up to partitioning 100s. For AM steels, the tensile/yield strength decreased and the total elongation increased as the austempering temperature increased. The stability of the retained austenite controlled the elongation for Q&P steels and the volume fraction of the retained austenite controlled the elongation for AM steels.

We have tested the stability of paeoniflorin, a new cosmetic ingredient, extracted from the roots of Paeoniae lactiflora. The stability of aqueous paeoniflorin solution at pH 3, 5 and 7 varied by adding buffer solution was tested at 0℃, 25℃, 40℃, and 65℃. The test was performed with or without UV light. The solution of paeoniflorin was stable at pH 3.0, however, the recovery rate of paeoniflorin was 40% at pH 7.0. The stability of paeoniflorin solution was decreased as the pH of paeoniflorin solution was increased by pH 7.0. The effect of storage temperature of paeoniflorin solution shows that the stability of paeoniflorin solution was decreased as the temperature was increased. The stability of paeoniflorin was rather good under UV light than the condition given above 40℃. The stability of paeoniflorin in W/O emulsions shows similar pattern to that of aqueous solution.

묘도-광양간 현수교는 광양항에 진입하는 항로에 위치해있으므로 큰 배들에 대하여 충돌 방지공이 필요하다. 본 논문은 선박충돌을 고려하여 위험도 분석과 비선형 수치해석을 실시하였다. 위험도 분석 결과 충돌 방지공 설치 이전에는 연간 파괴확률이 기준치인 0.0001을 초과하여 충돌 방지공이 필요한 것으로 분석되었다. 따라서, 선박의 충돌을 방지하기 위해서 인공섬과 콘리트트 블록으로 만든 방파제 벽을 사용하여 설계하였다. 계획된 충돌 방지공 설치 후 비선형 수치해석 결과 교량에 미치는 하중이 교량의 내하력 이내로 나타나 선박 충돌시에도 교량의 안정성이 확보되는 것으로 나타났다.

Caprylic/Capric triglyceride-in-water emulsions stabilized by Nikkol HCO-60 and HCO-10 were prepared using emulsion inversion point method at different HLB values. Emulsions with various droplet sizes were formed, and emulsion inversion point was detected by electrical conductivity. The change in emulsion droplet sizes and long term stability were monitored using laser scattering method and visual method. The droplet sizes and stability of emulsions were affected by HLB of surfactant. At emulsion inversion point, the water volume fraction increased as the HLB of surfactants decreased. According to our analysis, this resulted from a tendency of forming the W/O (water-in-oil) emulsion as the HLB of surfactants was decreased. The emulsion inversion point was clearly detected by the microscope and the electric conductivity meter. Nanometer-sized emulsion was obtained at the optimum HLB by using emulsion inversion point method. The main pattern of instability of emulsions in HLB 12 and 13 systems was Ostwald ripening. However, The patterns of instability of emulsions below 11 of HLB systems were Ostwald ripening and coalescence. All emulsions produced with surfactants in the range of HLB 8-13, creaming caused by density difference between water phase and oil phase.

This experiment was conducted to investigate the effect of wa-song (Orostachys japonicus A. Berger) extracts on the oxidative stability of edible oil. Wa-song was dried from hot air (HWE) and freeze (FWE), and then they were extracted by hot water. The different levels (0.1, 0.5 and 1.0 g/100 mL) of HWE and FWE were added to soybean oil and lard. The chromaticity of edible oils was generally increased with prolonged heating time and HWE was higher than FWE. The anisidine value showed significant increase during heating for 48 hrs. After heating for 48 hrs, it was lower than control, except for HWE added sample of 0.5 and 1.0 g/100 mL, FWE added sample of 1.0 g/ 100 mL. In lard, it was lower in sample added wa-song extract than control. The acid value was not significant by added amount of wa-song. Its value in HWE added sample was lower than FWE, after heating for 48 hrs. POV was lower HWE than FWE, also. After heating for 24 hrs, TBA values in soybean oil containing HWE and FWE added sample was lower than control. In lard, its value in HWE and FWE added sample was lower than control during heating for 12~48 hrs. Therefore, those results suggested that HWE has higher antioxidant activity than FWE added sample, and then oxidative stability of HWE in edible oil was more potential for lard during its heating.

The thermal stability and mechanical properties of Nephila clavata and Bassaniana decorata spider silks were measured and compared with those of aramid and polyester fibers. The thermal stability of the spider silk was lower than those of the commercial aramid and polyester fibers. However, the mechanical properties of the spider silk were far superior to that of the polyester fiber. The effect of the water content of the spider silk on its thermal stability and mechanical property was examined by conducting the silk to heat treatment at 100℃ under vacuum for various times. The results indicated that spider silk subjected to heat treatment for 1.5 hr had excellent thermal stability and mechanical property.