The en-riched 58Ni powders are dissolved in acid solution and coated on a Cu target for proton irradiation at cyclotron to produce 57Co radioisotope. The condition of the plating bath and the coating process are determined using the en-riched powders. To establish the coating conditions for 57Co, non-radioactive Co ions are dissolved in an acid solution and electroplated on to a rhodium plate. The thermal diffusion of electroplated Co into a rhodium matrix was studied to apply a 57Co Mssbauer source. The diffusion depth from surface to matrix of Co is depended on the annealing temperature and time. The deposited Co atoms diffuse completely into a rhodium (Rh) matrix without substantial loss at an annealing temperature of 1200 for 4 hours.

본 논문에서는 굽힘하중이 가해지는 스마트 복합재 적층판의 자유단에서 발생하는 박리응력을 압전 작동기를 이용해서 감소시키는 방법을 응력함수를 이용해 해석하는 방법을 제안하였다. 전기-기계 연성에 의해 나타나는 지배방정식은 최소 보족일의 원리를 이용해 구하였다. 응력상태는 일반적인 고유치 해석과정을 통해 구하였다. 스마트 복합재 적층판의 자유단 박리응력은 압전 작동기를 이용해 감소시킬 수 있었다. cross-ply 복합재 적층판의 박리응력 감소가 angle-ply 복합재 적층판 보다 크게 나타났다.

In order to prepare anode materials for high power lithium ion secondary batteries, carbon composites were fabricated with a mixture of petroleum pitch and coke (PC) and a mixture of petroleum pitch, coke, and natural graphite (PCNG). Although natural graphite has a good reversible capacity, it has disadvantages of a sharp decrease in capacity during high rate charging and potential plateaus. This may cause difficulties in perceiving the capacity variations as a function of electrical potential. The coke anodes have advantages without potential plateaus and a high rate capability, but they have a low reversible capacity. With PC anode composites, the petroleum pitch/cokes mixture at 1:4 with heat treatment at 1000 oC (PC14-1000C) showed relatively high electrochemical properties. With PC-NG anode composites, the proper graphite contents were determined at 10~30 wt.%. The composites with a given content of natural graphite and remaining content of various petroleum pitch/cokes mixtures at 1:4~4:1 mass ratios were heated at 800~1200 oC. By increasing the content of petroleum pitch, reversible capacity increased, but a high rate capability decreased. For a given composition of carbonaceous composite, the discharge rate capability improved but the reversible capacity decreased with an increase in heat treatment temperature. The carbonaceous composites fabricated with a mixture of 30 wt.% natural graphite and 70 wt.% petroleum pitch/cokes mixture at 1:4 mass ratio and heat treated at 1000 oC showed relatively high electrochemical properties, of which the reversible capacity, initial efficiency, discharge rate capability (retention of discharge capacity in 10 C/0.2 C), and charge capacity at 5 C were 330 mAh/g, 79 %, 80 %, and 60 mAh/g, respectively.

Ceramics biomaterials are useful as implant materials in orthopedic surgery. In this study, porous HA(hydroxyapatite)/β-TCP(tricalcium phosphate) composite biomaterials were successfully fabricated using HA/β-TCP powders with 10-30 wt% NH4HCO3 as a space holder(SH) and TiH2 as a foaming agent, and MgO powder as a binder. The HA/β-TCP powders were consolidated by spark plasma sintering(SPS) process at 1000 oC under 20 MPa conditions. The effect of SH content on the pore size and distribution of the HA/β-TCP composite was observed by scanning electron microscopy(SEM) and a microfocus X-ray computer tomography system(SMX-225CT). These microstructure observations revealed that the volume fraction of the pores increased with increasing SH content. The pore size of the HA/β-TCP composites is about 400-500 μm. The relative density of the porous HA/β-TCP composite increased with decreasing SH content. The porous HA/β-TCP composite fabricated with 30%SH exhibited an elastic modulus similar to that of cortical bone; however, the compression strength of this composite is higher than that of cortical bone.

본 논문에서는 복합재 구조물에 손상이 있을 경우, 손상에 의해 변화된 구조물의 동적특성을 손상이 없는 상태로 회복하여, 전체 시스템의 안정성을 유지할 수 있도록 하였다. 층간 분리가 있는 구조물의 유한요소모델 구축을 위하여 향상된 층간 변위장 모델을 적용하였으며, 유한요소해석을 진행하여 구조물의 고유 진동수와 모드 형상을 관찰하였다. 능동제어 알고리즘과 압전 작동기를 적용하여 구조물의 진동 응답특성을 확인하였으며, 이를 바탕으로 손상된 구조물의 동적특성을 손상이 없는 상태로 회복할 수 있음을 확인하였다.

Process conditions for the impregnation of polycarbosilane preceramic polymer into SiC-based composites were investigated. Two kinds of preceramic polymer (PCP) was impregnated into SiC-fiber fabrics with different solvents of n-hexane and divinylbenzene (DVB). Both microstructural observations and mechanical tests were conducted to evaluate the impregnation. The matrix phases were particulated in the case of hexane solvents. Apparent relative density of the matrix was about 78.8%. The density of matrix was increased to about 96.1-98.8% when the DVB was used; however, brittle fracture was observed during a bending test. The modulus of toughness was less than 0.74J/m3. The fabric impregnated with a mixed PCP-dissolved solution showed intermediate characteristics with relative high density of filling (apparent density of ~96.1%) as well as proper bending behavior. The modulus of toughness was increased to about 5.31J/m3. The composites developed by changing the precursor and solvent suggested the possibility of fabricating SiCf/SiC composites without a fiber to matrix interphase coating.

강화재의 복잡한 배열로 인하여 복합재 구조에 대한 유한요소 모델링은 상당히 까다로운 문제가 될 수 있다. 본 논문에서는 복합재 구조에 대하여 효율적으로 주기 격자망을 생성시킬 수 있는 기법을 제안한다. 먼저 육면체 유한요소로 구성된 규칙적인 격자망을 준비하고, 이를 복합재 내의 강화재에 대한 표면 정보에 맞추어 깎아낸다. 강화재와 기지재 사이에서 깎여진 육면체 유한요소는 임의의 절점과 면을 가질 수 있는 다면체 유한요소에 해당한다. 일관된 알고리즘을 이용하여 육면체 유한요소를 깎아내기 때문에 강화재와 기지재 사이의 요소는 자동적으로 적합한 형태로 구성된다. 또한 대표체적영역 내에서 강화재의 주기성을 추가적으로 고려하면, 대표체적영역에 대한 각각의 주기 경계 쌍에서 절점과 요소의 형태가 모두 일치하는 주기 격자망을 효율적으로 생성시킬 수 있다. 그러므로 별도의 처리 없이 대표체적영역에 주기 경계조건을 부여할 수 있다. 수치예제에서는 본 논문에서 제안한 기법의 효용성을 검증한다.

In this paper, the response of graphite/epoxy laminated composite beams subjected to impact loads without damage, is studied by the use of the developed finite element program. The modified Hertzian contact law considered elasto-plastic process is used to calculate the dynamic responses between the impactor and laminated target. Numerical results are presented to demonstrate the effects on the histories of contact force, deflection, damage energy, strain and stress through the thickness due to stacking sequence. In view of the kinetic energy response, [0/30/0/-30]2S laminate is faster than that of other two laminates due to its flexural stiffness. In special, the distribution of stress through the thickness shows nearly linear despite its discontinuity of stacking sequences for dynamic analysis unlike static analysis in a laminated composites.

Silicon-carbon composite was prepared by the magnesiothermic reduction of mesoporous silica and subsequent impregnation with a carbon precursor. This was applied for use as an anode material for high-performance lithium-ion batteries. Well-ordered mesoporous silica(SBA-15) was employed as a starting material for the mesoporous silicon, and sucrose was used as a carbon source. It was found that complete removal of by-products (Mg2Si and Mg2SiO4) formed by side reactions of silica and magnesium during the magnesiothermic reduction, was a crucial factor for successful formation of mesoporous silicon. Successful formation of the silicon-carbon composite was well confirmed by appropriate characterization tools (e.g., N2 adsorption-desorption, small-angle X-ray scattering, X-ray diffraction, and thermogravimetric analyses). A lithium-ion battery was fabricated using the prepared silicon-carbon composite as the anode, and lithium foil as the counter-electrode. Electrochemical analysis revealed that the silicon-carbon composite showed better cycling stability than graphite, when used as the anode in the lithium-ion battery. This improvement could be due to the fact that carbon efficiently suppressed the change in volume of the silicon material caused by the charge-discharge cycle. This indicates that silicon-carbon composite, prepared via the magnesiothermic reduction and impregnation methods, could be an efficient anode material for lithium ion batteries.

This paper shows the feasibility on the application of E-glass fiber/epoxy(GFRP) composite materials to an automotive leaf spring. In order to keep much lighter weight by replacing the steel with the composite material, it is important to optimize the material parameters and design variables consisting of the structure. This paper focused on the effects of material compositions and its fiber orientations for estimating the static behaviors of leaf spring. First of all, basic material properties of GFRP composite were measured by five types of coupon specimens from ASTM standard test. The reverse implementation was also done to obtain the complete set of in-situ fiber and matrix properties from ply test results. Finally, the static spring rates was examined for the variation of thickness and material parameters such as fiber angles and resin contents of composite leaf spring.

본 논문에서는 탄소 섬유 강화 플라스틱 샌드위치 복합재료의 시뮬레이션 해석을 통해 기계적 충격특 성에 대해 연구를 하였다. 스트라이커에 30 J, 60 J, 100 J의 충격에너지를 부여하여 고정 된 시험편에 충격을 가했다. 시뮬레이션 해석 방법은 ANSYS를 이용하여 실제와 같은 경계조건을 주며 유한요소해 석을 진행하였다. 그 결과는 100J의 충격에 에너지를 가해졌을 때 스트라이커가 시험편을 완전히 관통하는 모습이 보이고 충격에너지 30J과 60J일 때는 스트라이커가 시험편을 관통하지 않았다. 본 연구의 결과로 탄소 섬유 강화 플라스틱과 알루미늄 폼으로 조립한 복합재료의 구조적 안전성을 예측과 구조적 안전성이 높이는 사료가 된다.

복합재료 사이에 주파수 선택적 투과막(Frequency Selective Surface)을 삽입하여 동시경화 공정을 이용하여 주파수 선택적 투과 기능을 가지는 하이브리드 복합재료를 성형하면 재료들 간의 열팽창 계수와 강성의 차이로 인해 구조 내에 잔류 열응력이 발생하게 되고, 이로 인하여 스프링 백 현상이 발생한다. 따라서 복합재의 적층에 따른 영향을 알아보기 위해 복합재료의 적층각을 선택적 투과막(Frequency Selective Surface)을 중심으로 대칭과 비대칭 적층으로 적용하여 하이브리드 구조의 잔류 열응력을 예측하고, 이에 대한 스프링 백에 대해서 연구하였다.

본 연구에서는 탄소나노튜브와 폴리프로필렌 기지 간 계면결합력과 나노튜브의 국부적 응집에 따른 나노복합재의 탄소성거동 변화에 대한 파라메트릭 연구를 수행한다. 나노복합재의 탄소성 거동 예측을 위해 분자동역학 전산모사를 수행하고, 분자동역학 결과와 Mori-Tanaka 모델을 적용한 비선형 미시역학 모델을 연계하여 나노복합재 내 흡착계면의 탄소성 거동을 역으로 도출하는 2단계 영역분할 기법을 적용하였다. 미시역학 모델에서는 시컨트 계수방법을 Mori-Tanaka 모델에 적용하여 나노복합재의 비선형 거동을 예측하는 방법을 적용하였으며, 나노튜브와 기지 간 재료계면의 불완전 결합을 고려하기 위해 변위 불연속 조건을 적용하였다. 흡착영역을 고려한 미시역학 모델을 통해 흡착계면의 유무 및 재료계면 결합력 변화 그리고 나노튜브의 국부적 응집현상에 따른 나노복합재의 응력-변형률 관계를 예측하였다. 그 결과 나노튜브의 국부적 응집이나노복합재의 강화효과를 저하시키는 가장 중요한 변수임을 확인하였다.

In this study, carbon/epoxy composite DCB(double cantilever beam) specimens based on K-means clustering and wavelet transform analyses are presented. For the fracture Mode I, the fiber orientation θ = [0 ]24 and θ = [±45]12 both shown up stable crack growth in DCB testing. For the fiber orientation θ = [0 ]24 , the continuous type AE signal showed at central frequency 130～270kHz, which means that matrix micro cracking was occurred. The Burst type AE signal was occurred at central frequency 200～300kHz due to fiber bridging and fiber breaking. Other burst type AE signals were occurred at central frequency 130～180kHz with very high amplitude due to fiber bridging. For the fiber orientation θ = [±45]12 , the burst type signal showed at central frequency 220～300kHz, which means that fiber breaking was occurred. Mixed type of burst and continuous signals were captured at central frequency 250～480kHz due to fiber friction.

Magnetic and dielectric properties of rubber composites are controlled by using two kinds of high-permeability metal particles with different electrical conductivity (Sendust, Permalloy), and their effect on microwave absorbance has been investigated, focusing on the quasi-microwave frequency band (0.8-2 GHz). Noise absorbing sheets are composite materials of magnetic flake particles of high aspect ratio dispersed in polymer matrix with various filler amount of 80-90 wt.%. The frequency dispersion and magnitude of complex permeability is almost the same for Sendust and Permalloy composite specimens. However, the complex permittivity of the Permalloy composite (, ) is much greater than that of Sendust composite (, ). Due to the large dielectric permittivity of Permalloy composite, the absorbing band is shifted to lower frequency region. However, the investigation of impedance matching reveals that the magnetic permeability is still small to satisfy the zero-reflected condition at the quasi-microwave frequency band, resulting in a small microwave absorbance lower than 10 dB.

The Ti-6Al-4V extra low interstitial (ELI) alloy has been widely used as an orthopedic implant material because of its excellent mechanical properties and biocompatibility. However, it still has many problems, including a high elastic modulus and toxicity of the Al and V elements. Therefore, non-toxic biomaterials with a low elastic modulus need to be developed. A high energy mechanical milling (HEMM) process is introduced to improve the effect of sintering. Rapid sintering of spark plasma sintering (SPS) under pressure was used to make an ultra fine grain of Ti-25 wt.%Nb-7 wt.%Zr-10 wt.%Mo-(10 wt.%CPP) composites with bio-attractive elements for increasing strength. These composites were fabricated by SPS at 1000˚C at 60 MPa using HEMM powders. During the sintering process, CaTiO3, TixOy, and CaO were formed because of the reaction between Ti and CPP. The effects of CPP content on the physical and mechanical properties of the sintered Ti-Nb-Zr-Mo-CPP composites were investigated. The biocompatibility and corrosion resistance of the Ti-Nb-Zr-Mo alloys were improved by the addition of CPP.

This study aims to analyze the structural behavior on TDCB models bonded adhesively with aluminum foam composite. These simulation models are designed on the basis of British industrial and ISO standards. The variable of configuration factor(m) is set up to investigate the fracture toughness of bonded joint due to the volume of material. Equivalent stress, deformation energy, pressure at bonded part, reaction force-crack length, energy release rate-crack length are obtained by this analysis. Through the data of this study, the fracture behavior can be analyzed by applying the practical composite structure bonded with aluminum foam and the mechanical property can be understood.

The study of grinding behavior characteristics on aluminum powders and carbon nano tubes (CNTs) has recently gained scientific interest due to their useful effect in enhancing advanced nano materials and components, which significantly improves the property of new mechatronics integrated materials and components. We performed a series of dry grinding experiments using a planetary ball mill to systematically investigate the grinding behavior during Al/CNTs nano composite fabrication. This study focused on a comparative study of the various experimental conditions at several variations of rotation speeds, grinding time and with and without CNTs. The results were monitored for the particle size distribution, median diameter, crystal structure from XRD pattern and particle morphology at a given grinding time. It was observed that pure aluminum powders agglomerated with low rotation speed and completely enhanced powder agglomeration. However, Al/CNTs composites were achieved at maximum experiment conditions (350 rpm, 60 min.) of this study by a mechanical alloy process for Al/CNTs mixed powders because the grinding behavior of Al/CNTs composite powder was affected by addition of CNTs. Indeed, the powder morphology and crystal size of the composite powders changed more by an increase of grinding time and rotation speed.

A bulk metallic glass-forming alloy, metallic glass powders was used for good commercial availability and good formability in supercooled liquid region. In this study, the Ni-based metallic glass was synthesized using by high pressure gas atomized metallic glass powders. In order to create a bulk metallic glass sample, the metallic glass powders with ball-milled Ni-based amorphous powder with 40%vol brass powder and Cu powder for 20 hours. The composite specimens were prepared by Spark Plasma Sintering for the precursor. The SPS was performed at supercooled liquid region of Ni-based metallic glass. The amorphous structure of the final sample was characterized by SEM, X-ray diffraction and DSC analysis.