Cemented carbide for cutting tools, which is composed of carbide as a hard phase and metallic component as a metallic phase, mainly uses cobalt as the metallic phase due to the excellent mechanical properties of cobalt. However, as the demand for machining difficult-to-machine materials such as titanium and carbon fiber-reinforced plastics has recently increased, the development of high-hardness cemented carbide is necessary and the replacement of cobalt metal with a high-hardness alloy is required. In this study, we would like to introduce high-hardness cemented carbide fabricated using nickel-tungsten alloy as the metallic phase. First, nickel-tungsten alloy powder of the composition for formation of intermetallic compound confirmed through thermodynamic calculations was synthesized, and cemented carbide was prepared through the sintering process of tungsten carbide and the synthesized alloy powder. Through evaluating the mechanical properties of high-hardness cemented carbide with the nickel-tungsten alloy binder, the possibility of producing high-hardness cemented carbide by using the alloys with high-hardness was confirmed.

Molten salt reactors represent a promising advancement in nuclear technology due to their potential for enhanced safety, higher efficiency, and reduced nuclear waste. However, the development of structural materials that can survive under severe corrosion environments is crucial. In the present work, pure Ni was deposited on the surface of 316H stainless steel using a directed energy deposition (DED) process. This study aimed to fabricate pure Ni alloy layers on an STS316H alloy substrate. It was observed that low laser power during the deposition of pure Ni on the STS316H substrate could induce stacking defects such as surface irregularities and internal voids, which were confirmed through photographic and SEM analyses. Additionally, the diffusion of Fe and Cr elements from the STS316H substrate into the Ni layers was observed to decrease with increasing Ni deposition height. Analysis of the composition of Cr and Fe components within the Ni deposition structures allows for the prediction of properties such as the corrosion resistance of Ni.

With the increasing demand for electronic products, the amount of multilayer ceramic capacitor (MLCC) waste has also increased. Recycling technology has recently gained attention because it can simultaneously address raw material supply and waste disposal issues. However, research on recovering valuable metals from MLCCs and converting the recovered metals into high-value-added materials remains insufficient. Herein, we describe an electrospinning (E-spinning) process to recover nickel from MLCCs and modulate the morphology of the recovered nickel oxide particles. The nickel oxalate powder was recovered using organic acid leaching and precipitation. Nickel oxide nanoparticles were prepared via heat treatment and ultrasonic milling. A mixture of nickel oxide particles and polyvinylpyrrolidone (PVP) was used as the E-spinning solution. A PVP/NiO nanowire composite was fabricated via Espinning, and a nickel oxide nanowire with a network structure was manufactured through calcination. The nanowire diameters and morphologies are discussed based on the nickel oxide content in the E-spinning solution.

Transition metal chalcogenides are promising cathode materials for next-generation battery systems, particularly sodium-ion batteries. Ni3Co6S8-pitch-derived carbon composite microspheres with a yolk-shell structure (Ni3Co6S8@C-YS) were synthesized through a three-step process: spray pyrolysis, pitch coating, and post-heat treatment process. Ni3Co6S8@C-YS exhibited an impressive reversible capacity of 525.2 mA h g-1 at a current density of 0.5 A g-1 over 50 cycles when employed as an anode material for sodium-ion batteries. However, Ni3Co6S8 yolk shell nanopowder (Ni3Co6S8-YS) without pitch-derived carbon demonstrated a continuous decrease in capacity during charging and discharging. The superior sodium-ion storage properties of Ni3Co6S8@C-YS were attributed to the pitchderived carbon, which effectively adjusted the size and distribution of nanocrystals. The carbon-coated yolk-shell microspheres proposed here hold potential for various metal chalcogenide compounds and can be applied to various fields, including the energy storage field.

본 연구는 에너지 저장 응용을 위한 PVI-PGMA/LiTFSI 고분자 막 전해질 및 CxNy-C 유연 전극의 합성 및 특성 에 관한 연구이다. 이중 기능을 갖는 PVI-PGMA 공중합체는 우수한 이온 전도성을 나타내었으며, PVI-GMA73/LiTFSI200 막 전해질은 1.0 × 10-3 S cm-1의 최고 전도도를 달성하였다. CxNy-C 전극의 전기화학적 성능을 체계적으로 분석하였으며, C3N2-C는 나노와이어와 다면체로 구성된 높은 연결성을 갖는 하이브리드 구조와 이중 Co/Ni 산화물을 포함하여 풍부한 산 화환원 활성 부위와 이온 확산을 용이하게 하는 특징으로 인해 958 F g-1의 최고용량 및 최소한의 전하 전달 저항(Rct)을 달성 하였다. 흑연 탄소 껍질의 존재는 충전-방전 동안 높은 전기화학적 안정성에 기여하였다. 이러한 결과들은 고성능 에너지 저 장 장치인 슈퍼커패시터 및 리튬 이온 전지와 같은 첨단 에너지 저장 장비에 PVI-PGMA/LiTFSI 고분자 막 전해질과 CxNy-C 전극을 활용하는 잠재력을 보여주었으며, 지속 가능하고 고성능의 에너지 저장 기술을 더욱 발전시키는 길을 열어가 고 있다.

High-temperature oxidation of a Ni-based superalloy was analyzed with samples taken from gas turbine blades, where the samples were heat-treated and thermally exposed. The effect of Cr/Ti/Al elements in the alloy on high temperature oxidation was investigated using an optical microscope, SEM/EDS, and TEM. A high-Cr/high-Ti oxide layer was formed on the blade surface under the heat-treated state considered to be the initial stage of high-temperature oxidation. In addition, a PFZ (γ’ precipitate free zone) accompanied by Cr carbide of Cr23C6 and high Cr-Co phase as a kind of TCP precipitation was formed under the surface layer. Pits of several μm depth containing high-Al content oxide was observed at the boundary between the oxide layer and PFZ. However, high temperature oxidation formed on the thermally exposed blade surface consisted of the following steps: ① Ti-oxide formation in the center of the oxide layer, ② Cr-oxide formation surrounding the inner oxide layer, and ③ Al-oxide formation in the pits directly under the Cr oxide layer. It is estimated that the Cr content of Ni-based superalloys improves the oxidation resistance of the alloy by forming dense oxide layer, but produced the σ or μ phase of TCP precipitation with the high-Cr component resulting in material brittleness.

In order to apply to high-nickel cathodes for high-capacity and stability enhancement of lithium-ion batteries, the characteristics of the coating film were reviewed using the conventional nickel plating method. The surface morphology of the plating layer and the measurement of the surface roughness were analyzed according to scan size and rate using the contact mode of Atomic Force Microscopy. The hydrogen ion concentration (pH) of the electrolyte played an important role in shaping the metal ion plating. As the overpotential of the surface increased during plating, the crystals grew in a direction other than the main crystal growth direction. The increase in on-time during pulse plating appears to result in coarse particles as much of the applied current is consumed by the reduction of hydrogen ions, resulting in lower current efficiency. From the AFM image, it was confirmed that the blackening of the plated film was due to a partial overvoltage phenomenon during electrolytic degreasing. In order to be used as a high-nickel cathode, it seems that the current must be uniformly distributed on the surface of the substrate during plating.

본 실험은 붕어(Crucian carp, Carassius carassius)(무게 39.7±3.1 g, 전장 14.8±0.5 cm)의 수인 성 니켈 0, 10, 20, 40, 80 및 160 mg Ni2+/l 농도로 96시간 급성 노출을 실시하였다. 수인성 니 켈에 노출된 붕어의 반수치사농도(LC50)는 117.69 mg Ni2+/l으로 나타났다. 혈액학적 성상에서 RBC count는 수인성 니켈 96시간 급성 노출 중 48시간에서 유의적으로 증가한 반면, 96시간에 서 유의적 감소가 나타났다. MCV와 MCH는 96시간에서 80 mg Ni2+/l 농도에서 유의적으로 증 가했다. Calcium, magnesium, glucose, cholesterol, total protein, AST, ALT 및 ALP 와 같은 혈장 성분은 수인성 니켈 노출에 의해 유의적 변화가 나타났다. 이 연구의 결과는 수인성 니켈 노출 에 따른 붕어의 생존율, 혈액학적 성상 및 혈장 성분의 변화를 확인하고 이는 수인성 니켈의 독성에 의한 것으로 판단했다.

Due to environmental pollution, regulations on fossil fuels are required. There is a movement for the regulations by using LNG fueled propulsion ships. LNG is an eco-friendly fuel that does not emit NOx or SOx during combustion, but its boiling point is -163°C. Under that condition, the use of metal is restricted, and IMO defined applicable materials through IGC code. Among the metals, 9% nickel steel is one of excellent mechanical properties such as yield strength and tensile strength in cryogenic condition. Thus 9% nickel steel is widely used in cryogenic storage containers for ships. In addition, laser welding, which minimizes thermoelastic distortion by applying a concentrated heat source to a narrow area for a short period of time, is in the spotlight. So, this study is a basic research to predict and respond to thermal distortion during laser welding. Secondary version of the representative heat source model was derived through the author's previous research with STS304L, and the heat source model was derived by applying the heat source model to 9% nickel steel in this study. 9% nickel steel is a material that is in high demand and is widely used in the manufacture of cryogenic containers, so this study is expected to be able to respond immediately to the field.

9% nickel steel has remarkable mechanical properties in a cryogenic condition and is widely used in storage containers for LNG fueled ships. Demand for laser welding rather than conventional arc welding has grown to increase manufacturing efficiency. However there are various types of heat sources which are suggested by other researchers. With that, it is difficult to select a proper heat source shape for welding conditions. The author proposed a representative heat source model that can cover most of suggested heat source models through previous studies. Welding power was fixed at 4kW and the speed was changed to 1.0m/min, 1.5m/min, and 2.0m/min respectively. The shapes of the welding heat sources were derived, and the tendency of the main parameters was also deducted. It was observed that the width and depth of the weld bead decreased as the welding speed increased through welding experiment, parameters of welding heat source are changed linearly. Based on this study, it is expected that it will be possible to estimate the shape of the heat source under untested welding conditions.

The lattice oxygen mechanism (LOM) is considered one of the promising approaches to overcome the sluggish oxygen evolution reaction (OER), bypassing -OOH* coordination with a high energetic barrier. Activated lattice oxygen can participate in the OER as a reactant and enables O*-O* coupling for direct O2 formation. However, such reaction kinetics inevitably include the generation of oxygen vacancies, which leads to structural degradation, and eventually shortens the lifetime of catalysts. Here, we demonstrate that Se incorporation significantly enhances OER performance and the stability of NiFe (oxy)hydroxide (NiFe) which follows the LOM pathway. In Se introduced NiFe (NiFeSe), Se forms not only metal-Se bonding but also Se-oxygen bonding by replacing oxygen sites and metal sites, respectively. As a result, transition metals show reduced valence states while oxygen shows less reduced valence states (O-/O2 2-) which is a clear evidence of lattice oxygen activation. By virtue of its electronic structure modulation, NiFeSe shows enhanced OER activity and long-term stability with robust active lattice oxygen compared to NiFe.

Due to the environmental regulations of the International Maritime Organization (IMO), the number of ships using cryogenic fuel such as LNG (liquefied natural gas) is increasing rapidly, and the demand for eco-friendly ships is expected to grow further in the future. The material of the tank for storing cryogenic fuel such as LNG is limited within the IGC Code, and available materials include 9% nickel steel, Invar (36% nickel steel), Al5083-0, STS304L, and high manganese steel. Recently, 9% nickel steel has been used as a tank in LNG fuel-powered ship projects, and it has excellent thermal/mechanical properties in cryogenic LNG environmental conditions (-163°C). In this study, it is conducted an experimental study on SAW(Submerged Arc welding), which has better welding efficiency than FCAW(Flux Cored Arc Welding), which is mainly used for 9% nickel steel materials. In addition, to verify the reliability of the welded part after the welding test, cross-sectional observation of the welded part was performed and the mechanical properties such as the tensile strength and cryogenic impact strength of the welded part were evaluated.

The capacity of high nickel Li(NixCoyMn1-x-y)O2 (NCM, x ≥ 0.8) cathodes is known to rapidly decline, a serious problem that needs to be solved in a timely manner. It was reported that cathode materials with the {010} plane exposed toward the outside, i.e., a radial structure, can provide facile Li+ diffusion paths and stress buffer during repeated cycles. In addition, cathodes with a core-shell composition gradient are of great interest. For example, a stable surface structure can be achieved using relatively low nickel content on the surface. In this study, precursors of the high-nickel NCM were synthesized by coprecipitation in ambient atmosphere. Then, a transition metal solution for coprecipitation was replaced with a low nickel content and the coprecipitation reaction proceeded for the desired time. The electrochemical analysis of the core-shell cathode showed a capacity retention of 94 % after 100 cycles, compared to the initial discharge capacity of 184.74 mA h/g. The rate capability test also confirmed that the core-shell cathode had enhanced kinetics during charging and discharging at 1 A/g.

Recently, due to high theoretical capacitance and excellent ion diffusion rate caused by the 2D layered crystal structure, transition metal hydroxides (TMHs) have generated considerable attention as active materials in supercapacitors (or electrochemical capacitors). However, TMHs should be designed using morphological or structural modification if they are to be used as active materials in supercapacitors, because they have insulation properties that induce low charge transfer rate. This study aims to modify the morphological structure for high cycling stability and fast charge storage kinetics of TMHs through the use of nickel cobalt hydroxide [NiCo(OH)2] decorated on nickel foam. Among the samples used, needle-like NiCo(OH)2 decorated on nickel foam offers a high specific capacitance (1110.9 F/g at current density of 0.5 A/g) with good rate capability (1110.9 - 746.7 F/g at current densities of 0.5 - 10.0 A/g). Moreover, at a high current density (10.0 A/g), a remarkable capacitance (713.8 F/g) and capacitance retention of 95.6% after 5000 cycles are noted. These results are attributed to high charge storage sites of needle-like NiCo(OH)2 and uniformly grown NiCo(OH)2 on nickel foam surface.

Due to environmental pollution, regulations on existing petroleum-based fuels are increasing day by day. LNG is in the spotlight as an eco-friendly fuel that does not emit NOx or SOx, but its boiling point is -163°C, so it needs to be handled with care. Materials that can be used at the above temperature are defined by IMO through the IGC Code. Among them, 9% nickel steel has great advantages in yield strength and tensile strength under cryogenic conditions, but it is difficult to use in arc welding such as FCAW for various reasons. This study is a study to apply fiber laser welding to solve this problem. As a previous study, this study conducted a study to find a welding heat source. After performing bead on plate welding, the optimal heat source was derived by analyzing the shape of the bead and adjusting the parameters of the heat source model. In this case, by applying the multi-island genetic algorithm, which is a global optimization algorithm, not the intuition of the researcher, accurate results could be derived in a wide range.

Due to stricter environmental regulations of the International Maritime Organization(IMO), the number of ships fueled by Liquefied Natural Gas(LNG) is rapidly increasing. The International Code of the Construction and Equipment of Ships Carrying Liquefied Gases in Bulk(IGC Code) limits the material of tanks that can store cryogenic substances such as LNG. Among the materials listed in the IGC Code, ASTM A553M-17 has been recently adopted as a material for LNG fuel tank projects because of its excellent mechanical properties at cryogenic temperatures. In shipyards, this material is being used to build tanks through Flux Cored Arc Welding (FCAW). However, there is a problem that magnetization occurs during welding and there is a big difference in welding quality depending on the welding position. In order to overcome this problem, this study intends to conduct basic research to apply laser welding to ASTM A553M-17 material. In this study, a study on penetration (HAZ depth, Penetration) and welding defects during fiber laser welding according to three types of shielding gases(nitrogen, argon, and helium) was conducted. To this end, a Bead on plate(BOP) experiment was performed under four fiber laser conditions(Power, Speed) for each shielding gas and welding defects caused by the use of the shielding gas were compared through cross-sectional observation, and the penetration depth was analyzed.

Because of the International Maritime Organization(IMO)'s regulation to regulate emissions of ships, a change is taking place to replace ship fuels from Heavy Fule Oil(HFO) to Liquefied Natural Gas(LNG). In the case of LNG, it is a material obtained by liquefying Natural Gas(NG), and it is -163 degrees below zero, and the volume is reduced to 1/600 level. The material of the tank that can store LNG must be a material that can safely store LNG in a cryogenic environment, and the materials of the tank that can store LNG are limited in the International Code of the Construction and Equipment of Ships Carrying Liquefied Gases in Bulk(IGC Code). Among the materials listed in the IGC Code, 9% nickel steel is used as a material for LNG fuel propulsion tanks that are recently ordered because of relatively high mechanical properties under cryogenic environments. In this study, the mechanical properties of butt welds were measured following the weld reliability evaluation of Flux Cored Arc Welding(FCAW) butt welds made of 9% nickel steel by PARTI. The measured mechanical properties are tensile strength, bending strength, hardness, and cryogenic impact test required by the classification for Welding Procedure Specification(WPS) approval.

Because of the International Maritime Organization(IMO)'s regulation to regulate emissions of ships, a change is taking place to replace ship fuels from Heavy Fule Oil(HFO) to Liquefied Natural Gas(LNG). In the case of LNG, it is a material obtained by liquefying Natural Gas(NG), and it is -163 degrees below zero, and the volume is reduced to 1/600 level. The material of the tank that can store LNG must be a material that can safely store LNG in a cryogenic environment, and the materials of the tank that can store LNG are limited in the International Code of the Construction and Equipment of Ships Carrying Liquefied Gases in Bulk(IGC Code). Among the materials listed in the IGC Code, 9% nickel steel is used as a material for LNG fuel propulsion tanks that are recently ordered because of relatively high mechanical properties under cryogenic environments. In this study, butt welding was performed on a 9% nickel steel material using Flux Cored Arc Welding(FCAW), the most widely used welding method in shipyards. In PARTI, after securing the welding conditions, cross-sectional observation results analysis, liquid penetrating test, and radiographic test were performed to verify the reliability of the weld.