연구에서 나노 알루미나와 마그네지아의 첨가에 의한 304 스테인레스 스틸에 170 ℃ 2시간 열 경화시켰다. 레이저유도 분광학에 의한 코팅된 시료를 전하결합 장치와 SEM을 활용한 장치를 설계 하여 시험 측정하였다. 이 결과 나노 알루미나와 마그네지아가 함유된 세라믹 코팅이 나노 무기화합물이 함유되지 않은 시료보다 부착성, 내스크래치성이 우수하였으며, 또한 산용액속에서 시료의 질량감소의 변화가 매우 작았다. 그리하여 본 연구는 304 스테인레스 스틸의 내부식성을 개선하기 위해 시료가 코 팅되었으며, 분석공정이 설계되어 고분해능 CCD와 함께 분석되었다. 요즈음, 스테인레스 스틸의 코팅은 산업에 특이응용이 발전됨에 따라 위생학, 우주항공, 기기장치, 관측 등의 분야 등에 산업적 요구가 증 가되고 있다.

Chrysene 및 Pyrene 유도체를 합성하였고, 열적 안정성은 phenanthrene기를 도입한 BC6이 mp: 406oC 이었다. 용액상태에서 Host-Dopant 시스템으로 각각의 분광특성을 측정하여 NP5-BC1, NP5-BC5 system이 우수한 결과를 얻을 수 있었고, 이들의 밴드갭은 3.04, 2.66, 2.67eV 이었다.

In this study, optical emission spectroscopy was used to monitor the plasma produced during the RF magnetron sputtering of a BaTiO3 target. The intensities of chemical species were measured by real time monitoring with various discharge parameters such as RF power, pressure, and discharge gas. The emission lines of elemental and ionized species from BaTiO3 and Ti targets were analyzed to evaluate the film composition and the optimized growth conditions for BaTiO3 films. The emissions from Ar(I, II), Ba(I, II) and Ti(I) were found during sputtering of the BaTiO3 target in Ar atmosphere. With increasing RF power, all the line intensities increased because the electron density increased with increasing RF power. When the Ar pressure increased, the Ba(II) and Ti(I) line intensity increased, but the Ar+ line intensity decreased with increasing pressure. This result shows that high pressure is of greater benefit for the ionization of Ba than for that of Ar. Oxygen depressed the intensity of the plasma more than Ar did. When the Ar/O2 ratio decreased, the intensity of Ba decreased more sharply than that of Ti. This result indicates that the plasma composition strongly depends on the discharge gas atmosphere. When the oxygen increased, the Ba/Ti ratio and the thickness of the films decreased. The emission spectra showed consistent variation with applied power to the Ti target during co-sputtering of the BaTiO3 and Ti targets. The co-sputtered films showed a Ba/Ti ratio of 1.05 to 0.73 with applied power to the Ti target. The films with different Ba/Ti ratios showed changes in grain size. Ti excess films annealed at 600˚C did not show the second phase such as BaTi2O5 and TiO2.

The compound of 2,6-Bis[(9-phenylcarbazolyl)ethenyl]naphthalene (BPCEN-1), 2-[6-1-Cyano-2-(9-phenylcarbazoly)vinylnaphthyl]-3-(9-phenylcarbazolyl)acrylonitrile (BPCEN-2), 2,6-Bis[4-(1-naphthy l)phenylamino styrenyl] naphthalene (BNPASN-1), 2-[6-1-Cyano-2-(naphthylphenylaminophenyl) vinylnaphthyl]-3-(naphthylphenylaminophenyl)acrylonitrile (BNPASN-2) was analyzed electrochemically and spectroscopically and can be obtained by bonding phenylcarbazolyl, naphthylphenylaminophenyl and -CN ligands to 2,7-naphthalene. The electrochemical and spectroscopic study resulted in the P-type (BPCEN-1, BNPASN-1) being changed to N-type (BPCEN-2, BNPASN-2) according to -CN bonding despite having the same structure. The value of band gap(Eg) was revealed to be small as HOMO had shifted higher and LUMO lower. The Eg value for naphthylphenylaminophenyl ligand was reduced because it has a smaller HOMO/LUMO value than that of phenylcarbazolyl from a structural perspective. The electrochemical HOMO/LUMO values for BPCEN-1, BPCEN-2, BNPASN-1, BNPASN-2 were measured to be 5.55eV / 2.83eV, 5.73eV / 3.06eV, 5.48eV / 2.78eV, and 5.53eV / 2.98eV, respectively. By -CN ligand, the UV max, Eg and PL max were shifted to longer wavelength in their spectra and the luminescence band could be also confirmed to be broad in the photoluminescence (PL) spectrum.

The benzophenone derivatives(4-CH3O-4'-NO2 and 3,4'-di-NO2) are synthesized by the Fridel-Craft acylation and the nitration method. Electrochemical redox potentials of the benzophenone derivatives (4-CH3O, H, 3-Cl, 3-NO2, 4-NO2, 4-CH3O-4'-NO2, 3,4'-di-NO2) are measured by using cyclic voltammometry. In the relationship of summing Hammett value and redox potential, we find a proportional constant(σ) that shows a good relation with an electrochemical property and a reactivity of the benzophenone derivatives. The benzophenone substituted with the electron donating groups(4-OCH3 and 4-OCH3-4'-NO2) are higher the energy in the LUMO level, then increasing a band-gap energy(Eg), their Egs are obtained as a 3.94 eV and 3.59 eV, respectively.

Symbiotic stars are known as binary systems with both cool and hot components with enshrounding nebulous gas. The cool component, M-type giant, is presumably loosing its mass into a hot white or main sequence companion star through the inner Lagrangian point. The lines emit from the ionized nebulous region around the hot star while the mass loss or accretion activity is believed to be the main cause of sudden variation of the continuum and line fluxes. We selected 17 symbiotics for which the emission line fluxes were measured from the IUE SWP, LWR data, to find variability of spectrum. We also investigated the periodic variation of emissions or eclipsing effect from the IUE lines. All of our symbiotics show very high electron densities in the emission regions. For other optical symbiotics, the observations had been carried in 1999 with BOAO mid-resolution spectrometer. We classified symbiotics based on their outburst activities, or emission line characteristics, i.e., OVIλ6830.TheOVIλ6830 OVIλ6830.TheOVIλ6830 emission lines are also found in S-type symbiotics, which have been known as charateristics of D-types.

The purposes of spectroscopy in astronomy are to measure the radiation flux of the spectroscopic emission or absorption line and to measure the dynamical parameters of the line profile. In order to use an appropriate instrument for the scientific purpose, we need to understand the characteristics of various spectrometers, e.g., a prism spectrometer, a grating spectrometer, and a Fabry-Perot spectrometer (FPS), which are being used in ultra-violet, optical, and infrared bands. The Fabry­Perot spectrometer is not very popular compared to the grating spectrometer, because of its complex and tricky operations. The Fabry-Perot spectrometer, however, can get a two-dimensional image at one exposure, so we can study radiation mechanisms and dynamical properties of extended sources, e.g., clusters, nebula, and galaxies.

The symmetric benzoxazolo carbocyanine is of industrial importance as green-sensitizing dye in the spectral sensitization of emulsion microcrystals in positive paper and negative film-making. The stability on the solvents of benzoxazolo carbocyanine dye was measured by UV-Vis spectrophotometer, and then all of solvents were stabilized sensitizer. The maximum absorption peak range in methanol, acetonitrile, acetone, DMF, dichloromethane, chloroform solvents was 501nm~511nm. But it was identified that only methanol can be used to photographic emulsion. The photographic characteristics have contrast of 2.8, speed of 50-55(lux·sec)-1, fog of 0.07-0.08, respectively.

산화물 자성체 (F e2 O3)5(A l2 O3)4-x(G a2 O3)x)SiO계에 대한 결정구조 및 자기적 특성을 X-선 회절법과 Mossbauer분광법을 이용하여 연구하였다. Mossbauer분광법을 통해 Ga 이온의 치환량과 온도변화에 따른 자기구조의 변화를 조사하고 초전도 양자간섭장치 (SQUID)에 의한 거시적 자성정보와 비교하였다. X-선 회절법에 의한 결정구조는 Ga 이온의 치환량에 따라 입방정스피델 구조에서 사방정 구조로의 결정학적 전이가 관측되었으며 양이온 빈자리가 상당수 포함된 새로운 형태의 페라이트임을 알았다. 비자성 Ga 이온의 치환량 증가로 초상자성 군집체 (cluster)가 형성되어 치환전의 준강자성체 질서가 점차로 초상자성 군집체와 공존하는 초상자성체 특성을 보였다 x > 0.2 경우 상온이하 온도영역에서 Mossbauer 스펙트럼은 다양하고 복잡한 형태를 보이는데 이것은 초상자성 군집체의 동결에 의한 것으로 설명된다. 또한 SQUID 측정에서 나타난 50K 이하에서의 급격한 자화값의 감소는 스핀 canting의 효과로 설명된다.명된다.다.