PURPOSES : This study is conducted to evaluate the development of materials for extinguishing ESS(Energy Storage System) fires in electric vehicles using industrial byproducts. METHODS : Grout containing an appropriate amount of fly ash, silica fume, blast furnace slag powder, and ferronikel slag, which are industrial byproducts, was prepared. The fluidity, stress, and mechanical properties were evaluated in accordance with standard test methods. RESULTS : The fluidity of the materials used for the evolution of ESS fires differed depending on the material of the industrial byproducts. In the case of blast furnace slag, its fluidity is low owing to viscosity even when it content is high, and the use of ferronikelsrag is shown to be suitable for the evolution of ESS fires in fluidity and curing tests. CONCLUSIONS : Fire-extinguishing materials using industrial byproducts require a long curing time but exhibit the fluidity required for ESS fire extinguishment. In particular, the curing and fluidity of Peronikel slag and fly ash are suitable for ESS fire extinguishing.

This study addresses the environmental impact associated with waste management and natural aggregate production. It explores the potential of utilizing Coal Bottom Ash (CBA) and Reclaimed Asphalt Pavement Aggregate (RAPA) as complete replacements, respectively, for fine and coarse aggregates in concrete. Despite their similarities to natural aggregates, CBA and RAPA often end up in landfills. Laboratory tests were conducted, revealing satisfactory performance in drying shrinkage and air void parameters. However, while the flexural strength met design requirements, the compressive and splitting tensile strengths were lower than predicted. The deviation in strength development behavior from natural aggregate concrete (NAC) was attributed to weak agglomerated aggregates in RAPA and the large size of the interfacial transition zone (ITZ) due to the old asphalt coating surrounding RAPA. To enhance the strength behavior, two methods were employed: compaction in the form of roller-compacted concrete and RAPA abrasion carried out by rolling RAPA in a concrete mixer. Compaction improved aggregate interlock, while RAPA abrasion decreased agglomerated aggregates and minimized asphalt coating, reducing ITZ size. These treatments resulted in improvements in compressive, flexural, and splitting tensile strengths, with the combination of both treatments having the most significant effect. Analysis of relationships between flexural, splitting tensile, and compressive strengths indicated that CBA and RAPA concrete behaved more similarly to NAC after the treatments. This research suggests that with appropriate interventions, it is feasible to utilize CBA and RAPA in concrete, contributing to sustainable construction through improved waste management, carbon footprint reduction, and conservation of natural resources.

PURPOSES : In this study, high-viscosity grout for increasing ground stiffness is developed using industrial byproducts. METHODS : Based on literature review, the viscosity and viscosity expression time of domestic and foreign anti-washout admixture underwater were evaluated. In addition, grout was prepared by mixing 5% to 40% of fly ash (FA) in a standard mixture. Flow, setting time, and compressive strength tests were conducted to evaluate the quality of the grout. RESULTS : Experimental results show that the viscosity required is 35,000 to 40,000 cps, whereas the viscosity expression time required exceeds 300 min. As the amount of FA used for grouting increases, the physical and mechanical performances deteriorate. The strength of a test specimen manufactured underwater is lower than that of a test specimen manufactured under air, and the decrease on day 28 is lower than that on day 3. The FA applied to the grout should be less than 20%. CONCLUSIONS : Although industrial byproducts, which exhibit high viscosity, offer excellent mechanical performance and are thus suitable as a solidifying agent for strengthening grout, their application in the field must be evaluated.

PURPOSES : Recently, the generation of industrial by-products has been increased owing to the increase in electrical power consumption. This experimental study investigated a special mortar development using outstanding benefits of porous structures in heavy oil fly ash (HOFA) and bottom ash (BA) to reduce heat transfer and weight of tunnel repair mortar. METHODS : Based on the concept of materials usable for this objective being porous and light, the physical and chemical properties of heavy oil fly ash and bottom ash were analyzed to determine the application possibility for tunnel repair mortar. In addition to satisfying this primary requirement, the research aimed at determining the relationships between the characteristics of porous structures and effectiveness of reducing weight and thermal conductivity. This study was undertaken on the use of bottom ash as fine aggregate and heavy oil ash as filler in mortar mix proportion. Four different levels of bottom ash (25%, 50%, 75%, 100%, and 5%), and 10%, 15%, and 20% of heavy oil fly ash were investigated to determine the proper replacement amount within the designed specification. According to the analytic results on the effectiveness of both by-products and chemical additives, the repair mortar with optimum mixture proportion was investigated using various tests including thermal conductivity and porosity. RESULTS : The use of porous by-products increased the demand for mixing water in obtaining the required flowability, but the compressive strength did not decrease significantly in proportion by adding an amount of bottom ash. Based on the results, bottom ash can be replaced with aggregate as much as 50%, but adding an amount of heavy oil ash is suggested as below 10% in formulation. CONCLUSIONS : The optimized repair mortar, which was produced by conclusive formulation, was evaluated as a high-performance material to repair tunnels with the effectiveness of porous and remarkable physical properties.

알칼리성 산업부산물의 혼합에 따른 연안 오염퇴적물의 성상 변화를 평가하기 위해 해수 교환을 고려한 mesocosm 실험을 수행 하였다. 실험시작 1개월 후 실험구의 인산인 농도는 대조구 대비 간극수와 직상수에서 각각 19.0, 0.4 mg/L 낮게 검출되었다. 이는 GCA에서 용출된 칼슘이온과 인산인의 흡착반응을 통한 간극수 내의 인 고정 및 직상수로의 용출 억제에 따른 결과로 판단된다. 실험구의 간극수 내 황화수소 농도는 5.0 mg/L로 112.5 mg/L인 대조구에 비해 매우 낮게 나타났으며, 실험구 직상수의 DO 농도는 대조구에 비해 3.47 mg/L 높게 나타났다. 이상의 결과로부터 알칼리성 산업부산물인 GCA는 연안 오염퇴적물의 개선에 효과적인 재료임을 확인하였다.

Seaweed by-products have been dumped into the sea and induced marine pollution. However, they can be recycled as a valuable natural resources. Approximately 240,000 tons of sea mustard and kelp by-products were estimated to be producted during the last three years. The estimate corresponds 6.7% of the total production of marine aquaculture and 14.9% of the total production of seaweeds. When adding up the by-products from fish and mollusks, approximately 1,000,000 tons of fisheries by-products were thrown out into the sea every year. A three-step strategy is required for the industralization of fisheries by-products. The first step is the construction of the processing foundation of by-products, the second is its food industralization, and the third is its recycling as raw biomaterials. The stable supply of raw materials is the prerequisite for the industralization. Thus, it is necessary to construct the refuse logistics around chief production districts and to build the processing facility and frozen storage of by-products. Cooperation among private enterprises and government investment for research and development is required the second and third steps.

최근, 시멘트 사용량을 줄이고, 경제성을 확보하기 위하여 혼화재료를 적용한 콘크리트 포장에 대하여 많은 연구가 이루어지고 있다. 국내외적으로 콘크리트 포장용 결합재로써 활용되어지고 있는 혼화재료로써 고로슬래그, 플라이애시 등이 있으며, 이 중 고로슬래그는 냉각방법에 따라 급수로 냉각처리된 급냉슬래그와 공기 중에 냉각처리된 서냉슬래그로 분류될 수 있다. 서냉슬래그는 화학조성이 급냉슬래그와 유사하고 염기도가 높아 콘크리트용 혼화재료로 사용될 경우, 콘크리트 중 수산화칼슘과의 잠재수경성 발현에 유리하여 콘크리트 포장용 결합재로써 활용이 가능할 것으로 보고되고 있으며, 서냉슬래그의 물리화학적 특성을 기반으로 하여 서냉슬래그를 콘크리트 포장재료로써 활용하기 위한 몇몇의 연구가 진행되어 오고 있다. 본 연구에서는 서냉슬래그를 콘크리트 포장재료로 사용하여 공시체를 제조하였으며, 콘크리트의 공학적 특성을 실험적으로 평가함으로써, 서냉슬래그의 콘크리트 포장재료로써 적용가능성을 실험적으로 검토하였다.

본 연구는 아스팔트 혼합물에 사용되는 재료들을 산업부산물로 활용함으로써, 경제성 확보 및 공용성 능의 개선 효과를 확인하기 위한 것으로써, 천연골재를 대체하기 위해 제강공정에서 발생되는 전기로 산 화슬래그 골재를 분쇄, 선별하여 사용하였으며, 석회석 등의 채움재는 자동차유리를 분쇄 선별하여 사용 하였다. 아스팔트 바인더의 성능개선을 위하여 폐자동차의 폴리머 재료도 활용하였다. 실내시험 및 현장 적용 결과, 전기로 슬래그 골재의 일반적인 물성이 천연골재와 유사한 것으로 나타났으며, 폐유리를 이용 한 채움재 또한 석회석을 대체하는데 문제가 없을 것 판단된다. 표 1과 2는 각 재료별 물성시험결과로 관 련기준을 만족하는 것으로 나타났다. 또한 각 재료별 유해성을 평가하기 위한 중금속 용출 시험결과에서도 관련기준에 적합한 것으로 나타 났다. 표 3 및 표 4는 중금속 용출 실험결과이다. 각 재료를 이용하여 혼합물을 제작하고 실시한 물성시험결과 표 5에서와 같이 안정도가 천연골재를 활 용한 일반아스팔트 혼합물에 비해 우수한 것으로 나타나, 전기로 산화 골재 등을 활용하여 경제적이고 우 수한 품질의 생산 및 시공이 가능할 것으로 판단된다.

본 연구에서는 비소 오염 토양의 안정화소재로서 주로 사용되고 있지만 그 품질관리가 어려운 제강슬래그의 재료적 특성을 파악하기 위한 기초적인 실험을 수행하였다. 제강슬래그의 입도에 따른 화학적 성질의 변화와 비소 안정화에 중요한 성분인 Fe 성분의 입도에 따른 용출특성 그리고 제강슬래그의 주요 성분인 철(Fe)과 칼슘(Ca) 성분의 구성 비율이 비소의 흡착에 미치는 영향 등에 대해서 흡착실험을 실시하여 관찰하였다. 제강슬래그의 입도는 화학적 성질에 영향을 주지는 못하는 것으로 나타났다. 그러나 용출은 입도가 작은 분말상태에서 높게 나타났으나 pH=2 조건에서만 용출이 발생되어 실제 자연상태에서 용출이 일어나기는 어려울 것으로 판단되었다. 철과 칼슘성분의 혼합비에 따른 비소의 흡착실험에서는 철과 칼슘이 일정비율 섞여 있는 경우에서 효과가 매우 우수한 것으로 나타났으며, 철이나 칼슘 성분 모두 25%이상만 혼합되면 비슷한 효과를 나타내는 것으로 보인다. 한편 칼슘만 존재하는 경우에는 초기의 효과는 높았으나 시간이 경과하면서 재용출 현상이 나타나 적당하지 않은 것으로 나타났으며, 철 성분만 사용한 경우에는 초기 효과는 낮았으나 시간이 경과하면서 흡착효과가 지속적으로 증가하는 것으로 나타나 장기효과가 높을 것으로 기대되었다.

본 연구에서는 이산화탄소 고정화에 있어 이산화탄소 전환을 위해 MEA를 이용한 습식화학흡 수법의 셔틀메카니즘을 도입하였다. 또한 알칼리 무기물질을 다량 함유한 산업부산물을 습식탄산화법을 이용해 처리하고자 하였다. 즉, 산업부산물의 화학적 처리를 통해 칼슘이온을 용출하였다. 산성물질을 이용한 용출상징수를 ICP로 분석한 결과, 칼슘이온이 최대 17,900 ppm(1.79%)을 확보하였다. 또한 MEA를 이용한 습식 흡수공정을 통해 상온, 상압조건의 이산화탄소 분위기에서 94%의 전환률을 얻었 다. 슬러지의 액상탄산화를 통해 슬러지 mg 당 0.175 mg의 이산화탄소를 고정하였으며, 최종생성물의 XRD 분석결과 일반적인 탄산칼슘의 결정구조인 calcite 형상을 확인하였다.

Since it was developed by Joseph Aspdin, cement has been a common construction materials up to the present time.However, there are trace constituents in cement clinker. One of the trace constituents included in cement clinker, chromium,has become prominent and highly noticed lately as a social issue both inside and outside of this country because it affects thehuman body negatively. The aim of the present study was to investigate the concentration of water-soluble hexavalent chromiumin cement clinker by using industrial by-products. For that reason, raw materials were prepared to add different SiO2 , Al2O3,and Fe2O3 sources. After the raw materials such as the limestone, the sand and the clay, iron ore was pulverized and mixed,and the raw meal was burnt at about 1450oC in a furnace with an oxidizing atmosphere. The part in the raw materials of theclinker was substituted with slag, sludge, etc. and this was used to manufacturing cement clinker. To investigate the water-soluble hexavalent chromium content in clinker, raw meal was prepared by changing the modulus, the type, and the contentof clinker materials and tested concentrations of hexavalent chromium in the clinkers. To determine Cr+6 formation of theclinker, tests were done with raw meals adding chromium by using different industrial by-products. Consequently because thechromium was to be included in the raw materials of the clinker, production of Portland cement clinker was included with thechromium. Also, the chromium was converted into hexavalent chromium in the burning process.

본 실험은 알코올 발효사료 처리에 따른 in vitro 발효 pattern의 변화를 검토하기 위하여 반추위내 ammonia, pH, alcohol 및 volatile fatty acids 농도와 NDF 분해율에 미치는 영향을 구명하고자 실시하였다. 비지박 알코올 발효사료(AFS)는 비지박(DM 20%)과 시판중인 배합사료(DM 87%)를 각각 50:50의 비율로 혼합하고 당밀 5%, yeast 0.5%를 첨가한 후 에서 24시간 혐기적으로 배양하여 제조