알칼리 금속 이온과 염소 이온이 포함된 용액으로부터 이온교환수지를 이용한 이온 제거에 대한 연구를 진행하였다. 양이온인 금속이온(Na+와 K+)의 제거에는 양이온교환수지를, 음이온인 염소 이온(Cl-)의 제거에는 음이온교환수지를 사용하였다. 용액 A (Na+를 36,633 ppm, Cl-를 57,921 ppm 함유)의 경우, Na+ 이온과 Cl- 이온은 20분 이내에 99% 이상 제거되었다. 용액 B (K+를 1,638 ppm 함유)의 경우, K+ 이온은 3분 이내에 99% 이상 제거되었다.

최근 노후화된 구조물의 재건축 또는 재개발과 같은 건설 사업의 급속한 팽창으로 인하여 발생되는 건 설폐기물의 발생량은 점차적으로 증가하고 있으며, 향후 건설폐기물 처리는 점차 사회적으로 매우 중요한 부분을 차지할 것으로 예상된다. 또한 국내의 천연골재 부존량은 제한적이며, 이는 빠른 시일 내에 고갈 될 전망이다. 따라서 본 연구에서는 천연골재를 대체할 수 있는 순환골재를 활용하여 포장용 콘크리트에 적용하기 위한 연구의 일환으로, 천연골재 중량대비 50%, 70% 및 100%를 순환골재로 치환하여 재령 28 일의 압축강도 및 염소이온침투에 대한 저항성을 분석하였다. 또한 염소이온침투 저항성 실험은 ASTM C 1202에 의거하여 수행하였다. 그림 1 및 그림 2는 각 변수별 압축강도 및 염소이온침투 저항성을 비교하 고 있다. 압축강도 실험결과, 순환골재를 50% 치환한 R50 변수의 압축강도는 30MPa 수준으로 분석되었다. 또 한 순환골재 치환 70% 및 100% 변수인 R70 및 R100 변수는 R50 변수보다 약 10.9% 및 11.3% 감소한 압축강도 값을 나타내었다. 또한 염소이온침투 저항성 실험결과, R50 변수의 통과전하량은 2,862쿨롱의 값으로 ASTM C 1202 평가기준에 따라“보통”으로 분석되었다. 반면, R70 및 R100 변수의 염소이온침 투 저항성 실험결과, 3,592 및 4,466쿨롱의 통과전하량 R50 변수보다 다소 높은 통과전하량 값을 나타내 었으며 이는 평가기준에 의거하여“보통” 및“높음”으로 분석되었다. 순환골재 치환율 증가에 따라 압축 강도는 감소하였고, 통과전하량은 증가하는 경향을 나타내었다. 이는 포장용 콘크리트에 순환골재의 다량 치환으로 순환골재의 낮은 밀도 및 높은 흡수율에 기인한 것으로 판단된다. 또한 순환골재를 포장용 콘크 리트에 적용하기 위해서 추가적인 역학적 특성 및 내구 특성을 분석하여 적용함이 바람직할 것으로 사료 된다.

It has been well known that concrete structures exposed to chloride and sulfate attack environments lead to significant deterioration in their durability due to chloride ion and sulfate ion attack. The purpose of this experimental research is to evaluate the resistance against chloride ion and sulfate attack of the cementless concrete replacing the cement with ground granulated blast furnace slag. For this purpose, the cementless concrete specimens were made for water-binder ratios of 40%, 45%, and 50%, respectively and then this specimens were cured in the water of 20±3℃ and immersed in fresh water, 10% sodium sulfate solution for 28 and 91 days, respectively. To evaluate the resistance to chloride ion and sulfate attack for the cementless concrete specimens, the diffusion coefficient for chloride ion and compressive strength ratio, mass change ratio, and length change ratio were measured according to the NT BUILD 492 and JSTM C 7401, respectively. It was observed from the test results that the resistance against chloride ion and sulfate attack of the cemetntless concrete were comparatively largely increased than those of OPC concrete with decreasing water-binder ratio.

Expanded graphites were used as anode materials of high power Li-ion secondary battery. The expanded graphite was prepared by mixing the graphite with HClO4 as a intercalation agents and KMnO4 as a oxidizing agents. The physical and electrochemical properties of prepared expanded graphites through the variation of process variables such as contents of intercalation agent and oxidizing agent, and heat treatment temperature were analyzed for determination of optimal conditions as the anode of high power Li-ion secondary battery. After examing the electrochemical properties of expanded graphites at the different preparing conditions, the optimal conditions of expanded graphite were selected as 8 wt.% of oxidizing agent, 400 g of intercalation agent for 20 g of natural graphite, and heat treatment at 1000℃. The sample showed the improved charge/discharge characteristics such as 432 mAh/g of initial reversible capacity, 88% of discharge rate capability at 10 C-rate, and 24 mAh/g of charge capacity at 10 C-rate. However, the expanded graphite had the problems of potential plateaus like natural graphite and lower initial efficiency than the natural graphite.

운반체(감응물질)로 제 4급 인산염을 사용하여 PVC를 지지체로 하여 과염소산이온의 농도 10-6 M까지 선형적인 이온선택성 전극을 제작하였다. 운반체의 화학적구조와 함량 가소제의 종류 및 막 두께에 따른 전극의 기울기 선형응답범위 및 한계측정농도 등 전극전위특성을 고려하여 최적의 과염소산 이온선택성 PVC막 전극을 제조한 다음 측정 가능한 pH 범위 선택계수 및 전극의 교류임피던스 특성을 비교 검토하였다 운반체로 tetraoctyl-phosphonium perchlorate(TOPP) tetraphenylphosphonium perchlorate(TPPP) 및 tetrabutylphosponium perchlorate (TBPP) 등의 제 4급 인산염의 과염소산 이온 치환체를 사용하였다 알킬기의 탄소고리 수가 증가할수록 전극특성은 TBPP, 선형응답범위 10-1×10-6 M 및 한계측정농도는 9.66×10-7 M 이었으며 시판되고 있는 Orion 전극특성보다 좋은 결과를 나타내었다 전극전위는 pH3~11범위에서 ph의 영향을 받지 않았으며 CIO4 에 대한 방해이온의 선택계수 서열은 SO24 < F < Br < I 이었다 임피던스 측정결과 TOPP의 경우 등가회로는 용액저항 이중층용량과 벌크저항의 병렬 및 Warburg 임피던스의 직렬이었다 이 경우 용액저항은 거의 나타나지 않았고 확산에 의한 Warburg 임피던스는 크게 나타났으며 Warburg 계수는 1.32×1074 Ω cdot cm2/s1/2이었다.

수산화물법에 의해 제작된 α-stannic acid의 열분해 거동과 SnO2분말의 성질에 미치는 잔류염소이온의 영향을 관찰하였다. SnCl4와 NH4OH 수용액을 중화시켜 α-stannic acid침전물을 제작하고 NH4NO3수용액으로 세척하였다. 분말내의 잔류 염소이온의 양을 주절하기 위하여 세척정도를 3단계로 조정하였다. 세척후 100˚C에서 건조하고, 500˚C ~ 1100˚C에서 하소함으로써 SnO2분말을 제조하였다. α-stannic acid의열분해 거동ㅇ르 DT-TGA 와 FTIR을 통하여 관찰하고, SnO2분말의 조성과 입자크기 및 비표면적을 각각 AES, TEM 및 BET을 통하여 측정하였다. 잔류 염소이온 양이 감소되면, 저온 하소시 일차입자의 상대적 크기가 커지는 반면 고온하소시에는 상대적으로 감소되었ㄷ. 잔류 염소이온의 일부는 α-stannic acid내의 격자산소 자리에 위치함으로써, 저온가열시 결정수탈리와 결정화를 지연시키고 또한 고온가열시에는 이의 증발에 의해 산소공공이 생성되어 소결을 촉진시킨다고 제의하였다.

감응물질로 제4급 암모늄염을 사용하여 PVC를 지지체로 과염소산이온의 농도 10-6M까지 측정가능한 이온 선택성 전극을 제작하였다. 감응물질의 화학적 구조와 함량, 가소제의 종류 및 막 두께에 따른 선형응답 범위와 Nernst의 기울기 등 전극특성을 검토하여, 최적 막조건을 구한 다음 측정가능 pH범위와 여러 방해이온에 대한 선택계수를 비교 검토하였다. 과염소산 이온선택성 전극에서 감응물질의 화학적 구조 즉, 알킬기의 탄소고리수가 증가할수록 선형응답 범위 등 전극 특성은 Aliquat 336P, TOAP, TDAP 및 TDDAP의 순서로 좋아졌다. 가소제는 DBP가 가장 좋았고, 감응물질의 양은 최적 함량 이상에서 적을수록 좋았다. 최적 막 조성은 TDDAP 9.09, PVC 30.3 및 DBP 60.61wt%이었고, 막두께 0.45mm이었다. 이 조건에서 선형응답 범위 10-1~1.2 × 10-6M, 검출한계 5.1×10-7M 및 Nernst기울기 57mV/pClO4이었다. 막전위는 pH 4~11 범위에서 pH의 영향을 받지 않았으며, 선택계수 서열은 다음과 같았다. SCN->I->NO3->Br->ClO3->F->Cl->SO42-

본 연구에서는 세 종류의 알루미나 시멘트 모르타르의 염소이온 프로파일을 통해 깊이별 염소이온농도를 측정한 후 Fick’s 2nd 법칙을 이용하여 유효확산계수 및 표면 염소이온 농도를 산정하였다. 그 결과, 알루미나 시멘트 내 산화알루미늄 함량이 높을수록 표면 염소이온 농도 및 유효확산계수는 증가하는 경향을 나타냈다. 이는 높은 산화알루미늄으로 인한 염소 이온 고정화 능력의 증가로 공극수 내 염소이온 농도가 감소하여 이온 침투가 촉진된 것으로 사료된다. 따라서, 해양, 도로 구조물 등 염소이온 노출 환경에서 높은 산화알루미늄 함량의 알루미나 시멘트 사용은 배제되어야 할 것으로 판단된다.

The purpose of this experimental study is to chloride ion penetration resistance performance of concrete using Nano-TiO2 Carrier. As a result, concrete using Nano-TiO2 Carrier was confirmed to be superior than ordinary concrete and commercial TiO2 concrete chloride ion penetration resistance performance.

In this study, the effect of calcium leaching on chloride ion penetration resistance of mortar specimens was evaluated. According to test results, the penetration depth of chloride ion was increased after the calcium leaching attack.

This study is to perform experiment of concrete according to addition of blast furnace slag powder and sulfur activator dosages. Blast furnace slag powder used at 30, 50, 80% replacement by weight of cement, and liquid sulfur additives was chosen as the alkaline activator. As a result, it should be noted that the sulfur alkali-activators can not only solve the disadvantage of blast furnace slag concrete but also offer the chloride resistance of alkali-activated blast furnace slag concrete to blast furnace slag concrete.

When the reinforced concrete structure is in a high salinity environment, chlorine ions penetrate from the surroundings, resulting in corrosion of the reinforcing bars, resulting in low durability. Therefore, studies on the immobilization of chlorine ions are underway, and anion exchange resin, one of them, was used in this study. In this study, chloride ion fixing ability was confirmed by replacing OPC, conventional bead anion exchange resin, and powder anion exchange resin with mortar and then using an electron probe X-ray micro-analyzer. The bead anion exchange resin replaced 3% of the fine aggregate volume and the powder anion exchange resin 5% of the cement volume. The fabricated specimens were cured for 28 days, immersed in NaCl solution for 28 days, and confirmed by electron probe X-ray micro-analyzer.

In this study, the absorption protection agent was applied to the surface of fiber reinforced concrete to evaluate the chloride ion penetration resistance. The evaluation was based on the method presented in KS F 2711. It was confirmed that the resistance performance against chloride ion was improved by 56∼71% when the coating material was applied.

In this study, poly-silicon sludge was used in replacement with Portland cement as SCMs. Poly-silicon sludge has an ability to improve the durability to the concrete system. Thus, the chloride penetration test of PS specimens was conducted for the confirmation of the durability. From the results, The penetration depth of the plain specimens is deepest, and gradually decreases as PS substitution rate increases.

The aim in this study was to remove Cl−, which can be problematic in the recycling of bottom ash, by identifying the optimum operating conditions for a soil electrolysis apparatus with spiral paddles and to use these as the base data in removing contaminants from various polluted soils using electrolysis. Unprocessed bottom ash collected from the openair storage yard at thermoelectric power plant H in Gyeong sang nam - do Province was used as the experimental material. The experimental methodology was to identify the optimum operating conditions to remove Cl− contained in the bottom ash using the following variables: use or not of spiral paddles, application or not of electrolysis, change of concentration of the electrolyte solution, electrolysis application time, and the voltage level during electrolysis. From the results, the highest removal efficiency of 91.4% was shown under the following conditions: use of the spiral paddles, use of 0.3% NaOH electrolyte solution, 20 min of electrolysis; and a voltage level of 5 V during electrolysis. It is evident that application of the soil electrolysis apparatus for removal of Cl− from bottom ash could be valuableas base data for purification of polluted soils in the future.

The present study was conducted for the purpose of analyzing the growth response of Dracaena braunii treated with chloride ions and to evaluate its salt tolerance. Distilled water (CON) was spiked with 1 (C1), 2 (C2), 5 (C5), 10 (C10) and 15 g/L (C15) CaCl2, respectively. Acidity (pH) and electrical conductivity of hydroponic solution, and leaf width, leaf length, root length, number of leaves, fresh weight, dry weight and the water content of Dracaena braunii were measured. Acidity and electrical conductivity remarkably increased commensurate with increasing concentrations of CaCl2. Growth in the C1 treatment was better than that in CON, whereas the C10 or C15 treatments caused either slow growth or withering of the plants. Fresh weight, dry weight and water content were significantly decreased in response to CaCl2 concentration, compared with those in the control. These results showed that CaCl2 concentration less than 1 g/L may be used as a hydroponic solution for D. braunii, as long as the water quality is not too saline. The chlorine ion has a negative effect on the growth.

From the test results, it was found that the compressive strength and the resistance of chloride ion penetration were evaluated the slag content of the concrete for bridge pavement. Compressive strength test results showed that initial strength was decreased as slag replacement ratio increased. The chlorine ion penetration performance increased with increasing strength.

Recently, self-healing concrete has been researched as maintenance and repair of concrete structures are important challenges we face. This paper focused on possibility of ion exchange resin as a novelty material directly and actively controlling harmful ions of concrete, whereas most self-healing concrete researches have been focused on methods to automatically filling and repairing internal crack of concrete. Because equilibrium properties between ion exchange resin and harmful ion is important before design of cement mixing proportion, it was conducted to remove chloride or sulfate in saturated Ca(OH)2 solutions containing NaCl or Na2SO4. The removal performance was analyzed using kinetic equation and isothermal equation. Consequently, the removal properties of anion exchange resin were relatively more dependent on pseudo second reaction equation and Langmuir equation than pseudo first reaction equation and Freundlich equation. And it was concluded that each chloride and sulfate can be removed to the maximum 1068 ppm and 1314 ppm.