본 연구는 고성능 폴리머 시멘트계 프리캐스트 제품의 개발 및 미세균열 발생 시 자기치유기능을 확보할 목적으로 경화제 무첨가 EMM의 물리적 성질을 검토하고, 그 물성에 영향을 끼치는 시멘트 매트릭스 내의 에폭시수지 경화도와 현미경을 통한 조직구조의 관찰과 함께 자기치유효과를 검토하였다. 그 결과, 경화제 무첨가 EMM의 폴리머 혼입에 의한 강도 개선 효과는 인장강도, 휨강도, 압축강도의 순으로 나타났다. 접착성은 콘크리트 피착체의 모세관 공극에 폴리머 필름의 형성에 기인한 투묘효과에 기인하여 크게 향상되었다. 투수저항성은 폴리머 결합재비 20% 및 고로슬래그 미분말 치환율 30%를 병용한 EMM에서 보통시멘트 모르타르 대비 97%의 감소율을 나타내 매우 우수하였 다. 고로슬래그미분말, 팽창재 및 황산나트륨을 병용한 EMM의 균열 폭은 고로슬래그 치환율이 증가함에 따라 미미하게 감소하였으나, 고로 슬래그미분말 치환율 20%에서 수중침지기간의 증가와 함께 서서히 균열부 자기폐색 효과를 관찰할 수 있었다.

The purpose of this study is to understand a compressive strength and propose a dry shrinkage strain equation being able to predict dry shrinkage of alkali-activated materials(AAM) mortar samples manufactured using fly-ash(FA) and ground granulated blast furnace slag(GGBFS). The main parameters investigated were the GGBFS replace ratios(30, 50, 70 and 100%) and sodium silicate modules(Ms[SiO2/Na2O] 1.0, 1.5 and 2.0). The compressive strength of AAM increased with increases GGBFS replace ratios or Ms contents. The dry shrinkage strain of AAM decreased with increases Ms contents. But, the dry shrinkage strain of AAM increased as the GGBFS replace ratio increases. Therefore, the GGBFS replace ratio seems to have very significant and important consequences for the mix design of the AAM mortar. The results indicated the R-square of single regression analysis based on each mix properties was the highest value; 0.7539~0.9786(average 0.9359). And the presumption equation of dry shrinkage strain with all variables(GGBFS, Ms and material age) has higher accuracy and its R-square was 0.8020 at initial curing temperature 23 degrees Celsius and 0.8018 at initial curuing temperature 70 degrees Celsius.

본 연구에서는 경량기포 콘크리트를 이용한 육성용 토양골재의 적용성을 평가하기 위해서 고로슬래그 기반 기포콘크리트의 총 8 배합과 인공토양골재를 제조하였다. 고로슬래그 기반 기포콘크리트 배합의 주요변수는 단위결합재량으로서 100에서 800 kg/m3으로 변화하 였다. 경량기포콘크리트는 플로우, 슬러리 및 절건 밀도와 재령별 압축강도를 측정하였으며, 파쇄된 인공토양골재는 pH, 입도분포, 투수계수, 양이온치환용량(CEC), 유기물함유량(C/N비)을 측정하였다. 측정결과 경량기포콘크리트의 플로우, 슬러리 및 절건밀도와 재령별 압축강도는 단위결합재량이 증가함에 따라 증가하였다. 경량기포콘크리트의 단위결합재량이 500 kg/m3 이상인 배합의 28일 압축강도는 4 MPa 이상이었 다. 인공토양골재에 3일 이상의 15% 희석된 제1인산암모늄의 수용액침지는 pH를 저감시키는데 효과적이었다. 또한 제조된 인공토양골재는 양이온 치환용량(CEC) 측면에서 상급으로 평가되었지만 C/N비 측면에서는 조경시방서를 만족시키지 못하였다.

The study is compressive strength of 110MPa PHC pile using ground granulated blast furnace slag to NAC, AC curing method. In the result, 20% of ground granulated blast furnace slag could be substituted for cement in PHC pile concrete.

In experimental results, the prediction equation for 28 day-strength of GGBF slag concrete could be produced through the linear regression analysis of early strength and 28 day-strength. In order to acquire the reliability, all mixture were repeated as 3 times and each mixture order was carried out by random sampling. The prediction equation for 28 day-strength of GGBF slag concrete by 1 day strength won the good reliability.

본 연구는 혼합 활성화제에 의한 알칼리 활성화 슬래그 시멘트(AASC)의 역학적 특성에 관한 연구이다. 사용된 활성화제는 황산칼슘(CaSO4, 이하 CS), 황산나트륨(Na2SO4, 이하 SS) 및 수산화나트륨(NaOH)이다. 황산염은 슬래그 중량의 2.5, 5.0, 7.5 및 10.0%로 치환하여 사용하였으며, NaOH는 2M 및 4M 농도의 수용액으로 사용하였다. 본 연구에서는 황산염(CS 및 SS) 치환율에 따른 배합(4가지 배합)과 2M 및 4M의 각각의 NaOH 수용액에 치환된 황산염을 혼합하여 시험체를 제작하였다. 시험체는 총 24가지의 배합에 따라 페이스트로 제작되었으며, 물－결합재 비는 0.5로 하였다. 경화된 시험체에 대해서 압축강도, 휨강도, 초음파속도(UPV), 흡수율 및 XRD 분석을 수행하였다. CS의 활성화제를 사용한 경우는 7.5% CS 치환율, 2M NaOH 수용액+ 5.0% CS 치환율 및 4M NaOH 수용액+ 5.0% CS 치환율의 시험체에서 최고의 압축강도를 나타내었다. 또한, SS의 활성화제를 사용한 경우는 10.0% SS 치환율, 2M NaOH + 7.5% SS 치환율 및 4M NaOH + 2.5% SS 치환율에서 최고의 압축강도 발현을 나타내었다. 휨강도, UPV 및 흡수율은 압축강도 발현 결과와 유사한 경향을 나타내는 것을 알 수 있었으며, XRD 분석결과 시험체 내에 생성된 반응물질은 ettringite, CSH 및 실리케이트계 수화물인 것으로 나타났다. AASC에서 황산염과 NaOH의 혼합 사용은 황산염의 단독 사용의 경우와 비교하여 일정 수준의 농도 범위에서 강도를 향상시키고 조직을 치밀화 시키는 등의 긍정적인 영향을 미치는 것으로 판단된다.

This research investigated the effects of adding ground granulated blast furnace slag (GGBS) on the pullout resistance of smooth steel fibers embedded in GGBS cement grouts. 40% of cement in the grouts was replaced with GGBS to enhance the flowability and durability of grouts containing steel fibers. The pullout resistance of steel fibers embedded in grouts showed continuous enhancement as the age of grouts increased. The pullout resistance of GGBS grouts was higher than that of grouts without GGBS.

In experimental results, the prediction equation for 28 day-strength of GGBF slag concrete could be produced through the linear regression analysis of early strength and 28 day-strength. In order to acquire the reliability, all mixture were repeated as 3 times and each mixture order was carried out by random sampling. The prediction equation for 28 day-strength of GGBF slag concrete by 1-day strength won the good reliability.

The study on physical properties of PHC pile and pile filler using blast furnace slag were evaluated. In the results, it was found that compressive strength and workability of PHC pile concrete with 20% of blast furnace slag adjusted S/a 27% were satisfied with desired properties and it was available to improve flow and compressive strength of file filler with 35% of blast furnace slag and TG as additive.

CO2 emitted from building materials and construction materials industry reaches about 67 million tons, which occupy about 30% of CO2 emitted from the construction field. Controls on the use of consumed fossil fuels and reduction of emission gases are essential for the reduction of CO2 in the construction area as we reduce the second and third curing to emit CO2 in the construction materials industry. Accordingly, this study applied the low energy curing admixture (hereinafter “LA”) to the extruded panels to observe the physical properties, depending on the mixing amount of fiber, type of fiber and mixing ratio of fiber. The type of fiber did not appear to be a main factor to affect strength, while the LA mixing ratio and mixing amount of fiber appeared to be major factors to affect strength. Especially, the highest strength was developed when the LA mixing ratio was 40%, whereas the test object with the mixing ratio of 50% resulted in the decrease of strength. In addition, it appeared that the mixing ratio of fiber greatly affected flexural strength and strength increased as the mixing ratio increased.

Environmental problems caused by the occurrence of carbon dioxide are recognized as a critical issue throughout the world. As a result, a measure for the use of cement and improvement of its quality must be sought out. In order to reduce the occurrence of carbon dioxide during the manufacturing process of cement, this study creates an alkali-activated slag cement that utilizes ground granulated blast furnace slag, an industrial by-product, and substitutes metakaolin as an alternative for silica fume to improve the process of manufacturing high-strength concrete and its quality. The study discerns the mechanical characteristics by measuring the flexibility and compressive strength through the mortar matrix and discerns the durability by conducting an acid resistance test and chloride ion penetration resistance test. Also, the study discerns the hydration products through an XRD test. Based on the results of such tests, it is anticipated that it may be used as a secondary product for concrete or buildings that require superior long-term strength and durability compared to regular Portland cement. However, as no clear results were found in this study regarding the substitution of metakaolin, it displayed mixed results in comparison to previous studies. Nevertheless, it is expected that metakaolin will become a more superior admixture if its issues are improved through continuous research studies.

본 연구에서는 표준실험체 (BSS), 순환굵은골재와 고로슬래그 미분말의 치환과 하이브리드섬유를 보강한 실험체 (BSPRR1, BSPRR2시리즈), 순환굵은골재와 고로슬래그 미분말의 치환과 PVA섬유를 보강한 실험체 (BSPG시리즈)로 총 13개의 실험체를 실물크기의 1/2로 축소 제작하여 실험을 수행하였다. 실험을 통하여 얻어진 결과를 비교⋅분석하여 하중-변위, 파괴형태, 최대내력 등을 규명함으로써 구조성능의 개선정도를 평가하였다. 실험결과 순환굵은골재와 고로슬래그 미분말을 치환한 콘크리트에 하이브리드섬유를 보강한 실험체 (BSPRR1, BSPRR2시리즈)의 경우 표준실험체 (BSS)에 비하여 압축강도는 최대 13%, 최대내력은 4~21%, 연성능력은 각각 4~28% 증가하는 결과를 나타내었다. 그리고 또한, 충분한 연성적인 거동과 안정적인 휨인장 파괴를 나타내었다.

Carbon dioxide generated from construction materials and construction material industry among the fields ofconstruction is approximately 67million tons. It is about 30% of the carbon dioxide generated in the fields of construction.In order to reduce carbon dioxide in the fields of construction, it is necessary to control the use of fossil fuel consumedand decrease carbon emission by reducing the secondary and tertiary curing generating carbon dioxide in constructionmaterial industry. Therefore, this study produced an extrusion panel by using cement as the base materials and substitutingbinding materials up to 40% to analyze strength characteristics. According to the results of strength characteristics bythe replacement binder (Low energy curing Admixture) showed an apparent active strength improvement. In particular,specimens substituting binder as 45% indicated the greatest strength improvement. When binding materials was used withsubstitution, it showed strength characteristics similar or higher than specimens made from tertiary autoclave curing assecondary steam curing.

Reaction degree of ground granulated blast furnace slag(GGBFS) in cement paste was measured by water-binder ratio and GGBFS replacement ratio, curing temperature with ages using selective dissolution. In result of experimental, when water-binder ratio and curing temperature were high and replace ratio of GGBFS was low, reaction degree was estimated high.

This study investigated the effect of cement type and ground granulated blast furnace slag (GGBS) on the mechanical properties and workability of grout for offshore PSC structures. As the replacement ratio of GGBS increased, the flowability of the grout increased and both intial and final setting times of grout was delayed regardless of cement type. However, the effects of GGBS on the bleeding of grout were different according to the type of cement: as the ratio of GGBS increased, less bleeding was observed for the grout with typeⅠ cement whereas higher bleeding was generated for the grout with type Ⅲ cement. However, there was no significant difference in their compressive strength at 28 day according the different replacement ratio of GGBS from 0 to 40%.

In this study, high performance fiber composites has developed using GGBS and Flyash with PVA fiber. Thus, four mixtures was determined accoding to the ratio of binder. A series of experiments, including slump flow, compressive strength, uniaxial tensile strength tests were carried out to characterize the mechanical properties of the fiber composites. The result of tests, slump flow showed an average 428mm and tensile strain 2% of behavior strain hardening of due to the occurrence multiple micro crack.

To evaluate the durability characteristics of low permeable concrete using ground granulated blast-furnace slag with fineness 4,650 cm2/g, carbonation depth was measured. From the test results, persisting period of that was calculated. And it was found that carbonation depth of concrete was proceed 29.5 mm for 100 years.

이 연구에서는 고로슬래그 미분말을 사용한 프리캐스트 보의 전단성능에 대하여 평가하였다. 실험체는 고로슬래그 미분말 치환율에 따라 총 4체의 실험체를 제작하였다. 모든 실험체는 전단경간비 2.5, 보의 폭 200mm, 유효깊이 300mm이며, 3점 가력을 받는 단순보로 계획하였다. 또한 이 연구에서는 실험체의 전단강도를 예측하기 위하여 기존 전단강도 예측식을 이용하여 실험결과와 비교하였으며, 총 89개의 기존 전단 실험결과를 이용하여 실험결과와 비교 분석하였다. 실험결과, 고로슬래그 미분말을 치환한 실험체는 포틀랜드 시멘트만을 사용한 실험체와 비교분석한 결과 유사한 전단성능을 나타내었다.