본 논문은 고온 환경에 노출된 TRM 보강 RC 보의 잔존강도를 예측하기 위한 해석적 연구결과를 제시한다. 연구를 위해 상용 유한요소해석 프로그램인 ABAQUS가 사용되었으며, 콘크리트, 철근, CFRP grid, 모르타르에 대한 재료모델이 제안되었다. 본 연구에서 제안된 유한요소해석 모델의 검증을 위해 선행 연구결과에 대한 재현 해석이 수행되었다. 제안된 유한요소해석 모델의 예측 된 결과는 실험결과와 비교하여 잔존 극한하중과 극한하중 시점에서 각각 약 97.6%, 90.58%의 정확도를 보이는 것으로 나타났다. 또한, 유한요소해석을 통한 균열양상은 실험결과와 비교적 정확하게 예측되었다. 따라서 본 연구에서 제안된 해석모델은 고온 환경에 노출된 TRM 보강 RC 보의 잔존강도를 예측하기 위해 효과적으로 사용될 수 있을 것으로 판단된다.

In order to optimize the manufacturing of polypropylene-derived few-layer graphene, an innovative utilization of nonsupported iron oxide nanoparticles generated under various fuel environment conditions was studied. Three distinct fuel combustion environment circumstances (fusion, fuel shortage, and fuel excess) produced a variety of Fe2O3 nanoparticles for cost-effective and green graphene deposition. XRD, H2- TPR, Raman, and TGA measurements were used to characterize both new and spent catalysts. Remarkably, the microstructure of the generated Fe2O3 nanoparticles could be controlled by the citric acid/iron nitrate ratio, ranging from spheroids ( Fe2O3(0)) to sheets ( Fe2O3(0.5-0.75)) and a hybrid microstructure that consists of sheets, spheroids, and interconnected strips ( Fe2O3(1-2)). According to fuel situation (citric acid/iron nitrate ratio, Fe2O3( 0-2)), various graphitization level and yields of graphene derivatives including sheets, ribbons, and onions have been developed. With the ideal fuel/oxidant ratio (ɸ = 1), the Fe2O3( 0.75) catalyst demonstrated the best catalytic activity to deposit the largest yield of highly graphitized few graphene layers (280%). Lean and rich fuel conditions (1 > ɸ > 1) have detrimental effects on the amount and quality of graphene deposition. It is interesting to note that in addition to graphene sheets, an excess of citric acid caused the production of metallic cores, hollow, and merged carbon nano-onions, and graphene nano-ribbons. It was suggested that carbon nano-onions be converted into graphene nano-ribbons and semi-onion shell-like graphene layers.

This study prepared a (TiO2-CeO2)/Sr4Al14O25: Eu2+,Dy3+ heterojunction photocatalyst by coating (TiO2-CeO2) nanoparticles on a Sr4Al14O25:Eu,Dy phosphor substrate using a hydrothermal reaction method. The fabricated (TiO2- CeO2)/Sr4Al14O25: Eu2+,Dy3+ composites were characterized with X-ray diffraction (XRD), scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray photo electron spectroscopy (XPS), UV-visible diffuse reflectance spectroscopy (UV/Vis DRS), Brunauer-Emmett-Teller (BET), and Raman spectroscopy. The photocatalytic performance of the (TiO2-CeO2)/Sr4Al14O25: Eu2+,Dy3+ composites was investigated through the decomposition of toluene gas for various ratios of TiO2 to CeO2 (3:7, 5:5, and 7:3) and heat treatment ranging from 300 to 700 °C. The coupling between (TiO2-CeO2) and the highly persistent Sr4Al14O25:Eu2+,Dy3+ phosphor reduced the energy band gap and enhanced visible light absorption. In particular, the 5:5 ratio of TiO2 to CeO2 on Sr4Al14O25:Eu2+,Dy3+ showed excellent photocatalytic performance, decomposing over 85 % of the toluene gas within 150 min even under visible-light irradiation. The results suggest that the CeO2 particles might increase the specific surface area, and effectively suppress the recombination of electrons and holes generated from TiO2, thereby enhancing the photocatalytic reactivity.

Researchers have made significant strides in developing high-performance anode-supported tubular solid oxide fuel cells (SOFCs). These cells feature a thin, dense electrolyte made of Ba(Zr0.1Ce0.7Y0.2)O3-δ (BZCY). The fabrication process involved several key steps. First, fine BZCY powder was prepared using a co-precipitation method. Next, Ni-BZCY anode tubes were created via an extrusion process, boasting a 34 % porosity and an average pore size of 0.381 μm. To optimize cell performance, a Ni-BZCY/BZCY nanocomposite slurry was applied as an anode functional layer (AFL) using a dip-coating method. The BZCY electrolyte itself was then coated with a vacuum slurry coating, and finally, an LSCF-BZCY cathode was added, prepared with dip-coating methods. Impedance analysis, conducted under open-circuit conditions at 700 °C, revealed impressive electrical characteristics. The BZCY electrolyte showed an ohmic resistance of approximately 0.79 Ωcm-2 and a very low polarization resistance of about 0.036 Ωcm-2. When tested in a humidified hydrogen atmosphere (3 % H2O) at temperatures ranging from 600 °C to 700 °C, these tubular BZCY cells delivered outstanding power output. Specifically, they achieved a remarkable maximum power density of roughly 0.51 Wcm-2 at 700 °C. This research highlights the potential of these advanced tubular solid oxide fuel cells based on the BZCY as a proton conductor for efficient energy conversion.

본 연구는 넷플릭스 오리지널 드라마 <오징어 게임> 시즌 2의 O/X 투표 시스템을 게임이론과 대리인 이론의 통합적 관점에서 분석한다. 연구의 핵심 가설은 게임 운영자가 정보 비대칭과 전략적 개입을 활용 하여 참가자들의 집단 의사결정을 체계적으로 조작한다는 것이다. 게임 이론적 분석 결과, O/X 투표는 다중 균형을 가진 조정 게임으로서 전 략적 불확실성과 조정 실패로 인해 사회적으로 비효율적인 균형이 실 현됨을 확인하였다. 대리인 이론적 분석에서는 전통적인 주인-대리인 관계가 역전된 구조를 발견하였다. 형식적으로는 참가자들이 주인이지 만, 실제로는 운영자가 핵심 정보를 독점함으로써 실질적 권력을 행사 한다. 이러한 정보 비대칭은 역선택과 도덕적 해이를 발생시켜 참가자 들의 합리적 의사결정을 왜곡시킨다. 운영자는 O/X 투표 시스템에서 선택적 정보 공개와 프레이밍을 통해 참가자들의 인식을 조작한다. 본 연구는 형식적 민주주의가 정보 비대칭과 전략적 조작에 의한 왜곡 과 정을 규명하며, 이는 현실의 의사결정 상황에 실천적 통찰을 제공한다.

Inspired by the recycling approach of electronic waste, within this research paper, we extracted exhausted materials from spent primary zinc batteries and then annealed them in a modified condition, forming a ZnMn2O4/ C composite with a uniform nanoparticles’ porous morphology. The produced material has been examined as a supercapacitor active one, which showed promising electrochemical properties for supercapacitor application. At a current density of 3 A g− 1, it exerted a comparatively significant capacitance of 1696.88 F g− 1 along with a capacity of 807 C g− 1. Furthermore, the fabrication of a flexible all-solid-state symmetric supercapacitor prototype has been accomplished. It exhibited promising initial results that carried a specific energy of 76.75 Wh kg− 1 at a specific power of 333.86 W kg− 1. After 3000 cycles, it maintained an acceptable capacity. Thus, this eco-friendly approach can successfully convert the spent battery material to new value-added materials for supercapacitors in the clean energy area.

To optimize the electrochemical properties of Ni-rich cathode materials, CPAN@SC-NCM811 is prepared via surface modification of single-crystalline LiNi0.8Co0.1Mn0.1O2 cathode material by adding 1, 2 and 3 wt.% of polyacrylonitrile, respectively. Significantly, the results obtained from X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), field emission scanning electron microscopy (FESEM), and transmission electron microscopy (TEM) verify the successful synthesis of CPAN@SC-NCM811 cathode, which exhibits better electrochemical properties compared to SC-NMC811. After thorough milling and calcination of 2 wt.% polyacrylonitrile with SC-NCM811, the initial discharge specific capacity of prepared S2 sample is 197.7 mAh g− 1 and the capacity retention reached 89.2% after 100 cycles at a rate of 1.0 C. Furthermore, the S2 sample exhibits superior rate performance compared to the other three samples, in which these superior electrochemical properties are largely attributed to the optimal ratio of conductive cyclized polyacrylonitrile coatings. Overall, this work offers guidelines for modifying the surface of SC-NCM811 cathode materials for lithium-ion batteries with exceptional cycling and rate performance.

In this work, we reported a method for a fabrication of bead-on-string structured g-C3N4/CoFe2O4 composite nanofibers by electrospinning coupled with in situ calcination. For the first time, this catalyst effectively removed high concentrations of mixed organic pollutants through the synergistic effects of adsorption and photocatalysis. The composite materials removal efficiency of adsorption and photocatalytic for high concentrations of organic pollutants in wastewater can exceed 90%. Surface potential analysis using in situ Kelvin probe force microscopy demonstrated the electron transfer pathways on the catalyst surface. The formation of the heterojunction was demonstrated through DFT calculations to significantly enhance the efficiency of electron–hole separation. This work provided valuable insights for the development of efficient catalysts for the synergistic adsorption-photocatalytic treatment of environmental pollutants, thus addressing increasingly severe environmental challenges.

Using durian shell as a carbon source and triethanolamine as a nitrogen dopant, nitrogen-doped carbon dots (N-CDs) were prepared via the hydrothermal method. First, by exploring different reaction times, reaction temperatures, and carbon source/dopant ratios to synthesize nitrogen-doped carbon dots, it is concluded that the best process conditions are 200 ℃, reaction time being 15h, and the dopant addition amount being 2mL. Structure and characteristics of the synthesized CDs were analyzed using X-ray photoelectron spectroscopy, Fourier-transform infrared, fluorescence (FL), ultraviolet–visible absorption, and Raman spectra. The N-CDs showed blue FL with a quantum efficiency of 4.28%. The FL characteristics of the N-CDs were utilized for ion detection, which demonstrated that MnO− 4 and Cr 2 O2− 7 ions caused distinct FL quenching through static quenching, while other ions had no significant quenching effect. The detection limits for MnO− 4 and Cr 2 O2− 7 were 37.5 and 46.2 nM, respectively. The N-CDs were subsequently employed to detect these ions in actual water samples, producing satisfactory results. Therefore, the preparation of N-CDs using durian shell as raw material and its application in practical detection work have good application feedback, which not only provides a new way for the reuse of fruit and vegetable wastes but also provides a new detection means for environmental monitoring pollutants.

식용버섯은 1-3일의 제한된 유효 섭취기간을 가진 가장 부패하기 쉬운 재료 중 하나로서 바실러스 세레우스(Bacillus cereus), 장(관)출혈성 대장균(enterohemorrhagic Escherichia coli), 리스테리아 모노사이토제넨스(Listeria monocytogenes) 및 황색포도상구균(Staphylococcus aureus) 등의 병원성 세 균에 오염될 수 있으며, 특히 팽이버섯은 포장 및 소비 전 에 추가적인 세척이나 가공 단계를 거치지 않기 때문에 이를 그대로 섭취 시 소비자의 식품안전에 문제를 미칠 수 있다. 무엇보다 팽이버섯은 소비자들이 자연스럽고 영 양가 있는 식단을 선호하는 이유로 종종 날 것으로, 즉 샐 러드와 샌드위치 등의 형태로 섭취된다는 점에 유의할 필 요가 있다. 따라서 본 연구는 팽이버섯(Flammulina velutipes)에 접종한 병원성 대장균 O157:H7(pathogenic Escherichia coli O157:H7) 및 리스테리아 모노사이토제넨 스를 제어하기 위하여 초음파(ultrasound, US)와 유기산 (organic acids, OAAs) 및/또는 식물성 에센셜(essential) 오 일의 병행 처리에 따른 저감 효과를 조사하고자 수행되었다. 팽이버섯에 105-6 CFU/g의 수준에 상응하는 각 병원성 세균을 접종하고 다양한 농도의 유기산, 최소저해농도 (minimal inhibitory concentrations, MICs)의 티몰(thymol) 및/또는 20 kHz 초음파를 상온에서 15분 동안 개별적으 로 또는 병행하여 처리하였다. 그 결과로써, 상온에서 15 분 동안 3% 유기산, 2×MIC 티몰 또는 20 kHz 초음파를 개별적으로 처리한 후 병원성 대장균 O157:H7과 리스테 리아 모노사이토제넨스의 균 밀도가 약 1.7 로그 이하로 감소한 반면, 3% 젖산과 2×MIC 티몰의 혼합액에 20 kHz 초음파를 상온에서 15분간 병행처리한 경우 팽이버섯에 접종한 병원성 대장균 O157:H7과 리스테리아 모노사이토 제넨스의 균 밀도가 대략 3.0 로그 이상으로 감소함에 따 라 additive 효과가 관찰되었다. 특히 3% 젖산(lactic acid, LA)+2×MIC 티몰+20 kHz 초음파의 병행처리를 하기 전∙ 후에 팽이버섯의 색상 변화에 유의미한(P<0.05) 차이가 관 찰되지 않았다. 결론적으로 팽이버섯에 접종한 병원성 대장균 O157:H7 및 리스테리아 모노사이토제넨스의 제어에 단일 처리로서 3% 젖산이 가장 효과적이었던 반면, 초음파의 단일 처리 로서는 이러한 병원성 세균에 대한 저감 효과를 관찰할 수 없었다. 특히 유기산(즉 젖산) 및 초음파를 단일 처리 하였을 때보다 젖산과 티몰의 혼합액(mixture)에 20 kHz 초음파를 동시에 병행 처리하였을 때 유의적으로(P<0.05) 가장 높은 저감 효과를 관찰할 수 있었다. 이에 따라 초 음파는 유기산과 티몰의 혼합용액이 병원성 대장균 O157:H7 의 세포에 더 수월하게 접근을 가능케 하여 결국 세포막 파괴를 수반하는 것으로 확인되었다.

The structural, thermal, and electrical characteristics of the superconducting Bi2Ba2Ca2Cu3O10+δ compound are the main subjects of this work. The solid-state reaction (SSR) method was used to prepare the samples. The samples were placed in a furnace and heated at 820 °C for 70 hours at a heating rate of 5 °C/min. X-ray diffraction (XRD) studies were then performed on the prepared samples. XRD results revealed an orthorhombic crystal structure with variations in the lattice constants a, b, and c (where a = 5.416, b = 5.432, and c = 36.5 Å). The highest superconducting transition phase fraction (HTP%) was 78.76 %. The composition and morphology of the superconducting compound were studied using a scanning electron microscope (SEM). Images were taken at 20 kX magnification, where we observed nanoparticles with a size of 86.65 nm had formed. The elemental analysis of the sample was conducted with energy-dispersive X-ray spectroscopy (EDS), and the results showed the presence of different elements and their proportions for each sample. Thermal conductivity was also measured and it was found that the sample conductivity increased with increasing temperature. The electrical resistivity was examined, and it was observed that the resistivity decreased as the sample was cooled. The results showed that the highest initial critical temperature was 131 K, while the zero critical temperature was 114 K.

본 연구는 바이오차를 혼입한 콘크리트를 구조용 재료로 활용할 가능성을 검토하기 위해, 보강근의 종류에 따른 부착 성능 차이를 실험적으로 분석하였다. 이를 위해 직접 인발 실험을 수행하였으며, 실험 변수로는 콘크리트의 종류(일반/바이오차), 보강근의 종류(철근/GFRP), 보강근 직경(D13/D16)을 설정하였다. 실험 결과, 일반 철근을 적용한 실험체에서는 바이오차 혼입이 부착강도 저 하를 유발하였으며, 특히 D13 보강근에서 약 30%의 감소가 확인되었다. 반면, GFRP 보강근을 적용한 실험체에서는 바이오차 콘크리 트를 적용한 경우 부착성능이 소폭 향상되는 경향을 보였다. 또한 보강근의 직경이 증가할수록 최대 인발하중 및 평균 부착강도가 증가하는 양상이 일관되게 관찰되었다. 이러한 결과는 GFRP 보강근과 바이오차 콘크리트의 조합이 기계적 결합력 증대를 통해 긍정적인 구조 성능을 발휘할 수 있음을 시사하며, 향후 지속가능한 콘크리트 구조물의 보강설계에 기초자료로 활용될 수 있을 것으로 기대된다.