토석 채취 후 식생복구지의 토양 특성은 복구 식생의 생육에 중요하다. 본 연구는 토석 채취 후 식생복구지와 인접 소나무 및 굴참나무 임분을 대상으로 0∼10cm, 10∼20cm, 20∼30cm 깊이에 토양의 물리·화학적 특성을 조사하였다. 토양용적밀도와 토양 pH는 식생복구지가 소나무나 굴참나무 임분에 비해 유의적으로 높았으나(P<0.05), 유기탄소와 전질소농도는 인접 산림지에 비해 낮았다. 유효 인은 0~10cm 깊이에서 식생복구지 와 산림지 간 유의적인 차이가 없었으나, 교환성 칼슘은 식생복구지가 인접 산림지에 비해 유의적으로 높게 나타났다. 토양 유기 탄소저장량은 식생복구지가 9,896 kg C ha-1로 소나무 임분 131,368 kg C ha-1나 굴참나무 임분 154,381 kg C ha-1에 비해 유의적으로 낮았으며 질소저장량도(식 생복구지: 2,406 kg N ha-1; 소나무: 10,496 kg N ha-1; 굴참나무: 8,081 kg N ha-1) 유사한 경향을 보였다. 그러나 인, 포타슘, 마그네슘 저장량은 식생복구지와 인접 산림 간 유의적인 차이는 없었다. 한편, 칼슘저장량은 식생복구지가 8,998 kg Ca ha-1로 소나무 임분 697 kg Ca ha-1나 굴참나무 임분 660 kg Ca ha-1에 비해 유의적으로 크게 나타났다. 본 연구 결과에 따르면 토석 채취 후 식생복구지는 토양용적밀도와 토양 pH를 낮추고 유기물의 증가와 질소 시비 같은 양분관리가 필요한 것으로 나타났다.

When decommissioning a nuclear power plant, the structure must be made to a disposable size. In general, the cutting process is essential when dismantling a nuclear power plant. Mainly, thermal cutting method is used to cutting metal structures. The aerosols generated during thermal cutting have a size distribution of less than 1 μm. The contaminated structures are able to generate radioactive aerosols in the decommissioning. Radioactive aerosols of 1 μm or less are deposited in the respiratory tract by workers’ breathing, causing the possibility of internal exposure. Therefore, workers must be protected from the risk of exposure to radioactive aerosols. Prior knowledge of aerosols generated during metal cutting is important to ensure worker safety. In this study, the physical and chemical properties of the aerosol were evaluated by measuring the number and mass concentrations of aerosols generated when cutting SUS304 and SA508 using the laser cutting method. High-resolution aerosol measuring equipment (HR-ELPI+, DEKATI) was used to measure the concentration of aerosols. The HR-ELPI+ is an impactor-type aerosol measuring equipment that measures the aerosol number concentration distribution in the aerodynamic diameter range of 6 nm to 10 um in real-time. And analyze the mass concentration of the aerosol according to the diameter range through the impactor. ICP-MS was used for elemental mass concentration analysis in the aerosol. Analytical elements were Fe, Cr, Ni and Mn. For the evaluation of physical and chemical properties, the MMAD of each element and CMAD were calculated in the aerosol distribution. Under the same cutting conditions, it was confirmed that the number concentration of aerosols generated from both materials had a uni-modal distribution with a peak around 0.1 um. CMAD was calculated to be 0.072 um for both SUS304 and SA508. The trend of the CMAD calculation results is the same even when the cutting conditions are changed. In the case of MMAD, it was confirmed that SUS304 had an MMAD of around 0.1 μm in size for only Fe, Cr and Mn. And SA508, Fe, Cr, Ni and Mn were all confirmed to have MMAD around 0.1 μm in size. The results of this study show that a lot of aerosols in the range of less than 1 μm, especially around 0.1 μm in size, are generated when metal is cut using laser cutting. Therefore, in order to protect the internal exposure of workers to laser metal cutting when decommissioning NPPs, it is necessary to protect from nano-sized aerosols beyond micron size.

Bentonite containing >50wt% montmorillonite is being considered as a buffer material in a deep geological repository to dispose of high-level radioactive wastes (HLRW). Bentonite is considered a buffer material because of its exceptional properties such as high swelling capacity, low hydraulic conductivity, and high radionuclide sorption capacity. The bentonite buffer can be exposed to heat from the radioactive decay of HLRW and to groundwater. Water in bentonite buffer can be converted to steam under elevated temperature and pressure conditions. Previous studies reported contrasting results showing that steam treatment could decrease the swelling capacity due to changes in the surface properties from hydrophilic to hydrophobic or could not change. The contrasting results were probably because different studies used different experimental conditions and methods. Therefore, the effect of steam treatment on the bentonite properties is still unclear. The purpose of this study is to determine how the bentonite properties change after steam treatment, in particular swelling and hydrophilic properties. Two types of bentonite were used for steam treatment and analysis; Gyeongju Ca-bentonite (KJ- II) and Wyoming Na-bentonite (GCL-B). Steam treatment was performed at 150°C in an oven for various periods (7, 30, 60, and 90 days). Free swell test, X-ray fluorescence (XRF) analysis, surface-area measurement (BET), thermal gravimetric analysis (TGA), cation exchange capacity (CEC), and water uptake test were performed on steam-treated bentonite for various periods and raw bentonite. After steam treatment, some properties of steam-treated bentonite changed when compared to raw bentonite. Free swell index, which means the swelling capacity, decreased significantly as the results of previous studies. CEC and BET surface area values depended on the bentonite type. For Wyoming Na-bentonite, in which the dominant interlayer cation is a monovalent cation, CEC and BET surface area values were increased. On the other hand, Gyeongju Ca-bentonite, in which the dominant interlayer cation is a divalent cation, has no change in the above two properties. Results of XRF analysis, TGA, and water uptake test showed that these properties of both bentonites did not change after steam treatment. The results of this study confirmed that steam treatment affected the swelling and physicochemical properties of bentonite, in particular Na-bentonite. Further studies will focus on the surface properties of bentonite to investigate whether the surface properties have changed from hydrophilicity to hydrophobicity, or whether the montmorillonite structure has changed.

Surface morphology and optical properties such as transmittance and haze effect of glass etched by physical and chemical etching processes were investigated. The physical etching process was carried out by pen type sandblasting process with 15~20 μm dia. of Al2O3 media; the chemical etching process was conducted using HF-based mixed etchant. Sandblasting was performed in terms of variables such as the distance of 8 cm between the gun nozzle and the glass substrate, the fixed air pressure of 0.5bar, and the constant speed control of the specimen stage. The chemical etching process was conducted with mixed etching solution prepared by combination of BHF (Buffered Hydrofluoric Acid), HCl, and distilled water. The morphology of the glass surface after sandblasting process displayed sharp collision vestiges with nonuniform shapes that could initiate fractures. The haze values of the sandblasted glass were quantitatively acceptable. However, based on visual observation, the desirable Anti-Glare effect was not achieved. On the other hand, irregularly shaped and sharp vestiges transformed into enlarged and smooth micro-spherical craters with the subsequent chemical etching process. The curvature of the spherical crater increased distinctly by 60 minutes and decreased gradually with increasing etching time. Further, the spherical craters with reduced curvature were uniformly distributed over the etched glass surface. The haze value increased sharply up to 55 % and the transmittance decreased by 90 % at 60 minutes of etching time. The ideal haze value range of 3~7 % and transmittance value range of above 90 % were achieved in the period of 240 to 720 minutes of etching time for the selected concentration of the chemical etchant.

Cellulose acetate (CA) has been used for microfiltration/ultrafiltration applications because of its good solubility in common solvents. However, it is sensitive to chemical and physical degradation. Therefore, in this study, cellulose acetate was crosslinked with terephthaloyl chloride (TPC) in dimethylacetamide (DMAc) solution to complement these weakness. Cross-linking was confirmed by increasing in dope solution viscosity and FT-IR. To indicate the chemical resistance, weight loss was observed after the cross-linked CA membranes were immersed in ethanol, hexane, acetone and DMAc solvent for 24h. The physical properties were evaluated by the tensile strength. In the result of experience, effect of the degree of cross-linking by increasing of the concentration of TPC improved the chemical and physical properties of CA.

We have carried out optical spectroscopic measurements of emission lines for a sample of Galactic plan- etary nebulae with Wolf-Rayet (WR) stars and weak emission-line stars (wels). The plasma diagnostics and elemental abundance analysis have been done using both collisionally excited lines (CELs) and optical recombination lines (ORLs). It was found that the abundance discrepancy factors (ADF = ORL/CEL) are closely correlated with the difference between temperatures derived from forbidden lines and those from He i recombination lines, implying the existence of H-deficient materials embedded in the nebula. The Hβ surface brightness correlations suggest that they might be also related to the nebular evolution.

Tuberculation and slime accumulated in water mains play an important role in modifying water quality of drinking water. Therefore, in this study, it was investigated that what materials were accumulated, and what components were included in the tuberculation and slime of water mains. The Various tuberculation and slime sample were collected from the 12 water mains to analyze their physical and chemical properties and crystal structure. As a analysis method, VSS(Volatile suspended solid), SEM(scanning electron microscope), EDS(Energy Dispersive X-ray spectroscope), ICP(Inductively Coupled Plasma Mass Spectrometer) and XRD(X-Ray Diffractomete) were used. The results of analysis on the samples, the representative materials were verified such as iron corrosion products, the fine sand particles generated during backwash, fine particles of activated carbon, aluminum used in coagulation process, and manganese included in raw water.

In this study, the effects of silver treatment and activation on the physical and chemical properties of spherical activated carbon (SAC) were studied. The textural properties of SAC were characterized by BET surface area, XRD, SEM, iodine adsorption, strength intensity, pressure drop and antibacterial effects. BET surface areas of SACs decreased with an increase of the amount of PR before and after activation, and the BET surface areas of SACs were found to be about 2-3 times the size of those before activation. The XRD patterns showed their existing state as stable Ag crystals and carbon structure. The Ag particles are seaweedlike and uniform, being approximately 5-10 μm in size deposited on the surface of activated carbon. All of the samples had much more iodine adsorption capability after activation than before activation. The strength values of SACs increased with an increase of the amount of PR, and there was a smaller drop in the strength values of SACs with silver treatment than with non-silver treatment after activation. The Ag-SAC composites showed strong antibacterial activity against Escherichia coli (E. Coli).

최근 국제 유가의 상승으로 인한 선박 운용비를 절감하기 위하여 중소형 선박에서도 저질연료유의 사용이 검토되고 있는 추세이다. 이 연구에서는 현재 중소형 선박에서 연료유로 사용중인 경유와 중유MF380을 혼합하여 소형선박에 사용이 가능하도록 제조한 혼합연료유인 MF30 연료유에 대하여 그 물리 화학적 특성을 분석하고 정제처리 및 연료유첨가제 효과에 대해 알아보았다. 연구결과 두 가지 전처리 방식인 원심식청정기와 가열 및 균질 방식(M.C.H)의 효과는 다소 미약하였지만, 유동점과 인화점은 다소 낮아졌다. 연료유첨가제로 인한 개질 효과는 뚜렷이 나타나지 않았다.

This study was carried out in order to produce useful material for the forest multiple use and forest protection by soil physico-chemical analysis of studied area in Mt. Palgong. The results of soil physico-chemical analysis and statistical analysis represented as following 2 points. 1. Soil depth was in the range of average 61.1 cm and soil texture was loamy sand and sandy loam except Donghwasa area. The part of solid phase and gaseous phase were higher than other areas, but liquid phase was less in verse. Soil water content was in an average 49.5%, penetrability was average and the average of soil hardness was . This data showed that soil water content, penetrability and soil hardness were good at Mt. Palgong forest soils. 2. Soil pH was the range of 3.4 to 6.0, organic carbon content was 2.8% that is nearly mean of the Korea brown forest soils, total N content is somewhat smaller than that of other places, and total average C/N ratios was 13.9. Average available concentration was 5.05 mg/kg that is lower than that of any others. The concentration of available P of coniferous forests is higher than that of deciduous forests. Exchangeable cations content is similar to those of the Korea brown forest soil and the order of the cation content extent is > > > .

Ash ball 배지의 이화학적특성과 사용배지의 염류집적 및 제거효과를 펄라이트 및 입상암면과 비교하였다. ash ball의 가비중, 진비중, 공극율은 각각 0.93 g.cm-3, 2.29 g.cm-3, 40.6%, 59.4%로서 그중 가비중은 펄라이트 및 입상암면에 비해 현저히 높았고 가공율은 낮았다. 배지의 포화수분함량(saturation moisture capacity)은 ash ball이 52%, 펄라이트가 71%, 입상암면이 90%로 나타났고, 배수 1시간 후 수분율은 ahs ball이가 21%, 펄라이트가 27%, 입상암면이 80%로 낮아졌다. Ash ball의 입도별 수분율은 소립(3~5 mm)이 대립 (7~15mm)에 비해 5% 정도 높았다. Ash ball의 배드내 수분율은 수직 및 수평방향의 분포가 균일하여 수분확산성이 좋은 것으로 나타났다. ash ball의 pH는 7.6으로 약염기성을 나타내었다. 배지를 침지한 배양액의 pH는 7.6으로 약염기성을 나타내었다. 배지를 침지한 배양액의 pH는 다소 증가하는 경향을 보였으며 EC는 거의 변호가 없었으며, 배지내 무기이온의 흡착은 ash ball과 입상암면은 인산의 흡착이 비교적 많았다. 토마토 재배에 사용된 ash ball의 염류집적은 펄라이트와 비슷하였고 8회 정도의 침수처리로 배지표면에 흡착된 무기염을 대부분 제거할 수 있었다. 위의 결과로부터, ash ball 배지는 보수력은 다소 낮지만 통기성 및 수분확산성이 우수하여 배지내의 수분조절이 용이한 배지임을 알 수 있었다.

A trial was carried out to investigate the effect of fermented saw-dust pig manure (FSP) and N fertilizer application on physical, chemical properties and microbial population of soil on Cheju brown volcanic ash pasture during the period from September, 1

An important business-field of world-wide steel-industry is the coating of thin metal-sheets with zinc, zinc-aluminum and aluminum based materials. These products mostly go into automotive industry. in particular for the car-body. into building and construction industry as well as household appliances. Due to mass-production, the processing is done in large continuously operating plants where the mostly cold-rolled metal-strip as the substrate is handled in coils up to 40 tons unwind before and rolled up again after passing the processing plant which includes cleaning, annealing, hot-dip galvanizing / aluminizing and chemical treatment. In the liquid Zn, Zn-AI, AI-Zn and AI-Si bathes a combined action of corrosion and wear under high temperature and high stress onto the transfer components (rolls) accounts for major economic losses. Most critical here are the bearing systems of these rolls operating in the liquid system. Rolls in liquid system can not be avoided as they are needed to transfer the steel-strip into and out of the crucible. Since several years, ceramic roller bearings are tested here [1.2], however, in particular due to uncontrollable Slag-impurities within the hot bath [3], slide bearings are still expected to be of a higher potential [4]. The today's state of the art is the application of slide bearings based on Stellite\ulcorneragainst Stellite which is in general a 50-60 wt% Co-matrix with incorporated Cr- and W-carbides and other composites. Indeed Stellite is used as the bearing-material as of it's chemical properties (does not go into solution), the physical properties in particular with poor lubricating properties are not satisfying at all. To increase the Sliding behavior in the bearing system, about 0.15-0.2 wt% of lead has been added into the hot-bath in the past. Due to environmental regulations. this had to be reduced dramatically_ This together with the heavily increasing production rates expressed by increased velocity of the substrate-steel-band up to 200 m/min and increased tractate power up to 10 tons in modern plants. leads to life times of the bearings of a few up to several days only. To improve this situation. the Mechanical Alloying (MA) TeChnique [5.6.7.8] is used to prOduce advanced Stellite-based bearing materials. A lubricating phase is introduced into Stellite-powder-material by MA, the composite-powder-particles are coated by High Energy Milling (HEM) in order to produce bearing-bushes of approximately 12 kg by Sintering, Liquid Phase Sintering (LPS) and Hot Isostatic Pressing (HIP). The chemical and physical behavior of samples as well as the bearing systems in the hot galvanizing / aluminizing plant are discussed. DependenCies like lubricant material and composite, LPS-binder and composite, particle shape and PM-route with respect to achievable density. (temperature--) shock-reSistibility and corrosive-wear behavior will be described. The materials are characterized by particle size analysis (laser diffraction), scanning electron microscopy and X-ray diffraction. corrosive-wear behavior is determined using a special cylinder-in-bush apparatus (CIBA) as well as field-test in real production condition. Part I of this work describes the initial testing phase where different sample materials are produced, characterized, consolidated and tested in the CIBA under a common AI-Zn-system. The results are discussed and the material-system for the large components to be produced for the field test in real production condition is decided. Outlook: Part II of this work will describe the field test in a hot-dip-galvanizing/aluminizing plant of the mechanically alloyed bearing bushes under aluminum-rich liquid metal. Alter testing, the bushes will be characterized and obtained results with respect to wear. expected lifetime, surface roughness and infiltration will be discussed. Part III of this project will describe a second initial testing phase where the won results of part 1+11 will be transferred to the AI-Si system. Part IV of this project will describe the field test in a hot-dip-aluminizing plant of the mechanically alloyed bearing bushes under aluminum liquid metal. After testing. the bushes will be characterized and obtained results with respect to wear. expected lifetime, surface roughness and infiltration will be discussed.

본 연구에서는 유기물 재료로 구득이 쉽고 수량이 풍부하며 재료의 균일성이 좋은 왕겨를 팽연화 하여 양액재배용 배지 재료 사용하기 위해 적합한 조건을 탐색해 보았다. 팽연화 왕겨의 물리성은 CEC 37.0cmol.kg-1, 가비중 0.19g.㎤, -0.1 bar 상태에서 보수력 271.0으로 펄라이트보다 우수하였으나 흡수속도는 펄라이트에 크게 떨어지는 경향이었다. 팽연화 수준이 높아짐에 따라 보수력, 흡수속도 등 수분관련 물성이 좋아지는데 반해 입도가 작아지고 부숙속도가 빨라지는 변화가 있었고 재배중 부숙이 진행됨에 따라 급액 15일 이후부터 pH가 상승되며 15~20일 사이에 NO3 부족이 심화되어 작물에 스테레스를 주는 것으로 판단되었다. ERH a처리에서 당도가 펄라이트에 비해 약 1.0 。Brix정도 높고 수량의 유의성은 없었으므로 틈새간극 8mm, 날높이 3mm에서 생산된 팽연화 왕겨의 물성이 양액재배용 배지 재료로 사용하기에 적정하였다.

강원도 고성군 죽왕면과 토성면 일대의 소나무군락을 대상으로 1996년 4월에 발생한 산화에 따른 산림환경변화가 토양의 이화학성에 미치는 영향을 구명하기 위하여 비산화지역(NF) 산화후 비벌채지역(FNC), 산화후 벌채지역(FC) 및 산화후 조림지역(FCP)으로 분류하여 토양의 특성을 분석하였다. 전조사지역의 토성은 사질식양토이었고, 토양의 입경조성을 비교하면 비산화지역은 표토의 모래함량이 심토보다 낮았고, 점토함량은 높았지만 산화지역은 모두 표토의 모래함량이 점토에 비해 높았다. 토양공극 분포 중 전공극량은 지역별로 큰 차이가 없었으나, 조공극량과 투수성은 비산화지역 ＞ 산화후 비벌채지역 ＞ 산화후 조림지역 ＞ 산화후 벌채지역 순이었고, 세공극량과 가비중은 반대의 경향을 나타내었다. 이는 산화에 따른 산림환경변화로 지피식생이 제거되어 토양침식이 가속화되면서 토양 내 수분함유능력의 지표인 토양공극과 투수성에 큰 영향을 주면서 토양물리성을 악화시키고 있는 것으로 판단된다. 토양 pH는 비산화지역과 산화후 비벌채지역이 산화후 벌채지역과 조림지역보다 표토 및 심토 모두 높게 나타났다. 유기물함량 및 전질소함량 변화는 표토와 심토 모두 비산화지역＞ 산화후 비벌채지역＞ 산화후 조림지역＞ 산화후 벌채지역 순이었다. 양이온치환용량 및 치환성 양이온(K+ , Na+ /, Ca2+, Mg2+)함량 변화는 모두 표토가 심토보다 높았으며, 지역별로는 비산화지역＞ 산화후 비벌채지역＞ 산화후 조림지역＞ 산화후 벌채지역 순으로, 이는 산화후 표토층의 침식으로 지력이 악화된 결과로 사료된다.

본 실험은 펄라이트의 물리성, 화학성 및 배수 특성을 구명하고 이를 근거로 배지내 적정 수분관리를 시도해 보고자 수행하였다. 입자 분포를 5단계로 분류하였고, very-coarse 이상의 입자들이 98.5%를 점유하였다. 물리적인 특성은 very-coarse 이상의 입자들이 coarse 이하의 입자들보다 기상 비율은 각각 76.7%와 87.5%로 낮았지만, 고상 비율은 각각 13.2%와 7.0%, 액상 비율은 각각 10.2%와 5.5%로 높았다 양이온치환용량은 fine 입자가 1.867 me.100g-1로 크게 나타났다. 배수 면적이 클록 배수량이 많았으며, 관수 후 5분 이내에 관수량의 65~70% 정도가 배수되었다. 배지 깊이에 비례해서 배지내 수분량의 차이가 있었으며, 배수 후 펄라이트의 수분량은 약 2mL.cm-2.cm-1 / 정도로 추정된다. 시간이 경과됨에 따라 pF 수치는 증가하는 경향을 보였으며, 배지내 수분함량과 pF치간의 관계는 고도로 유의한 부의 상관(R2＝0.997)이 있었다. 펄라이트 배지의 배수 특성을 파악하여 배지내 적정 수분함량을 조절할 수 있을 것으로 판단되었다.

This study examined the physical and chemical properties of soil in Jang-San wetland in Busan Metropolitan City. The wetland covers wide and flat area comparing to its outside. The samples of the wetland soil were collected and analyzed in order to identify the profiles and chemical properties. According to the analyses of soil moisture and particle size distribution, the wetland soil mostly belongs to sandy loam with the soil moistures of 14.9-153.2%. The soil profiles are configured with O, A, B, and C horizons from the land surface. The organic matter content (2.38-16.7%) at most sampling locations decreases downwardly with the highest at 0-20 cm depth. The organic matter content has a good positive relationship with soil moisture content. According to X-ray diffraction analysis, the wetland soils contain quartz and feldspar (the main components of rhyolite porphyry) as well as montmorillonite, gibbsite, and kaolinite (the weathered products of feldspar). The wetland soil displays the highest iron concentration (average 22,052 mg/kg), indicating oxidation of iron. High concentrations of potassium (average 17,822 mg/kg) and sodium (average 5,394 mg/kg) originate from the weathering of feldspar. Among anions, sulfate concentration is highest with average 9.21 mg/kg that may originate from sulfate minerals and atmosphere.