In the decommissioning process of nuclear power plants, Ni-59, Ni-63 and Fe-55 present in radioactive waste are crucial radionuclides used as fundamental indicators in determining waste treatment methods. However, due to their low-energy emissions, the chemical separation of these two radionuclides is essential compared to others. Therefore, this study aims to evaluate the suitability of various pre-treatment methods for decommissioning waste materials by conducting characteristic assessments at each chemical separation stage. The goal is to find the most optimized pre-treatment method for the analysis of Ni-59, Ni-63 and Fe-55 in decommissioning waste. The comparative evaluation results confirm that the chemical separation procedures for Fe and Ni are very stable in terms of stepwise recovery rates and the removal of interfering radionuclides. However, decommissioning waste materials, which mainly consist of concrete, metals, etc., possess unique properties, and a significant portion may be low-radioactivity waste suitable for on-site disposal. Considering that the chemical behavior and reaction characteristics may vary at each chemical separation stage depending on the matrix properties of the materials, it is considered necessary to apply cascading chemical separation or develop and apply individual chemical separation methods. This should be done by verifying and validating their effectiveness on actual decommissioning waste materials.

To secure approval for a decommissioning plan in Korea, it is essential to evaluate contamination dispersion through groundwater during the decommissioning process. To achieve this, licensees must assess the groundwater characteristics of the facility’s site and subsequently develop a groundwater flow model. It is worth noting that Combustible Radioactive Waste Treatment Facility (CRWTF) is characterized by their simplicity and absence of liquid radioactive waste generation. Given these facility characteristics, the groundwater flow model for CRWTF utilizes data from neighboring facilities, with the feasibility of using reference data substantiated through comparative analysis involving groundwater characteristic testing and on-site modeling. To enable a comparison between the actual site’s groundwater characteristics and the referenced modeling, two types of hydraulic constant characterization tests were conducted. First, hydraulic conductivity was determined through long-term pumping and recovery tests. The ‘Theis’ and ‘Cooper-Jacob’ equations, along with the ‘Theis recovery’ equation, were applied to calculate hydraulic conductivity, and the final result adopted the average of the calculated values. Secondly, a groundwater flow test was conducted to confirm the alignment between the main flow direction of the referenced model and the groundwater flow in the CRWTF, utilizing the particle tracking technique. The evaluation of hydraulic conductivity from the hydraulic constant test revealed that the measured value at the actual site was approximately 1.84 times higher than the modeled value. This variance is considered valid, taking into consideration the modeling’s calibration range and the fact that measurements were taken during a period characterized by wet conditions. Furthermore, a close correspondence was observed between the groundwater flow direction in the reference model (ranging from 90° to 170°) and the facility’s actual flow direction (ranging from 78° to 95°). The results of reference data for the CRWTF, based on the nearby facility’s model, were validated through the hydraulic properties test. Consequently, the modeling data can be employed for the demolition plan of CRWTF. It is also anticipated that these comparative analysis methods will be instrumental in shaping the groundwater investigation plans for facilities with characteristics similar to CRWTF.

Various types of radioactive liquid and solid wastes are generated during the operation and decommissioning of nuclear power plants. To remove radionuclides Co-60, Cs-137 etc. from a liquid waste, the ion-exchange process based on organic resins has been commonly used for the operation of nuclear facilities. Due to the considerations for the final disposal of process endproduct, other treatment methods such as adsorption, precipitation using some inorganic materials have been suggested to prepare for large amounts of waste during decommissioning. This study evaluated sintering characteristics for radioactive precipitates generated during the liquid waste treatment process. The volume reduction efficiency and compressive strength of sintered pellets were the major parameters for the evaluation. Major components of a simulated precipitate were some coagulated (oxy) hydroxides containing light elements, such as Si, Al, Mg, Ca, and zeolite particles. Green pellets compressed to around 100 MPa were heated at a range of 750~850°C to synthesize sintered pellets. It was observed that the volume reduction percentages were higher than 50% in the appropriate sintering conditions. The volume reduction was caused by the reduction of void space between particles, which is an evidence of partial glassification and ceramization of the precipitates. This result can also be attributed to conversion reactions of zeolite particles into other minerals. The compressive strength ranged from 6 to 19 MPa. These results also showed a significant correlation with the volume reduction of sintered body. Although our lab-scale experiments showed many benefits of sintering for the precipitates, optimized conditions are needed for large-scale practical applications. Evaluation of sintering characteristics as a function of pellet size and further testing will be conducted in the future.

Various dry active wastes (DAWs) have been accumulated in nuclear power plants since the DAWs are mostly combustible. KAERI has developed a thermochemical treatment process for the used decontamination paper as an operational waste to substitute for incineration process and to decontaminate radionuclides from the DAWs. The thermochemical process is composed of thermal decomposition in a closed vessel, chlorination of carbonated DAWs, separation of soluble chlorides captured in water by hydroxide precipitation, and immobilization of the precipitate. This study examined the third and fourth steps in the process to immobilize Co-60 by fabricating a stable wasteform. Precipitation behaviors were investigated in the chloride solution by adding 10 M KOH. It was shown that the precipitates were composed of Mg(OH)2 and Al(OH)3. Then, the glass-ceramic wasteform for the precipitates were produced by adding additive mixtures in which silica and boron oxide were blended with various ratios. The wasteform was evaluated in terms of volume reduction ratio, bulk density, compressive strength, and leachability.

The type of radioactive waste that may occur in the process of nuclear power plant dismantling can be classified into solid, liquid, gas, and mixed waste. The amount of these wastes must be defined in the Final Decommissioning Plan for approval of the licensing. Also, in the case of Metal radioactive waste, it is necessary to calculate the generation amount in order to treat radioactive waste at a Radioactive Waste Treatment Facility (RWTF). Since a large quantity of metal radioactive waste is generated during the decommissioning of a nuclear power plant, the application of a metal melter for reduction is considered. The metal waste is heated to a temperature above the melting point and separated into liquid and gas forms. Nuclides existing on the surface of metal waste vaporize in a melting furnace to become dust or collect in sludge. Nonvolatile nuclides such as Co, Fe and Mn remain in ingot, but other nuclides can be captured and reduced with dust and sludge. And the types of melting furnaces to be applied can be broadly classified into Atmospheric Induction Melter (AIM) and Vacuum Induction Melter (VIM). Therefore, this review intends to compare the two types of metal furnaces to be included in RWTF.

When aluminum is in an alkaline state, the aluminum oxide film surrounding aluminum is dissolved and moisture penetrates the exposed aluminum surface, causing corrosion of aluminum. At this time, hydrogen gas is generated and there is a risk of explosion due to the generated hydrogen gas. Aluminum radioactive waste is difficult to permanently dispose of because it does not meet the standards for the acquisition of low- and intermediate-level radioactive waste cave disposal facilities currently managed and operated by the Korea Nuclear Environment Corporation. However, because of this risk, it is necessary to study how to safely treat and dispose aluminum waste. In this study, overseas cases were investigated and analyzed to ensure the safety of aluminum waste disposal, and the current status of aluminum radioactive waste generated during decommissioning of the Korea Research Reactor 1&2 and a treatment plan to secure disposal suitability were presented. The process of removing a little remaining oxygen in molten steel during the reduction of iron oxide in the iron refining process is called deoxidation, and a representative material used for deoxidation is aluminum. In the case of metal melting decontamination, which is one of the decontamination processes of radioactive metal waste, a method of treating aluminum waste by using aluminum as a deoxidizer is proposed.

During the operation of nuclear power plant (NPP), the concentrates and spent resin are generated. They show relatively high radioactivity compared to other radioactive waste, such as dry active waste, charcoals, and concrete wastes. The waste acceptance criteria (WAC) of disposal facility defines the structure and property of treated waste. The concentrates and spent resin should be solidified or packaged in high integrity container (HIC) to satisfy the WAC in Korea. The Kori NPP has stored history waste. The large concrete package with solidified concentrates and spent resin. The WAC requires identification of 18 properties for the radioactive waste. Since some of the properties are not clearly identified, the large concrete packages could not satisfy the WAC in this moment. The generation of the large concrete package (rectangular type and cylindrical type), pretreatment of the package, treatment of inner drum, process development for clearance waste, etc. will be discussed in this paper. In addition, the conceptual design of whole treatment process will be discussed.

In light of recent significant seismic events in Korea and worldwide, there is an urgent need to reevaluate the adequacy of seismic assessments conducted during facility construction. This study reexamines the ongoing viability of the Safety Shutdown Earthquake (SSE) criteria assessment for the Combustible Radioactive Waste Treatment Facility (CRWTF) site at the Korea Atomic Energy Research Institute (KAERI), originally established in 1994. To validate the SSE assessment, we delineated 13 seismic structure zones within the Korean Peninsula and employed two distinct methodologies. Initially, we updated earthquake occurrence data from 1994 to the present year (2023) to assess changes in the site’s horizontal maximum earthquake acceleration (g). Subsequently, we conducted a comparative analysis using the same dataset, contrasting the outcomes derived from the existing distance attenuation equation with those from the most recent attenuation equations to evaluate the reliability of the applied attenuation model. The Safety Shutdown Earthquake (SSE) criterion of 0.2 g remains unexceeded, even when considering recent earthquake events since the original evaluation in 1994. Furthermore, when applying various assessment equations developed subsequently, the maximum value obtained from the previously utilized ‘Donvan and Bornstein’ attenuation equation is 0.1496 g, closely resembling the outcome derived from the recently employed ‘Lee’ reduction equation of 0.1451 g. The SSE criteria for CRWTF remain valid in the current context, even in light of recent seismic occurrences such as the 2016 Gyeongju earthquake. Additionally, the attenuation equation employed in the evaluation consistently yields conservative results when compared to methodologies used in recent assessments. Consequently, the existing SSE criteria remain valid at present. This study is expected to serve as a valuable reference for confirming the SSE criterion assessment of similarly constructed facilities within KAERI.

Among the nuclear power plant facility improvement projects, out of a total 10 replacement reactor vessel closure head (RRVCH), five have been replaced, starting with Gori Unit 1, and five, including Hanul Unit 1, Hanbit Units 5 and 6, and Hanul Units 3 and 4 will be replaced in the future. This paper presents the method of treating Latch Housing among radioactive waste generated during the replacement of Hanul Unit 2 (February 2023). Latch Housing controls the control rod by receiving magnetic force from the CRDM’s Coil Stack. Located in the Old Reactor Vessel Head (ORVH) Hot Spot, the range of measured radiation dose rate was 0.3 to 0.8 mSv h-1 (up to 4.5 mSv h-1). The amount of radioactive waste generated was 35.8 Baler-Drum (based on 200L), and the order of treatment was to cut into the Omega Seal of the CRDM, the CRDM and Latch Housing Transfer, the boundary of the CRDM and Latch Housing, the Rod Travel Housing, the Motor Housing and the Latch Assembly, and then transfer and Drumming. In the United States, out of 93 operating reactors, 31 reactor vessel heads have been replaced and 19 reactor vessel heads are scheduled to be replaced. In Korea, 25 reactors are in operation, and two reactors have been permanently shut down. Among them, the nine old reactors for more than 30 years (as of September 2021) are expected to achieve ALARA and reduce radwaste management costs through the management method applied to replace the reactor vessel head.

Radioactive iodine-129, a byproduct of nuclear fission in nuclear power plants, presents significant environmental and health risks due to its high solubility in water and volatility. Iodine-129, with its half-life of 1.57×1017 years, necessitates safe management and disposal. Therefore, safely capturing and managing I-129 during spent nuclear fuel reprocessing is of paramount importance. To address these challenges, various glass waste forms containing silver iodide have been developed, such as borosilicate, silver phosphate, silver vanadate, and silver tellurite glasses. These glasses effectively immobilize iodine, but the high cost of silver raises affordability concerns. This study introduces CuI·Cu2O·TeO2 glass waste forms for iodine immobilization, a novel approach. The cost-effectiveness of copper, in contrast to silver, makes it an attractive alternative. The CuI·Cu2O·TeO2 glass waste forms were synthesized with varying CuI content (x) in (1-x)(0.3Cu2O·0.7TeO2) glass matrices. Xray diffraction (XRD) confirmed amorphous structures, and X-ray fluorescence (XRF) quantified composition. X-ray photoelectron spectroscopy (XPS) and Raman spectroscopy provided insights into structural properties. Durability assessments using a 7-day product consistency test (PCT-A) and inductively coupled plasma-mass spectrometry (ICP-MS) revealed compliance with U.S. glass regulations, making CuI·Cu2O·TeO2 glasses a promising choice for iodine immobilization in radioactive waste.

The type of radioactive waste that may occur in the process of NPP dismantling can be classified into solid, liquid, gas, and mixed waste. Most of the radioactive waste generated during the dismantling of a NPP is metal solid waste, but liquid radioactive waste is also a very important factor in terms of radiation environmental impact assessment. In the case of liquid radioactive waste, it is necessary to calculate the generation amount in order to design liquid radioactive waste processing system of Radioactive Waste Treatment Facility (RWTF). Depending on the amount of liquid radioactive waste generated, the type of liquid radioactive waste processing system included in the RWTF is different. In addition, in order to apply to the domestic RWTF, it is important to secure the site area occupied by the each system, the liquid radioactive waste treatment capacity of the system, and how to secure circulating water used for dilution and discharge of liquid radioactive waste. Therefore, this review aims to suggest an optimal method for the treatment system for liquid radioactive waste included in RWTF of Wolseong.

The decommissioning of Korea’s nuclear power facilities is expected to take place starting with the Kori Unit 1 followed by the Wolsong Unit 1. In Korea, since there is no experience of decommissioning, considerations of site selection for the waste treatment facilities and reasonable selection methods will be needed. Only when factors to be considered for construction are properly selected and their effects are properly analyzed, it will be possible to operate a treatment facility suitable for future decommissioning projects. Therefore, this study aims to derive factors to be considered for the site selection of treatment facilities and present a reasonable selection methodology through evaluation of these factors. In order to select a site for waste treatment facilities, three virtual locations were applied in this study: warehouse 1 to warehouse 3. Such a virtual warehouse could be regarded as a site for construction warehouses, material warehouses, annexed building sites, and parking lots in nuclear facilities. If the selection of preliminary sites was made in the draft, then it is necessary to select the influencing factors for these sites. The site of the treatment facility shall be suitable for the transfer of the waste from the place where the dismantling waste is generated to the treatment facility. In addition, in order for construction to take place, interference with existing facilities and safety should not be affected, and it should not be complicated or narrow during construction. Considering the foundation and accessibility, the construction of the facility should be economical, and the final dismantling of the facility should also be easy. In order to determine one final preferred plan with three hypothetical locations and five influencing factors, there will be complex aspects and it will be difficult to maintain consistency as the evaluation between each factor progresses. Therefore, we introduce the Analytic Hierarchical Process (AHP) methodology to perform pairwise comparison between factors to derive an optimal plan. One optimal plan was selected by evaluating the three virtual places and five factors of consideration presented in this study. Given the complexity and consistency of multiple influencing factors present and prioritizing them, AHP tools help users make decisions easier by providing simple and useful features. Above all, it will be most important to secure sufficient grounds for pairwise comparison between influencing factors and conduct an evaluation based on this.

The intermediate level spent resins waste generated from water purification for the the moderator and primary heat transport system during operaioin of heavy water reactor (HWR). Especially, moderator resins contain high level activity largely because of their C-14 content. So spent resins are considered as a problematirc solid waste and require special treatment to meet the waste acceptance criteria for a disposal site. Various methods have been studied for the treatment of spent resins which include thermal, destructive, and stripping methods. In the case of solidification methods, cement, bitument or organic polymers were suggested. In the 1990s, acid stripping using nitric acid and thermal treatment methods were actively investigated in Canada to remove C-14 nuclide from waste resin. In Japan, thermal distructive method was studied in the 1990s. Since 2005, KAERI developed acid stripping method using phosphate salt. However, acid stripping method are not suitable due to large amounts of 2nd waste containing acid solution with various nuclides. To solve this probelm, KAERI has been suggested the microwave treatment method for C-14 selective removal from waste resin in the 2010s. Pilot scale demonstration tests using radioactive waste resin generated from Wolsung unit 1 and unit 2 were successfully conducted and 95% of C-14 was selectively removed from the radioactive waste resin. In recent years, price of C-14 source is dramatically increased due to market growth of C-14 utilization and exclusive supply chain depending on China and Russia. High purity of C-14 were captured in HWR waste resin. Interest of C-14 recovery research from HWR waste resin is currently increased in Canada. In this study, microwave method is suggested to treat HWR waste resin with C-14 recovery process. Additionally, status of waste resin management and research trends of HWR waste resin treatment are introduced.

The type of radioactive waste that may occur in the process of nuclear power plant dismantling can be classified into solid, liquid, gas, and mixed waste. In addition, according to the level of radioactivity, it can be divided into high level, intermediate level, low level, and clearance level waste. In the case of solid radioactive waste, it is necessary to secure disposal suitability in order to deliver it to a disposal facility, so safe and efficient treatment of a large amount of radioactive waste generated during decommissioning is one of the most important issues. For the treatment of radioactive waste generated during decommissioning, technologies in various fields such as cutting, decontamination, melting, measurement, and packaging are required. Therefore, this study intends to present and application plan for decommissioning domestic nuclear power plants through overseas case studies for the treatment of radioactive waste expected to occur during nuclear power plant decommissioning.

Various dry actives wastes (e.g., gloves, wipers, shoes, clothes) are generated during operation and maintenance of nuclear facilities. Among those, latex gloves gets interest because they contain both organic and inorganic compounds. CaCO3 is a common filler material for production of latex rubbers. Here, latex gloves were thermally treated in a closed vessel to separate the organic and inorganic compounds. Using the closed vessel is beneficial as it can prevent escape of any species, including radioactive nuclides in a real case, generated during the treatment. It was found that thermal decomposition of latex gloves occurred above 250°C. Latex gloves were decomposed to gas, liquid, and solid compounds. The gas product is thought to be volatile organic compounds (VOCs). The liquid product seems to be a mixture of oils and water. A CaCO3 phase was identified in the solid product, as expected. The VOCs can be easily separated at room temperature by purging in vacuum or inert atmosphere. The liquid-solid mixture can be separated by distillation. It is thought that gammaemitting nuclides, such as Cs-137, Sr-90, and Co-60, dominantly remain in the solid product. In the best situation, the solid product is the only subject to be transferred to final wasteform fabrication stream and thus volume of final waste can be reduced. Surrogates of contaminated latex gloves (containing Cs, Sr, and Co) were prepared and they were treated at 350°C in the closed vessel. How these contaminants behaves in this thermal process will be discussed in the presentation.

A large amount of small and medium-sized metal waste is generated during the decommissioning of nuclear power plants (NPPs). Metal waste is mostly contaminated with low-level radioactive, so it needs decontamination for self-disposal and recycling. A large amount of Organic Decontamination Liquid Waste during decontamination will be generated. The generated organic liquid waste is low in concentration, so the decomposition efficiency is low in the decomposition process. A conditioning process is necessary to concentrate at a high concentration. For effective treatment for Organic Decontamination Liquid Waste, the composition of organic liquid waste and conditioning process were analyzed. Organic acids, metal ions, radioactive nuclides, surfactants, etc. are present in the Organic Decontamination Liquid Waste, and suspended solids are sometimes generated by various reactions. According to previous studies, the concentration of organic acids including surfactants obtained results from several tens of ppm to a maximum of 1,000 ppm, so the maximum value of 1,000 ppm was assumed. For the composition and total amount of metal ions, the average value (52.7wt% Fe, 16.3wt% Ni, 15.1wt% Cr, 15.9wt% Mn) of the distribution of metal species removed by the actual decontamination process is applied, and the total amount is 1,000 ppm was assumed. As for the radionuclides, only 60Co and 137Cs, which are expected to be mainly present, were considered, and 60Co was assumed to be 2,000 Bq/g and 137Cs to be 360 Bq/g by referring to the literature. The amounts of suspended solids were assumed to be 500 ppm by referring to the characteristics of the liquid waste generated in the decontamination process of the NPPs. Based on the estimated value, a reaction formula was established and a simulated Organic Decontamination Liquid Waste was prepared. As a result of measurement using an analysis device, the composition of the estimated and simulated Organic Decontamination Liquid Waste had similar values. The conditioning and treatment process largely consists of pretreatment, conditioning, decomposition processes. Organic Decontamination Liquid Waste goes through a pretreatment process to remove impurities with large particles. In the conditioning process, treated water that has passed through the UF/RO membrane system is discharged into the environment. At this time, Concentrated water goes through a decomposition process for processing the Organic Decontamination Liquid Waste, and is discharged to the environment through a secondary RO membrane system. The conditioning process is the low-concentration Organic Decontamination Liquid Waste in the UF membrane system is forming a micelles in an RO membrane system, concentrating it to a high concentration and then go through a recirculation process in the UF membrane system. An experiment was conducted to confirm whether the concentration of surfactants occurred during the conditioning process. As a result of the experiment confirmed that the highly concentrated surfactant formed micelles and was filtered out in the UF membrane system.

Decommissioning of Nuclear Power Plant (NPP) projects in South Korea starts with permanent shutdown of Kori unit 1 and Wolsung unit 1. It is important to establish a treatment and disposal method for radioactive waste generated during the decommissioning of the nuclear power plants. Large quantities of the wastes during decommissioning of NPP are generated in a short period of time and the wastes have various types and characteristics. For efficient decommissioning of NPP process, the radioactive waste is classified by types and each treatment method and packaging concept is presented respectively in this paper. Radioactive waste generated during decommissioning of NPP is classified into reactor vessel, reactor internals, metals, Dry Active Waste (DAW), concreate, spent fuel storage rack, spent resin and spent filter, etc., and the packaging concept for each type should be established to meet the waste acceptance criteria. Major waste acceptance criteria requirements include nuclides concentration, filling rate, free water, surface radiation does rate and weight. Radioactive waste containers can be classified into packaging containers, transport containers, and disposal containers. The packaging container is used to contain, transport, and store radioactive waste within the radiation control area, and a control number has been assigned as a radioactive waste drum after the final treatment has been completed. The transport container is used for transporting radioactive waste filled-containers from a radiation control area through an uncontrolled area. In this paper, the concept of disposal of dismantled radioactive waste and packaging methods were reviewed in comprehensive consideration of domestic radioactive waste transport and storage regulations, permanent disposal environment, and development status of large containers.

Kori Unit 1 was permanently shut down in 2017 and is preparing to be dismantled. Decommissioning nuclear power plants is expected to generate a lot of decommissioning waste. Therefore, a radioactive waste treatment complex will be built on the site to safely and effectively the process of decommissioning waste generated from the Kori Unit 1, and the details are specified in the decommissioning plan. Therefore, a safety assessment should be conducted according to the facility’s normal and abnormal operations to construct a radioactive waste treatment complex. Currently, a safety assessment for a radioactive waste treatment complex can be conducted by the Safety Assessment Framework (SAFRAN) Tool based on the Safety Assessment Driving Radioactive Waste Management Solutions (SADRWMS) methodology developed by the International Atomic Energy Agency (IAEA). The SAFRAN Tool can be calculated radiation dose and hazard quotient (HQ) for workers and the public under normal and abnormal conditions of the radioactive waste treatment complex. When evaluating the radiation dose for the public due to releasing radioactive materials into the air or discharging radioactive materials into liquids, the radiation dose is calculated using the amount discharged or released from the treatment complex, and the Pathway Dose Factors (PDFs) derived from the generic environmental model given in the IAEA Safety Reports Series No.19. PDFs, which reflect the specific site data rather than the generic environmental model data, should be calculated and evaluated when performing the safety evaluation of the radioactive waste treatment complex to be built on the Kori site. In addition, in the SAFRAN tool, there is an inconvenience in that it must be calculated separately by radionuclides to calculate the contribution of dose or HQ for each radionuclide. Therefore, in this study, a safety assessment tool for a radioactive waste treatment complex was developed using Visual Basic by supplementing the limitations of the SAFRAN tool. This tool was developed to allow users to choose whether to apply PDFs based on the IAEA SRS-19 based on the generic environmental model or PDFs calculated to reflect the specific site data. Furthermore, the tool considered all types of decommissioning wastes that may occur during the decommissioning of the Kori Unit 1 and the treatment process scheduled to be introduced. Therefore, this study is expected to be used as basic data when conducting the safety assessment of radioactive waste treatment complex scheduled to be introduced in Korea.

The nuclear facilities at Korea Atomic Energy Research Institute (KAERI) have generated a variety of liquid radioactive waste and most of them have low-level radioactive or lower levels. Some of the liquid radioactive waste generated in KAERI is transported to Radioactive Waste Treatment Facility (RWTF) in 20 L container. Liquid radioactive waste transported in a 20 L container is stored in a Sewer Tank after passing through a solid-liquid separation filter. It is then transferred to a very low-level liquid radioactive waste Tank after removing impurities such as sludge through a pre-treatment device. The previous pre-treatment process involved an underwater pump and a cartridge filter device passively, but this presented challenges such as the inconvenience of having to install the underwater pump each time, radiation exposure for workers due to frequent replacement of the cartridge filter, and the generation of large amounts of radioactive waste from the filter. To address these challenges and improve efficiency and safety in radiation work, an automated liquid radioactive waste pre-treatment device was developed. The automated liquid radioactive waste pre-treatment device is a pressure filtration system that utilizes multiple overlapping filter plates and pump pressure to effectively remove impurities such as sludge from liquid radioactive waste. With just the push of a button, the device automatically supplies and processes the waste, reducing radiation hazards and ensuring worker safety. Its modular and mobile design allows for flexible utilization in various locations, enabling efficient pre-treatment of liquid radioactive waste. To evaluate the performance of the newly constructed automated liquid radioactive waste treatment device, samples were taken before and after treatment for 1 hour cycling and analyzed for turbidity. The results showed that the turbidity after treatment was more than about four times lower than before treatment, confirming the excellent performance of the device. Also, it is expected that the treatment efficiency will improve further as the treatment time and number of cycles increase.

Thermal treatment, such as combustion, is the most effective way to solve the spatial problem of radioactive waste disposal. Existing incineration technology has the problem of discharging harmful pollutants (CO2 and dioxin, etc.) into the environment. Therefore, it was evaluate the validity of the thermal treatment process that can reduce the volume of dry active waste (DAW) in an eco-friendly. In addition, the stability of the alternative incineration process under development was evaluated by evaluating the emission of harmful pollutants to the environment during the thermal treatment process. We selected 14 samples identical to those discarded by each nuclear power plant (Kori, Saeul, Wolsong, Hanbit, Hanul). And EA (Elemental Analysis) analysis was performed on each sample. As a result, excluded samples containing wastes containing POPs (Persistent Organic Pollutants) such as PCBs (Polychlorinated Biphenyls), which could generate harmful pollutants during thermal treatment, and halogenated organic wastes such as PVC (Polyvinyl Chloride). In addition, the thermal treatment conditions for the four DAWs were derived by Thermogravimetric Analysis/Differential Thermal Analysis (TG/DTA) analysis. At this time, Py-GC/MS analysis was performed at the temperature at which each waste causes thermal decomposition (cotton is 437°C, paper is 562°C, latex glove is 430°C, plastic bag is 485°C). As a result of analyzing the exhaust gas produced during thermal decomposition, about 77.0% of the cotton was Benzoic acid series, the paper was 41.1% Glucopyranose series, and 15.8% hydroxy acetaldehyde. Latex glove was identified to be 45.9% and 19.2% for Limonene and 2-methyl-1, 3-Butadiene, and for plastic bags, Octacosanol and 2-octyl-1-Dodecanol were 38.8% and 15.2%. In addition, it was confirmed that dioxin and harmful heavy metals, which are discussed as environmental risks, were not detected in all samples.