Change in chemical constitution of a zirconium sample treated at the simulated condition of a pressurized water reactor (water at 315°C and 15.5 MPa) was investigated using X-ray diffraction (XRD) and Raman spectroscopy. We observed swelling of the zirconium sample as well as the change in its color from silver to gray treated after the pressurized water at high temperature. On the basis of XRD and Raman data, we confirmed that the variation in composition of zirconium specimen from hexagonal Zr to monoclinic ZrO2 occurred at the simulated PWR condition. Therefore, we suggested that the oxidation of zirconium appeared due to the reaction with water at high temperature and pressure, as shown in the following reaction: Zr + 2H2O → ZrO2 + 2H2.

Since 1992, various numerical codes, such as TOUGH-FLAC and ROCMAS, have been developed and validated to dispose of Spent Nuclear Fuel (SNF) safely through a series of DEvelopment of COupled models and their VALidation against EXperiments (DECOVALEX) projects. These codes have been developed using different approaches, such as general two-phase flow and Richards’ flow which is an approximated approach neglecting gas pressure change, to implement the same multiphysics behaviors. However, the quantitative analysis for numerical results, which originated from different fundamental approaches, has not been conducted accurately. As a result, improper utilization of the approach to analyze certain conditions occurring such as dramatic gas pressure change may result in erroneous outcomes and systemic problem pertaining to TH analysis. In this study, the quantitative analysis of the two approaches, in terms of TH behavior, was conducted by comparing them with a 1D simulation of the CTF1 experiment carried out by laboratory experiment. The results calculated by different approaches show agreement in terms of TH behaviors and material properties change until 120°C. The results verify the applicability of Richards’ flow approach in a high temperature environment above the current thermal criteria, set as 100°C, and gas pressure change does not have a significant impact until 120°C. Therefore, although further studies for applicability of Richards’ flow are needed to suggest the appropriate temperature range, these quantitative analyses may contribute to the performance assessment of a compact repository using the high-temperature bentonite concept, which is currently gaining attention.

This study aims to select eggplant cultivars adaptive to the hot temperature period greenhouse climate by water consumption, and growth performance of plants and fruits of different European eggplant cultivars, including ‘Bartok (BA)’, ‘Bowie (BO)’, ‘Black Pearl (BP)’, ‘Ishbilia (I)’, ‘Mabel (M)’, ‘Vestale (VE)’ and ‘Velia (VL)’, in substrate hydroponic cultivation under hot and humid greenhouse conditions. On the 118 DAT, the leaf number and stem dry weight were highest in ‘VL’, followed by ‘M’, and there was no significant difference in leaf dry weight among cultivars. The marketable fruit number per plant was 16.4 for ‘M’, which was higher than other cultivars, and ‘VE’ and ‘VL’ were 8.5 and 8.8, respectively. The weight per fruit was low for ‘M’ at 136 g, and the highest in ‘VE’ and ‘VL’ at 332 and 281 g, respectively. There was no significant difference in fruit production per plant. In this study, ‘M’, which has high water use efficiency and a large number of fruits, and ‘VL’, which required less quantity to water consumption for producing 200 g of fruit and had a high product weight, will have excellent adaptability in the UAE greenhouse condition.

This study was conducted to apply with an air duct for the cooling and a utilizing cultivating method that uses the fruiting node and the defoliation to the high-temperature vertical and hydroponic cultivation of the oriental melon. The lower fruiting node (LF) was to remove all third vines generated from 5 nodes of a secondary vine. The higher fruiting node (HF) was fruiting on the third vine generated from a first node of the third vine. The direction of the stem string; upward (UW), downward (DW). Four treatment conditions were applied with the LF-UW, LF-DW, HF-UW (control), and HF-DW. The leaf age of melon leaves was measured for photosynthesis at 3 days intervals, and the fruit characteristic was conducted on 79 fruits in each treatment. The photosynthesis rate steadily increased after leaf development, reaching 20.8 μmol CO2·m-2·s-1 on the 10 days, gradually increasing to 21.3 μmol CO2·m-2·s-1 on the 19 days, and reaching 23.4 μmol CO2·m-2·s-1 on the 32 days. After that, it lowered to 16.8 μmol CO2·m-2·s-1 on the 38 days and dropped significantly to 7.6 μmol CO2·m-2·s-1 on the 47 days. As a result of the fruit characteristics by fruiting nodes, the treatments of the fruit length was 12.6-13.4 cm, respectively, which was significant, and the fruit width was 7.9- 8.6 cm, respectively, was not significant. The soluble content ranged from 12.9 to 15.7°Brix, and the significance of all treatments, and higher than of LF-DW and HF-UW. The photosynthesis rate of melon leaves was good until 32 days after leaf development, but after that, the rate decreased. As for fruit quality, it was conformed that melons can be cultivated at the LF because the fruit enlargement and soluble content dose not decrease even when set at the LF. Results indicated that those can be used for LF and defoliation in the development of vertical and hydroponic cultivation method in high-temperature season.

Coking coal is an important raw material for coke production. In this study, in an inert atmosphere, two Chinese coking coal samples were, respectively, heated gradually to 1200 °C to release volatile and form char and coke in succession, then cooled naturally to close room temperature to age the coke. The whole heating and cooling process on carbonization were monitored in situ by simultaneous small and wide-angle X-ray scattering (SAXS-WAXS) technique based on a synchrotron radiation platform. The simultaneous structural changes of pore and skeleton in coal during carbonization are revealed for the first time. The two raw coal samples, with similar carbon content and slightly different coalification degree, undergone a carbonization process similar in whole and different in parts. The carbonization presents approximately three stages during heating process and one stage during cooling process. The coal structure changes wavily during heating and monotonously during cooling. The corresponding structural change mechanism is analyzed.

High-temperature oxidation of a Ni-based superalloy was analyzed with samples taken from gas turbine blades, where the samples were heat-treated and thermally exposed. The effect of Cr/Ti/Al elements in the alloy on high temperature oxidation was investigated using an optical microscope, SEM/EDS, and TEM. A high-Cr/high-Ti oxide layer was formed on the blade surface under the heat-treated state considered to be the initial stage of high-temperature oxidation. In addition, a PFZ (γ’ precipitate free zone) accompanied by Cr carbide of Cr23C6 and high Cr-Co phase as a kind of TCP precipitation was formed under the surface layer. Pits of several μm depth containing high-Al content oxide was observed at the boundary between the oxide layer and PFZ. However, high temperature oxidation formed on the thermally exposed blade surface consisted of the following steps: ① Ti-oxide formation in the center of the oxide layer, ② Cr-oxide formation surrounding the inner oxide layer, and ③ Al-oxide formation in the pits directly under the Cr oxide layer. It is estimated that the Cr content of Ni-based superalloys improves the oxidation resistance of the alloy by forming dense oxide layer, but produced the σ or μ phase of TCP precipitation with the high-Cr component resulting in material brittleness.

동해연안의 반폐쇄성 해역인 영일만에서 고주파해양레이더(HF-Radar)로 측정된 표층 해수유동 자료를 활용하여 1)바람과 수평 적인 해수유동 사이의 상관성을 파악하고 2)수직적으로 조밀한 간격의 층별 수온시계열 자료와 연계하여 수평적 및 수직적 해수유동의 특성을 파악하였다. 시계열 관측기간 중 영일만 해역의 전역에 걸쳐 북동풍이 우세하게 나타났을 때 표층부터 저층까지 수온의 급격한 상승이 동반되었다. 또한 표층의 장주기 해수유동에서도 풍향과 유사한 방향의 흐름이 뚜렷하게 관측되었다. 바람과 표층 해류 사이의 지 연상관 분석을 통해 영일만에 북동풍의 바람이 불기 시작하여 일정하게 지속된다면 짧은 시간(1 ~ 2시간) 내에 남서향의 표층 해류가 발 생되는 것을 확인하였다. 일평균된 장주기 표층 해류로부터 수렴과 발산을 계산하였고 이를 통해 층별 관측지점에서 발생한 두 번의 급 격한 저층수온 상승이벤트가 모두 영일만의 북동풍과 연관된 표층 해수(상대적 고온수)의 수렴(침강) 현상으로 인해 나타난 것으로 판단 하였다.

PURPOSES : When fire event occurs in tunnel the reinforced concrete is exposed to very high temperature at a very short time period. This study investigates the tensile behavior of steel rebar that experienced high temperature. METHODS : The steel rebar was exposed to 200, 400, 600, and 800℃ following the ISO 834 temperature-time fire curve. Hightemperature- exposed steel rebars were tested using the UTM for their yielding and tensile strengths, and elongation rate. RESULTS : Up to an exposure temperature of 600℃, the tensile properties of the rebar did not vary considerably. However, at 800℃ (which corresponds to a temperature rise time of approximately 22 min), the rebar lost its yielding and tensile strength by approximately 27 and 13%, respectively, compared to the control specimen. Further, the elongation rate increased after exposure to 600℃. The above fundamental tensile test results can be a good reference for future guidelines in the repair manual for tunnels after severe fire events. CONCLUSIONS : When steel rebar experiences high temperatures of 800℃, the yield strength of the rebar reduces approximately 27%. This strength reduction can cause severe structural damage to tunnels that use reinforced concrete as the primary structural elements.

High-pressure sodium (HPS) lamps have been widely used as a useful supplemental light source to emit sufficient photosynthetically active radiation and provide a radiant heat, which contribute the heat requirement in greenhouses. The objective of this study to analyze the thermal characteristics of HPS lamp and thermal behavior in supplemented greenhouse, and evaluate the performance of a horizontal leaf temperature of sweet pepper plants using computational fluid dynamics (CFD) simulation. We simulated horizontal leaf temperature on upper canopy according to three growth stage scenarios, which represented 1.0, 1.6, and 2.2 plant height, respectively. We also measured vertical leaf and air temperature accompanied by heat generation of HPS lamps. There was large leaf to air temperature differential due to non-uniformity in temperature. In our numerical calculation, thermal energy of HPS lamps contributed of 50.1% the total heat requirement on Dec. 2022. The CFD model was validated by comparing measured and simulated data at the same operating condition. Mean absolute error and root mean square error were below 0.5, which means the CFD simulation values were highly accurate. Our result about vertical leaf and air temperature can be used in decision making for efficient thermal energy management and crop growth.

Roses are one of the most produced flower species in the world, and cut roses are produced in the greenhouses all year round. Recently, due to the increase in the temperature in the greenhouses in summer, the quality of cut roses is seriously deteriorated, such as shortening the stem length. This study was conducted to investigate the effects of the growing seasons on the qualities of cut roses and also to test the effect of cooling at night in high temperature season on the cut flower qualities of roses. Comparing the qualities and yields of cut roses for each season, the major cut flower qualities such as flower stem length, stem diameter and fresh weight were statistically significantly decreased in roses (‘Pink Beauty’ and ‘Pink Shine’) produced in summer. The yields didn’t show a statistically significant difference in both cultivars. Investigating the cut flower qualities, the flower stem length increased by 15% for ‘Pink Beauty’, 11% for ‘Ararat’, and 12% for ‘Pink Shine’ when treated with cooling at night in warm season than the untreated control. In addition, when treated with cooling at night in warm season, the fresh weight of all three cultivars increased by 20-30% statistically significantly than conventionally cultivated control. It is expected that cooling at night in warm season will be helpful to improve the cut flower quality deterioration in summer.

Yttria-stabilized zirconia (YSZ) has a low thermal conductivity, high thermal expansion coefficient, and excellent mechanical properties; thus, it is used as a thermal barrier coating material for gas turbines. However, during long-time exposure of YSZ to temperatures of 1200oC or higher, a phase transformation accompanied by a volume change occurs, causing the YSZ coating layer to peel off. To solve this problem, YSZ has been doped with trivalent and tetravalent oxides to obtain coating materials with low thermal conductivity and suppressed phase transformation of zirconia. In this study, YSZ is doped with trivalent oxides, Nd2O3, Yb2O3, Al2O3, and tetravalent oxide, TiO2, and the thermal conductivity of the obtained materials is analyzed according to the composition; furthermore, the relative density change, microstructure change, and m-phase formation behavior are analyzed during long-time heat treatment at high temperatures.

고온 구동형 고분자 전해질 막 연료전지(high temperature polymer electrolyte membrane fuel cell, HT-PEMFC)는 전극의 빠른 활성과 피독 현상에 대한 높은 저항성으로 인해 저온 구동형 PEMFC의 대안으로 많은 연구가 진행되고 있다. 폴리벤즈이미다졸(polybenzimidazole, PBI)을 기반으로 한 PEM의 경우 고온 구동 조건에서 이온 전도성 물질과의 높은 상호 작용과 우수한 열적ㆍ기계적 안정성 특징으로 인해 HT-PEMFC용 PBI 기반 전해질 막 개발과 관련된 다양한 연구들이 진행 되고 있다. 본 총설에서는 고성능/고내구성의 PBI 기반 PEM을 개발하기 위해 1) 인산 및 다양한 이온전도성 물질이 도핑된 PBI 막의 특성 분석과 막 제조법에 따른 PBI 막의 물성 비교에 관한 연구를 우선적으로 살펴본 후 2) 다공성 폴리테트라플루 오르에틸렌 지지체 및 무기 입자 혼입을 통한 PBI 복합 막의 성능 개선 연구 및 3) 고분자 블렌딩을 통해 가교 구조가 도입 된 PBI 기반 가교 막의 내구성 향상에 관한 연구 동향에 대하여 소개하고자 한다.

살리실산은 식물의 생장 및 발달, 항산화 방어기작, 광합성 작용 그리고 생물적 및 비생물적 스트레스 조건에서 다양한 생리적 기능을 조절하는 물질로 알려져 있다. 본 연구에서는 고온･건조 스트레스 조건에서 살리실산 경엽처리가 고추의 생육, 광합성 특성 및 항산화효소 활성에 미치는 영향을 구명 하고자 하였다. 광합성 특성 측정결과 광합성 속도, 기공전도 도 및 증산 속도가 증가하였고, 3회차 처리에서 가장 높았다. 세포내 MDA와 H2O2 함량은 살리실산 3회차 처리에서 현저 하게 감소하는 경향을 보였다. APX, CAT, POD 및 SOD 활 성이 현저하게 증가하였으며, 무처리 대비 최대 247, 318, 55 및 54% 증가하였다. 고추의 생육 특성은 무처리구와 유의한 차이를 보이지 않았으나, 상품 수량은 15% 정도 증가하였다. 이러한 결과들을 종합해 볼 때, 살리실산의 경엽처리는 고추 의 광합성 특성과 항산화효소 활성을 증진시켜 고온･건조 스트 레스에 의한 피해 경감에 긍정적 효과를 유발함을 확인하였다

본 연구는 근권부 냉방이 토마토 육묘 시 묘 생육에 미치는 영향을 구명하고자 수행되었다. 생장상 하부 파이프 냉방을 이용하여 근권부 온도를 20°C와 25°C로 설정하여 실험을 수 행하였다. 전 생육기간동안 초장, 근장, 엽수는 두 온도 처리구 간 차이를 보이지 않았다. 엽면적, 지상부와 지하부의 생체중 및 건물중, 엽록소 함량은 파종 28일 경과 시 25°C 처리구가 더 높았으며, 실험 종료 시 두 처리구 간 유의한 차이를 보이지 않았다. 이상의 결과로 근권부 온도 20°C와 25°C에서 토마토 생육 차이를 확인하지 못했다. 따라서, 본 연구는 고온기 토마 토 묘 생산 시 온실 냉방 효율을 높이기 위한 국부 냉방 기술 확 립에 도움을 줄 수 있을 것이다.

Viscosity is a fundamental physical property that is important in any system in which fluid movement occurs. In addition, most of the elements exist as ions in molten state in high-temperature molten salt, and electrical conductivity in such molten state is closely related to viscosity as a transport property. Molten salt reactor (MSR) and pyroprocess are representative processes dealing with high-temperature molten salts, actinide elements, and other radioactive materials. In MSR and pyroprocesses, the viscosity data must be provided as one of the fundamental physical property data required for safe process operations and countermeasures to severe accidents. In order to measure the viscosity of highly corrosive molten salt at high temperatures, we have built a in-house developed molten salt viscosity measurement system based on the Brookfield rotationary viscometer. We also developed a special correction technique to improve the accuracy of the viscosity measurement. In this study, the viscosity was measured at 500°C for NaCl-MgCl2 molten salt, which is selected as the base salt material of MSR system under development in Korea Atomic Energy Research Institute (KAERI), using our viscosity measurement system installed in a oxygen- and moisture-free Ar-atmosphere glovebox. Our viscosity measurement system was calibrated using a LiCl-KCl eutectic mixture with well-known viscosity value, and viscosity values obtained using our own correction methodology were compared with those of other conventional correction methods. In our further study, we plan to measure the NaCl-MgCl2-UCl3 system at various compositions and temperatures.

Radioactive mixed waste (RMW) is containing radioactive materials and hazardous materials. Radioactive wastes containing asbestos are include in RMW. These wastes thus must be treated considering both radioactive and hazardous aspects. In this study, a high temperature melt oxidation system consisting of an electric arc furnace and a molten salt oxidation furnace has been developed for the treatment of of radioactive waste containing asbestos. A surrogate waste of the radioactive waste containing asbestos (content of asbestos: 13wt%) was treated in this system. It was melted and fabricated into a glass waste form in the system. Asbestos was not detected in this glass waste form. This means that the asbestos was converted to a glass component in the glass waste form. The waste form was homogeneous glass, and it had a high value of compressive strength (475.13 MPa). It was also confirmed through a leaching test (ANS 16.1) that the waste form had a high chemical durability (Leaching Index > 6). Based on these results, it is considered that the high temperature melt oxidation system will be utilized for the treatment of a significant amount of radioactive waste containing asbestos generated from decommissioning a nuclear power plant.