Recently, there has been growing interest in harmful substances released from household items such as volatile organic compounds (VOCs) and this has increased people’s environmental awareness. In this study, adhesives and manicures were used as samples of indoor household goods and formaldehyde emission and tested over time under temperature conditions of 15oC, 25oC, 35oC, and 45oC. The small chamber method as the indoor air quality process test method was employed and used to evaluate the concentration of formaldehyde emissions. As a result, formaldehyde emissions gradually decreased over time in both tests using adhesives and manicures. The cumulative emission showed a logarithmic function over time, and the formaldehyde can be released for longer periods of time at lower temperature conditions. The logarithmic value and response time showed linear relationships, and it can be inferred that the formaldehyde was released from the sample through the first order reaction. Furthermore, the relationship between temperature and velocity constants which was determined using the Arenius linear equation showed that the reaction rate of formaldehyde can be estimated by a temperature change.

In this study, the effects of fuel injection pressure changed from 45 to 65 MPa on combustion and emission characteristics were investigated in a common rail direct injection (CRDI) diesel engine fueled with diesel and palm oil biodiesel blends. The engine speed and engine load were controlled at constant 1700rpm and 100Nm, respectively. The tested fuel were PBD20 (20 vol.% palm oil biodiesel blended with 80 vol.% diesel fuel). The main and pilot injection timing was fixed at 3.5°CA BTDC and 27°CA BTDC (before top dead center), respectively. The experimental results show that the combustion pressure and heat release rate increased. In addition, the indicated mean effective pressure (IMEP) and maximum combustion pressure increased with an increase of the fuel injection pressure. Hydrocarbon (HC), smoke opacity and carbon monoxide (CO) decreased, but oxides of nitrogen (NOx) emissions increased as fuel injection pressure increased.

In this study, blending oils of diesel oil and butanol were used as fuel oil for diesel engine to measure combustion pressure, fuel consumption, air ratio and exhaust gas emission due to various operating conditions such as engine revolution and torque. Using these data, the results of analyzing the engine performance, combustion characteristics and exhaust emission characteristics such as NOx (nitrogen oxides), CO2 (carbon dioxide), CO (carbon monoxide) and soot were as follows. The fuel conversion efficiency at each load was highest when driven in the engine revolution determined by a fixed pitch propeller law. Except 30% butanol blending oil, fuel conversion efficiency of the other fuel oils increased as the load increased. Compared to diesel oil, using 10% and 20% butanol blending oil as fuel oil was advantageous in terms of thermal efficiency, but it did not have a significant impact on the reduction of exhaust gas emissions. On the other hand, future research is needed on the results of the 20% butanol blending oil showing lower or similar levels of smoke concentration and carbon monoxide emission rate other than those types of diesel oil.

The emission of particulate matter and volatile organic compounds (VOCs) from a motor vehicle painting booth was quantitatively evaluated. Most particulate matter was emitted during the spraying process, in which the PM10 concentration was 16.5 times higher than that of the drying process. When the paint was being sprayed, the particles with a diameter of 1.0~2.5 μm accounted for 39.4% and particles greater than 2.5 μm in diameter accounted for 30.6% of total particles. On the other hand, small particles less than 0.5 μm in diameter accounted for 52.4% of total particles during the drying process. In contrast to the particulate matter, high concentrations of VOCs were emitted during both spraying and drying processes. Butyl acetate, xylene, toluene, and m-ethyltoluene were the most abundant VOCs emitted from the motor vehicle painting booth. Additionally, xylene, butyl acetate, toluene, and 1,2,3-trimethylbenzene were the dominant ozone precursors. Especially, xylene exhibited the highest ozone production contribution (32.5~44.4%) among 34 species of the ozone precursors. The information obtained in this study can be used to establish a suitable management strategy for air pollutants from motor vehicle painting booths.

The effect of the change in air inflow velocity has been investigated at the opening of the malodor emission source to determine its influence on the Complex odor concentration. Both the Complex odor collection efficiency and concentrations were measured according to the change in airflow velocity. When the air inflow velocity was 0.1 m/s, it was observed that some of the generated gas streams were diffused to the outside due to low collection efficiency. In contrast, only the increased gas collection volume up to 0.5 m/s showed no substantial reduction of the Complex odor concentration, which indicates an increase in the size of the local exhaust system as well as the operation cost for the Complex odor control device. When the air inflow velocity reached 0.3 m/s, the Complex odor concentrations not only were the lowest, but the odorous gas could also be collected efficiently. The air inflow velocity at the opening of the malodor emission source was considered the key factor in determining the gas collection volume. Therefore, based on the results of this study, an optimal air inflow velocity might be suggestive to be 0.3 m/s.

구조와 사육환경이 동일한 3개의 돈방(room A~C)에서 48일 동안 비육돈의 암모니아 농도 및 환기량을 모니터링하여 배출계수를 산정하였다. 실험 결과, 온도 22.5℃, 습도 53.9% 환경에서 평균 암모니아 순발생 농도 5.93 ppm, 환기량 23.7 m3/h·pig로 나타났다. 일별 상관관계 분석결과, 암모니아 농도는 온도와 음의 상관관계(R2: -0.65 ~ -0.53)를 가지는 것으로 나타났으며, 환기량은 암모니아 농도에 거의 영향을 미치지 않는 것으로 나타났다. 암모니아 농도는 이른 오전을 기점으로 서서히 증가 경향을 보이다가 12~13시경 최댓값에 도달하였고, 상호 상관도가 높은 온도, 습도, 환기량의 경우 14~15시에 최댓값을 갖는 것으로 분석되었다. 시간별 데이터 상관관계 분석결과, 암모니아 배출량에 영향을 미치는 요소는 암모니아 농도(R2=0.71)와 환기량(R2=0.61)으로 이 중, 암모니아 농도가 더 상관성이 높은 것으로 분석되었다. 암모니아 배출계수는 2.28 g/d·pig로 분석되었다.

The characteristics of ammonia during the growing period of pigs in a facility with a mechanical ventilation system were analyzed, and the emission factor was calculated. Real-time ammonia concentration was measured using photoacoustic spectroscopy equipment, and a ventilation measuring device was fabricated to measure the amount of air vented from an exhaust fan according to the operation rate. All data were collected as one-hour averages. The mean ammonia concentration, indoor temperature, and ventilation rate was 1.44~2.08 ppm, 25.5~26.4oC, and 24~32 m3/h per pig, respectively. Both concentration and ventilation rate are important factors in terms of emission management, but correlation analysis shows that the impact of concentration is higher than that of ventilation. Using ammonia concentration and ventilation data, the ammonia emissions per pig were calculated by considering the number of pigs (0.25~1.74 g/day·pig). The final ammonia emission factor yielded a value of 0.81 g/day·pig.

In this study, we investigated the effects of diesel-palm oil biodiesel-ethanol blends on combustion and emission characteristics in a 4-cylinder common rail direct injection (CRDI) diesel engine at low idling operations. The engine speed and engine load was 750 rpm and 40 Nm, while the main and pilot injection timing was respectively fixed at 2 °CA before top dead center (BTDC) and 20 °CA BTDC. The experimental results showed that the cylinder pressure increased with the increasing of palm oil biodiesel ratio from 20% to 100%. In addition, the peak value of cylinder pressure increased by 4.35% compared with pure diesel fuel when 5 vol.% ethanol oil added to diesel oil. Because the palm oil biodiesel and ethanol are the oxygenated fuel, the oxygen content played an important role in improving combustion. Based on the high oxygen content of biodiesel and ethanol, their mixing with diesel fuel effectively reduced PM emissions but increased NOx slightly, while CO and HC had no significant changes.

In this study, the effect of various pilot injection timings on combustion and emission characteristics were investigated in a common-rail direct injection (CRDI) diesle engine fueled with diesel-ethanol blends. The engine speed and engine load were controlled at constant 1500rpm and 70Nm, respectively. The tested fuels were DE0 (pure diesel fuel), DE5 (5 vol.% ethanol blended with 95 vol.% diesel oil), DE10 (10 vol.% ethanol blended with 90 vol.% diesel oil) and DE15 (15 vol.% ethanol blended with 85 vol.% diesel oil). The main injection timing was fixed at 0°CA TDC (top dead center), while various pilot injection timings including 25°CA BTDC (before top dead center), 20°CA BTDC and 10°CA BTDC were selected as the experimental variable. The experimental results showed that various pilot injection timings had little effect on the peak value of cylinder pressure, but had great influence on the start of combustion. The peak value of heat release rate (HHR) increased with the increase of ethanol content. However, the peak value of HRR reduced as the pilot injection is delayed. The diesel fuel containing 10% ethanol had a highest peak value of combustion pressure compared with the others, while the pilot injection timing occurred at 25°CA BTDC. On the other hand, the exhaust emissions of DE10 was also the lowest compared with the others. In addition, with the increase of ethanol content in diesel the PM and NOx emissions reduced.

최근 지구의 기후변화는 온실가스가 원인으로 전 세계적 대기환경문제로 크게 부각되고 있다. 국내에서도 기후변화에 적극 대응하기 위한 기술개발이 꾸준히 진행되고 있다. 날씨의 이상고온으로 인한 환경에 미치는 영향과 갑작스런 집중호우가 환경에 미치는 영향을 대상으로 하였다. 우리생활 주변 대기온도가 상승하였을 때 온도변화에 의한 대기오염발생에 미치는 영향을 연구하고자 한다. 본 연구의 실험조건은 선박 디젤기관에서 회전수 1400 rpm, 1600 rpm 그리고 1800 rpm, 부하는 0 %에서 25 %씩 100 %까지 하였고, 흡기 온도변화 는 20℃에서 50℃까지 구분하여 연구하였다. 연구한 결과 흡기온도가 증가함에 따라 일산화탄소 및 탄화수소는 약간 감소하였으나 연료 소비율, 질소산화물, PM은 약간 증가하였다. 또한 연소온도는 큰 변화가 없었다.

We analyzed volatile organic compounds (VOCs) of petroleum-based laundry solvents in closed systems by static headspace analysis and investigated the emission characteristics of odorous compounds emitted from organic solvents in the small-scale dry cleaning process. The compounds containing eight to eleven carbon atoms were analyzed to account for 96.92% of the total peak area in a GC-MS chromatogram. It was found that the compounds with ten carbon atoms showed the largest proportion. In the small-scale dry cleaning process (3 kg of laundry and 40 min of drying time), a total of 36 VOCs was quantified, and the odor contribution of these compounds was evaluated. The sum of the odor quotient (SOQ) was analyzed up to 151±163 in the first 12 min of operation. The main odor-causing compounds were acrolein, ethylbenzene, hexane, acetone, and decane, and their odor contributions were 32.28%, 13.47%, 10.52%, 10.20%, and 8.08%, respectively.

Recently, public complaints about unpleasant odor are increasing, particularly in urban areas. One of the odor sources is meat grilling restaurants in the vicinity of the residential areas. In this study, we characterized the odorous compounds generated from the stack of grilling restaurants, and evaluated the removal efficiency of the control facilities. As a result of the field investigation, the dilution index of the complex odor exceeded 500 times that of all test restaurants. The main substance was acetaldehyde. In addition, the correlation coefficient (R2) between the total odor and the sum of odor activity values (SOAV) was 0.73, a value high enough to indicate significant responsibility. The performance of the control facility has been shown to be strongly influenced by maintenance activities, such as cleaning and filter replacements.

The purposes of improving air pollution and suggesting energy resources have intensified research on various alternative energy for diesel combustion engines to solve severe environmental influences caused by air pollution. In this study, the applicable possibility of biodiesel and oxygenates (EGBE) was investigated as a cuspy method on decreasing the smoke emission. The smoke emission of blending fuel (biodiesel and EGBE) was reduced in comparison with commercial diesel fuel and it was reduced almost 63% at 2000 rpm, full load. But torque and brake specific energy fuel consumption rate didn't have any large changes. Also, the effectiveness of exhaust gas recirculation (EGR) for the reduction of NOx emission has been investigated. It was shown that simultaneous reduction of NOx and smoke emission was achieved with biodiesel(90%), oxygenates (10%) and cooled EGR rates (10%) in an IDI diesel engine.

To understand the effect of high pressure on nitrogen oxides (NOx) formation in water added methane flames, opposed nonpremixed Water-methane/air (H2O-CH4/air) flames are numerically studied with high initial pressure. With GRI 3.0 detailed kinetic mechanism, NOx emissions are predicted for various strain rates. Due to high pressure, the chemical species are distributed in a narrow region, which means the thickness of the flame is thin. This can be clearly seen with high strain rate. Elevated pressure increases maximum temperature of flames which results in increased NOx emission. Even with elevated initial pressure, NOx emissions for H2O added methane flames are significantly decreased compare to pure methane flame. In addition, increased strain rate is also significant factor for decreasing NOx emission. With detailed rate of production analysis, in case of high pressure, it is confirmed that NO2 pathway is the most dominant reaction pathway than any other pathways.

In the Geumho River, 4-nitrophenol has been detected, thus it is necessary to investigate the contamination sources in order to prevent the release of this compound. However, the research to estimate the potential source is regarded as complicated research. In this study, the distributions of 4-nitrophenol were simulated and the contribution of the potential sources was estimated using a numerical model(HydroGeoSphere; HGS) and the measuring data of 4-nitrophenol from 2013 to 2017. The altitude data, the land cover data, the flow rates of the tributaries and wastewater treatment plants, and the decay rate of 4-nitrophenol was used as the input data. The results of this research showed that the contribution rates of potential contamination sources in the upstream area were higher than that of the downstream area. Most of the upstream area is the agricultural area, it seemed that 4-nitrophenol was originated from the pesticides. In order to achieve more specific location of sources, an intensive investigation in the upstream is required.