수도(水稻)의 양질(良質) 품종육성(品種育性)을 위한 기초자료(基礎資料)를 얻고자 벼 7개친(個親)과 이를 이면교배(二面交配)한 21조합(組合)의 에 있어서 심복백(心腹白), 알카리붕괴도(崩壞度)를 조사(調査)하고, 조합능력(組合能力)의 검정(檢定) 및 유전분석(遺傳分析)을 한 바, 얻어진 결과(結果)를 요약(要約)하면 다음과 같다. 분산분석결과(分散分析結果) 모든 형질(形質)에서 친간(親間) 및 간(間)에 유의차(有意差)가 있었으며 친대(親對) 간(間)에도 모든 형질(形質)에서 유의차(有意差)가 있었다. 모든 형질(形質)에서 일반조합능력(一般組合能力)과 특정조합능력(特定組合能力)이 유의(有意)하였고, 12시간처리(時間處理)에서의 알카리붕괴도(崩壞度)는 비상가적유전분산(非相加的遺傳分散)이 상가적유전분산(相加的遺傳分散)보다 컸으며 타형질(他形質)은 상가적유전분산(相加的遺傳分散)이 비상가적유전분산(非相加的遺傳分散)보다 컸다. 12시간처리(時間處理)에서의 알카리붕괴도(崩壞度)는 완전우성(完全優性)을 나타내었으며 타형질(他形質)은 모두 부분우성(部分優性)을 나타내었다. 우성(優性)의 방향(方向)은 부(負)의 방향(方向)이었으며 전(全) 형질(形質)에서 광의(廣義) 및 협의(狹義)의 유전력(遺傳力)이 높게 추정(推定)되었다. 심백(心白)과 복백간(腹白間) 및 복백(腹白)과 알카리붕괴도간(崩壞度間)에 정(正)의 유의상관(有意相關)이 인정(認定)되었다.

본 연구는 건설 디지털 제조를 위한 3D 프린팅 기술 개발을 위하여, 플라이애시 및 고로슬래그 미분말 등의 알칼리 활성화 결합재를 Binder Jetting 3D 프린팅 방식으로 출력하고, 후처리 방법을 통해 출력물의 압축강도를 증진하는 것이다. 진공 펌프 및 규산나트륨-수산화나트륨 복합 수용액을 적용하여 후처리 방법을 검토하였으며, 후처리 용액에 침지한 후 -0.1 MPa 진공 압력으로 처리한 공시체의 압축강도는 11.04 MPa 로써 강도 증진을 확인하였다.

본 연구에서는 저탄소 친환경 콘크리트의 일반적인 원재료로 널리 알려져 있는 플라이애시, 고로슬래그미분말을 혼합하여 알칼리 활성화 결합재를 제작한 후, 양생 조건에 따른 내구성을 파악하고자, 탈형한 시험체를 15 및 25°C의 해수에 양생 시켜 재령 91일까지의 내구 특성을 살펴보았다. 플라이애시와 고로슬래그미분말의 혼합비에 대해서 일부 혼합에 대해서는 재령 28일에 비해 재령 91일에서 흡수율 증가 및 강도 감소를 나타났지만, 그 이외에는 양생 조건에 관계없이 재령에 따라 흡수율 감소 및 강도 증가를 보여주었다.

A zeolitic material (Z-Y2) was synthesized from Coal Fly Ash (CFA) using a fusion/hydrothermal method under low-alkali condition (NaOH/CFA = 0.6). The adsorption performance of the prepared zeolite was evaluated by monitoring its removal efficiencies for Sr and Cs ions, which are well-known as significant radionuclides in liquid radioactive waste. The XRD (X-ray diffraction) patterns of the synthesized Z-Y2 indicated that a Na-A type zeolite was formed from raw coal fly ash. The SEM (scanning electron microscope) images also showed that a cubic crystal structure of size 1~3㎼ was formed on its surface. In the adsorption kinetic analysis, the adsorption of Sr and Cs ions on Z-Y2 fitted the pseudo-second-order kinetic model well, instead of the pseudo-first-order kinetic model. The second-order kinetic rate constant (k2) was determined to be 0.0614 g/mmol·min for Sr and 1.8172 g/mmol·min for Cs. The adsorption equilibria of Sr and Cs ions on Z-Y2 were fitted successfully by Langmuir model. The maximum adsorption capacity (qm) of Sr and Cs was calculated as 1.6846 mmol/g and 1.2055 mmol/g, respectively. The maximum desorption capacity (qdm) of the Na ions estimated via the Langmuir desorption model was 2.4196 mmol/g for Sr and 2.1870 mmol/g for Cs. The molar ratio of the desorption/adsorption capacity (qdm/qm) was determined to be 1.44 for Na/Sr and 1.81 for Na/Cs, indicating that the amounts of desorbed Na ions and adsorbed Sr and Cs ions did not yield an equimolar ratio when using Z-Y2.

This research provides an analysis of experiments on sulfuric acid resistance of alkali-activated slag mortar with dolomite powder. The results show that the longer the bedding time, the lower the mass change in all specimens. Among them, the mass change in a dolomite replaced specimens are shown to be less than that of a non-dolomite specimens. Since the composition of dolomite reacts with sulfuric acid solution to produce a product, it is thought to play a role in reducing mass reduction.

This study is to perform experiment of concrete according to addition of blast furnace slag powder and sulfur activator dosages. Blast furnace slag powder used at 30, 50, 80% replacement by weight of cement, and liquid sulfur additives was chosen as the alkaline activator. As a result, it should be noted that the sulfur alkali-activators can not only solve the disadvantage of blast furnace slag concrete but also offer the chloride resistance of alkali-activated blast furnace slag concrete to blast furnace slag concrete.

In this study, the performance of the self-healing with the granulated alkali activator (Ca(OH)2) manufactured in seawater environment is investigated for crack healing under 300 μm of cracks. Specimens combined with GGBFS and OPC with and without the granulated alkali activator were manufactured and immersed in seawater. After that, crack recovery on the surface of the specimens with the granulated alkali activator (Ca(OH)2) was also evaluated by the ultrasonic pulse velocity test. From the results, it was verified that cementitious materials with the granulated alkali activator, exposed in marine environments, could be able to heal or seal inside cracks

In this study, alkali-activated slag (AAS) concrete made with blast furnace slag (BFS) was investigated as a replacement for ordinary Portland cement (OPC) concrete for changes in the compressive strength before and after CO2 exposure and chemical reactions with CO2. Before CO2 exposure, the compressive strength of AAS concrete was found to be up to 21 MPa, which was higher than that of OPC concrete. Exposing AAS concrete to CO2 at 5,000 ppm for 28 days did not significantly change the compressive strength. In contrast, the compressive strength of OPC concrete decreased by 13% in the same conditions. In addition, AAS concrete had the highest CO2 capture capacity of greater than 50 g CO2/kg, while the CO2 capture capacity of OPC concrete was only 2.5 g CO2/kg. Rietveld analyses using XRD results showed that fractions of main calcium-silicate-hydration (C-S-H) gels on the surface of AAS concrete did not significantly drop after CO2 exposure; the C-S-H gel on the AAS concrete was continuously produced by reacting with the SiO2 produced after the reaction with CO2 and Ca(OH)2 inside the concrete, with the result that the compressive strength of AAS concrete did not change after CO2 exposure. Thus, AAS concrete can be applied to CO2-rich environments as both a stable construction material and a CO2 sequestrate agent.

고속도로에서 콘크리트 포장의 알칼리-골재반응 발생 구간이 증가하고 있다. 알칼리-골재반응이 발생한 콘크리트 포장은 팽창하 면서 인접 교량에 교대 변위를 발생시켜 다수의 손상을 발생시키고 있다. 현장 조사 결과 콘크리트 포장의 팽창량은 온도 신축에 의한 팽창률을 상회하면서 교량에 치명적인 하중으로 작용하고 있어 손상 방지를 위한 선제적인 조치가 필요하다. 알칼리-골재 반응에 의한 팽창 정도는 알칼 리-골재반응의 상태, 포장의 길이 및 도로구조에 따라 달라짐을 알 수 있었다. 교량의 손상 방지를 위해선 콘크리트 포장의 팽창력을 이완시켜 주는 방안이 효과적이며 콘크리트 포장의 길이가 긴 구간은 아스팔트 치환공법이 유리할 것이다.

There increasing demand for technologies that are capable of producing heat and electric energy by burning fuels such as solid refuse fuel (SRF) and biomass to mitigate the effects of greenhouse gas emissions from fossil fuels and global warming in the field of thermal power generation. In particular, conversion of SRF into energy (Waste to Energy) is the promising technology with high economic and social benefits. The high temperature corrosion of the heat exchange tube is the most important factor that affects the economic deterioration of a circulating fluidized bed boiler using solid refuse fuel, due to operating time decrease and the periodic shutdown during plant operation. The purpose of this study was to examine the high temperature corrosion characteristics of boiler superheater tubes. The change of corrosion characteristics according to the temperature and alkali chloride salt can be investigated by analyzing the morphology of the surface and the microstructure of specimen cross-section and examining the changes in the physical and chemical properties. The degree of corrosion increased as the temperature increased and the weight of the alkali chloride specimen deposit decreased due to the volatilization of the metal chloride compound above 700°C. Deposits of KCl were found to accelerate corrosion by destroying the oxide layer and forming potassium compounds.

This paper investigates the strength properties of ground granulated blast furnace slag(GGBFS) with magnesium sulfate(MgSO4). GGBFS was replaced with 1, 2, 3, 4, and 5% MgSO4 by weight. Mixtures of sodium hydroxide(NaOH) and sodium silicate(Na2SiO3) were used as the alkaline activator; a mixture of 5% NaOH and 5% Na2SiO3, and a mixture of 10% NaOH and 10% Na2SiO3 by slag weight. The added activators were dissolved in the water, and the weight ratio of water to slag was 0.45. This study was performed using compressive strength testing, ultrasonic pulse velocity(UPV), water absorption and X-ray diffraction(XRD). In this study, the strength of hardened samples decreases with increasing MgSO4 content. In addition, the water absorption of samples increases and UPV decreases, with the increase of MgSO4 content. Brucite, gypsum and M-S-H(magnesium silicate hydrate) are present in the XRD patterns of the hardened samples.

The purpose of this study is to understand a compressive strength and propose a dry shrinkage strain equation being able to predict dry shrinkage of alkali-activated materials(AAM) mortar samples manufactured using fly-ash(FA) and ground granulated blast furnace slag(GGBFS). The main parameters investigated were the GGBFS replace ratios(30, 50, 70 and 100%) and sodium silicate modules(Ms[SiO2/Na2O] 1.0, 1.5 and 2.0). The compressive strength of AAM increased with increases GGBFS replace ratios or Ms contents. The dry shrinkage strain of AAM decreased with increases Ms contents. But, the dry shrinkage strain of AAM increased as the GGBFS replace ratio increases. Therefore, the GGBFS replace ratio seems to have very significant and important consequences for the mix design of the AAM mortar. The results indicated the R-square of single regression analysis based on each mix properties was the highest value; 0.7539~0.9786(average 0.9359). And the presumption equation of dry shrinkage strain with all variables(GGBFS, Ms and material age) has higher accuracy and its R-square was 0.8020 at initial curing temperature 23 degrees Celsius and 0.8018 at initial curuing temperature 70 degrees Celsius.

In this experimental study, the characteristic of damages on GFRP rebar exposed to high temperature only and immerged in alkaline solution after the exposure to high temperature was analyzed through microscopic image analysis. The found microcrack and pores in resin matrix were quantitatively compared if there was effect of pre-exposure to high temperature. The damages, such as microcrack and pores in resin matrix, by alkali exposure were mainly found in rebar surface. On the other hand, the pores caused by high temperatures were extensively found in a section and had greater width than those caused by the alkali exposure. In results of the quantitative comparison, the accumulated length and widths of microcrack and pores in resin matrix in pre-exposed GFRP rebar to high temperature were respectively 1.5 and 1.4 times of those in the GFRP rebar only immerged in alkali solution. Therefore, the deterioration of resin matrix by the alkali exposure could be accelerated due to the pre-exposure to high temperature.

This paper investigates the strength properties of ground granulated blast furnace slag(GGBFS) with magnesium sulfate(MgSO4). GGBFS was replaced with 1, 2, 3, 4, and 5% MgSO4 by weight. Mixtures of sodium hydroxide(NaOH) and sodium silicate(Na2SiO3) were used as the alkaline activator; a mixture of 5% NaOH and 5% Na2SiO3, and a mixture of 10% NaOH and 10% Na2SiO3 by slag weight. The added activators were dissolved in the water, and the weight ratio of water to slag was 0.45. This study was performed using compressive strength testing, ultrasonic pulse velocity(UPV), water absorption and X-ray diffraction(XRD). In this study, the strength of hardened samples decreases with increasing MgSO4 content. In addition, the water absorption of samples increases and UPV decreases, with the increase of MgSO4 content. Brucite, gypsum and M-S-H(magnesium silicate hydrate) are present in the XRD patterns of the hardened samples.

본 연구는 플라이애시 및 고로슬래그 미분말을 활용하여 알칼리 활성화 결합재로 제조된 모르타르 및 페이스트 샘플의 황산염 저 항성을 평가하고 황산염 침투에 대한 고저항성 결합재를 제시하는 것이다. 이를 위하여 플라이애시 및 고로슬래그미분말 등의 광물질 혼화재 를 결합재로 활용하여 고로슬래그미분말 치환율을 30, 50 및 100%로 제작하였다. 규산나트륨 모듈 Ms[SiO2/Na2O]은 1.0, 1.5 및 2.0으로 조정 하였으며, 10% 황산나트륨, 10% 황산마그네슘, 10% 질산마그네슘 및 5% 질산마그네슘+5% 황산나트륨 용액에 각각 침지시키고, 황산염 저 항성을 평가하기 위하여 압축강도, 질량변화율, 길이변화율 및 X선 회절분석을 측정하였다. 그 결과 10% 황산나트륨, 10% 질산마그네슘 및 5% 질산마그네슘+5% 황산나트륨에 침지한 경우에는 모든 시험조건에서 장기적인 강도발현과 질량 및 길이변화율이 작아 저항성이 우수한 것으로 나타났으나, 10% 황산마그네슘에 침지한 경우에는 장기적인 강도저하와 질량 및 길이변화가 크게 나타났으며, 그 경향은 고로슬래그 미분말 치환량 및 Ms비가 증가할수록 현저하였다. 이것은, X선 회절분석 결과 황산마그네슘 용액 침지에서는 gypsum(CaSO4 ․ 2H2O) 및 brucite(MgOH)생성되어 내부조직이 팽창하는 것에 의한 것으로 확인되었다. 결론적으로 일정 농도의 SO4 2-이 존재하는 조건에서 Mg2+가 추 가로 존재할 경우 열화현상은 가속화되는 것을 알 수 있다.

국내･외 간접탄산화 연구는 기술의 경제성 확보를 위해 용제 재사용 방안에 초점을 맞추고 있으며, 효과적으로 재사용이 가능한 새로운 용제에 대한 연구를 필요로 하고 있다. 이에 본 연구에서는 킬레이트제인 trisodium citrate, malonic acid disodium salt, adipic acid disodium salt를 이용하여 알칼리 산업부산물인 제지슬러지 소각재(PSA)와 시멘트 킬른 더스트(CKD)로부터 칼슘을 용출하는 실험을 수행하였으며, 탄산화를 통해 고순도 탄산칼슘을 생성하고 용제를 재사용하는 방법을 알아보았다. 각 용제 별로 PSA와 CKD로부터 칼슘을 용출하고 탄산화하는 과정을 3회 반복하였고, 용제 재사용을 위한 칼슘용출 및 탄산화반응의 적정조건을 도출하였다. 실험결과, 모든 용제에 대해 칼슘용출효율은 CKD가 PSA보다 더 높았으나, 탄산화효율은 두 가지 산업부산물의 차이가 거의 없었다. 또한 3회의 용제 재사용 실험이 진행되는 동안 칼슘용출효율, 탄산화효율, 탄산칼슘 생성량 및 순도가 일정하게 유지되는 것을 확인하였다. 고액비 1:50 조건에서 PSA와 CKD로부터 칼슘을 용출하는 용제의 최적농도는 0.1~0.3 M이었으며, 탄산화효율은 70~90 %이었다. 용제를 3회 반복 사용하여 얻은 평균 이산화탄소 저장량은 용제별로 차이가 있었고, trisodium citrate, malonic acid disodium salt, adipic acid disodium salt 용제에 대해 각각 199, 125, 102 kg-CO2/ton-waste이었다. 탄산칼슘 생성량은 세 가지 용제에 대해 각각 452, 284, 232 kg-CaCO3/ton-waste이었다. 수득한 탄산칼슘은 XRD 분석을 통해 calcite임을 확인하였으며, 탄산칼슘의 순도는 최대 99.6 %이었다.

The purpose of the present study is to investigate some effects of concrete according to addition of blast furnace slag and sulfuric alkali-activator. Blast furnace slag was used at 30~80% replacement by weight of cement, and liquid sulfur having NaOH additives was chosen as the alkaline activator. In order to evaluate characteristics of blast furnace slag concrete with sulfuric alkali activators, compressive strength test, carbonation test were performed.

In the study, we review the resistance to freezing of alkali-activated slag-red mud cement according to the red mud content. The purpose of the paper is improved durability and application for alkali-activated slag-red mud cement.

This paper presents an investigation of the mechanical properties on alkali-activated binders immersed in sea water. The alkali-activated binders were synthesized using blended binder(Class F fly ash; FA and ground granulated blast furnace slag; GGBFS) and alkali activator(sodium hydroxide and sodium silicate). Binders were prepared by mixing the FA and GGBFS in different blend ratios of 6:4, 7:3 and 8:2. The alkali activators were used 5wt% of blended binder, respectively. Calcium carbonate was used as an chemical additive. The compressive strength and absorptiion were measured at the age of 3, 7 and 28 days, and the XRD and SEM tests were performed at the age of 28 days.