이 연구의 목적은 일기도, 850 hPa 면의 유선, 후방궤적과 기상, 그리고 대기질 모델을 이용하여 비황사기간 동안 청주시 미세먼지 PM2.5의 고농도 원인을 분석하는 것이다. 청주시 PM2.5 고농도 사례일 동안 시계열과 일기도를 분석한 결과, 중국 또는 주변 지역으로부터 PM2.5의 장거리 수송과 관련된 기상 패턴을 나타내었다. 실제로 PM2.5 시계열 에서 자체 기여 농도보다 2-3배 이상 증가한 60-80 μg m−3가 장거리 수송과 관련된 배경농도로 관측되었다. PM2.5의 고 농도는 대체로 상층 제트류가 한반도를 통과하면서 지상 고기압과 저기압의 발달 위치에 따라 분포하였다. 결과적으로 청주시 PM2.5 고농도 발생 원인은 중국 북경이나 기타 인근 지역에서 산업, 가정 및 에너지 연소 기원으로 발생한 스모그 형태의 대기 오염물질 덩어리가 장거리 수송의 기압배치에 따라 빠른 풍속 대를 타고 이동했기 때문이다. PM2.5를 포함한 대기오염물질이 지상 고기압 확장역이나 절리저기압 또는 지상저기압 배치에 따라 벨트나 띠 형태의 오염 덩어리로 북쪽에서 남쪽으로 청주시 분지 지형을 통과하는 M자형 패턴을 나타내거나, 강줄기 형태의 띠들이 바람의 영향을 받아 U자형으로 변하는 점진적 증가형 패턴으로 나타난다.

High-pressure membrane system like nanofiltration(NF) and reverse osmosis(RO) was investigated as a part of water treatment processes to produce high quality potable water with low organic matter concentration through membrane module tests and design simulation. River water and sand filtration permeate in Busan D water treatment plant were selected as feed water, and NE4040-90 and RE4040-Fen(Toray Chemical Korea) were used as NF and RO membranes, respectively. Total organic carbon(TOC) concentrations of NF and RO permeates were mostly below 0.5 mg/l and the average TOC removal rates of NF and RO membranes were 93.99% and 94.28%, respectively, which means NF used in this study is competitive with RO in terms of organic matter removal ability. Different from ions rejection tendency, the TOC removal rate increases at higher recovery rates, which is because the portion of higher molecular weight materials in the concentrated raw water with increasing recovery rate increases. Discharge of NF/RO concentrates to rivers may not be acceptable because the increased TDS concentration of the concentrates can harm the river eco-system. Thus, the idea of using NF/RO concentrate as the raw water for industrial water production was introduced. The design simulation results with feed water and membranes used in this work reveal that the raw water guideline can be satisfied if the recovery rate of NF/RO system is designed below 80%.

To remove phosphorus from the effluent of public wastewater treatment facilities, hundreds of enhanced phosphorus treatment processes have been introduced nationwide. However, these processes have a few problems including excessive maintenance cost and sludge production caused by inappropriate coagulant injection. Therefore, the optimal decision of coagulant dosage and automatic control of coagulant injection are essential. To overcome the drawbacks of conventional phosphorus removal processes, the integrated sedimentation and dissolved air flotation(SeDAF) process has been developed and a demonstration plant(capacity: 100 m3/d) has also been installed. In this study, various jar-tests(sedimentation and / or sedimentation·flotation) and multiple regression analyses have been performed. Particularly, we have highlighted the decision–making algorithms of optimal coagulant dosage to improve the applicability of the SeDAF process. As a result, the sedimentation jar-test could be a simple and reliable method for the decision of appropriate coagulant dosage in field condition of the SeDAF process. And, we have found that the SeDAF process can save 30 – 40% of coagulant dosage compared with conventional sedimentation processes to achieve total phosphorus (T-P) concentration below 0.2 mg/L of treated water, and it can also reduce same portion of sludge production.

PURPOSES : This study analyzes the characteristics of nitrogen oxide concentration by applying titanium dioxide to existing roads in urban areas, using correlation analysis and a generalized linear model. METHODS : To analyze the characteristics of nitrogen oxide concentration with/without applying titanium dioxide to the urban road segment, data acquisition was conducted for nitrogen oxide concentration, weather information, and traffic information, etc., and a correlation analysis was conducted for each factor, with/without applying titanium dioxide to the roads. In addition, nitrogen oxide concentration generation models with/without the application of titanium dioxide to the roads were estimated using a generalized linear model. RESULTS : The results demonstrate that relative humidity and temperature were found to be slightly correlated with the nitrogen oxide concentration, both with and without the application of titanium dioxide to the roads; however, wind speed, solar radiation, and traffic volume were found to have somewhat low correlation according to the results of a correlation analysis. Moreover, relative humidity, temperature, solar radiation, and traffic volume were significant when titanium dioxide was applied to the roads, based on the estimated model from a generalized linear model, and the wind speed, solar radiation, and traffic volume were significant for the absence of titanium dioxide on the roads. CONCLUSIONS : Analytical results indicated that the characteristics of nitrogen oxide concentration vary depending on the application of titanium dioxide to the roads. In particular, when titanium dioxide was applied to the roads, the relative humidity and temperature were analyzed; according to both analyses, i.e., correlation analysis and a generalized linear model, the nitrogen oxide concentration was affected.

PURPOSES : The objective of this study is to determine the characteristics of nitrogen oxide (NOx) concentration in an exclusive median bus lane station. The hourly variations of NOx concentration and the effect of traffic volume on NOx concentration were analyzed using NOx measurement data and the number of vehicles at the station. METHODS : Data were collected using the chemiluminescence method for NOx concentration. Atmospheric information and traffic volume of buses were collected from the Korea Meteorological Administration and Bus Information System, respectively. RESULTS : As a result, the NO2 concentration in the test section was found to have a strong correlation with those in the atmospheric measurement station located near the test-bed. In addition, the average NOx concentrations in the test section were significantly higher than those of the other monitoring stations due to bus emissions. The average NOx concentration in the exit section was higher than that in the entry section owing to the vehicle’s frequent stops and fuel consumption due to acceleration. During the measurement period, the average NOx concentration was measured as approximately 33 % higher in the exit section than in the entry section. In addition, the NOx concentration at the bus station was found to increase as the bus dwell time increased, rather than the number of bus passages. CONCLUSIONS : This study provides clear characteristics of the NOx correlations with traffic information in an exclusive median bus lane station. It was shown that the NOx concentration at the bus station increased as the number of passes and bus dwell time increased. According to the coefficient of determination, the dwell time is more closely correlated to the NOx concentration at the bus station than the number of bus passes, indicating that it is a better parameter for predicting NOx concentration at bus stations.

We investigated the distributions of airborne radon concentration on the platforms of the stations of Seoul Metro by the underground depth of each subway line, and explored the correlation between the radon concentration and the depth and geological conditions around each underground station. The measurements of radon levels were performed in 254 subway stations within Seoul Metro Lines 1 to 8 using the passive sampler (RADUET). Radon concentration data from 2007 to 2017, as well as the depth of each subway station were obtained from the Seoul Metro corporation. The geological information of each subway station were purchased from the Korea Institute of Geoscience and Mineral Resources. Student t-test and correlation analyses were performed to compare the levels of radon by the depth of subway stations, and to investigate the association of radon levels based on geological information. The geometric mean concentration of the all subway stations was 27.9 Bq/m3 ( range, 3 . 7Bq/ m3~124.0 Bq/m3). The depth of Lines 5-8 (geometric mean, –20.3 m) was significantly deeper by about 50% or more than that of Lines 1-4 (–13.1 m) (P<0.01). The radon levels increased significantly in deeper depths and as the number of Lines increased (P<0.05). A significant higher mean concentration of radon above the igneous rock (33.0 Bq/m3) was observed, comparing to that of non-igneous rock (27.5 Bq/m3) (P<0.00001). Our findings indicate that the deeper the subway is built or the more it is constructed on the granite area, the more careful management, including frequent ventilation and measurement monitoring, is necessary.

This study investigated 180 students’ indoor environmental awareness of rest spaces and measured the indoor and outdoor concentrations of PM10, TVOCs, and HCHO in 8 rest spaces from October 2019. 89.4% of the students responded that they use rest spaces at least once a day and most of the respondents are using rest spaces in the university. The largest number of students responded to the tight space as the main cause of air pollution in rest spaces. 62.1% of the students answered they experienced health symptoms from using rest spaces. Among them, 32.5% said they experienced irritation symptoms of eyes, neck, nose, and 12.1% answered that they experienced headaches. Indoor PM10, TVOCs, and HCHO levels did not exceed indoor air quality recommendations nor the maintenance standard for multi-use facilities. Indoor PM10, TVOCs, and HCHO levels did not exceed indoor air quality recommendations nor the maintenance standard for multi-use facilities. According to the type of rest space, concentrations of PM10, TVOCs, and HCHO were higher among the closed-type than open-type rest space. Even if the concentration of pollutants is less than the environmental standard, continuous exposure may cause negative health effects. In addition, considering that 62.1% of the respondents experienced health symptoms, it is deemed necessary to take measures to manage indoor environments in rest spaces and to develop measures to reduce pollutants.

This study conducted a survey on environmental awareness and analyzed outdoor PM10 and heavy metals (cadmium, lead) for 60 local residents living in the Gwangyang national industrial complex from July 2019. 40.0% of subjects responded that local environmental pollution was serious. Especially, there was a high proportion of residents living near the industrial complex or roads where it was perceived that local environmental pollution was serious. The average concentration of PM10 in the outdoors of the houses was 10.95 μg/m3 and the average concentration of heavy metals in PM10 was 1.90 ng/m3 for Cd and 24.92 ng/m3 for Pb. Overall, the average concentration of PM10 and heavy metals revealed a tendency to be high in the houses located near the industrial complex or the roads. As a result of a risk assessment carried out, the cancer risk of Cd was estimated to exceed 106 in the CTE, RME and Monte Carlo analysis. These results suggest that the urgent implementation of specific environmental health education for local residents is necessary.

Radon is a radioactive gas material, which is not detectable by humans because of the absence of color and odor. Radon gas can exist indoors through a number of pathways and long-term exposure to such material can affect the human body, which may result in serious health issues such as lung-cancer. It is thus essential to reduce and maintain indoor radon concentration in order that potential health risks from radon can be diminished. In order to achieve the aforementioned goals, it is requisite to utilize a practical detector which is capable of continuous radon monitoring. In relation to this, a recently developed prototype radon detector, i.e., RS9A, provides highperformance comparable to existing research-grade radon detectors for the purpose of continuous radon monitoring in the air. Furthermore, RS9A is a convenient piece of equipment for use by the public as it is compact in size and affordable. In this paper, we conducted continuous measurements of indoor radon concentrations by using sets of RS9A and evaluated the equivalence of RS9A in terms of quality assurance.

Due to the serious air pollution problem, interest in eco-friendly vehicles is increasing. Solving the problem of pollution will necessitate the securing of high energy storage technology for batteries, the driving force of eco-friendly vehicles. The reason for the continuing interest in the transition metal oxide LiMO2 as a cathode material with a layered structure is that lithium ions reveal high mobility in two-dimensional space. Therefore, it is important to investigate the effective intercalation and deintercalation pathways of Li+, which affect battery capacity, to understand the internal structure of the cathode particle and its effect on the electrochemical performance. In this study, for the cathode material, high nickel Ni0.8Co0.1Mn0.1(OH)2 precursor is synthesized by controlling the ammonia concentration. Thereafter, the shape of the primary particles of the precursor is investigated through SEM analysis; X-ray diffraction analysis is also performed. The electrochemical properties of LiNi0.8Co0.1Mn0.1O2 are evaluated after heat treatment.

Mass mortality of mariculture fish due to high summer temperatures is a major issue in the mariculture industry in many coastal waters of Korea, yet measures to mitigate the impact are generally limited. We injected a micro-bubble of liquefied oxygen into the bottom of rockfish cages (about 6-8 m deep) in order to maximize the dispersal of micro-bubbled seawater and reduce fish mortality. The injection of low-temperature oxygen in micro-bubbles lowered the water temperature at the injection area by as much as 1℃ and increased dissolved oxygen concentration by 0.5 ppm. In early August, following a week with persistent high water temperature (above 28.5℃), there was an increase in fish mortality despite the micro-bubble system, which resulted in approximately 7% death of the total introduced fish population. However, this mortality appeared to be much lower than mortality reported in a neighboring mariculture facility (approximately 50% mortality). We also estimated the volume that can be recirculated with pumped seawater using a micro-bubble system. We suggest that this approach of injecting liquefied oxygen through a micro-bubble system may reduce fish mortality during high temperature periods.

본 연구는 도로에서 발생하는 미세먼지 농도가 도시 개발 형태에 따라 인접 생활권별로 어떻게 확산되는지 시뮬레이션을 통해 파악하고자 하였다. 연구는 경상남도 밀양시청 앞 6차선 도로를 중심으로 한 도로영향권 시가지를 대상으로 진행하였다. 시뮬레이션 프로그램인 ENVI-met 모델을 가로녹지 유무, 도로변 건축물의 높이에 따라 변수를 조정하여 미세먼지 농도의 확산정도를 파악하였다. 모델링 결과 도로변 건물이 고층으로 형성되어 있고 가로녹지가 조성되어 있는 경우 인접 생활권으로 확산된 미세먼지 농도가 가장 낮았으며, 다음으로는 고층건물군에 가로녹지가 없는 상태의 농도가 낮았다. 반면 저층건물군이 형성된 경우에는 가로녹지 유무에 관계없이 인접생활권으로 확산된 미세먼지 농도는 높게 나타났다. 고층건물의 경우 빌딩풍에 의해 건축물 주변으로 강한 바람이 형성되는 만큼 바람에 의해 미세먼지가 빠르게 외부로 확산되어 농도가 낮아지는 것으로 확인할 수 있었다. 반면 가로녹지 조성이 도로변 생활권에 미치는 미세먼지 저감효과는 뚜렷하지 않았다. 특히 도로변 건축물이 저층일 경우 가로녹지를 조성과 생활권미세먼지농도변화와 관련성은 없는 것으로 확인되었다. 본 연구는 미세먼지가 도로에서만 발생하는 것을 가정하여 모델링을 진행한 것으로 향후 다양한 변수에 따른 미세먼지 확산모형 연구 및 현장연구의 보완을 필요로 하였다.

본 연구에서는 K-means 군집 분석을 통하여 최근 5년간(2014-2018) 한반도 남동 지역의 고농도 미세먼지 발생에 영향을 미치는 주요 종관 기상 패턴을 분류하였다. 또한 고농도 미세먼지 사례일의 발생과 관련된 지역적 차이를 살펴보기 위하여 NCEP (National Centers for Environmental Prediction)/FNL (Final Operational Global Analysis) 재해석 기상자료를 이용하여 부산, 울산, 경남 지역의 미세먼지 발생 특성과 관련된 종관 규모 기상의 특성에 대한 비교 연구도 수행하였다. 한반도 남동 지역의 고농도 미세먼지 사례일과 관련된 종관 기상 패턴은 총 5개(C1-C5)로 분류된다. 각 군집의 발생빈도는 24.8% (C1), 21.3% (C2), 20.4% (C3), 17.3% (C4), 16.2% (C5)이다. 기상 패턴 분석을 통하여 제시된 남동 지역의 고농도 미세먼지를 유발하는 요인에는 지역 외부에서 장·단거리 수송(C1, C3, C5)에 의한 영향과 지역내 배출(C2, C4)에 의한 것임을 알 수 있었다. 또한 고농도 미세먼지 발생일에 대해 부산, 울산, 경남 세 지역의 기상장을 분석하였을 때, 500 hPa 지위 고도 및 풍속 등의 기상학적 특성이 지역별로 다르게 나타났다. 그리고 고기압 의 작은 위치 변화가 각 지역의 미세먼지 발원과 장거리 이동 경향성에 영향을 미치고 있었다.

Molybdenum trioxide (MoO3) is used in various applications including sensors, photocatalysts, and batteries owing to its excellent ionic conductivity and thermal properties. It can also be used as a precursor in the hydrogen reduction process to obtain molybdenum metals. Control of the parameters governing the MoO3 synthesis process is extremely important because the size and shape of MoO3 in the reduction process affect the shape, size, and crystallization of Mo metal. In this study, we fabricated MoO3 nanoparticles using a solution combustion synthesis (SCS) method that utilizes an organic additive, thereby controlling their morphology. The nucleation behavior and particle morphology were confirmed using ultraviolet-visible spectroscopy (UV-vis) and field emission scanning electron microscopy (FE-SEM). The concentration of the precursor (ammonium heptamolybdate tetrahydrate) was adjusted to be 0.1, 0.2, and 0.4 M. Depending on this concentration, different nucleation rates were obtained, thereby resulting in different particle morphologies.

In this study, a model to optimize residual chlorine concentrations in a water supply system was developed using a multi-objective genetic algorithm. Moreover, to quantify the effects of optimized residual chlorine concentration management and to consider customer service requirements, this study developed indices to quantify the spatial and temporal distributions of residual chlorine concentration. Based on the results, the most economical operational method to manage booster chlorination was derived, which would supply water that satisfies the service level required by consumers, as well as the cost-effectiveness and operation requirements relevant to the service providers. A simulation model was then created based on an actual water supply system (i.e., the Multi-regional Water Supply W in Korea). Simulated optimizations were successful, evidencing that it is possible to meet the residual chlorine concentration demanded by consumers at a low cost.