주파수 변화에 따른 에폭시 복합체의 전기적 특성을 알아보기 위하여 온도 범위 20[℃], 100[℃], 140[℃], 주파수 범위 30[Hz]~3[MHz] 사이에서 유전율 및 유전손실을 측정하였다. 저주파 영역에서 유전분산과 유전 손실이 나타나고 있음을 확인하였다. 또한 고온 영역에서는 충진제의 영향으로 유전율이 감소하는 것을 확인하였다.

Composites of P25 TiO2 and hexagonal WO3 nanorods are synthesized through ball-milling in order to study photocatalytic properties. Various composites of TiO2/WO3 are prepared by controlling the weight percentages (wt%) of WO3, in the range of 1–30 wt%, and milling time to investigate the effects of the composition ratio on the photocatalytic properties. Scanning electron microscopy, x-ray diffraction, and transmission electron microscopy are performed to characterize the structure, shape and size of the synthesized composites of TiO2/WO3. Methylene blue is used as a test dye to analyze the photocatalytic properties of the synthesized composite material. The photocatalytic activity shows that the decomposition efficiency of the dye due to the photocatalytic effect is the highest in the TiO2/ WO3 (3 wt%) composite, and the catalytic efficiency decreases sharply when the amount of WO3 is further increased. As the amount of WO3 added increases, dye-removal by adsorption occurs during centrifugation, instead of the decomposition of dyes by photocatalysts. Finally, TiO2/WO3 (3 wt%) composites are synthesized with various milling times. Experimental results show that the milling time has the best catalytic efficiency at 30 min, after which it gradually decreases. There is no significant change after 1 hour.

In the present work, a comparative study of the mechanical behavior of two series of elastomeric composites, based on carboxylated styrene butadiene rubber (X-SBR) and reinforced with rice bran carbon (RBC) and graphite, is reported. Hybrid composites of X-SBR filled with RBC-graphite were also investigated in terms of the cure characteristics, hardness, tensile properties, abrasion resistance, and swelling. It was observed that the cure times decreased with the incorporation of a carbon filler whereas the torque difference, tensile strength, tensile modulus, hardness, and swelling resistance increased compared to the neat X-SBR revealing a favorable characteristic of crosslinking. Dynamic rheological analysis showed that the G' values of the composites, upon the addition of RBC-graphite, were changed to some extent. This demonstrates that the presence of a strongly developed network of fillers will ensure a reinforcing characteristic in a polymer matrix.

본 연구에서는 polypropylene glycol(PPG) 을 이용한 수분산 폴리우레탄에 카제인을 그래프트 합성한 다음 카본블랙을 분산하여 발생하는 변화를 분석하였다. 이를 위해 카제인을 그래프트한 수분산 폴리우레탄 (PUD와 CPUD’s) 시료를 준비한뒤 카본블랙이 분산된 CPCB’s 시료를 준비하였다. 준비된 시료를 이용하여 인장강도를 측정 한 결과 카제인이 높게 함유된 CPUD3 가 3.01 kgf/㎟ 로 인장강도가 증가하였으며, CPCB’s 에서는 카본 블랙이 증가할수록 인장강도가 2.54 kgf/㎟ 로 낮게 측정되었다. 연신율은 카제인이 적게 함유된 PUD 시료가 278 % 로 측정되었으며, CPCB’s에서는 CP3CB4 가 157% 로 측정되었다. 내마모성은 CPUD3 시료가 36.97 mg.loss, CP3CB4가 41.11 mg.loss 로 표면 강도가 측정되었다. 내용제성은 PUD’s 시료와 CPCB’s 시료 양쪽 모두 물성변화가 없음을 확인 할 수 있었다.

An electroless deposition method was used to modify the surface properties of rice husk ceramic particles (RHC) by depositing nano-nickel on the surface of the RHC (Ni-RHC). The dry tribological performances of aluminum matrix composite adobes containing different contents of RHC and Ni-RHC particles have been investigated using a micro-tribometer. Results showed that the Ni–RHC particles substantially improved both the friction and wear properties of the Ni-RHC/aluminum matrix adobes. The optimal concentration was determined to be 15 wt% for both the RHC and Ni–RHC particles. The improvements in the tribological properties of aluminum adobes including the Ni-RHC were ascribed to frictioninduced peeling off of Ni coating and formation of protection layer on the wear zone, both of which led to low friction and wear volume.

Multi-walled carbon nanotube (MWCNT)–copper (Cu) composites are successfully fabricated by a combination of a binder-free wet mixing and spark plasma sintering (SPS) process. The SPS is performed under various conditions to investigate optimized processing conditions for minimizing the structural defects of CNTs and densifying the MWCNT–Cu composites. The electrical conductivities of MWCNT–Cu composites are slightly increased for compositions containing up to 1 vol.% CNT and remain above the value for sintered Cu up to 2 vol.% CNT. Uniformly dispersed CNTs in the Cu matrix with clean interfaces between the treated MWCNT and Cu leading to effective electrical transfer from the treated MWCNT to the Cu is believed to be the origin of the improved electrical conductivity of the treated MWCNT–Cu composites. The results indicate the possibility of exploiting CNTs as a contributing reinforcement phase for improving the electrical conductivity and mechanical properties in the Cu matrix composites.

Al2O3-SiC ceramic composites are produced using pressureless sintering, and their plasma resistance, electrical resistance, and mechanical properties are evaluated to confirm their applicability as electrostatic-discharge-safe components for semiconductor devices. Through the addition of Mg and Y nitrate sintering aids, it is confirmed that even if SiC content exceeded 10%, complete densification is possible by pressureless sintering. By the uniform distribution of SiC, the total grain growth is suppressed to about 1 μm; thus an Al2O3-SiC sintered body with a high strength over 600 MPa is obtained. The optimum amount of SiC to satisfy all the desired properties of electrostatic-discharge-safe ceramic components is obtained by finding the correlation between the plasma resistance and the electrical resistivity as a function of SiC amount.

Optimization was performed on the static dynamic behavior of a simply supported laminated composite plate. Thickness optimization was performed with respect to Gr/E laminated composites with simultaneous mechanical load, thermal load and hygro-load. Displacement, fundamental frequency and composite damping were imposed as constraints for optimization. The results of the optimization were much better than those of the conventional methods.

β-Tricalcium phosphate (TCP) was added to Al2O3 to make a biomaterial with good mechanical properties. Using a TCP powder synthesized by a polymer complexation method, Al2O3 composites containing 30 wt% TCP were fabricated and characterized for densification, phase, microstructure, strength, and fracture toughness. With optimizing the powder preparation conditions, a high densification of 97 % was obtained by sintering at 1350 ℃ for 2 h. No reaction between the two components occurred and there was no transition to α-TCP. TCP grains with a size of 2-4 μm were well surrounded by Al2O3 grains with a size of 1 μm or less. Strength 61(Brazilian) or 187(3-p MOR) MPa, and fracture toughness 1.7 (notched beam) or 2.5 (indentation) MPa·m1/2 were obtained, which are large improvements over the strength of TCP/Al2O3 composites and toughness of TCP and hydroxyapatite in previous studies.

본 연구에서는 투명도와 기계적 특성을 향상시키기 위해 저온 공정의 졸-겔 법을 이용하여 하이브리드 복합체의 코팅 박막을 제조하였다. 하이브리드 복합체로는 ZrO2/TiO2/organosilane을 사용하였으며, 그 중 organosilane은 3-(trimethoxysilyl)propyl methacrylate을 사용하였고 이는 저온 공정의 광경 화 반응을 위해 도입되었다. 다양한 조성비로 합성된 복합체를 폴리 카보네이트 기판 위에 저온 공정의 졸 -겔 법을 이용하여 광경화와 열처리 공정을 거처 코팅 박막을 제조하였고 이 코팅 박막의 광학 특성 및 기계적 강도를 확인하였다. 코팅 박막은 가시광선 영역에서 97.5 % 이상의 투과도를 가짐을 확인하였고 기계적 강도는 9H 이상의 연필 경도를 가진 것을 확인하였다. 특히 ZTS-2-1 코팅 박막의 나노 압입 경도는 1.14 GPa로 가장 높게 측정되었다.

This study suggests the novel thermoplastic toughening agent, which can be applied in the monomer forms without increasing the viscosity of the epoxy resin and polymerized during the resin curing. The diazide (p-BAB) and dialkyne (SPB) compounds are synthesized and mixed with the epoxy resin and the carbon fiber reinforced epoxy composites are prepared using vacuum infusion process (VIP). Then, flexural and drop weight tests are performed to evaluate the improvement in the toughness of the prepared composites to investigate the potential of the novel toughening agent. When 10 phr of p-BAB and SPB is added, the flexural properties are improved, maintaining the modulus as well as the toughness is improved. Even with a small amount of polytriazolesulfone polymerized, due to the filtering effect of the solid SPB by the layered carbon fabrics during the VIP, the toughening and strengthening effect were observed from the novel toughening agent, which could be added in monomer forms, p-BAB and SPB. This suggests that the novel toughening agent has a potential to be used for the composites prepared from viscosity sensitive process, such as resin transfer molding and VIP.

In this study, a thermal-gradient chemical vapor infiltration (TG-CVI) process was numerically studied in order to enhance the deposition uniformity within the preform. The computational fluid dynamics technique was used to solve the governing equations for heat transfer and gas flow during the TG-CVI process for two- and three-dimensional (2-D and 3-D) models. The temperature profiles in the 2-D and 3-D models showed good agreement with each other and with the experimental results. The densification process was investigated in a 2-D axisymmetric model. Computation results showed the distribution of the SiC deposition rate within the preform. The results also showed that using two-zone heater gave better deposition uniformity.

고성능 복합재의 설계와 제작에 있어서 경량화는 필수 트랜드이다. 본 연구에서는 DGEBA계 에폭시 그리고 폴리아마이드 아민으로 조합된 수지시스템과 글라스 버블을 이용한 경량 복합재료를 제조하고 그 특성을 평가하였다. 제조한 경량 복합제의 밀도는 0.31-0.53 g/cm3 범위였다. 실온에서 2일간 방치한 후 성형한 시료의 압축강도가 바로 60 oC에서 2시간 경화시킨 시편보다 2배 이상 높게 나타났다.

The purpose of this study is to investigate the optimum conditions of dispersion and strength to maximize the mechanical properties of woody cellulose nano–crystal (CNC). As a dispersing method, ultrasonic dispersing machine and magnetic stirrer were used as the mechanical dispersion method. The mixing ratio of cellulose nano-crystals (CNCs) was 0.2% and the dispersion time was 10 minutes. Steam curing was carried out for 6, 24 and 48 hours. Based on the experimental results, we will propose source technology regarding CNC for construction materials.