Homogenous silica-coated samples with controlled silica thickness were synthesized by the reverse microemulsion method. First, 7 nm size cobalt ferrite nanoparticles were prepared by thermal decomposition methods. Hydrophobic cobalt ferrites were coated with controlled using polyoxyethylene(5)nonylphenylether (Igepal) as a surfactant, and tetraethyl orthosilicate (TEOS). The well controlled thickness of the silica shell was found to depend on the reaction time and the amount of surfactant used during production. Thick shell was prepared by increasing reaction time and small amount of surfactant.

동적 불안정 좌굴현상에 관한 연구는 다소 발표되고 있으나 주기성을 가진 히중하에서의 동적 좌굴을 다룬 연구는 그리 많지 않은 편이다. 주기성을 가진 하중하에서의 거동은 스텝 하중하에서 거동과는 다르리라 예상된다. 본 논문에서는 동적 불안정의 기본 메커니즘을 파악하기 위하여 2자유도의 얕은 EP(Elliptic Paraboliodal)쉘이 정현파 하중을 받았을 때의 직접좌굴과 간접좌굴 현상을 조사한다. Newma가-β법에 의한 수치적분을 이용하여 비선형 운동 방정식의 변위응답을 구하고 얻어진 비선형 변위응답으로 위상곡면선의 끌개를 비교하고, FFT(Fast Fourier Transform)에 의한 연속 응답 스펙트럼을 구해 동적 불안정 특성에 관해서 분석한다. 그 결과 동적 좌굴하중은 구조물의 고유주기와 외력 탁월진동수와의 관계에 크게 영향을 받는다.

Silicone dioxide absorbed polyoxyethylene alkylether sulfate (EU-S75D) surfactant was prepared. The core-shell composite of inorganic/organic were polymerized by using styrene(St) as a shell monomer and potassium persulfate(KPS) as an initiator. We studied the effect of surfactants on the core-shell structure of silicone dioxide/styrene in the presence of an anionic surfactant lauryl sulfate(SLS). The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer(TGA) and morphology of latex by scanning electron microscope(SEM).

Titanium dioxide particles are used as photocatalysts, sensors, adsorbents and catalyst. Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using Acrylate as a shell monomer and potassium persulfate (KPS) as an initiator. We found that when Acrylate core prepared by adding 0.5~2.0 wt% EU-S133D, Titanium dioxide / Acrylate core-shell polymerization was carried out on the surface of Titanium dioxide particle without forming the new Titanium dioxide particle during acrylate shell polymerized in the inorganic/organic core-shell polymer preparation. The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer(TGA) and morphology of latex by scanning electron microscope(SEM).

Si nanowire/multiwalled carbon nanotube nanocomposite arrays were synthesized. Vertically aligned Si nanowire arrays were fabricated by Ag nanodendrite-assisted wet chemical etching of n-type wafers using HF/AgNO3 solution. The composite structure was synthesized by formation of a sheath of carbon multilayers on a Si nanowire template surface through a thermal CVD process under various conditions. The results of Raman spectroscopy, scanning electron microscopy, and high resolution transmission electron microcopy demonstrate that the obtained nanocomposite has a Si nanowire core/carbon nanotube shell structure. The remarkable feature of the proposed method is that the vertically aligned Si nanowire was encapsulated with a multiwalled carbon nanotube without metal catalysts, which is important for nanodevice fabrication. It can be expected that the introduction of Si nanowires into multiwalled carbon nanotubes may significantly alter their electronic and mechanical properties, and may even result in some unexpected material properties. The proposed method possesses great potential for fabricating other semiconductor/CNT nanocomposites.

Geopolymer materials are attractive as inorganic binders due to their superior mechanical and eco-friendly properties. In the current study, geopolymer-based cement was prepared using aluminosilicate minerals from fly-ash with KOH as an alkaline-activator and Na2SiO3 as liquid glass. Then, calcium carbonate powder from a clam shell was mixed with the geopolymer and the mixture was coated on a concrete surface to provide points of attachment for environmental organisms to grow on the geopolymers. We investigated the effect of the shell powder grain size on the microstructure and bonding property of the geopolymers. A homogeneous geopolymer layer coated well on the concrete surface via aluminosilicate bonding, but the adhesiveness of the shell powder on the geopolymer cement was dependent on the grain size of the shell powder. Superior adhesive characteristics were shown in the shell powder of large grain size due to the deep penetration into the geopolymer by their large weight. This kind of coating can be applied to the adhesiveness of eco-materials on the surface of seaside or riverside blocks.

Silicone dioxide absorbed polyoxyethylene alkylether sulfate (EU-S133D) surfactant was prepared. Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using Acrylate as a shell monomer and potassium persulfate (KPS) as an initiator. We found that when Acrylate core prepared by adding 2.0 wt% EU-S133D, silicone dioxide/Acrylate core-shell polymerization was carried out on the surface of silicone dioxide particle without forming the new silicone dioxide particle during acrylate shell polymerization in the inorganic/organic core-shell polymer preparation. The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of latex by scanning electron microscope(SEM).

Today, wastes of much quantity by fast industrialization and increase in population, population concentration etc. of modem society are increasing. Much oyster shell is breeding by character and conduct of oyster-industry for a long time among them. Oyster shell which breed by-product in oyster cultivating industry that specific gravity of domestic seashore cultivating industry is high is causing environmental problem by problem and so on hindrance, nature spectacle's waste and health hygiene on administration if it is pollution of district along the coast fishing ground, number of public ownership being stored in open area in seashore. About new material just-in-time through recycling and he of oyster shell by these problem wide that study. Go forward more and investigate special quality that is oyster shell's physical chemistry red in this research and oyster shell oyster shell which cause several environmental problems developing ability agricultural chemicals that use this encapsulating micro by ability carrier that is environmentally application possibility examine wish to.

The purpose of this study was to investigate the effect of shrimp flour on quality characteristics of dumpling shell. Dumpling shell samples were prepared with wheat flour along with the addition of different amount of shrimp flour, followed by functional measurements and sensory evaluations. According to amylograph data, the composite shrimp flour/wheat flour samples had increased gelatinization temperature with increasing shrimp flour content, while initial viscosity at 95℃, viscosity at 95℃ after 15 minutes, and maximum viscosity were reduced. In terms of color values, L value decreased, but a and b values increased with increasing shrimp flour content. Furthermore, the addition of shrimp flour increased hardness and decreased chewiness in all samples. Overall, sensory evaluations proved that dumpling shell with 10% added shrimp flour was preferred over the other samples.

The inorganic-organic composite particles with core-shell structure were polymerized by using styrene and potassium persulfate (KPS) as a shell monomer and an initiator, respectively. We studied the effect of surfactants on the core-shell structure of silicone dioxide/styrene composite particles polymerized in the presence of sodium dodecyl sulfate(SDS), polyoxyethylene alkylether sulfate (EU-S133D), and at none surfactant condition. We found that SiO2 core / polystyrene(PS) shell structure was formed when polymerization of styrene was conducted on the surface of SiO2 particles, and the concentration SDS and EU-Sl33D was 8.34×10-2mole/L. The core-shell structure was confirmed by measuring the thermal decomposition of the polymer composite using thermogravimetric analyzer (TGA), and the morphology of the composite particles was characterized by transmission electron microscope (TEM).

The moisture contained in conventionally extracted red crab shell samples was lower than than in samples extracted using high pressure. In contrast, ash content increased as the extraction time increased and displayed no significant variation in high pressure extraction. Extraction time was influential, with lower lightness (L-value) being obtained in samples extracted at high pressure as compared to traditional extraction. However, large variation in a- and b-values resulted from traditional extraction. For both traditional and high pressure extraction increases in pH, salinity and saccharide content were noted with increasing extraction time, but these parameters did not vary substantially in red crab shell extracted at high pressure. The mineral content in samples extracted by high pressure was higher than in traditionally extracted samples. The mineral content increased with time, with marginally higher contents of essential amino acids and flavor enhancing amino acids noted following high pressure extraction. The contents of the flavor enhancing amino acids increased from 30?60 min, thereafter decreasing. Assessment of consumer acceptance revealed that, while traditionally manufactured red crab sauce was popular, sauce manufactured using a 60 min high pressure extraction was preferred. Extending the high pressure extraction time to 75 min produced a less sensory acceptable product, due to higher mineral and protein levels.

The core-shell composite particles of inorganic/organic were polymerized by using styrene(St) as a shell monomer and potassium persulfate (KPS) as an initiator. We studied the effect of core-shell structure of silicone dioxide/styrene in the presence of an anionic surfactant sodium lauryl sulfate (SLS) and polyoxyethylene alky lether sulfate (EU-S133D). We found that when SiO2 core/PSt shell polymerization was prepared on the surface SiO2 particle, to minimize the coagulation during the shell polymerization, the optimum conditions were at concentration of 2.56×10-2mole/L SLS. The structure of core-shell polymer was confirmed by measuring the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of core-shell polymer particles by transmission electron microscope (TEM).

쉘형 구조물은 외력에 대해 효과적으로 저항할 수 있어, 두께를 얇게하면서 대공간 구조물을 만들 수 있는 장점이 있다. 이러한 장점은 구조형태에 크게 의존한다. 그러므로 많은 설계자들은 최적 형태를 설계에 반영하고자 하지만, 이는 간단치 않다. 지금까지 보다 최적의 형태를 얻기 위한 많은 기법들이 발표되어 왔고, 이들은 각각 장단점을 나타낸다. 본 논문에서는 최적의 곡면을 얻기 위해 기하학적 비선형을 고려한 유한요소법을 이용한 비교적 간단한 방법을 제안한다. 이러한 방법을 이용하여 다양한 쉘형 곡면에 적용하여 최적곡면을 얻고, 이를 비교한다.

The core-shell latex particles were prepared by sequential emulsion polymerization using alkyl methacrylate as a shell monomer and potassium persulfate (KPS) as an initiator. We study the effects of core-shell structure of calcium carbonate/alkyl methacrlyate in the presence of an anionic surfactant sodium lauryl sulfate (SLS) and polyoxyethylene alkyl ether sulfate (EU-S133D)). The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of latex by transmission electron microscope (TEM).

This study was designed to evaluate effects of BSA, PVA, gonadotropins and follicle shell during IVM of porcine oocytes and subsequent development to the blastocyst stage after IVF. Cumulus oocyte complexes (COCs) were cultured in TCM-199 media containing 4 mg/ml BSA and 1 mg/ml PVA during IVM for 44 hr. To compare the effect of gonadotropins on oocyte maturation, COCs were cultured with FSH+LH, FSH, LH and FSH-LH-free media during IVM, respectively. Also, different number of follicle shells (0, 2, 4 and 6) was used to examine whether the presence of follicle shell in culture medium affects oocyte maturation. The percentages of fertilization and blastocyst formation, respectively, were higher in the medium containing the PVA (49.0 and 17.9%) than those containing the BSA (40.0 and 12.2%). Significantly higher rates of MII oocytes were in the presence of FSH+LH and FSH (88.6 and 85.1%) compared to other treatments (64.0 and 53.4% at LH and FSH-LH-free media). Co-culture with inverted follicle shells in 2 ml maturation medium enhanced the developmental competence of porcine oocytes. In conclusion, PVA could be used as a macromolecules instead of BSA, and FSH and follicle shell played important roles in maturation of porcine oocytes.

PSC 박스 교량은 콘크리트, 철근과 텐던으로 구성된 구조물로서 콘크리트의 인장 균열, 철근의 비선형 거동 등 재료의 비선형성 거동 특성 및 콘크리트의 시간 의존적 특성을 가지고 있는 복합 구조물이다. PSC 박스 교량의 시공 중 거동 특성을 고려하기 위하여 뼈대 요소(프레임 요소)를 이용한 시공단계의 설계가 수행되고 있다. 그러나 PSC 박스 교량 중 곡선램프교 등의 경우는 교량의 외측 및 내측의 변위 및 응력 값이 현저히 다르다. 따라서 PSC 박스 교량의 텐던량 및 시공 중 긴장력이 외측 및 내측에서 다르게 산정되어야 함에도 불구하고 현실적으로는 계산이 불가능하여 같은 양의 텐던과 부적절한 긴장력을 사용하고 있어 시공 중 항상 안전사고에 노출되고 있다. 이러한 단점을 해결하기 위하여 3차원 해석이 필수적으로 요구되고 있으며 본 연구에서는 PSC 박스 교량의 해석 기법에 필요한 준 적합 쉘 요소를 제안하고자 한다.

본 논문에서는 적응적 h-유한요소 세분화에 의한 박스형 절판 구조물의 선형좌굴 유한요소해석법을 제안한다. 면내회전 자유도를 갖는 변절점 평판쉘유한요소를 사용하여 유한요소의 거동을 개선하고 6자유도를 갖는 다른 유한요소와의 자유도의 연결을 용이하게 한다. 이와 같이 개발된 평판쉘유한요소에 의하여 박스형 절판구조물의 정확한 구조해석이 가능한데, 변절점유한요소를 정식화함으로써 적응적 h-유한요소 세분화시에 발생하는 다른 패턴의 사각형 유한요소 세분화망의 연결을 용이하게 해결한다. 오차평가에 대한 개선된 응력장을 얻기 위하여 상위수렴 조각회복법을 적용한다. 이와 같이 상위수렴 조각회복법에 의한 개선된 응력장에 의하여 구성된 유한요소 세분화망을 이용하여 좌굴하중과 좌굴모드를 자동적으로 구할 수 있도록 한다.