The purpose of this study was to compare the efficiency of air and oxygen injected into the underwater non-thermal dielectric barrier discharge plasma (DBD plasma) device used to remove five types of antibiotics (tetracycline, doxycycline, oxytetracycline, clindamycin, and erythromycin) artificially contained in the fish farm discharge water. The voltage given to generate DBD plasma was 27.8 kV, and the measurement intervals were 0, 0.5, 1, 2, 4, 8, 16 and 32 minutes. Tetracycline antibiotics significantly decreased in 4 minutes when air was injected and were reduced in 30 seconds when oxygen was injected. After the introduction of air and oxygen at 32 minutes, 78.1% and 95.8% of tetracycline were removed, 77.1% and 96.3% of doxycycline were removed, and 77.1% and 95.5% of oxytetracycline were removed, respectively. In air and oxygen, 59.6% and 83.0% of clindamycin and 53.3% and 74.3% of erythromycin were removed, respectively. The two antibiotics showed lower removal efficiency than tetracyclines. In conclusion, fish farm discharge water contains five different types of antibiotics that can be reduced using underwater DBD plasma, and oxygen gas injection outperformed air in terms of removal efficiency.

본 연구는 점오염원인 하수종말처리장으로부터 배출되는 물의 수질을 분석하고 배출수의 영향을 받는 어류 중 지점들에서 공통적으로 출현하는 어종인 피라미 (Z. platypus) 를 선택하여 조직학적 변화를 참조하천 지점의 수질과 어류 조직을 비교·분석하였다. 2019년 6월 27~28일 하수종 말처리장 4곳 (대전, 전주, 청주, 익산)의 채집 결과, 참조하 천에서 22종 450개체로 가장 많은 종수 및 개체수가 확인 되었다. 지점별로 5개체씩 2~3년생 피라미의 조직표본을 제작하여 아가미와 근육조직 (피부조직)을 관찰한 결과, 참조하천을 제외한 나머지 지점의 조직은 병리적인 양상을 나타내었다. 수질분석 결과, 각 WTP에서는 배출수질 기준을 준수 혹은 더 좋은 수질로 방류하고 있었다. 그러나 하수종말처리수 배출수 및 방류수계 수질에서 오염도지표를 나타내는 항목인 BOD, COD, TP, TN, SS 값이 참조하천에 비해 높은 것으로 나타났다. 빈약한 어류상과 바이오마커로 이용된 종의 조직병리학적 상태는 참조하천에 비해 낮은 수질에서 기인한 것으로 추측되며, 따라서 원인이 되는 하수종말처리장 배출수 수질개선이 이루어져야 할 것으로 사료된다.

As water resources are limited and legal regulations are strengthened, there is a growing need to reuse residuals in WTP(Water Treatment Plant). In this study, membrane filtration system was constructed and its operation method was studied for water quality stabilization and reuse of WTP residuals. The operation parameters were stable for 1 year and 6 months. Membrane fouling was identified as particulate pollution (activated carbon) and inorganic pollution (manganese). The membrane system was operated steadily with raw water of high concentration SS(Suspended solid) containing activated carbon because membrane fouling was reduced by the effect of End-Free type. In the case of inorganic contamination, dissolved manganese eluted by chemicals and acted as a membrane fouling source, and the operating conditions for minimizing membrane fouling were confirmed by newly developing application methods and types of cleaning chemicals. Based on the results, design parameters for reducing manganese membrane fouling were derived.

Desalination plants have been recently constructed in many parts of the world due to water scarcity caused by population growth, industrialization and climate change. Most seawater desalination plants are designed with a submarine pipeline for intake and discharge. Submarine pipelines are installed directly on the bottom of the water body if the bottom is sandy and flat. Intake is located on a low-energy shoreline with minimal exposure to beach erosion, heavy storms, typhoons, tsunamis, or strong underwater currents. Typically, HDPE (High Density Polyethylene) pipes are used in such a configuration. Submarine pipelines cause many problems when they are not properly designed; HDPE pipelines can be floated or exposed to strong currents and wind or tidal action. This study examines the optimal design method for the trench depth of pipeline, analysis of on-bottom stability and dilution of the concentrate based on the desalination plant conducted at the Pacific coast of Peru, Chilca. As a result of this study, the submarine pipeline should be trenched at least below 1.8 m. The same direction of pipeline with the main wind is a key factor to achieve economic stability. The concentrate should be discharged as much as high position to yield high dilution rate.

아산만의 해양수질을 이해하기 위하여 2011년 12월부터 2013년 2월까지 아산만과 주변 방조제 호수의 수질을 계절별로 조사하였으며, 이를 바탕으로 아산만을 3개의 해역(Bay1, Bay2, Bay3)으로 구분하여 물질수지를 분석하였다. 현장 조사 결과 여름철인 2012년 7월에 아산만의 중앙해역(Bay2)에서 영양염이 증가하는 현상이 관측되었으며, 물질수지 결과에서도 동일시기에 중앙해역에서 영양염이 생성됨을 보였다. 이렇게 중앙해역에서 영양염 농도를 증가시킬 수 있는 공급원은 노후한 방조제 호수의 배출수와 미처리된 도시하수 등 비점오염물질을 포함한 배수로의 배출수로 추정되었다. 결과적으로 이러한 중앙해역의 높은 영양염이 외만으로 확장되는 과정 중 식물플랑크톤에 이용되면서 외만에서 높은 Chl-a의 농도가 관측된 것으로 해석된다. 따라서 아산만의 건강한 해양생태계 유지를 위해서는 방조제 호수의 배출수와 비점오염에 대한 적절한 관리가 필요하다.

Membrane backwashing waste shows seasonally different characteristics and it has bad settleability differently from general backwashing waste in water treatment plant. When chemicals was injected to membrane backwashing waste, the settleability was better than chemicals was not injected. However, when settled lower sludge was not discharged, flowing sludge continuously was concentrated over a certain surface and floatation penomena occurred according to flowing velocity. When the lower sludge was discharged continuously in the thickener to prevent floatation penomena of turbidity materials, the depth of sludge surface was the least and the settleability increased.

Various treatment system for residuals have applied to save water resources, but most of them were not be satisfied with legal standard consistently. In this study, submerged membrane treatment system was operated to treat water treatment plant residuals and operation parameters was evaluated. Result of this experiment, high concentration organic matters contributed to high increase Transmembrane pressure(TMP) of membrane system(from 0.05 bar to 0.35 bar). And backwash process was effective to stabilize membrane system operation. After Cleaning-In-Place(CIP), permeability was recovered about 100 % from first operation condition. Inorganic matters (Fe, Mn, Al, Ca, Mg) were not effective membrane filtration performance. The quality of residual treatment was satisfied with drinking water quality standard and a treated water from that system was suitable for water reuse.

Analysis of design parameters of residual treatment process at eight model water treatment plants, which were located in the four major watersheds, showed that there were large differences between those design parameters and the actual conditions. In this background, a new procedure was proposed and applied to the Chungju water treatment plant as an example of the optimum design of residual treatment process based on the characteristics of raw water. In this design example, a filter backwash recycle system consisting of a surging tank and sedimentation basin was newly proposed for more safe recycle of spent backwash water. It is expected that the design procedure proposed in this study would be estimated as a meaningful attempt to develope new design procedure for the domestic water industry.

최근 내수면양식장의 BFT 양식 배출수의 도시농업용 활용에 관한 연구가 활발하게 본 연구진에 의해 진행되어지고 있다. 하지만 도시농 업용으로 한정된 연구에서 비료가 다량으로 사용되어 지고 있는 과수에의 활용에 대한 연구 필요성이 대두되어 누구나 가정에서도 재배가 가능한 블루베리에서 BFT 배출수의 효과를 구명하여 보고자 본 연구를 수행하였다. BFT 배출수는 내수면양식연구센터 틸라피아를 양식 하고 있는 양식조의 물을 채취하여 무처리, 농장 관행법, 배출수 원액, 배출수 1/2희석액, 배출수 1/4 희석액 시비 등 5처리로 실험하여 다음 과 같은 결론을 얻었다. 블루베리의 총생산량과 과립당 무게는 처리간 유의성이 없어 배출수가 기존의 비료를 대체하여도 블루베리 열매 의 생육에 영향을 주지 않아 비료로서의 이용가능성이 있었음을 확인하였다. 그리고 과실내 무기성분의 변화에서는 나트륨과 철의 함량이 높게 나와 이를 줄일 수 있는 배출수 비료화의 또 다른 연구 점을 보여주고 있다. 블루베리의 고유 기능성 물질인 안토시아닌의 함량 결과에 서는 처리에 따른 일관성을 보이고 있지 않아 기능성물질의 변화에도 배출수의 처리가 나쁜 영향을 보이지 않음을 알 수 있어 블루베리의 재배에 있어서도 배출수의 비료활용도는 가능성이 있다는 결론을 얻을 수 있었다. 하지만 비료로서의 사용가능성을 더 높이기 위해서는 보다 정제된 배출수의 사용과 효과를 얻기 위해서는 배출수의 가공적 연구가 더욱 필요하다고 판단된다.

본 연구는 국제적으로 해양투기의 기준이 엄격해지고 있는 현재의 실정에 맞추어 양식장에서 배출되는 배출수를 자원의 선순환의 개념으로 이를 토마토 재배에 적용하여 도시농업용 비료로서의 이용가치를 구명하고자 수행하였다. 시험용 작물로는 완숙형 토마토‘슈퍼 선로드’를 사용하였으며, BFT 배출수는 내수면양식연구센터 틸라피아를 양식하고 있는 양식조의 물을 채취하여 무처리, 상업용 하이포넥스500배 희 석액, 배출수 원액을 매일 관주, 배출수 원액을 1주에 1회 관주, 완효성 고체비료 시비 등 5처리로 실험하여 다음과 같은 결론을 얻었다. 배출 수원액을 매일 처리하는 구가 T/R율과 엽록소함량이 제일 높은 결과를 보였으며, 과실의 당도도 제일 높은 결과를 보였다. 또한 토마토의 기 능성 물질은 리코펜함량의 결과에서도 하이포넥스와 관행의 재배방법보다 3배가 많은 함량의 결과를 보였다. 하지만 토마토 체내의 무기성 분의 함량결과 질소가 다른 처리구에 비해 제일 많은 결과를 보여 비료사용으로서의 보완점을 연구해야하는 문제점도 보였다. 하지만 생육 과 기능성 물질의 함량결과등을 고려하여 본다면 BFT 양식 배출수의 비료효과에 대한 가능성은 매우 높은 것으로 나타났다.

The objective of this study is to find a useful method of utilizing effluent water from the BFT inland water culture. Recently Sludge and effluent water have been noted to cause water pollution. Therefore, this progressive study of recycling method will replace the use of chemical fertilization. Effluent water from inland water culture contains many fertilization ingredients. This study used different using methods of fertilization. As a result, effluent water that isn't matured and diluted had positive effects on the growth of lettuce. Effluent water of undiluted involved many mineral elements and proper pH concentration for plants growth but which are involved many concentrations of Na + ion. High concentrations of Na + ions are harmful for the growth of plants. This experiment did not show plants adversely affected by Na + ions. Potentially Na + ions can cause physiological disturbances of the plant. Effluent water smells because effluent waters using is need to additional pre-treatment for removal its high concentration Na + ions and bad smell.

Recently, increasing interest in environmental pollution problems that can be discharged emerging from inland water cultures, problems in the processing of effluents are recognized as environmental pollution sources are difficult accordingly. As a result, in this study, the effluent water as such a source of environmental pollution carried examine the availability of as organic fertilizer to be used for cultivation of crops. The study tested using 3 types of crops, As a method of using as a fertilizer in a particular solution that was created and practices to liquid fertilizer solution used to the concentration of the effluent. After you grow crops in a certain amount of irrigation once every week for each processing it was analyzed for the differences of content of the functional substance and growth of crops. As a result a certain amount of the effluent water in the stock solution, the content of functional materials and growth of crops were found to be superior to other processes in irrigation which was treated weekly. In conclusion, according to these results the effluent water from BFT inland water culture has been found to give a positive effects on the contents of the functional materials and growth of crops. Studies on a method for utilizing the effluent water as a fertilizer is considered further required.

Daphnia Magna Stratus has been widely accepted as useful species for estimating the toxicity of chemicals to aquatic invertebrate and recommended as species for the testing chemicals from the international guideline as well as Korean guideline. The study was performed for the acute toxicity test by using water flea(D. Magna) for effluents from several wastewater treatment plants and drainage canals in GyeongBuk area. Five heavy metals, 1,4-Dioxane and Perchlorate were tested. Most Toxicity Units(TU) of Industrial wastewater effluents were less than 1 which means effluent was not toxic to D. Magna. However, effluents containing 1,4-Dioxane and Perchlorate were significantly toxic to D. Magna. Therefore, facilities should reduce the 1,4-dioxane since new regulations will force them after the year of 2011.