기존에 국내에서 지하수에 대한 해수의 영향 연구가 거의 이루어지지 않았던 다도해상의 도서 지역인 전라남도 신안군의 지하수 수질 특성을 평가하였다. 지하수에 대한 해수의 영향을 평가하기 위해 지하수의 현장 수질 측정과 주요 용존성분 등을 포함한 수리지구 화학적 인자를 조사하였다. 총 4회에 걸친 현장 수질 측정 결과, 500 μS/cm 이상의 높은 전기전도도 값을 나타내는 관정은 163개 중 74개로 나타났으며, 용존이온 분석을 통한 Cl−/HCO3− 몰 비로 지하수의 해수 영향을 분석한 결과 심한 영향 및 매우 심한 영향을 의미하는 2.8 이상의 값을 갖는 시료가 74개 중 40개에 해당하였다. 지하수 수질유형의 경우, 직접적인 해수의 영향을 받는 것으로 판단되는 Na-Cl 유형과 해수침투에 의한 지하수 진화단계에서 Na-Cl 이전 유형인 Ca-Cl 유형은 암반지하수의 경우 각각 35.3, 44.1%, 충적층/풍화대 지하수의 경우 52.5, 45%를 차지하였다. 이러한 대수층별 해수의 영향 특성은 각 관정의 해안에서의 거리, 양수량, 조석 등의 영향을 받을 것으로 판단된다.

본 연구에서는 결정질 기반암에 위치하는 12개 시추공의 지하수 수질을 분석하여, 다변량 통계 분석법을 활용하여 지하수 수질 진화 특성 및 성분 기원을 평가하였다. 지하수 수질 유형은 Na(Ca)-HCO3형과 Ca-HCO3형이 가장 우세하여, 물-암석 반 응에 의한 직접적인 양이온 교환 반응(Ca2+ → Na+)을 지시하며, 현장 지하수 특성과 실내 지하수 분석 결과에 기초한 연구 지역의 지하수 수질 진화는 초기 내지 중간 정도의 단계를 지시하는 것으로 사료된다. 다변량 분석 결과, 인위적인 기원인 NO3 -와 다른 성분들 간의 상관성을 살펴보면, Na+, Cl-와 양의 상관성을 나타난다. 염무의 기원인 Cl-와는 Na+, SO4 2-, Mg2+, K+ 와 양의 상관성을 나타낸다. 그러나 다른 성분들(Ca2+, Fe2+, HCO3 -, F-, SiO2)과는 상관성이 나타나지 않는다. Cl- 농도가 일반 적인 지하수 수질 범위에 포함되고 NO3 - 농도는 먹는물 수질기준치 이하로서 농도가 매우 낮으며, 대부분의 광물에 대해서 지하수 화학성분들은 불포화상태를 지시한다. 따라서, 연구지역의 수질 성분들은 대부분 물-암석 반응을 통한 자연적인 기 원을 지시하고 부분적으로는 자연적인 염무와 농업과 관련된 인위적인 오염으로부터 기인된다.

For introducing the groundwater quality assessment using background concentration of groundwater, several methods had been studied to estimate the background concentration of groundwater and to suggest the background concentration of study area. Some methods such as Box whisker plot, Percentile and Cumulative probability distribution had been adopted to estimate background concentration, and it was evaluated that the Cumulative probability distribution method presents more reasonable background concentration because it can consider the data distribution. So we estimated the background concentration of study area using cumulative probability distribution method. We suggested the background concentration for each hydrogeology respectively in case hydrogeological water quality similarity is very low.

This study characterized water quality of groundwater and purified water used for drinking water in 30 schools in Gyeongsangbukdo Province. The results of the study showed that 43% of groundwater and 45% of purified water were not suitable for drinking. Among them, microbial contaminations were the most serious problem. In raw groundwater, the exceeding rates of total colony counts was the highest in August (53.6%). Purified water samples showed higher rate of exceeding drinking water standard for total colony counts while showing lower rate of exceeding drinking water standard for total coliforms and fecal coliforms in March and August. Overall, proper managements for microbial contaminations are required for both groundwater and purified water. Furthermore, special attention should toward students not to drink water when groundwater or purified water exceeds the drinking water quality standard.

This study was performed to provide the basic information on characteristics of groundwater pollution in Gyeongsan city. Forty two groundwater samples were collected, and pH, DO, COD, NH3-N, NO3--N, T-N, PO43--P, Cl, Ca, Mg, hardness, evaporate residues and others were investigated. And, ANOVA analyses were carried out to reveal the differences in water pollution indicator values of by industry, commerce/residence and agriculture areas. The results were as follows. 1. The mean values of pH, DO, COD, NH3-N, NO3--N, T-N, PO43--P, Cl, evaporate residues, Ca and hardness were 6.9, 7.9 ㎎/ℓ, 0.4 ㎎/ℓ, 2.44 ㎎/ℓ, 2.73 ㎎/ℓ, 6.06 ㎎/ℓ, 0.82 ㎎/ℓ, 32.72 ㎎/ℓ, 381.67 ㎎/ℓ, 41.53 ㎎/ℓ, 177.17 ㎎/ℓ, respectively. 2. As groundwater became deeper, the values of Cl, Ca, Mg, Na, hardness and evaporate residues remarkably increased, but those of COD, NH3-N, NO3--N, NO2--N, T-N decreased. 3. The values of COD, Cl, Ca, Mg, Na, hardness and evaporate residues were very high in industrial area, and those of NH3-N, NO2--N, T-N were very high in commercial/residential area, and those of NO3--N were a little high in agricultural area. 4. The correlations between depth and each value of Mg, Na, Fe, hardness and evaporate residues were highly positive, and those between DO and each value of Mg, Cu, Fe, hardness and evaporate residues were highly negative. 5. According to ANOVA analyses, the differences in three area groups (industry, commerce/residence and agriculture) on the values of NH3-N, T-N, evaporate residues, hardness, Ca, Mg, K and Fe were significant at 1% level.

질산성질소와 염소이온은 지하수에서 흔히 나타나는 항목으로서 농약의 사용이나 도시화 등에 의하여 주로 발생한다. 일반적으로 동일 지점의 지하수 수질 자료는 관측망의 경우를 제외하고는 샘플의 수가 제한적이기 때문에 시계열 자료를 활용한 추세 평가에 한계가 있다. 본 연구에서는 제주도 수계의 분포 특성, 저지대의 낮은 지형 경사, 수리적 특성 및 다공질 지질 특성 등을 고려하여 간격의 격자를 작성하고 격자내에 포함된 수질검사 자료를 모두 취합하여 시계열 데

The characteristics of drinking groundwater quality at Chung Cheong Nam Do was analyzed by investigating the 3,086 groundwater data which were carried out the water quality inspection from Jan. 1998 to Dec. 1998. It was found that all the mean concentration of items was not over the drinking water quality standard except Zn at Yeongee area. The highest mean concentration of nitrate was 8.2 ㎎/ℓ at Hongsung area. And the mean concentrations of nitrate and ammonium at Sucheon, Yesan, Yeongee were relatively higher. It was considered that the groundwater of that area was contaminated by breeding livestock as farm pollutants. The mean concentrations of chloride, hardness and evaporation residual at coastal regions were higher than inland regions. Especially the mean concentration of chloride was 2.5 times higher. It was considered that the groundwater at coastal regions was affected by seawater. It was found that the correlation between Fe and Mn was relatively high(r=0.776) and the correlation between hardness and evaporation residual was very high(r=0.983). The rainfall series and detection rate of E-coli had the hydrologic persistence. The correlation between the detection rate and rainfall series over 150 mm was very high (r=0.9146). Therefore it is surely required to control the groundwater sanitation in the rainy season.

도시화가 빠르게 진행된 부천시 지역의 수질조사 당시 토지이용을 토지이용 변화과정에 의해 세부 분류하고 토지이용과 토지이용기간에 따른 지하수 수질차이 여부를 비모수통계기법으로 검정하였다. 연구지역에서 검출빈도가 높은 7개 성분의 수질자료를 이용하였다. 수질조사 당시 토지이용이 동일한 지역에서 천부지하수 수질은 토지이용기간에 따라 통계적으로 유의한 차이를 보인다. 20년 이상 이용된 오래된 주거지역의 과망간칼륨소비량(이하 KMnO), 경도 등의 농도는 10

The pollution characteristics of groundwaters in Taegu City and correlation coefficients(r) between water pollution indicators were investigated for two years from January 1996 to December 1997. Volatile organic compounds such as TCE(tri-chloroethylene), PCE(tetrachloroethylene), 1,1,1-trichloroethane, THM(trihalo-methane), dichloromethane, pesticides such as diazinon, parathion, malathion, and toxic inoganic matters such as As, Hg, Se, Pb, Cd, Cr6+ , CN were not detected in the groundwaters. Mean values of groundwater pollution indicators were below drinking-water standards, but hardness, KMnO4-C(potassium permanganate consumption), evaporate residues, SO4-2, Fe, NO3- -N, color and turbidity exceeded a little in some samples. As groundwater became deeper, hardness and evaporate residues remarkably increased, but KMnO4-C, NO3- -N, Cl-, color, turbity and bacteria decreased. KMnO4-C, evaporate residues, Cl- and SO4-2 were very high at industrial and commercial areas, and NO3- -N and NH4+-N were very high at agricultural and forest areas. It showed high positive significances in the relationships between hardness and each of evaporate residues, SO4-2, Zn and Mn, KMnO4-C and each of color, turbidity and Zn, color and each of turbidity, Cu, Zn and Mn, turbidity and each of Fe, Cu, Zn and Mn, and evaporate residues and each of Cl-, SO4-2 and Zn.

지하수 수질 감시를 위한 관측망의 설치는 지하수자원의 보호를 위해 매우 중요하다. 그러나 현재 지하수 수질 관측망의 설계는 합리적인 방법보다는 현장전문가의 경험과 직관에 의존하는 경우가 많다. 본 논문에서는 3차원 수질모의와 최적화를 이용하는 지하수질 관측망의 설계방법론을 제안하였다. 설계과정은 다음의 세 가지 경우로 정형화되었다. (Ⅰ) 평균농도를 감시하는 위치를 선정하되 관측정의 수기 제한되는 경우, (2) 최대농도를 감시하는 위치를 선정하되 관측정

지하수질 감시를 위한 관측은 지하수를 사용하는 주변 인구의 보건은 물론이고 궁극적으로는 지하수자원 보전이라는 측면에서 매우 중요하다. 그러나 지하수 수질관측망은 설계부터 운영에 이르기까지 임의적이고, 체계적이기보다는 경험에 의존하거나 과학적이지 못한 방식으로 시행되고 있는 것이 사실이다. 본 연구는 지하수질 관측망의 효율적 배치를 위한 방법론의 현장적용성을 검토하기 위하여 대표적인 설계방법론을 대상으로 비교연구 하였다. 그 결과, 지하수질 관측망의 설계

To examine water pollution status of agricultural water source of greenhouse area in Gyeongnam, the ground water quality was investigated six times at five areas in Gyeongnam from October in 1995 to March in 1996. pH of ground water were generally in the range of 5.9∼7.6. But a site in Changnyeong area was out of the range in 6.0∼8.5 which is water quality standard for agriculture. COD of ground water was below 8.0㎎/ℓ which is water quality standard for agriculture in all areas and the average was below 2.8㎎/ℓ. NH_4^+ -N contents in ground water was very low in all areas and the average of NO_3^- -N contents in Changnyeong and Chinju area was high with 13.2 and 11.5㎎/ℓ, respectively. Hardness, SO_4^2- and EC of ground water in Haman were higher than any other area. Fe and Mn contents of ground water in Kimhae were higher than any other area with 7.17 and 0. 95㎎/ℓ, respectively. Heavy metals such as Cu, Cd, Pb and Zn of ground water were below water quality standard for agriculture but some sites were over. Between COD and SS in ground water were not correlated with r=0.328, but between COD and NH_4^+ -N were positively correlated. And EC was positively correlated with Ca^2+, Mg^2+ and SO_4^2-. Ground water pollution status of agricultural water source of greenhouse area in Gyeongnam was generally high in order of Sacheon < Chinju < Haman < Kimhae < Changnyeong.

One hundred and thirty two ground water samples from the Ulsan area were divided into urban and non-urban groupings and were assessed between 1993 and 1996. The results of statistical analysis were as follows: There were significant differences between the two groupings in the average value of the following water quality parameters: total hardness, nitrate, pH, iron, ammonia and chloride ion in the order of Z-score. Because total hardness, nitrate, and pH were also significant in ANOVA test, these three parameters can be regarded as the most sensitive parameters of artificial pollutants. By the comprehensive comparison of Ulsan water quality to that of Kangwon-do, all of the major parameters(pH, KMnO_4 consumption, sulfate, chloride and hardness except nitrate) were confirmed as being significantly increased levels.

In order to provide for the guidance on groundwater quality monitoring network design and also, to suggest the index to the solution of the contaminated groundwater remediation problems in the lake watershed, it is necessary to analyze the contaminant transport in the groundwater. The solute transport was analyzed in the lake watershed to investigate the behavior of the injected contaminant sources depend on the relationships between the point of contaminant sources and position of the lake. Three hypothetical groundwater flow systems, which is composed of a flow-through lake and two solute sources, were considered. The lakes located in the upper, middle, and lower portions of a watershed respectively. The transported contaminant was numerically simulated for five years by using MT3D contaminant transport model under the three-dimentional steady state conditions. From the above simulations, it can be concluded that the contaminant concentration was high as the contaminant source located at the upper position of a watershed, and the influence of the contaminant injection was large as the solute source located at the lower position. When the injection of contaminant was continued for one year without regard to the position of contaminant source and the lake, the influence of contaminant source was reached to bedrock.