This study was conducted to solve the problem of the existing odor management method taking a long time to analyze samples. Using real-time air quality measurement equipment, 17 designated odor substances were measured three times at a business site causing odor complaints. As a result, three substances, hydrogen sulfide, trimethylamine, and methyl mercaptan, were measured at higher levels than the site boundary emission standards inside the business site. In the case of trimethylamine, it was measured about 500 times higher than Odor Threshold Values, and was estimated to be the substance causing the odor. Through an inspection of the business site, improvements were instructed to be made to the wastewater treatment process, which is the emission facility where trimethylamine is generated. Subsequent measurement results showed that designated odor substances were measured within the emission standards at all locations, and it was determined that efficient management of odorgenerating businesses would be possible if Selected Ion Flow tube-Mass Spectrometry was utilized.

Reported positive ion fragmentation of phenolic acid derivatives in rice (Oryza sativa L.) were summarized based on the literature. A total of eight phenolic acids (4 derivatives of ferulic acid, 3 derivatives of sinapic acid and p-coumaric acid) were isolated and identified from rice (raw and steamed) using UPLC-DAD-QToF/MS. Results revealed that 6-O-feruloylsurose was the major component with 3'-O-sinapoylsucorse being tentatively identified in Oryza sativa L. for the first time as a new hydroxycinnamoyl derivative in rice grains. In our study, raw brown rice had the highest phenolic acid contents with Samkwang showing higher phenolic acid content than Saeilmi and Sindongjin (12.41 vs. 7.89 and 3.10 mg/100 g dry weight, respectively). Of all varieties, brown rice had higher phenolic acid contents than white rice. These contents decreased considerably when rice was steamed whereas, p-coumaric acid and ferulic acid contents were increased. Additionally, contents of rice (raw and steamed) can be used as a fundamental report for new rice varieties.

이 논문에서는 보행교의 진동 사용성 평가에 있어서 보행자의 이동 질량 관성 효과의 고려 여부, 보행 패턴 등을 고려한 보행 시나 리오 등에 따른 해석 결과를 제시하고, 그에 따라 보행교 설계 단계에서 동적 유한요소 해석을 통한 진동 사용성 평가에 있어 적절한 해석 방법과 유의점을 제안한다. 지간 40m의 강합성 박스 단면을 갖는 단경간 단순교 형식의 보행교에 대하여 보행자 밀도, 보행 속 도, 임의 보행, 동기화 보행 등을 고려한 보행 시나리오에 대한 가속도 응답을 분석한다. 해석 결과 고정 질량 해석 방법은 임의 보행 시 나리오 해석에서 이동 질량 해석과 큰 차이를 보이지 않으며 진동 사용성 평가시에는 더 넓은 진동수 대역을 가진할 수 있는 임의 보행 시나리오를 고려하는 것이 바람직할 수 있음을 보였다.

이 논문에서는 이동하는 질량체의 연직 방향에 대한 관성 효과를 고려하여 보의 진동을 해석할 수 있는 유한요소해석 방법을 제안 한다. 제안하는 방법은 정밀한 상호작용 해석을 요하지 않는 경우에 계산의 효율성을 높이는 방법으로서, 이동하는 질량체의 관성 효 과를 운동방정식에 연계시키고 질량체와 보의 상호작용력은 외부 하중으로만 고려한다. 범용 유한요소해석 소프트웨어인 Abaqus를 이용하여 시간 영역 해석을 수행하고 보의 절점과 이동하는 강체 질량의 절점 변위를 다지점 구속조건으로 연계하여 해석하는 방법 을 제시하였다. 기존 해석적 방법에 의한 해와 비교하여 제안하는 방법을 검증하고 보행하중 모델을 이용한 이동 보행 하중해석에서 보행자의 질량 효과를 살펴보기 위한 간단한 연속 보 모델에 대한 해석 결과를 제시하였다.

본 연구에서는 열대우림인 브루나이 MDF와 PSF의 주요 수종 (D. aromatic, D. rappa, C. arborescens)을 대상으로 초기 분해 단계의 수종별 질량 감소율과 탄질율의 변화를 파악하였다. 2019년 5월에 총 48개의 고사목 시료 (15 cm×4.8 cm×5 cm)를 산림 지표면에 배치하고 16개월 후 수거하였다. 분해 전 수종별 고사목의 밀도 (g cm-3)는 0.64±0.01 (D. aromatic), 0.60±0.00 (D. rappa), 0.44±0.02 (C. arborescens) 등이었으며, 16개월 동안 수종별 연간 질량 감소율 (%)은 6.37 (D. aromatic), 8.17 (D. rappa), 18.53 (C. arborescens) 등으로 나타났다. 부후등급은 C. arborescens에 서 III등급이 약 25%로 높았으며 흰개미의 분해 흔적이 나타났다. 한편, 16개월 후 탄질율은 D. aromatic과 D. rappa에 서 통계적으로 유의하게 감소하였으나, C. arborescens에서는 감소하는 경향이 유의하지 않았다. 이러한 연구 결과는 열대우림 내 고사목의 초기 분해는 밀도와 같은 수종의 물리적 특성에 따라 차이가 나타날 수 있으며, 주요 분해자의 유형에 따라 탄질율의 변화에도 상대적으로 차이가 있을 수 있음을 시사하는 것이다.

본 연구에서는 구조물의 진동제어를 위하여 사용되는 가장 대표적인 수동형 제진장치로 알려진 동조질량 감쇠기(Tuned Mass Damper, TMD)의 동적특성을 운영 중에 추정하는 기법에 대해서 다룬다. 동적특성 추정법은 무향칼만필터에 기반하고 있으며, 구조물과 TMD의 계측 가속도를 이용한다. TMD 파라미터 중에 마찰계수를 추정 파라미터로 포함하는 경우와 그렇지 않은 경우로 구분하여 마찰계수가 TMD의 동적특성에 미치는 영향을 평가하였다. 추정된 TMD 파라미터와 TMD에 의해서 분화된 두 개의 인접모드의 동적 특성을 이용하여 제어 대상 모드의 동적특성을 추정하여 제진장치에 의한 제어성능을 평가하였다. 본 연구에서 제안된 TMD 파라미터 추정법을 실 구조물 계측응답에 적용한 결과 안정적인 파라미터 추정이 이루어지는 것을 확인할 수 있었으며 제어성능 평가가 가능함을 검증하였다.

As people's living standards and cultural standards have developed, interest in culture and art has increased, and the demand for large space structures where people can enjoy art, music, and sports has increased. As it accommodates a large number of personnel, it is most important to ensure safety of large spatial structures, and can be used as a space where people can evacuate in case of a disaster. Large spatial structures should be prepared for earthquake loads rather than wind loads. In addition to damage to the structure due to earthquakes, there are cases in which it was not utilized as a space for evacuation due to the fall of objects installed on top of the structure. Therefore, in this study, the dome-shaped large spatial structure is generalized and the displacement response according to the number of installations, position and mass is analyzed using a tuned mass damper(TMD) that is representative vibration control device.

규소(Si)는 지각의 구성 원소 중 두 번째로 흔히 존재하는 원소로, 3개의 안정동위원소, 28 Si (92.23%), 29 Si (4.67%), 30Si (3.10%)를 가진다. 규소 동위원소는 규소의 생지화학적 순환에 대한 지시자로 고환경 및 고기후 복원을 위해 전 세계에서 널리 연구되고 있다. 그러나 국내에서는 아직까지 생물 기원 규소에 대한 규소 동위원소 연구가 전 무한 실정이다. 본 연구에서는 대형 규조류 시료에 대한 규소 동위원소 분석을 위해 기존 보고된 알칼리 용융법을 정리하고 생물 기원 규소 분석에 가장 적합한 규소 분리법을 구축하고자 하였다. 해당 시료를 고온 알칼리 용융을 통해 완전 용해시킨 후 시료 내 규소를 AG® 50W-X8 양이온 교환수지를 이용하여 효과적으로 분리하였다. 분리된 시료에 대한 신뢰성 검증을 위하여 Si 동위원소 표준물질(NBS-28) 및 USGS 암석 표준시료(AGV-2, GSP-2, BHVO-2)에 대한 분석을 함께 실시하였으며, 분석된 시료 모두 기존 연구결과와 오차범위 내에서 일치하는 값을 나타내었다. 본 연구에서 개발한 규소 동위원소 분석법은 향후 국내의 지구과학 및 관련 연구 발전에 많은 도움을 줄 것으로 기대된다.

In this study, chemical information on a total of 20 individual compounds was constructed to identify isoflavones from the previous reports related with used parts(seeds, leaves, stems, pods) and products of soybean(Glycine max L.). Through constructed library and UPLC-DAD-QToF/MS analysis, a total of 19 individual isoflavones including aglycones, glucosides, acetylglucosides and malonylglucosides as major compounds was identified and quantified from 14 selected soybean seeds. Among them, genistein 7-O-(2"-O-apiosyl)glucoside and genistein 7-O-(6"-O-apiosyl)glucoside(ambocin) were identified tentatively as novel compounds in soybean seeds. Besides, among malonylglucosides, glycitein 4'-O-(6''-O-malonyl)glucoside was estimated for the first time. Total isoflavone contents were distributed from 240.21 to 445.21(mg/100 g, dry matter) and 7-O-6''-O-malonylglucosides were composed of 77.8% on total isoflavone as well as genistein derivatives were confirmed as major class. It was considered importantly that the development of isoflavone-rich varieties was necessary to strengthen their effects such as anti-inflammation, anti-cancer and menopause mitigation. The qualitative and quantitative data presented precisely in this study could be help to select and breed isoflavone-rich varieties. Furthermore, their basic isoflavone profile is expected to be applied to estimate the change of isoflavone conjugates on bioavailability after soy food supplements.

본 연구의 목적은 배드민턴 여자 중학생 전문선수(10명)와 방과 후 배드민턴 수업에 참여하는 일반학생(10명)의 하이클리어 동작 시 COM과 COP의 수평거리, 그리고 COM과 COP의 이동패턴의 차이를 비교 분석하는데 있다. 두 그룹 간 하이클리어 스트로크 이후 착지 시점(E4)에서 COM과 COP의 X 축과 Y축에서의 수평거리와 백스윙, 포워드스윙, 스윙전체의 X축, Y축, 그리고 Z축에서 COM의 최대이 동범위의 차이를 비교하기 위해 독립표본 T-test를 실시한 결과, 첫째, 하이클리어 스트로크 임팩트 이후 착지 시점(E4)에서 여자 중학생 전문선수는 전후방향(X축)에서 COM와 COP지점이 일반학생에 비해 매 우 가깝게 위치하였다. 둘째, 전문선수는 COM의 수직움직임, 일반선수는 COM의 수평움직임을 적극적으로 활용하였다.

In this paper, the displacement response to seismic loads was analyzed after installing TMD in spatial structures and high-rise buildings. In the case of a spatial structures, since it exhibits complex dynamic behavior under the influence of various vibration modes, it is not possible to effectively control the seismic response by installing only one TMD, unlike ordinary structures. Therefore, after installing eight TMDs in the structure, the correlation between displacement response and mass ratio was examined while changing the mass. The TMD must be designed to have the same frequency as the structure frequency so that the maximum response reduction effect can be exhibited. It can be confirmed that the most important variable is to select the optimal TMD mass in order to install the TMD on the structure and secure excellent control performance against the earthquake load. As a result of analyzing the TMD mass ratio, in the case of high-rise buildings, a mass ratio of 0.4% to 0.6% is preferable. In spatial structures, it is desirable to select a mass ratio of 0.1% to 0.2%. Because this study is based on the theoretical study based on numerical analysis, in order to design a TMD for a real structure, it is necessary to select within a range that does not affect the safety of the structure.

The concentrations of odor and volatile organic compound (VOC)-inducing substances were measured using selected ion flow tube mass spectrometers (SIFT-MS). SIFT-MS can continuously measure the concentration of odor-causing substances and VOCs in real time without pre-treatment steps. Measurements were conducted during the day and at night at 10 spots in the chemical block of the Sihwa industrial complex. Similar measurement results were observed in the daytime and nighttime for materials except methyl ethyl ketone with high concentrations. A high concentration of hydrogen sulfide was also measured at night. It is expected that an amount of emissions of VOCs and odor-causing substances under the absence of inspection can be traced if measured at other industrial complexes in vulnerable times.

본 논문은 기상 모델의 미세구름물리 모수화 과정 내의 눈송이의 질량-크기 관계가 지표 강수 모의에 미치는 영향에 대해 연구에 관한 것이다. WDM6와 WSM6 미세구름물리 모수화 방안이 연구를 위해 사용되었다. 실제 관측된 자료를 바탕으로 산출된 Thompson의 눈송이의 질량-크기 관계를 도입하여 WDM6와 WSM6 내의 눈송이의 질량-크기 관계식을 대체하였다. 이상적인 스콜선과 한반도 겨울철 강수 사례에 대해 수정된 WDM6와 WSM6를 사용하여 민감도 실험을 실시하였다. 결과적으로, 대기 하층에서는 싸락눈과 빗방울의 혼합비가 증가하였고 눈송이의 혼합비는 감소하였다. 이러한 혼합비와 지표 강수의 변화는 빗방울과 눈송이의 충돌 및 병합 과정과 싸락눈의 융해 과정에 기인한 것으로 분석되었다.

In this study, the retractable-roof spatial structure was chosen as the analytical model and a tuned mass damper (TMD) was installed in the analytical model in order to control the seismic response. The analysis model is mainly consisted of runway trusses (RT) and transverse trusses (TT), and the displacement response was analyzed by installing TMD on those trusses. The mass of the single TMD which is installed in the analytical model was set to 1% of the total structure mass and the total TMD mass ratio was set to be 8% or 6%. In addition, the mass of a single TMD was varied depending on the number of installations. As a result of analyzing the optimal number of installations of TMD, the displacement response was reduced in all cases compared to the case without TMD. Above all, the case with 8 TMDs was the most effective in reducing he displacement response. However, in this case, as the load on the upper structure of the retractable-roof spatial structure increases, the total mass ratio of TMD was maintained and the number of TMDs was increased to reduce the mass ratio of one TMD.

A conventional lumped-mass stick model is based on the tributary area method to determine the masses lumped at each node and used in earthquake engineering due to its simplicity in the modeling of structures. However the natural frequencies of the conventional model are normally not identical to those of the actual structure. To solve this problem, recently an updated lumped-mass stick model is developed to provide the natural frequencies identical to actual structure. The present study is to investigate the seismic response accuracy of the updated lumped-mass stick model, comparing with the response results of the shaking table test. For the test, a small size four-story steel frame structure is prepared and tested on shaking table applying five earthquake ground motions. From the comparison with shaking table test results, the updated model shows an average error of 3.65% in the peak displacement response and 9.68% in the peak acceleration response. On the other hand, the conventional model shows an average error of 5.15% and 27.41% for each response.

In the precedent study, the retractable-roof spatial structure was selected as the analytical model and a tuned mass damper (TMD) was installed to control the dynamic response for the earthquake loads. Also, it is analyzed that the installation location of TMD in the analytical model and the optimal number of installations. A single TMD mass installed in the analytical model was set up 1% of the mass of the whole structure, and the optimum installation location was derived according to the number of change. As a result, it was verified that most effective to install eight TMDs regardless of opening or closing. Thus, in this study, eight TMDs were installed in the retractable-roof spatial structure and the optimum mass ratio was inquired while reducing a single TMD. In addition, the optimum mass distribution ratio was identified by redistributing the TMD masses differently depending on the installation position, using the mass ratio of vibration control being the most effective for seismic load. From the analysis results, as it is possible to confirm the optimum mass distribution ratio according to the optimum mass ratio and installation location of the TMD in the the retractable-roof spatial structure, it can be used as a reference in the TMD design for large space structure.