PURPOSES : Carbon dioxide (CO2) is a cheaper and easier to installer fire suppressant than other extinguishing gases and is easy to install, but extinguishes fires by is suffocation. As a result, suffocation accidents continue to occur in facilities equipped with CO2 fire-extinguishing facilities, Emission standards have yet to be established. This study aims to address the issue. METHODS : To effectively remove CO2 emitted from installed systems, we reviewed and analyzed previous related research and existing international standards. RESULTS : In protected areas where CO2 fire-extinguishing systems are installed, emission facilities should discharge the emitted CO2 before it enters the protected spaces. CO2 sensors can determine whether safe entry is possible or whether respirators are required. CONCLUSIONS : This study presented a specific installation method for emission facilities capable of actively discharging CO2. Applying this method is expected to contribute to improving safety in facilities equipped with CO2 fire-extinguishing facilities.

본 연구에서는 중공사형 이산화탄소 분리막 모듈을 사용하여 수소개질기 배가스로부터 이산화탄소 포집을 목적 으로 한 분리막 공정 최적화 연구를 진행하였다. 랩스케일의 소형 분리막 모듈을 사용하여 혼합기체를 대상으로 이산화탄소 순도 90% 및 회수율 90%을 달성하는 2단 공정 조건을 도출하였다. 막 면적이 정해진 모듈의 분리막 공정에서는 스테이지-컷, 주입부 및 투과부 압력에 따라서 포집 순도 및 회수율이 모두 다르게 나타나기 때문에 운전 조건에 대한 최적화가 필수적이 다. 본 연구에서는 다양한 운전 조건에서 1단 분리막에서 보이는 공정 포집 효율의 한계를 확인하고, 높은 순도와 회수율을 동시에 달성하기 위한 2단 회수 공정을 최적화하였다.

Refined structured tin dioxide gets the amount of attraction because of its low cost and stability. The C@SnO2 nanospheres with mesoporous structures were produced using the hard template method in this work. The C@SnO2 is primarily gained attributed to the dehydration condensation of C6H12O6 and the hydrolysis of SnCl4 ·5H2O. The morphology of the C@SnO2 was analyzed by physical characterization and the diameter of the obtained C@SnO2 was around 138 nm. When C@SnO2 was applied to lithium-ion batteries as anode material, it performed outstanding electrochemical properties, with a capacity of 735 and 539 mA h g− 1 maintained at 1000 and 2000 mA g− 1, respectively. Furthermore, it exhibits favorable discharge/ charge cycle stability. This is probably because of the more chemically redox active sites provided by C@SnO2 nanocomposites and it also allows fast ion diffusion and electron migration.

Tomatoes in greenhouse are a widely cultivated horticultural crop worldwide, accounting for high production and production value. When greenhouse ventilation is minimized during low temperature periods, CO2 enrichment is often used to increase tomato photosynthetic rate and yield. Plant-induced electrical signal (PIES) can be used as a technology to monitor changes in the biological response of crops due to environmental changes by using the principle of measuring the resistance value, or impedance, within the crop. This study was conducted to investigate the relationship between tomato growth data, vital response, and PIES resulting from CO2 enrichment in greenhouse tomatoes. The growth of tomato treated with CO2 enrichment in the morning was significantly better in all items except stem diameter compared to the control, and PIES values were also higher. The growth of tomato continuously applied with CO2 was better in the treatment groups than control, and there was no significant difference in chlorophyll fluorescence and photosynthesis. However, PIES and SPAD values were higher in the CO2 treatment group than control. CO2 enrichment have a direct relationship with PIES, growth increased, and transpiration increased due to the increased leaf area, resulting in increased water absorption, which appears to be reflected in PIES, which measures vascular impedance. Through this, this study suggests that PIES can be used to monitor crops due to environmental changes, and that PIES is a useful method for non-destructively and continuously monitoring changes of crops.

This study was aimed to determine the changes in CO2 concentration according to the temperatures of daytime and nighttime in the CO2 supplemental greenhouse, and to compare calculated supplementary CO2 concentration during winter and spring cultivation seasons. CO2 concentrations in experimental greenhouses were analyzed by selecting representative days with different average temperatures due to differences in integrated solar radiation at the growth stage of leaf area index (LAI) 2.0 during the winter season of 2022 and 2023 years. The CO2 concentration was 459, 299, 275, and 239 μmol·mol-1, respectively at 1, 2, 3, and 4 p.m. after the CO2 supplementary time (10:00-13:00) under the higher temperature (HT, > 18°C daytime temp. avg. 31.7, 26.8, 23.8, and 22.4°C, respectively), while it was 500, 368, 366, 364 μmol·mol-1, respectively under the lower temperature (LT, < 18°C daytime temp. avg. 22.0, 18.9, 15.0, and 13.7°C, respectively), indicating the CO2 reduction was significantly higher in the HT than that of LT. During the nighttime, the concentration of CO2 gradually increased from 6 p.m. (346 μmol·mol-1) to 3 a.m. (454 μmol·mol-1) in the HT with a rate of 11 μmol·mol-1 per hour (240 tomatoes, leaf area 330m2), while the increase was very lesser under the LT. During the spring season, the CO2 concentration measured just before the start of CO2 fertilization (7:30 a.m.) in the CO2 enrichment greenhouse was 3-4 times higher in the HT (>15°C nighttime temperature avg.) than that of LT (< 15°C nighttime temperature avg.), and the calculated amount of CO2 fertilization on the day was also lower in HT. All the integrated results indicate that CO2 concentrations during the nighttime varies depending on the temperature, and the increased CO2 is a major source of CO2 for photosynthesis after sunrise, and it is necessary to develop a model formula for CO2 supplement considering the nighttime CO2 concentration.

가스 분리 방법 중에서도, 멤브레인을 이용한 CO2 포집 및 분리는 지속적으로 개발되고 있는 꾸준히 성장하는 분 야이다. 이온성 액체(IL) 기반 복합 막은 CO2를 분리하는 데 있어 우수한 성능값을 보여준다. 유사하게, 다양한 공중합체/IL 복합막 또한 향상된 성능을 보여준다. 이러한 공중합체/IL 복합만에 산화그래핀과 같은 필러를 첨가하면 IL과 유기 필러 사 이에서 발생하는 강한 상호작용으로 인해 필러의 효과가 더욱 향상되며, 이는 결과적으로 CO2의 친화도, 선택도 및 흡착과 같은 요소를 향상시킨다. 금속-유기 구조체(MOF)를 사용하는 공중합체/IL 복합 막은 향상된 CO2 투과도를 보여주었다. 이 총설에서는 이온성 액체와 공중합체복합막의 다양한 조합에 따른 이산화탄소분리성능에 대한 상관관계를 논의한다.

한국의 목조건축문화유산은 상당수가 산림에 인접하여 흰개미에 의한 피해에 취약하다. 국내 흰개미 방제법은 살충제 접촉을 통한 화학적 방제법이 주로 이용되며, 방제 기간을 단축하기 위해서는 흰개미를 빠르게 약제까지 유인시킬 방법이 필요하다. 본 연구에서는 한국 서식 흰개미 에 대한 유인물질로 이산화탄소를 선정하여 유인여부 및 적절한 유인농도를 탐색하였으며, 지중 환경에서의 유인효력 기초평가를 진행하였다. 평가를 통해 흰개미에 대한 이산화탄소의 유인 효과를 확인하였으며, 이산화탄소 농도 10% 이하의 유효한 범위를 선정하였다. 또한 지중에서의 유인 효과를 확인함으로써 지중 환경에서의 적용 가능성을 파악하였다. 향후 현장에서 이산화탄소의 적용방안을 연구함으로써, 목조건축문화유 산의 흰개미 방제 시 개선된 방제 효과를 가질 수 있을 것으로 사료된다.

본 연구에서는 복숭아혹진딧물의 포식 기생자인 콜레마니진디벌의 기능반응을 조사하였다. 이산화탄소 농도별(400, 600, 1000ppm) 복 숭아혹진딧물 밀도를 달리하여(2, 4, 8, 16, 32, 64, 128마리) 콜레마니진디벌 한 마리를 24시간 동안 노출시켰다. 각 이산화탄소 처리에서 콜레 마니진디벌은 제 3 유형의 기능반응을 보였다. 600 ppm (0.015 day)과 1000 ppm (0.014 day)에서 추정된 처리시간은 400 ppm에서 추정된 결 과(0.017 day)보다 짧았다. 이산화탄소 농도별 복숭아혹진딧물 기생률은 유사한 특징을 나타내었다. 가장 높은 기생률은 400, 600, 1000 ppm 에서 복숭아혹진딧물 16, 32, 32마리에 대해 0.57, 0.61, 0.70이었다. 이산화탄소 농도 증가는 콜레마니진디벌의 기능반응에서 공격율에는 영향 을 주지 않았지만 처리시간에는 영향을 주었다.

본 연구는 등유를 사용하는 농업용 난방기에서 배출되는 가 스를 포집하고, 농업용 난방기의 사용 연식에 따른 이산화탄 소의 배출농도를 파악하고자 수행되었다. 선형 회귀분석의 결과로 농업용 난방기의 연식에 따른 이산화탄소의 배출량은 R2 = 0.84로 y = 26.99x+721.98의 식을 따른다고 나타났다. 농업용 난방기의 사용 연식에 따라 세 그룹으로 분류하여 분 산분석을 수행하였다. 분산분석을 수행한 결과, 분석을 위해 설정한 유의확률 0.05보다 작은 2.1961×10-13으로 나타났으 며 이는 적어도 한 그룹에서 차이가 나타난다는 것을 의미한 다. 본 연구에서는 농업용 난방기의 기본적인 배출농도의 차 이를 분석하고자 기기의 제작사와 상관없이 농업용 난방기의 기기 연식만을 고려하여 배출가스 데이터를 수집하였다. 기 기의 연소 방식에는 제작사에 따라 연소 방식에 차이가 미미 하게 있었을 것으로 판단되며 데이터 변수의 개수가 늘어난다 면, SVR(support vector regression) 기반의 선형회귀 분석 등 을 실시하여 농업용 난방기의 이산화탄소 데이터가 온실가스 발생량 파악에 더욱 활용도가 높아질 것으로 판단된다. 추후 연구에서는 더욱 세분화된 데이터의 수집 방식을 따라 더욱 높은 정확도를 가진 결과값을 도출할 수 있다고 판단된다. 이 처럼 우리나라의 농업 분야에서 용도별 온실가스 발생량을 조 사하기 위하여 고정형 농기계인 농업용 난방기의 이산화탄소 발생량을 정확히 파악하여 온실가스 배출량 조사에 활용할 수 있을 것으로 판단된다.

Radioactive carbon dioxide (14CO2) capture using innovative materials is desirable due to associated radiological hazards, and growing climate change. Mineral carbonation technology (MCT) is amenable to irreversibly capture CO2. Typically, MCT is attractive because capturing carbon through the chemical reaction between alkaline earth metal ions and CO2 forms insoluble and significantly stable carbonates. However, most applications of MCT have an intrinsic restriction regarding their operational conditions since no forward reaction occurs within realistic time scales. Thereby, the CO2 capture performance, such as CO2 capacity and carbonation reaction rate, of MCTs and their applications are severely restricted by the difficulty of operations under mild conditions. For example, natural minerals require aggressive carbonation reaction conditions e.g. high pressure (≥ 20 bar), high temperature (> 373 K), and pH-adjusted carrier solutions. To overcome such obstacles, the fabrication of alkaline earth oxides impregnated into an amorphous glass structure have been recently developed. They show enhanced rates of dissolution of alkaline earth metal ions and carbonation reaction due to the loosely packed glass structure and the generation of a surface coating silica gel, consequently facilitating CO2 capture under mild conditions. In this presentation, we report the synthesis and application of a crystallized glass tailored by controlled heat treatment for CO2 capture under mild conditions. The controlled heat treatment of an alkaline earth oxide-containing glass gives rise to a structural transformation from amorphous to crystalline. The structural characterizations and CO2 capture performance, including CO2 capacity, carbonation reaction rate, and the dissolution rate of alkaline earth metal ion, were analyzed to reveal the impact of controlled heat treatment and phase transformation.

Radioactive contamination of soil on the site of a nuclear facility has a characteristic that radioactive nuclides are adsorbed into the pores between soil particles, making it quite difficult to decontaminate. For this reason, research on the development of various decontamination processes is being actively conducted. In this study, among various decontamination studies, a soil decontamination process using supercritical carbon dioxide was presented. The decontamination process uses supercritical carbon dioxide as the main solvent, which has a higher penetration power than other materials. Therefore, the process consists of the process of desorbing and extracting the target radionuclides between particles of soil. However, since nuclides exist as ions in the soil, polar chelating ligand material was introduced as an additive to nonpolar supercritical carbon dioxide for smooth chemical reactions in the soil. Thereafter, from the viewpoint of improving process continuity and efficiency, an alcohol material was introduced as an auxiliary solvent for liquefaction of chelating ligand in a solid state. Through prior research on the selection of a solvent for liquefaction of chelating ligand, ethanol and 2-propanol were finally selected based on whether the chelating ligand was dissolved. However, if the auxiliary solvent in which the chelating ligand is dissolved is to be combined with radionuclides in the soil, it must first be well dissolved in supercritical carbon dioxide, the main solvent. Therefore, in this study, the solubility of ethanol and 2-propanol in supercritical carbon dioxide was measured and the suitability was evaluated. The temperature conditions were carried out at 40°C, the same as the previously designed decontamination process, and the measurement was conducted by adjusting the pressure and volume through a syringe pump and a variable volume device. In addition, solubility was measured based on the observation of the ‘cloud point’ in which the image becomes cloudy and then bright. As a result of the experiment, several solubility points were measured at a pressure of 150 bar or less. If the flow rate ratio of supercritical carbon dioxide and auxiliary solvent derived from the results is applied to the soil decontamination process, it is expected that the process efficiency will increase in the future.

Korea faces decommissioning the nation’s first commercial nuclear power plant, the Kori-1 and Wolseong-1 reactors. In addition, other nuclear power plants that will continue to operate will also face decommissioning over time, so it is essential to develop independent nuclear facility decommissioning and site remediation technologies. Among these various technologies, soil decontamination is an essential not only in the site remediation after the decommissioning of the highly radioactive nuclear facility, but also in the case of site contamination caused by an accident during operation of the nuclear facility. But the soil, which is a porous material, is difficult to decontaminate because radionuclides are adsorbed into the pores. Therefore, with the current decontamination technology, it is difficult to achieve the two goals of high decontamination efficiency and secondary waste reduction at the same time. In this study, a soil decontamination process with supercritical carbon dioxide as the main solvent was presented, which has better permeability than other solvents and is easy to maintain critical conditions and change physical properties. Through prior research, a polar chelating ligand was introduced as an additive for smooth extraction reaction between radionuclides present as ions in soil and nonpolar supercritical carbon dioxide. In addition, for the purpose of continuity of the process, a candidate group of auxiliary solvents capable of liquefying the ligand was selected. In this research evaluated the decontamination efficiency by adding the selected auxiliary solvent candidates to the supercritical carbon dioxide decontamination process, and ethanol with the best characteristics was selected as the final auxiliary solvent. In addition, based on the decontamination effect under a single condition of the auxiliary solvent found in the Blank Test process, the possibility of a pre-treatment leaching process using alcohol was tested in addition to the decontamination process using supercritical carbon dioxide. Finally, in addition to the existing Cs and Sr, the possibility of decontamination process was tested by adding U nuclides as a source of contamination. As a result of this research, it is expected that by minimizing secondary waste after the process, waste treatment cost could be reduced and the environmental aspect could be contributed, and a virtuous cycle structure could be established through reuse of the separated carbon dioxide solvent. In addition, adding its own extraction capacity of ethanol used for liquefaction of solid-phase ligands is expected to maximize decontamination efficiency in the process of increasing the size of the process in the future.

In the case of decommissioning of a nuclear power plant, it is expected that a significant amount of VLLW and LLW that need to be disposed of are also expected. Conventional reduction technology is a method of extracting or removing radionuclides from waste, but this project is being carried out for the purpose of obtaining a reduction effect through the development of a material that treats another radioactive waste using radioactive waste. In this paper, the technology of impregnating LiOH capable of adsorbing radiocarbon to the gas filter material manufactured from concrete and soil waste as raw materials and the radiocarbon removal performance were reviewed. In this study, a raw material of ceramic filter was prepared by mixing concrete and soil waste with a powder of 40 m or less, and after sintering at 1,250°C, 5wt% to 40wt% of LiOH is impregnated with a filter capable of adsorbing carbon dioxide. was prepared. The prepared filter used ICP-OES and XRD to confirm the LiOH deposition result, and the concentration of carbon dioxide discharged through the carbon dioxide adsorption device was confirmed. It was possible to obtain the result that the amount of adsorption was changed depending on the flow rate of carbon dioxide supplied and the amount of material. Through this, it was possible to confirm the possibility of power generation in the adsorption performance of gas. In this study, after crushing waste concrete and waste soil, powders of 40 m or less were mixed with other additives to prepare raw materials for ceramic filters, and sintered at 1,250°C to manufacture filters. 5wt% to 40wt% of LiOH was impregnated on the prepared filter to give functionality to enable carbon dioxide adsorption. The results of LiOH deposition were confirmed using ICP-OES and XRD, and the change in the concentration of carbon dioxide emitted through a separately prepared adsorption device was confirmed. It was possible to obtain the result that the amount of adsorption was changed according to the flow rate of carbon dioxide supplied and the amount of material, and the possibility of developing a material for radioactive waste treatment using radioactive waste was confirmed when the porosity and specific surface area of the filter material were increased.

본 연구는 환경측정용 센서 위치에 따른 온실 환경의 공간· 수직적 특성을 조사하고 온실 종류에 따른 온도, 광도 및 CO2 농도 간의 상관관계를 구명하고자 수행하였다. 벤로형 온실의 공간적인 5지점을 선정한 후 각 지점에서 대표적 작물의 수 직적 높이 4지점과 지면부, 지붕 공간에 온도, 상대습도, CO2, 엽온 및 광센서를 설치하였다. 벤로형 온실과 반밀폐형 온실 에서 온도, 광도 및 CO2 농도 변화의 관계성을 Curve Expert Professional 프로그램을 이용하여 비교하였다. 벤로형 온실 의 공간적 위치에 따른 편차는 CO2 농도가 다른 요인보다 큰 것으로 나타났다. CO2 농도는 평균 465－761μmol·mol-1 범 위였고, 편차가 가장 큰 시간대는 오후 5시였으며, 최고 농도 는 액화 탄산가스 공급장치의 메인 배관(50∅)과 가까운 위치 인 중앙 후부(Middle End, 4ME)에서 646μmol·mol-1, 최저 농도는 좌측 중앙(Left Middle, 5LM)에서 436μmol·mol-1이 었다. 수직적 위치에 따른 편차는 온도와 상대습도가 다른 요 인보다 큰 것으로 나타났다. 평균 기온의 편차가 가장 큰 시간 대는 오후 2시대이며, 최고 기온은 작물 위 공기층(Upper Air, UA)에서 26.51℃, 최저 기온은 작물의 하단부(Lower Canopy, LC)에서 25.62℃였다. 평균 상대습도의 편차가 가장 큰 시간 대는 오후 1시대로 나타났으며, 최고 습도는 LC에서 76.90%, 최저 습도는 UA에서 71.74%이다. 각 시간대에 평균 CO2 농 도가 가장 높은 수직적 위치는 지붕 공간 공기층(Roof Air, RF)과 시설 내 지면(Ground, GD)이었다. 온실 내 온도, 광도 및 CO2 농도의 관계성은 반밀폐형 온실의 경우 결정계수(r2) 가 0.07, 벤로형 온실은 0.66이었다. 결과를 종합하여 볼 때, 온실 내 CO2 농도는 공간적 분포, 온도와 습도는 작물의 수직 적 분포 차이를 측정하여 분석할 필요가 있고 환기율이 낮은 반밀폐형 온실의 경우 목표 CO2 시비 농도가 일반 온실과 다 르게 설정해야 할 것으로 판단된다.

As the number of nuclear power plants whose design life has expired worldwide increases, the attempts are continuing to complete the project of nuclear back-end cycle, the last task of the nuclear industry. Decontamination is essential in the process of dismantling nuclear facilities and restoration sites to remove all or some of the regulatory controls from an authorized facility. Among radioactive wastes, particularly contaminated soil is characterized by difficult physical decontamination because radionuclides are adsorbed between soil particles, that is, pores. Therefore, chemical decontamination is mainly used, which has the disadvantage of generating a lot of secondary waste. In order to overcome these disadvantages, an eco-friendly soil decontamination process is being developed that can drastically reduce the amount of secondary waste generated by using supercritical carbon dioxide. Supercritical carbon dioxide can easily control its physical properties and has both liquid and gas properties. However, since supercritical carbon dioxide is non-polar, additives are needed to extract polar metal ions, which are the goal of decontamination. Therefore, ligand with both CO2-philic and metal binding regions was selected. In previous studies, the decontamination efficiency of soil was evaluated by reacting contaminated soil with solid ligand and co-ligand at once. When solid ligands were used, the decontamination efficiency was lower than expected, which was expected because chemical substances were somewhat difficult to exchange in the closed process. In this study, in order to increase the efficiency of the decontamination process, the need for a process of liquefying ligand and continuously flowing it has been raised. Therefore, a co-solvent that dissolves well at the same time in SCCO2, ligand, and co-ligand was selected. In the selection process, a total of eight substances were selected by dividing into six polar substances and two non-polar substances through various criteria such as economic feasibility, eco-friendliness, and harmlessness. Thereafter, ethanol was finally selected through solubility evaluation for SCCO2 and additives. It is expected that a more effective decontamination process can be constructed when the additive is liquefied using a solvent selected from the results of this study.

Today, the domestic and international nuclear power industry is experiencing an acceleration in the scale of the nuclear facility decommissioning market. This phenomenon is also due to policy changes in some countries, but the main reason is the rapid increase in the proportion of old nuclear power plants in the world, mainly in countries that introduced nuclear power plants in the early stages. Decontamination is essential in the process of decommissioning nuclear facilities. Among various decontamination targets, radionuclides are adsorbed between pores in the soil, making physical decontamination quite difficult. Therefore, various chemical decontamination technologies are used for contaminated soil decontamination, and the current decontamination technologies have a problem of generating a large amount of secondary wastes. In this study, soil decontamination technology using supercritical carbon dioxide is proposed and aimed to make it into a process. This technology applies cleaning technology using supercritical fluids to decontamination of radioactive waste, it has important technical characteristics that do not fundamentally generate secondary wastes during radioactive waste treatment. Supercritical carbon dioxide is harmless and is a very useful fluid with advantages such as high dissolution, high diffusion coefficient, and low surface tension. However, since carbon dioxide, a non-polar material, shows limitations in removing polar and ionic metal wastes, a chelating ligand was introduced as an additive. In this study, a ligand material that can be dissolved in supercritical carbon dioxide and has high binding ability with polar metal ions was selected. In addition, in order to increase the decontamination efficiency, an experiment was conducted by adding an auxiliary ligand material and ultrasonic waves as additives. In this study, the possibility of liquefaction of chelating ligands and auxiliary ligands was tested for process continuity and efficiency, and the decontamination efficiency was compared by applying it to the actual soil classified according to the particle size. The decontamination efficiency was derived by measuring the concentration of target nuclides in the soil before and after decontamination through ICP-MS. As a result of the experiment, it was confirmed that the liquefaction of the additive had a positive effect on the decontamination efficiency, and a difference in the decontamination efficiency was confirmed according to the actual particle size of the soil. Through this study, it is expected that economic value can be created in addition to the social value of the technology by ensuring the continuity of the decontamination process using supercritical carbon dioxide.