PURPOSES : Advancements in science and technology caused by industrialization have led to an increase in particulate matter emissions and, consequently, severity of air pollution. Nitrogen oxide (NOx), which accounts for 58% of road transport pollutants, adversely affects both human health and the environment. A test-bed was constructed to determine NOx removal efficiency at the roadside. TiO2, a material used to reduce particulate matter, was used to remove NOx. It was applied to a vertical concrete structure using the dynamic pressurized penetration TiO2 fixation method, which can be easily applied to vertical concrete structures. This study was conducted to evaluate the NOx removal efficiency of the dynamic pressurized-penetration TiO2 fixation method in a test-bed under real roadside conditions. METHODS : A test-bed was constructed in order to determine the NOx removal efficiency using the dynamic pressurized penetration TiO2 fixation method on the roadside. The dynamic pressurized-penetration TiO2 fixation method was applied by installing a vertical concrete structure. NOx was injected into the test-bed using an exhaust gas generator. By installing a shading screen, the photocatalytic reaction of TiO2 was suppressed to a maximum concentration of 1000 ppb along the roadside. The removal efficiency was evaluated by measuring NOx concentrations. In addition, illuminance was measured using an illuminance meter. RESULTS : From the results of the analysis of the NOx removal efficiency in the test-bed which the dynamic pressurized type TiO2 fixation method was applied to, an average removal efficiency ranging from 18% to 40% was achieved, depending on the illuminance. Similarly, according to the results of the evaluation of the NO removal efficiency, an average of removal efficiency ranging from 20% to 62% was achieved. Thus, the NOx removal efficiency increased when the illuminance was high. CONCLUSIONS : From the results of the experiment conducted, the efficiency of NOx removal per unit volume was obtained according to the illuminance of TiO2 concrete along an actual road. Field applicability of the dynamic pressurized-penetration-type TiO2 fixation method to vertical concrete structures along roads was confirmed.

This study evaluates the ammonia (NH3) reduction effect of Bio-curtains (hereinafter referred to as curtains) utilized for odor control in pig farms based on the distance outside the curtain and the spraying condition. The curtain (total area: 37.9m3) was constructed with two layers of light-shielding screens stretched over a rectangular parallelepiped structure installed around a ventilation fan (630 mm) on the side wall of a pig barn where 48 finishing pigs were reared. The real-time NH3 concentration was measured by using a photoacoustic spectrometer. In the first part of this study, the NH3 measurement position for each side of the curtain was selected based on the lowest standard deviation among 4 to 8 initial sampling points on the surface of the curtain and utilized for both experiments of distance and spraying. In the experiment concerning the distance outside the curtain, ammonia concentration decreased by 17.45% at 2m compared to the distance at 5 cm and by 6.94% at 4m compared to 2m on average. In contrast, the NH3 reduction rate for each distance compared to the ventilation fan was the lowest at the 100% operating rate in which the exhausted NH3 concentration from the ventilation fan was low. At this time, the spraying mist on the inside of the curtain increased the NH3 reduction rate by 4.98 to 10.36% compared to the non-spraying condition. Consequently, the NH3 be reduced as distance outside the curtain increases due to the diffusion effect caused by the surrounding wind and the spraying mist on the inside curtain on the dissolution of NH3.

Environmental DNA (eDNA) can exist in both intracellular and extracellular forms in natural ecosystems. When targeting harmful cyanobacteria, extracellular eDNA indicates the presence of traces of cyanobacteria, while intracellular eDNA indicates the potential for cyanobacteria to occur. However, identifying the “actual” potential for harmful cyanobacteria to occur is difficult using the existing sediment eDNA analysis method, which uses silica beads and cannot distinguish between these two forms of eDNA. This study analyzes the applicability of a density gradient centrifugation method (Ludox method) that can selectively analyze intracellular eDNA in sediment to overcome the limitations of conventional sediment eDNA analysis. PCR was used to amplify the extracted eDNA based on the two different methods, and the relative amount of gene amplification was compared using electrophoresis and Image J application. While the conventional bead beating method uses sediment as it is to extract eDNA, it is unknown whether the mic gene amplified from eDNA exists in the cyanobacterial cell or only outside of the cell. However, since the Ludox method concentrates the intracellular eDNA of the sediment through filtration and density gradient, only the mic gene present in the cyanobacteria cells could be amplified. Furthermore, the bead beating method can analyze up to 1 g of sediment at a time, whereas the Ludox method can analyze 5 g to 30 g at a time. This gram of sediments makes it possible to search for even a small amount of mic gene that cannot be searched by conventional bead beating method. In this study, the Ludox method secured sufficient intracellular gene concentration and clearly distinguished intracellular and extracellular eDNA, enabling more accurate and detailed potential analysis. By using the Ludox method for environmental RNA expression and next-generation sequencing (NGS) of harmful cyanobacteria in the sediment, it will be possible to analyze the potential more realistically.

Steel brace strengthening is the most popular seismic rehabilitation method for school buildings. This is because the design can be conducted by using relatively easy nonlinear pushover analysis and standard modeling in codes. An issue with steel brace strengthening is that the reinforced building should behave elastically to satisfy performance objectives. For this, the size of steel braces should be highly increased, which results in excessive strengthening cost by force concentration on existing members and foundations due to the considerable stiffness and strength of the steel braces. The main reason may be the brittle failure mode of columns, so this study investigated the relationship between the efficiency of steel brace strengthening and column failure modes. The result showed that the efficiency is highly dependent on the shear capacity ratio of columns and structural analysis methods. School buildings reinforced by steel braces do not need to behave elastically when the shear capacity ratio is low, and pushover analysis is used, which means reducing steel material is possible.

The research on dye-sensitized solar cells (DSSCs) is in the advanced stage today. The only concern observed so far has been regarding its stability and efficiency. Its power conversion efficiency can be increased by incorporating various methods and materials based on nanotechnology. Several attempts have been employed to develop advanced methods for eco-friendly, commercially viable, and sustainable DSSCs to minimize the energy crisis in the future. Photoanode is one of the essential components of DSSCs that can be modified using different nanostructures to enhance its efficiency. The TiO2 nanoparticlebased photoanode with gold and silver has proven to be potent materials for getting efficient DSSCs. The plasmonic and quantum confinement effects also play a vital role in efficiency enhancement. In this review, we discuss numerous attempts made by researchers in the last decade to modify the photoanode and their progress. We also look at different types of nanostructures, such as quantum dots, metal oxide doping, layered structures, nanocomposites, and thin film formation, that improve the efficiency of DSSCs. Several methods were reviewed to modify photoanodes to optimize electron transportation, light scattering, trapping power, surface area, and reduce charge recombination. The trend in the efficiency enhancement of DSSCs using TiO2, Au, ZnO, Ag, and graphene nanostructures-based photoanodes have been explored in great detail.

현재의 해양산업의 기술은 스마트 선박 및 자율운항선박 등의 개발과 같은 자율화 및 지능화와 환경규제의 강화에 맞추어 선 박의 운항 효율성을 개선하는 친환경 선박을 위한 기술이 함께 개발되고 있다. 이러한 흐름에 맞추어, 세계각국에서는 선박의 안전운항을 보장하는 선에서 선박운항효율을 극대화하기 위해 다양한 방식으로 노력하고 있다. 본 연구에서는, 현존하는 선박운항효율 개선 기술이 운항 당시의 기상환경, 선박조종 등의 선박운항상태를 실시간으로 반영하지 못하는 문제를 개선하기 위해, 선박에서 수집한 선박운항데 이터를 활용하여 실시간 선박운항효율 분석모델을 개발하고자 한다. 본 연구의 실시간 선박운항효율 분석모델은 연료소모를 기준으로 판 단한 선박운항효율과 당시의 선박운항상태를 감안하여 판단한 선박운항효율을 비교하여, 식별된 선박운항효율의 타당성을 확인할 수 있 는 모델이다. 분석의 주요 내용은 대상선박의 선정과 선박운항데이터의 수집, 선박운항효율 특성과 선박운항상태 특성의 구분, 그리고 이 를 활용한 분류모델의 개발을 포함한다. 연구의 결과는 기존의 선박운항효율과 항해 당시 선박운항상태를 감안한 운항효율을 제시하여 선박 운항자의 의사결정을 지원하여 운항효율을 개선하고자 한다.

본 연구의 목적은 스마트시티 구축의 핵심인 수소연료전지의 활용형태를 분석하고 해결방안을 제시하는 것이다. 수소연료전지를 활용하는 발전소의 경우 간헐성 문제가 없다는 장점 때문에 향후 가장 유망한 사용 형태로 분석됐다. 다만 많은 장점에도 불구하고 폭발 우려와 특정 수소 생산방식의 경우 이산화탄소 발생 문제 등으로 지역주민들의 반발이 지속적 으로 나타나고 있어 이를 해결하는 것이 스마트시티 구축의 주요 관건이 될 것으로 분석된다. 마지막으로 현재의 수소 생산 방식을 분석하고 이에 따른 문제점을 파악하여 스마트시티의 완전한 구축을 위한 해결책을 제시하였다.

As awareness about the danger of radon in indoor air has increased, various studies have been conducted to reduce the source of radon. This study was performed to investigate the effect of radon mitigation technology in a railway tunnel. Radon barrier paint and radon shield membrane developed to reduce the concentration of radon in soil and construction material were applied in the tunnel. The tunnel was divided into three sections, A, B, and C, and radon barrier paint, a buffer section, and radon shield membrane were applied, respectively. After securing a sealing screen to the floor and division of each section, radon concentrations were measured and compared before and after each product was applied, and statistical significance was confirmed through the Wilcoxon signed rank test. Measurement was performed with the In-Situ Method and Closed Chamber Method. Radon concentration measured by the in-situ method changed in A section to 124.1 Bq/m2/day from 614.1 Bq/m2/day (79.8%, z=-2.521, p<0.05), in B section to 416.2 Bq/m2/day from 467.1 Bq/m2/day (10.9%, z=-0.980, p=0.327), and in C section to 47.3 Bq/m2/day from 645.6 Bq/m2/day (92.7%, z=-2.521, p<0.05). Radon concentration measured by the closed chamber method recorded a decrease in A section to 88.8 Bq/m3 from 364.2 Bq/m3 (75.6%, z=-2.201, p<0.05), in B section to 471.8 Bq/m3 from 583.3 Bq/m3 (19.1%, z=-0.700, p=0.484), and in C section to 115.9 Bq/m3 from 718.8 Bq/m3 (83.9%, z=-2.521, p<0.05). In addition to soil, it is very important to mitigate radon from building materials with a high contribution rate of radon in order to manage radon by source. Due to the spatial characteristics of railway tunnels, soil and wall concrete structures are exposed as they are, so it is considered that radon mitigation actions are required utilizing verified methods with high mitigation efficiency.

The object of this study is to feasibility assesment for co-digestion efficiency of food waste recycling wastewater(FWR) with thermal hydrolysis process dehydration cake (THP Sludge). As a result of THP pre-treatment experimental conditions to 160oC and 30 minutes, the solubility rate(conversion rate of TCOD to SCOD) of the THP sludge increased by 34%. And the bio-methane potential in the THP sludge increased by about 1.42 times from 0.230 to 0.328 m3 CH4/kg VS compared to the non-pre-treatment. The substrates of the co-digestion reactor were FWR and THP sludge at a 1:1 ratio. Whereas, only FWR was used as a substrate in the digestion reactor as a control group. The experimental conditions are 28.5 days of hydraulic retention time(HRT) and 3.5 kg VS/m3-day of organic loading rate(OLR). During the 120 days operation period, the co-digestion reactor was able to operate stably in terms of water quality and methane production, but the FWR digestion reactor deteriorated after 90 days, and methane production decreased to 0.233 m3 CH4/kg VS, which is 67% of normal condition. After 120 days of the experiment, organic loading rate(OLR) of co-digestion reactor was gradually increased to 4.5 kg VS/m3-day and operated for 80 days. Methane production during 80 days was evaluated to be good at the level of 0.349 m3 CH4/kg VS. As a result of evaluating the dehydration efficiency of the sludge before/after 150-180oC THP using a filter press, it was confirmed that the moisture content of the sludge treated before THP at 180oC was 75% and improved by 8% from 83-85% level. Therefore, it is expected that the co-digestion reactor of FWR and THP sludge will ensure stable treatment water quality and increase bio-methane production and reduction effect of dehydration sludge volume.

본 연구는 전기투석과 용매추출을 융합한 희유금속 회수 공정에서 분리막과 음이온교환막의 개질을 통해 유기상 과 수상에 대한 분리막의 낮은 젖음성 및 AEM을 통한 수소이온 투과로 인한 금속이온의 회수 효율 감소를 개선하였다. 구체 적으로, 분리막 표면 중 한면은 polydopamine (PDA) 통한 친수성 개질, 다른 면은 SiO2 또는 graphene oxide를 통한 친유성 개질을 함으로써 분리막의 젖음성을 개선하였다. 또한, 음이온교환막의 표면을 polyethyleneimine, PDA, poly(vinylidene fluoride) 등을 이용, 개질해 수분 흡수(Water uptake) 감소 및 기공구조 변화를 통해 수소이온 수송을 억제해 수소이온 투과를 억 제할 수 있다. 개질된 막 표면 형상과 화학적 특성 및 조성은 주사전자현미경과 푸리에변환 적외선 분광법을 통해 확인되었 고, 이를 구리 이온 회수 시스템에 적용해 향상된 추출 및 탈거 효율과 수소이온 수송 억제능을 확인하였다.

The global power generation industry is becoming a key power generation industry with gas power generation and renewable energy solar power generation. This research aims to focus on solving two problems as a method to improve the solar light collection efficiency among fixed variable deformation methods. Maintaining the proper temperature of the water injection device through automatic temperature detection to solve efficiency degradation, and establishing an automatic operation system by finding the optimal angle for each season, are intended to derive a value that can represent the optimal power generation.

Organic scintillator is easy to manufacture a large size and the fluorescence decay time is short. However, it is not suitable for gamma measurement because it is composed of a low atomic number material. Organic scintillation detectors are widely used to check the presence or absence of radiation. The fluorescence of organic scintillators is produced by transitions between the energy levels of single molecules. In this study, an organic scintillator development study was conducted for use in gamma measurement, alternative materials for secondary solute used in basic organic scintillators were investigated, and the availability of alternative materials, detection characteristics, and neutron/gamma identification tests were performed. In other words, a secondary solute showing an improved energy transfer rate than the existing material was reported, and the performance was evaluated. 7-Diethylamino -4-methylcoumarin (DMC), selected as an alternative material, is a benzopyrone derivative in the form of colorless crystals, has high fluorescence and high quantum yield in the visible region, and has excellent light stability. In addition, it has a large Stokes shift characteristic, and solubility in solvent is good. Through this study, it was analyzed that the absorption wavelength range of DMC coincided with the emission wavelength range of PPO, which is the primary solute. Through this study, it was confirmed that the optimal concentration of DMC was 0.04wt%. As a result of performing gamma and neutron measurement tests using a DMC-based liquid scintillator, it showed good performance (FOM=1.42) compared to a commercial liquid scintillator. Therefore, the possibility of use as a secondary solute was demonstrated. Based on this, if studies on changes in the composition of secondary solute or the use of nanoparticles are conducted, it will be possible to manufacture and utilize a scintillator with improved efficiency compared to the existing scintillator.