AR (alkali resistant)-glass fibers were developed to provide better alkali resistance, but there is currently no research on AR-glass fiber manufacturing. In this study, we fabricated glass fiber from AR-glass using a continuous spinning process with 40 wt% refused coal ore. To confirm the melting properties of the marble glass, raw material was put into a (platinum) Pt crucible and melted at temperatures up to 1,650 °C for 2 h and then annealed. To confirm the transparent clear marble glass, visible transmittance was measured and the fiber spinning condition was investigated by high temperature viscosity measurement. A change in diameter was observed according to winding speed in the range of 100 to 700 rpm. We also checked the change in diameter as a function of fiberizing temperature in the range of 1,240 to 1,340 °C. As winding speed increased at constant temperature, fiber diameter tended to decrease. However, at fiberizing temperature at constant winding speed, fiber diameter tended to increase. The properties of the prepared spinning fibers were confirmed by optical microscope, tensile strength, modulus and alkali-resistance tests.
이 연구는 코르크보드를 보강하여 건축부재 및 놀이기구의 안전부재 등으로 폭넓게 활용할 것을 목적으로 코르크보드의 중층에 금속, 유리섬유, 탄소섬유를 삽입하여 보강한 3종의 코르크복합보드를 제조하였고, 코르크복합보드의 수분흡수에 따른 치수안정성 및 접착층 박리성능을 조사하였다. 코르크복합보드의 흡수율은 0.37% - 0.45%의 범위에 있었고, 코르크보드에 비해 0.61배 - 0.74배의 낮은 값을 나타내었다. 코르크복합보드의 두께팽창률은 0.92% - 1.58%의 범위에 있었고, 코르크보드 보다 1.4 - 2.4배의 높은 값을 나타내었다. 그러나 이 값들은 일반 목질보드보다 현저히 낮았고, KS규격의 12%이하를 하회하는 것이 확인되었다. 코르크복합보드의 준내수 및 내수침지박리시험후의 접착층박리율은 0%로 전혀 접착층의 박리가 일어나지 않아 우수한 내수성을 나타내었고, 흡수율과 흡수두께팽창률은 상온침지에 비해 다소 증가하였으나, 목질보드에 관한 KS규격을 하회하는 우수한 치수안정성을 나타내는 것이 확인되었다.
Glass fiber (GF) insulation is a non-combustible material, light, easy to transport/store, and has excellent thermal insulation performance, so it has been widely used in the piping of nuclear power plants. However, if the GF insulation is exposed to a high-temperature environment for a long period of time, there is a possibility that it may be crushed even with a small impact due to deterioration phenomenon and take the form of small particles. In fact, GF dust was generated in some of the insulation waste generated during the maintenance process. In the previous study, the disposal safety assessment of GF waste was performed under the abnormal condition of the disposal facility to calculate the radiation exposure dose of the public residing/ residents nearby facilities, and then the disposal safety of GF waste was verified by confirming that the exposure dose was less than the limit. However, the revised guidelines for safety assessment require the addition of exposure dose assessment of workers. Therefore, in this study, accident scenarios at disposal facilities were derived and the exposure dose to the workers during the accident was evaluated. The evaluation was carried out in the following order: (1) selection of accident scenario, (2) calculation of exposure dose, (3) comparison of evaluation results with dose limits, and confirmation of satisfaction. The representative accident scenarios with the highest risk among the facility accident were selected as; (a) the fire in the treatment facility, (b) the fire in the storage facility, and (c) fire after a collision of transport vehicles. The internal and external exposure doses of the worker by radioactive plume were calculated at 10m away from the accident point. In evaluation, the dose conversion factors ICRP-72 and FGR12 were used. As a result of the calculation, the exposure dose to workers was derived as about 0.08 mSv, 0.20 mSv, and 0.10 mSv, due to fire accidents (vehicle collision, storage facilities, treatment facilities). These were 0.2%, 0.4%, and 0.2% of the limit, and the radiation risk to workers was evaluated to be very low. The results of this study will be used as basic data to prove the safety of the disposal of GF waste. The sensitivity analysis will be performed by changing the radiation source and emission rate in the future.
Currently, Hanul NPP packages glass fiber classified as particulate waste in plastic packaging bags and stores them in 200 L drums. KORAD’s Waste Acceptance Criteria (WAC) presents that very low-level soil can be immobilized by loading it in a soft bag and then packaging it in a 200 L or 320 L steel drum. As currently accepted method of packaging with soft bag applies to only very low-level soils among the wastes with a risk of dispersion, it is necessary to develop a non-dispersible treatment suitable for the characteristics of other particulate waste in the future. Therefore, in order for Hanul packaging pack to be approved as an alternative method for immobilization of dispersible substances, it is necessary to verify the suitability of the packaging bag. In this paper, whether the glass fiber packaging bag used in Hanul NPP satisfies the characteristic of the soft bag presented in the WAC and the possibility of being considered as a non-dispersible measure for particulate are examined. The soft bag must meet the following requirements: material and structure, shape, drop test, and immersion test. The results of the review are as follows. First, since the glass fiber is already packaged in the drum, only the role of the inner layer, made of polyethylene, having a watertight function may be required. Second, when packaging a drum, the packaging bag is compressed into a shaped frame having an inner size of a 200 L drum, so it is packaged with little empty space in the drum. Third, as a result of a drop test of a packaging pack containing 20 kg of contents from a height of 1.2 m, it was confirmed that there was no leakage of contents. Fourth, the packaging bag was immersed in a 1-m depth water tank for 30-minutes, and the performance corresponding to the IPX7 was satisfied. As a result of reviewing the soft bag characteristic of Hanul glass fiber packaging bag, it is considered that the bag can be used as one of the non-dispersible measures because it meets almost the characteristics required by the WAC. In addition, the acceptance criteria of overseas disposal sites present various secure packaging methods in place of immobilization as a non-dispersible measure for waste containing particulate matter. It is necessary to reflect these overseas cases in the establishment of non-dispersible measures for domestic waste acceptance in the future.
Glass wool, the primary material of insulation, is composed of glass fibers and is used to insulate the temperature of steam generators and pipes in nuclear power plants. Glass fiber is widely adopted as a substitute for asbestos classified as a carcinogen. The insulations used in nuclear power plants are classified as radioactive waste and most of the insulation is Very Low-Level Waste (VLLW). It is packaged in a 200 L drum the same as a Dry Active Waste (DAW). In the case of the insulations, it is packaged in a vinyl bag and then charged into the drum for securing additional safety because of the fine particle size of the fiberglass. A safety assessment of the disposal facility should be considered to dispose of radioactive waste. As a result of analyzing overseas Waste Acceptance Criteria (WAC), there is no case that has a separate limitation for glass fiber. Also, in order to confirm that glass fibers can be treated in the same manner as DAW, research related to the diffusion of glass fibers into the environment was conducted in this paper. It was confirmed that the glass fiber was precipitated due to the low flow velocity of groundwater in the Gyeongju radioactive waste repository and did not spread to the surrounding environment due to the effect of the engineering barrier. Therefore, the glass fiber has no special issue and can be treated in the same way as a DAW. In addition, it can be disposed of in the disposal facility by securing sufficient radiological safety as VLLW.
Colloid migration is an important topic in post-closure safety assessment of radioactive waste repository as radionuclide can be adsorbed onto colloidal particles and migrated along with the colloids. This would reduce retardation of radionuclide migration, thus increasing the released concentration into biosphere. Recently, glass fiber waste has been found to contain small sized crushed glass fiber particles (GFPs), and concerns regarding the colloidal impact of GFP is being discussed. In this study, relevance of assessing GFPs facilitated radionuclide transport in the disposal environment of 1st phase disposal facility. Colloidal impact assessment can be divided into two sections, colloid mobility, and colloid sorption assessments. Considering GFP being denser than water, fluid velocity of 1st phase disposal facility is too slow to initiate movement of such dense particles. GFPs would remain settled, and no colloidal impact is expected. In this study, sorption assessment mainly focused to analyze the possible impact if migration of GFP does occur. The GFP is mainly composed of SiO2 and few other metal oxides. Due to high composition of SiO2 in the GFPs, negative surface charge is induced onto the surface of the GFPs in alkaline environment. This negatively charged surface can attract free positive ions (ex. Ni, Co, Fe, etc.) in the repository, and these ions would be adsorbed onto the surface of the GFPs via coulomb force. Thus, if GFPs migrate, colloid facilitated radionuclide transport can be expected. However, before being released into the biosphere, particles must pass through the engineered and natural barriers, where ion-colloid-rock interactions could result in transfer of radionuclide from one media to another. At Naka Research Center, Japan, ion-colloid-rock interactions are experimented with bentonite colloid, and the result showed that despite colloid’s sorption ability was 10 times higher than the barrier material, the overall released radionuclide concentration has negligible change. To reflect such phenomenon, coulomb attractive force of GFPs and concrete is calculated and compared, which the result showed that glass fiber was 10 times weaker than concrete. Considering the Japan’s experimental result, glass fiber facilitated transport would not enhance the radionuclide release into the biosphere. Nonetheless, assuming GFPs being mobile in 1st phase disposal facility, GFPs’ sorption ability is found to be negligible compared to the concrete of the repository, thus radionuclide transport is not expected to be enhanced. In future, this study could be used as basis for further colloidal impact analysis for the safety assessment of the repository.
In a recent preliminary inspection for disposal, the glass fiber waste (GFW), used as a pipe insulation, was judged as “pending evaluation” because some dust was found in drum opening tests. Therefore, additional inspection is required to ensure that the package corresponds with the acceptance criteria of the particulates. The dust was generated presumably due to GFW being used in a high-temperature environment for a long time, thus being easily degraded and crushed. For this reason, safety issues that may occur in the process of handling, transportation, and disposal are emerging. Therefore, in this study, a preliminary safety assessment of GFW disposal was performed, the exposure dose to the general public was derived, and compared with the dose limit. The evaluation was carried out in the following order: (1) evaluation of GFW radiation source term, (2) selection of accident scenario, (3) calculation of exposure dose, (4) comparison of evaluation results with dose limits, and confirmation of satisfaction. The average radioactivity of the GFW to be disposed of was used as the source term, and the main nuclides were identified as H-3, Fe-55, Co-60, Ni-63, and Pu-241. In general, the types of accidents that can occur at disposal facilities can be classified into falls, fires, collisions during transportation, off-site accidents, and nuclear criticality, and the accident scenarios are selected by analyzing and reviewing the probability of each accident. In this study, the accident analysis and scenarios presented in the safety assessment of the KORAD were reviewed, and the fire in the treatment facility, the fire in the storage facility, and the collision of the transport vehicle were selected as the evaluation scenarios. When an accident occurs, the radioactive material inside the container leaks out and diffuses into the atmosphere. In this evaluation, the internal and external exposure of the general public due to radioactive plume at the site boundary was evaluated and the dose conversion factors from ICRP-72 and FGR 12 were used. Based on the evaluation, general public was exposed to 0.004 mSv, 0.013 mSv, and 0.045 mSv, respectively, due to a fire at a treatment facility, at a storage facility, and in a transport vehicle. Most of the dose is due to internal exposure by Pu-241 nuclide, because the proportion of it in the waste is high, and when inhaled, the internal dose is high by emitting beta rays. It was confirmed that the result of dose was 0.4%, 1.3% and 4.5% of the annual dose limit, sufficiently satisfying the dose limit and safety.
Glass fiber, which was used as an insulation material in pipes near the steam generator system of nuclear power plants, is brittle and the size of crushed particles is small, so glass fiber radioactive waste (GFRW) can cause exposure of workers through skin and breathing during transport and handling accidents. In this study, Q-system which developed IAEA (International Atomic Energy Agency) for setting the limit of radioactivity in the package is used to confirm the risk of exposure due to an accident when transporting and handling GFRW. Also, the evaluated exposure dose was compared with the domestic legal effective dose limit to confirm safety. Q-system is an evaluation method that can derive doses according to exposure pathway (EP) and radioactivity. Exposure doses are calculated by dividing into five EP: QA, QB, QC, QD, and QE. Since the Q-system is used to set the limit of radioactivity that the dose limits is satisfied to nearby workers even in package handling accidents, the following conservative assumptions were applied to each EP. QA, QB are external EP of assuming complete loss of package shielding by accident and radiation are received for 30 minutes at 1 m, QC is an internal EP that considers the fraction of nuclides released into the air and breathing rate during accident, and QD is an external EP that skin contamination for 5 hours. Finally, QE is an internal and external EP by inert gases (He, Ne, Ar, Kr, Xe, Rn) among the released gaseous nuclides, but the QE pathway was excluded from the evaluation because the corresponding nuclide was not present in the GFRW products used for evaluation. In this study, the safety evaluation of GFRW was performed package shielding loss and radioactive material leakage due to single package accident according to assumption of four pathways, and the nuclide information used the average radioactivity for each nuclide of GFRW. As a result of the dose evaluation, QA was evaluated as 2.73×10−5 mSv, QB as 1.06×10−6 mSv, QC as 7.53×10−3 mSv, and QD as 2.10×10−6 mSv, respectively, and the total exposure dose was only 7.56×10−3 mSv, it was confirmed that when compared to the legal limits of the general public (1 mSv) and workers (20 mSv) 0.756% and 0.038%, respectively. In this study, it was confirmed that the legal limitations of the general public and workers were satisfied evens in the event of an accident as a result of evaluating the exposure dose of nearby targets for package shielding loss and radioactive material leakage while transporting GFRW. In the future, the types of accidents will be subdivided into falling, fire, and transportation, and detailed evaluation will be conducted by applying the resulting accident assumptions to the EP.
In recent, fiber-reinforced composites have been widely used in many fields because of their excellent performance. In order to manufacture lightweight, high-performance, and inexpensive composites various laminated structures were designed. Six types of hybrid composites were fabricated with glass/basalt/aramid fibers by VARTM process. The effect of the laminated structure on the mechanical properties of composites was investigated through impact energy, tensile and bending strength. Compared to other conditions more higher impact energy was obtained when the aramid fibers were in the center position and more higher bending strength was obtained when the fibers are laminated in the order of increasing bending performance from top to bottom. The laminate structure did not affect tensile strength which mainly depends on the property of fibers.
유리섬유강화 모르타르 관을 구성하는 보강섬유는 직교이방성 부재로 간주되며 재료의 성질은 서로 직각을 이루는 두 개의 축을 기준으로 정의된다. 유리섬유 모르타르 관의 구조적 거동 해석을 수행하기 위해서 길이방향과 원주방향의 재료의 역학적 성질, 즉 탄성계수, 전단탄성계수, 포아송비 등이 필요하며 각각의 성질들은 실험을 통해 결정하였다. 이 실험으로부터 구한 각각의 역학적 성질을 적용하여 간소화된 유한요소해석방법을 제안하기 위해 적층판 이론으로부터 유리섬유강화 모르타르 관의 탄성계수를 계산하고, 계산된 탄성계수를 적용하여 유한요소 해석을 수행하였다. 또한, 유한요소해석과 편평시험을 통해 구한 하중-변위 관계를 비교하였으며 ASTM D2412에서 제시하고 하고 있는 관의 강성 값을 유한요소해석과 실험을 통해 예측하여 비교하였다.
GRP관은 연성관으로 분류되며, 지중에서 지반과 함께 외부하중에 저항하는 상호거동을 한다. 또한 국내 설계기준에서는 GRP관의 설계에 대한 명확한 규정을 제시하지 못하고 있으나, AWWA M 45 및 ASTM D 2412에서는 지중매설 GRP관의 관변형에 대한 주요설계변수를 관강성, 지반반력계수, 기초각 등으로 규정하고 있다. 이 연구에서는 지중매설된 연성관의 구조적 거동을 파악하기 위하여 기존 연구에서 수행한 연구결과와 AWWA M 45에서 제시하고 있는 설계식을 이용하여, 관강성, 지 반반력계수, 기초각계수를 변수로 지반-관 상호작용 특성을 검토하였다. 검토결과 지중매설 GRP관의 구조적 거동에 가장 큰 영향을 미치는 설계변수는 지반반력계수이고, 기초각은 180°로 시공하여야 하며, 특히 대구경관에서는 지반의 영향이 더욱 중요한 것으로 나타났다. 따라서 GRP의 안전성을 확보하기 위해서는 시공과정에서 되메움토에 대한 다짐도, 상대밀도, 흙의 종류에 대한 세부적인 규정과 관리가 필요하며, 특히, 헌치부에 대한 시공관리가 이루어져야 할 것으로 판단된다.
전 세계적으로 건설폐기물에 의한 환경문제에 대한 관심이 증가하고 있다. 이에 따라 건설재료들에 대한 재활용방안 에 대한 연구가 많이 진행되고 있다. GFRP는 최근 구조물의 보강에 많이 사용되는 건설 재료이다. 본 연구에는 GFRP를 분쇄하 여 만든 재활용 GFRP파우더(RGP)의 잔골재 대체 가능성을 검토하고자 하였다. RGP는 GFRP의 제작 시 발생되는 GFRP 잉여물을 분쇄하여 사용하였다. RGP의 잔골재 치환율을 20%, 40% 60% 80%로 설정하였다. RGP가 혼합된 시멘트 모르타르의 재료 성능을 검토하기 위하여 압축강도, 쪼갬인장강도 및 휨 강도를 측정하였다. 실험결과, RGP의 혼입으로 시멘트 모르타르의 기초물성이 증가하는 경향이 나타났다. 본 연구결과는 장기적으로 GFRP의 건설재료로의 재활용을 위한 기초자료로 활용이 가능할 것으로 판단된다.
Cured-in-place-pipe(CIPP) is the most adopted trenchless application for sewer rehabilitation to extend the life of the existing sewer without compromising both direct construction and indirect social costs especially applied in the congested urban area. This technology is globally and domestically known to be the most suitable for partial and full deteriorated pipe structure rehabilitation in a sewer system. The typical design of CIPP requires a significant thickness of lining to support loading causing sewage flow interruption and increasing material cost. This paper presents development of a high strength glass fiber composite lining material for the CIPP application and structural test results. The test results exhibit that the new glass fiber composite lining material has 12 times of flexural strength, 6.2 times of flexural modulus, and 0.5 Creep Retention Factor. These test results can reduce lining design thickness 35% at minimum. Even though taking into consideration extra materials such as outer and inner films for actual field applications, the structural capacity of the composite material significantly increases and it reduces 20 percent or more line thickness as compared to the conventional CIPP. We expect that the newly developed CIPP lining material lowers material costs and minimizes flow capacity reduction, and fully replaceable to the conventional CIPP lining materials.
The fatigue characteristics of glass fiber reinforced plastic (GFRP) composites were studied under repeated loads using the finite element method (FEM). To realize the material characteristics of GFRP composites, Digimat, a mean-field homogenization tool, was employed. Additionally, the micro-structures and material models of GFRP composites were defined with it to predict the fatigue behavior of composites more realistically. Specifically, the fatigue characteristics of polybutylene terephthalate with short fiber fractions of 30wt% were investigated with respect to fiber orientation, stress ratio, and thickness. The injection analysis was conducted using Moldflow software to obtain the information on fiber orientations. It was mapped over FEM concerned with fatigue specimens. LS-DYNA, a typical finite element commercial software, was used in the coupled analysis of Digimat to calculate the stress amplitude of composites. FEMFAT software consisting of various numerical material models was used to predict the fatigue life. The results of coupled analysis of linear and nonlinear material models of Digimat were analyzed to identify the fatigue characteristics of GFRP composites using FEMFAT. Neuber’s rule was applied to the linear material model to analyze the fatigue behavior in LCF regimen. Additionally, to evaluate the morphological and mechanical structure of GFRP composites, the coupled and fatigue analysis were conducted in terms of thickness.