PURPOSES : This research was a laboratory study for evaluating the Reclaimed Asphalt Pavement (RAP) mixture added developed rejuvenator for warm mix recycling. Waste asphalt mixtures occupy about 18.2% of construction wastes in Korea. Moreover, most rejuvenators were imported from Europe or the U.S. Therefore, improving usage of RAP with a developed rejuvenator material provides environmental protection at a reduced cost. METHODS : The specimen used for this experiment was performed by only using RAP. A suitable rejuvenator for Target PG was then added. In addition, a conventional rejuvenator was selected to compare performance and specimens introduced with the same procedure as the developed rejuvenator was prepared. In order to evaluate rutting resistance and water susceptibility, we conducted a deformation strength test, a tensile strength ratio test, and a dynamic immersion test with the prepared mixtures. RESULTS: Laboratory test results indicated that both the developed additive and conventional additive improved performance of the recycled asphalt mixtures compared to mixtures without the rejuvenator. In addition, the deformation strength test and TSR test results satisfied standards for domestic recycling asphalt mixtures. The dynamic immersion test showed that the developed rejuvenator has superior scaling resistance than the conventional rejuvenator. CONCLUSIONS : In terms of rutting resistance and moisture susceptibility, the warm mix recycled asphalt mixtures with the developed rejuvenator appeared to effectively recovered performance.

The discontinuity movements of the Portland cement concrete (PCC) layer due to temperature fluctuations and traffic loading are primary causes of the reflection cracking in asphalt overlays. The thermal expansion and contraction of the discontinuities at the PCC layer induces tension at the bottom of the asphalt overlay layer creating excessive strains which causes cracking. The additional cyclic discontinuity movements from the thermal fluctuations and traffic loads propagates the cracks initiated until failure of the overlay layer. However, the crack behaviors of asphalt mixtures varies with temperature due to its viscoelastic property. As such, there is a need to investigate the cracking behavior of asphalt mixtures with varying temperatures and loading conditions. A modified overlay tester developed to evaluate the cracking resistance of asphalt mixtures in various loading directions and different confining temperatures was used to investigate the behavior of asphalt materials with various temperatures and loading conditions. The laboratory test was conducted in 2 segments. The first segment investigates the asphalt cracking behavior subjected to horizontal loading in 3 varying temperatures (10, 25 and 40C) which simulates the cyclic thermal contraction and expansion at the discontinuity. The second segment examines the cracking propagation of the asphalt mixture subjected to vertical loading in 3 varying temperatures. A load dissipation curve per loading cycle is generated in each test along with the images taken on the face of the specimen to monitor the crack propagation. Results have shown that asphalt mixtures undergo a 3-phase cracking behavior: initiation, propagation and failure. This is evident in the load dissipation curve when the initiation phase shows a rapid reduction of peak loads in first series of loading cycles which is followed by a slow and constant load reduction over a certain number of cycles. Failure occurs when there is a sudden decline in peak load and the percent reduction of the load is achieved. Figure 1 shows a fine dense grade asphalt mixture subjected to horizontal movement at 10C. Meanwhile, the load dissipation curve is further investigated by analyzing the images captured during testing. It can be seen that the first visible crack can be identified after 40 cycles which steadily propagates up to 600 cycles. However, between 600 and 700 loading cycles, there is a sudden dip in peak load which shows that at that the stage the crack has already propagated to the top of the test specimen as shown in Figure 2. Other tests have shown that the cracking patterns and load dissipation curves vary with different testing temperatures signifying that low temperature is more susceptible to early failure with constant differential movement. Further tests signify that using a general formula, parameters are calculated which refer to fracture properties of the material.

This study was conducted to investigate if the supplement formula may improve alcohol metabolism in healthy adult men.In a double-blinded, randomized, crossover study, subjects were administrated yeast extract mixtures (YEM, n=15), Hovenia dulcis mixtures (HDM, n=15), placebo (PLA, n=15), and control (CON, n=15) in an oral dose followed by one week washout periods. At each visit (0, 1, 2, 3, 4 week), subjects drank 450 mL, 20.1 percent alcohol after administered mixtures. Blood was drawn periodically (0, 0.25, 0.5, 1, 2, 4, 6, 15 hours). Fifteen subjects completed the protocol and were included in the analysis. Plasma ethanol concentration was lower in YEM (10 percent) and the HDM (5 percent) groups. The area under the curves (AUC) and Cmax for plasma ethanol were significantly decreased only in the YEM group, when compared with the CON group. The AUC and Cmax for plasma acetaldehyde concentration were significantly decreased in the YEM (45 and 54 percent) and the HDM (35 and 53 percent) groups respectively, when compared with PLA (p<0.01). Together, these findings validate that YEM or HDM improved alcohol metabolism and hangover syndromes, leading to reduce alcohol concentration and acetaldehyde concentration without adverse effects.

Densities of molten salt mixtures of eutectic LiCl-KCl with UCl3, CeCl3, or LaCl3 at various concentrations (up to 13 wt%) were measured using a liquid surface displacement probe. Linear relationships between the mixture density and the concentration of the added salt were observed. For LaCl3 and CeCl3, the measured densities were significantly higher than those previously reported from Archimedes’ method. In the case of LiCl-KCl-UCl3, the data fit the ideal mixture density model very well. For the other salts, the measured densities exceeded the ideal model prediction by about 2%.

This study was conducted to find out the effects of over seeding using new grass varieties orchardgrass ‘Kordione’ and ‘Onnuri’, and tall fescue ‘Greenmaster’ on botanical composition and dry matter productivity from 2013 to 2016 in low productivity hilly pasture, middle area of Korea. There were used 3 grass seed mixture types made of different compositions and amounts {T1: control - no over seeding, T2: tall fescue (TF) ‘Greenmaster’ 18 kg ha-1, orchardgrass (OG) ‘Kordione’ 9 kg ha-1, Perennial ryegrass (PRG) ‘Linn’ 5 kg ha-1, and Kentucky bluegrass (KBG) ‘Kenblue’ 2 kg ha-1, T3: TF ‘Greenmaster’ 9 kg ha-1, OG ‘Kordione’ 18 kg ha-1, PRG ‘Linn’ 5 kg ha-1, and KBG ‘ Kenblue’ 2 kg ha-1, T4: TF ‘Greenmaster’ 9 kg ha-1, OG ‘Onnuri’ 18 kg ha-1, PRG ‘Linn’ 5 kg ha-1, and KBG ‘Kenblue’ 2 kg ha-1}. In the botanical composition of grassland, T1 nearly remained constant in other seasons while ratio of weeds were increased in summer season. T2 was better than control (T1) in portion of grass ratio, which has increased by 80%. In the early time of establishment, the portions of OG were increased in T2, but TF rate was increased after 3 years later when grass was established. T3 and T4 showed a very similar patterns, grass ratio had increased by 80% and the portion of KBG had increased as time passed. T2 (129,763 kg ha-1) was showed the highest dry matter yield than other treatments (T1: 6,756 kg ha-1, T3: 9641, and T4: 10,738) in 2016.

PURPOSES:The objective of this study is to evaluate the performance of asphalt mixtures containing inorganic additive and a high content of reclaimed asphalt pavement (RAP).METHODS:The laboratory tests verified the superior laboratory performance of inorganic additive compared to cement, in cold recycled asphalt mixtures. To investigate the moisture susceptibility of the specimens, tensile strength ratio (TSR) tests were performed. In addition, dynamic modulus test was conducted to evaluate the performance of cold recycled asphalt mixture.RESULTS:It was determined that NaOH solution mixed with Na2SiO3 in the ratio 75:10 provides optimum performance. Compared to Type B and C counterparts, Type A mixtures consisting of an inorganic additive performed better in the Indirect tensile strength test, tensile strength ratio test, and dynamic modulus test.CONCLUSIONS:The use of inorganic additive enhances the indirect strength and dynamic modulus performance of the asphalt mixture. However, additional experiments are to be conducted to improve the reliability of the result with respect to the effect of inorganic additive.

PURPOSES:The objective of this study is to evaluate the effect of anti-stripping on asphalt mixtures constituting anti-stripping agents.METHODS:Based on the literature review, asphalt mixture added with anti-stripping agents was prepared, and these asphalt mixtures were evaluated for anti-stripping properties for each anti-stripping agent through various lab tests, namely, tensile strength ratio (TSR), dynamic immersion test, uniaxial compression test, and indirect tensile strength test (IDT). The liquid anti-stripping agents used in the lab test were premixed with each asphalt binder (PG 64-22, PG 76-22) before being mixed with the aggregate.RESULTS:The result of the TSR test revealed that the effect of anti-stripping was highest when hydrated lime and liquid anti-stripping agent W were added. The correlation coefficient R2 between the TSR result and cohesion ratio is 0.99, which indicates that the sensitivity of the TSR to moisture damage is reliable from the mechanical point of view. The covering ratio of the asphalt binder to the liquid anti-stripping agent W was determined to be higher than that to the other liquid anti-stripping agents.CONCLUSIONS:It is considered that the improved moisture resistance of asphalt mixture as a result of the use of anti-stripping agents can reduce the incidence of various pavement damages such as portholes caused by stripping, and the performance life of the asphalt road pavement can be prolonged.

PURPOSES:The objectives of this study are to evaluate moisture sensitivity of various asphalt mixtures and to suggest an alternate method for the dynamic immersion test, which is used to determine the application of anti-stripping agent, by analyzing bond strength.METHODS:The bond strength of various asphalt mixtures such as hot mix asphalt, warm mix asphalt, and polymer-modified asphalt was evaluated by the ABS test. In order to characterize moisture sensitivity at different temperatures of the mixtures, the ABS test was conducted at -10°C, 5°C, 20°C, 40°C, and 54°C under both dry and wet conditions. The concept of the bond strength ratio was applied for objective moisture sensitivity analysis. Moreover, the bond strength characteristic was compared to the dynamic immersion test to suggest an alternate method to determine the application of anti-stripping agent.RESULTS AND CONCLUSIONS :Overall, the polymer-modified asphalt demonstrates the highest bond strength characteristic regardless of moisture condition and temperature. The bond strength characteristic displays a highly reliable linear relationship from 5°C to 40°C, and the relationship could be used to predict bond strength at any intermediate temperature. Based on the analysis of bond strength and retained asphalt ratio, the bond strength value of 1254 kPa could be applied as a criterion for anti-stripping agent.

PURPOSES :The purpose of this study was to determine the optimum mix design of the content of 100 % reclaimed asphalt pavement (RAP) for spray injection application with different binder types.METHODS:Literature review revealed that spray injection method is the one of the efficient and economical methods for repairing a small defective area on an asphalt pavement. The Rapid-Setting Polymer modified asphalt mixtures using two types of rapid setting polymers-asphalt emulsion and a quick setting polymer asphalt emulsion-were subjected to the following tests to determine optimum mix designs and for performance comparison: 1) Marshall stability test, 2) Retained stability test, 3) Wet track abrasion test, and 4) Dynamic stability test.RESULTS AND CONCLUSIONS :Type A, B, and C emulsions were tested with different mix designs using RAP aggregates, to compare the performances and determine the optimum mix design. Performance of mixtures with Type A emulsion exceeded that of mixtures with Type B and C emulsion in all aspects. In particular, Type A binder demonstrated the highest performance for WTAT at low temperature. It demonstrated the practicality of using Type A mixture during the cold season. Furthers studies are to be performed to verify the optimum mix design for machine application. Differences in optimum mix designs for machine application and lab application will be corrected through field tests.

블루베리 재배시 토양 유기물 공급원으로 쓰이고 있는 피트모스가 전량 수입에 의존하고 있어 국내에서 생산되는 소나무잎, 왕겨, 톱밥 등 유기물을 블루베리 정식 전 피트모스와 혼합처리 한 후 토양 pH 변화와 생육 및 과실 특성에 미치는 영향을 구명하고자 본 시험을 수행하였다. 시험품종은 2년생 북부 하이부시 블루베리 ‘Duke’ 품종이었고 묘목 정식 전 피트모스를 근권에 20L 단용으로 처리하는 방법과 피트모스(10L)와 소나무잎, 왕겨, 톱밥을 각각 10L씩 혼합 처리하는 방법으로 실시하였다. 유기물의 화학성 분석 결과 pH는 피트모스가 4.3으로 가장 낮았고 소나무잎은 4.8, 왕겨는 7.3, 톱밥은 5.7이었다. 정식 직후 유기물을 투여한 토양의 pH는 5.3~5.9 로 나타났고 피트모스단용, 피트모스+소나무잎 처리가 왕겨, 톱밥 혼합처리에 비해 낮았다. 정식 후 3년차 토양 pH는 4.2~4.5로 피트모스단용, 피트모스+소나무잎 처리에서 낮게 유지되었다. 유기물 조성에 따른 생육 시기 별 토양수분 함량은 피트모스+소나무잎>피트모스단용> 피트모스+톱밥>피트모스+왕겨 순으로 높게 나타났다. 생육은 피트모스 단용과 피트모스+소나무잎 처리에서 양호하였고 꽃눈수가 많아 초기 수량이 많았다. 당도는 피트모스 단용 처리에서 11.3 oBrix로 높았고 경도는 피트 모스+소나무잎 처리에서 증가되었으나 과실 품질에 있어 처리별 유의차는 없었다.

The effects of the heat treatment temperature and of the atmosphere on the dehydrogenation and hydrogen reduction of ball-milled TiH2-WO3 powder mixtures are investigated for the synthesis of Ti-W powders with controlled microstructure. Homogeneously mixed powders with refined TiH2 particles are successfully prepared by ball milling for 24 h. X-ray diffraction (XRD) analyses show that the powder mixture heat-treated in Ar atmosphere is composed of Ti, Ti2O, and W phases, regardless of the heat treatment temperature. However, XRD results for the powder mixture, heat-treated at 600oC in a hydrogen atmosphere, show TiH2 and TiH peaks as well as reaction phase peaks of Ti oxides and W, while the powder mixture heat-treated at 900oC exhibits only XRD peaks attributed to Ti oxides and W. The formation behavior of the reaction phases that are dependent on the heat treatment temperature and on the atmosphere is explained by thermodynamic considerations for the dehydrogenation reaction of TiH2, the hydrogen reduction of WO3 and the partial oxidation of dehydrogenated Ti.

The objective of this study was to determine the growth characteristics of cool (C1) and warm season grasses (C2) in pastures mixed with C1 and C2 suitable for grazing horses and effect of pastures mixed with tall and short grasses on the intake characteristics of horses. C1 used in this study was Kentucky bluegrass, Redtop (short type grass) and tall type grasses were orchardgrass and tall fescue, respectively. The short type grass used as C2 was Bermudagrass. This study had the following four treatment groups: 1) Treatment 1 (Bermudagrass + Kentucky bluegrass + Redtop) 2) Treatment 2 (Bermudagrass + tall fescue + orchardgrass) 3) Treatment 3 (Kentucky bluegrass + Redtop) 4) Treatment 4 (tall fescue + orchardgrass). There was no winterkilling or lodging problem at an altitude of 200 m. Plant heights in mixed pasture of Treatment 1, 2, 3, and 4 were 53.9, 58.2, 57.5, and 78.1 cm, respectively. Plant height was the highest in Treatment 4. Dry matter yield was in the following order : Treatment 4 > Treatment 3 > Treatment 2 > Treatment 1. In the first investigation regarding vegetation distribution, Bermudagrass ratios among grasses in Treatment 1 and Treatment 2 were 70% and 66.7%, respectively. Overall, other grasses showed poor growth. In the second investigation of vegetation distribution, Bermudagrass ratios among grasses in Treatment 1 and Treatment 2 were 80% and 60.7%, respectively. Crude protein content, neutral detergent fiber content, acid detergent fiber content, digestibility value, and nutritive values were the lowest in Treatment 4, followed by those in Treatment 1, Treatment 2 and Treatment 3.

Detergency and surface active properties of mixed anionic surfactants with amphoteric and nonionic were investigated. Sodium dodecyl sulfate (SDS) and ammonium dodecyl sulfate (ADS) as anionic surfactants and cocamidopropyl betaine (CAPB) as an amphoteric surfactant were used. Nonionic surfactants, which are butyl glucoside (BG), octyl glucoside (OG), decyl glucoside (DG), lauryl dimethylamine oxide (AO) and saponin were also used. To study the synergy effects of mixed SDS/ADS anionic surfactant systems, amphoteric and nonionic surfactants were added into the mixed anionic surfactants. Investigated properties of surfactant mixtures were critical micelle concentration (CMC), surface tension (γ), wettability. In addition, based on these properties, detergency of each sample was examined. Surfactant mixtures are anionics (SDS/ADS), anionic/amphoteric/nonionic (SDS/ADS/CAPB/ saponin), and anionic/nonionic (SDS/ADS/BG/saponin, SDS/ADS/OG/saponin, SDS/ADS/ DG/saponin, and SDS/ADS/AO/saponin). With the addition of amphoteric and nonionic to mixed anionic surfactants, CMC and γ were decreased. Addition of CAPB, which is amphoteric, showed the best property at CMC and γ. Furthermore, as the chain length of hydrocarbon in alkyl glucosides was increased, the CMC and γ were enhanced. However, the wettability did not exactly match up with CMC and γ. The surfactant mixture, which contained DG, showed the best performance at wetting time. Detergency was measured at various temperatures (15 oC, 30 oC, 50 oC). The cleaning performance was enhanced by increasing washing temperature. Moreover, detergency was influenced by not only CMC and γ but also wettability. Although CMC and γ were not minimum at surfactant mixture that included DG, the best cleaning performance showed in that sample.

An optimum route to synthesize Ti-Mo system powders is investigated by analyzing the effect of the heat treatment atmosphere on the formation of the reaction phase by dehydrogenation and hydrogen reduction of ball-milled TiH2-MoO3 powder mixtures. Homogeneous powder mixtures with refined particles are prepared by ball milling for 24 h. XRD analysis of the heat-treated powder in a hydrogen atmosphere shows TiH2 and MoO3 peaks in the initial powders as well as the peaks corresponding to the reaction phase species, such as TiH0.7, TiO, MoO2, Mo. In contrast, powder mixtures heated in an argon atmosphere are composed of Ti, TiO, Mo and MoO3 phases. The formation of reaction phases dependent on the atmosphere is explained by the partial pressure of H2 and the reaction temperature, based on thermodynamic considerations for the dehydrogenation reaction of TiH2 and the reduction behavior of MoO3.

PURPOSES: The objective of this study was to determine the relationship between the dielectric characteristics of asphalt mixtures and the air voids present in them using ground penetrating radar (GPR) testing. METHODS : To measure the dielectric properties of the asphalt mixtures, the reflection coefficient method and the approach based on the actual thickness of the asphalt layer were used. An air-couple-type GPR antenna with a center frequency of 1 GHz was used to measure the time for reflection from the asphalt/base layer interface. A piece of aluminum foil was placed at the interface to be able to determine the reflection time of the GPR signal with accuracy. An asphalt pavement testbed was constructed, and asphalt mixtures with different compaction numbers were tested. After the GPR tests, the asphalt samples were cored and their thicknesses and number of air voids were measured in the laboratory. RESULTS: It was found the dielectric constant of asphalt mixtures tends to decrease with an increase in the number of air voids. The dielectric constant values estimated from the reflection coefficient method exhibited a slight correlation to the number of air voids. However, the dielectric constant values measured using the approach based on the actual asphalt layer thickness were closely related to the asphalt mixture density. Based on these results, a regression equation to determine the number of air voids in asphalt mixtures using the GPR test method was proposed. CONCLUSIONS: It was concluded that the number of air voids in an asphalt mixture can be calculated based on the dielectric constant of the mixture as determined by GPR testing. It was also found that the number of air voids was exponentially related to the dielectric constant, with the coefficient of determination, R2, being 0.74. These results suggest that the dielectric constant as determined by GPR testing can be used to improve the construction quality and maintenance of asphalt pavements.

Cu-30 vol% SiC composites with relatively densified microstructure and a sound interface between the Cu and SiC phases were obtained by pressureless sintering of PCS-coated SiC and Cu powders. The coated SiC powders were prepared by thermal curing and pyrolysis of PCS. Thermal curing at 200 oC was performed to fabricate infusible materials prior to pyrolysis. The cured powders were heated treated up to 1600 oC for the pyrolysis process and for the formation of SiC crystals on the surface of the SiC powders. XRD analysis revealed that the main peaks corresponded to the α-SiC phase; peaks for β-SiC were newly appeared. The formation of β-SiC is explained by the transformation of thermally-cured PCS on the surface of the initial α-SiC powders. Using powder mixtures of coated SiC powder, hydrogen-reduced Cu-nitrate, and elemental Cu powders, Cu-SiC composites were fabricated by pressureless sintering at 1000 oC. Microstructural observation for the sintered composites showed that the powder mixture of PCS-coated SiC and Cu exhibited a relatively dense and homogeneous microstructure. Conversely, large pores and separated interfaces between Cu and SiC were observed in the sintered composite using uncoated SiC powders. These results suggest that Cu-SiC composites with sound microstructure can be prepared using a PCS coated SiC powder mixture.

PURPOSES: This study evaluated the field applicability and laboratory performance of glass fiber-reinforced asphalt (GFRA) mixtures. METHODS : The general hot-mix asphalt (HMA) and GFRA mixtures were paved in five sites, including three national highways, one express highway, and an arterial road, to evaluate field applicability and durability. The plant mixing and construction method for the GFRA were similar to those for the general HMA. The lab performances of the field samples were relatively compared through the mechanical measures from the Marshall stability, indirect tensile strength, and dynamic stability. The field performance was surveyed after a year. RESULTS : The lab tests verified the superior lab performances of the GFRA compared to the general HMA. The Marshall stability of the GFRA increased for about 128% of the general HMA. The indirect tensile strength of the GFRA was 115% greater than that of the general HMA. The dynamic stability of the GFRA resulted in 16,180 reps/mm, which indicated that high rut resistance may be expected. No noticeable defects, such as cracks or deformation, were observed for the GFRA sections after a year. CONCLUSIONS: The lab tests and field survey for the five GFRA sites resulted in superior performances compared to the general HMA. The relatively low-cost GFRA, which required no pre-processing procedures, such as polymer modification, may be a promising alternative to the polymer-modified asphalt mixtures. The long-term performance will be verified by the superior field durability of the GFRA in the near future.

화학산업에 있어서 종래의 분리 기술에 의한 문제점을 해결하기 위해 투과증 발 공정 기술을 촉진시켜 왔다. 요즘 투과증발의 대부분은 bio-butanol, isopropanol 및 다른 유기용제류의 탈수를 위해 사용되고 있으며, 그 중 유기용 제의 탈수공정은 유기물의 분리공정에 비해 상당한 발전을 이루고 있다. 본 연 구에서는 물에 대한 고선택성을 나타내는 분리막 모듈을 이용하여 IPA와 물의 공비혼합물을 대상으로 공급액 온도, 투과액의 응축 온도와 같은 투과증발 공정 변수가 IPA 탈수 성능에 미치는 영향을 알아보았다. 또한 water uptake 및 접촉 각을 측정하여 친수화 정도를 알아보았다.