In the case of the companies selected for noise measurement in this study, even though noise exposure in the workplace begins with noise management for large machines or high-output machines, they only manage to write reports on how much workers are exposed to noise for 8 hours a day. is focused on. When large machines are delivered, little information on noise received from the manufacturer is kept, and noise information indicated on design drawings is also difficult to find. History management of noise information of large machines is necessary. There is also a problem with the professionalism of managers who manage noise information. Like odors and fine dust, it is judged that noise needs to be managed by a professional manager at the workplace and managed through a database of noise information.

The Cu2ZnSn(SxSe1-x)4 (CZTSSe) absorbers are promising thin film solar cells (TFSCs) materials, to replace existing Cu(In,Ga)Se2 (CIGS) and CdTe photovoltaic technology. However, the best reported efficiency for a CZTSSe device, of 13.6 %, is still too low for commercial use. Recently, partially replacing the Zn2+ element with a Cd2+element has attracting attention as one of the promising strategies for improving the photovoltaic characteristics of the CZTSSe TFSCs. Cd2+ elements are known to improve the grain size of the CZTSSe absorber thin films and improve optoelectronic properties by suppressing potential defects, causing short-circuit current (Jsc) loss. In this study, the structural, compositional, and morphological characteristics of CZTSSe and CZCTSSe thin films were investigated using X-ray diffraction (XRD), X-ray fluorescence spectrometer (XRF), and Field-emission scanning electron microscopy (FE-SEM), respectively. The FE-SEM images revealed that the grain size improved with increasing Cd2+ alloying in the CZTSSe thin films. Moreover, there was a slight decrease in small grain distribution as well as voids near the CZTSSe/Mo interface after Cd2+ alloying. The solar cells prepared using the most promising CZTSSe absorber thin films with Cd2+ alloying (8 min. 30 sec.) exhibited a power conversion efficiency (PCE) of 9.33 %, Jsc of 34.0 mA/cm2, and fill factor (FF) of 62.7 %, respectively.

For the transport of spent nuclear fuel, it is necessary to evaluate the amount of radioactivity for each assembly and the total amount of radioactivity for each cask. Currently, KHNP is evaluating the radioactivity using the Express mode of the OrigenArp program in the SCALE6.1 code. Express mode is a method to evaluate the radioactivity assuming that it has been burned with the same power per cycle, and Detail mode is a method to evaluate the actual combustion history such as power and cooling time for each cycle. For a total of 3,795 assemblies, including 1,391 assembliess for Kori Unit 1, 1,427 assemblies for Hanbit Unit 2, and 977 assemblies for Hanul Unit 3, the radioactivity was evaluated in Express mode and Detail mode, respectively, and the results were compared. As a result of the evaluation, it was confirmed that the results of the Express mode were evaluated more conservatively by 2.5~12.9% than that of the Detail mode. Accordingly, KHNP established a plan to change the evaluation method from Express mode to Detail mode in order to improve the accuracy of the radioactivity assessment results and eliminate conservatism.

매년 우리나라 연안해역에서 항해 중인 소형선박 및 소형어선과 연안에 어 로작업을 위해 설치된 시설물과의 접촉 사고가 빈번하게 발생한다. 이러한 사 고들은 주로 연안해역에 설치된 양식장, 정치망, 자망 등으로 인해 발생하며,선박 사고의 일반적인 원인으로는 항해 중인 선박에서 선원의 상무인 경계 소 홀, 침로 유지 및 선위 확인의 미충실, 항해 일반원칙과 국제해상충돌방지규칙 의 미준수 등 여러 가지가 될 수 있다. 본 논문에서는 어구손상사고와 관련된 사고의 원인을 검토하기 위해 해양안전심판원 재결서를 통해 분석하였으며, 그 결과 사고의 원인으로 경계 소홀, 설치된 어구와 적절한 거리 미확보, 항해 계 획 수립 미비 등이 사고의 원인으로 작용한 것을 알 수 있었다. 이러한 인적요 인으로 발생하는 사고를 줄이기 위해서는 선원의 꾸준한 안전교육이나 선박 안 전관리체제의 시스템 변경과 같은 오랜 시간과 많은 비용이 필요하다. 본 논문 에서는 어구를 조금 더 빨리 직관적으로 발견하여 인적요소를 제외한 다른 사 고요인을 제거하는 방법으로 사고 발생을 줄일 수 있는 방안을「수산업법」, 「어업면허의 관리 등에 관한 규칙」,「양식장ㆍ어장 표지시설의 설치 기준」, 「양식산업발전법」 등에서 문제점을 파악하고 개선하여 어구손상사고를 줄일 수 있는 방법을 모색해보고자 한다.

The research aims to develop a rapid and easy analytical method for methoprene using liquid chromatography- tandem mass spectrometry (LC-MS/MS). A simple, highly sensitive, and specific analytical method for the determination of methoprene in livestock products (beef, pork, chicken, milk, eggs, and fat) was developed. Methoprene was effectively extracted with 1% acetic acid in acetonitrile and acetone (1:1), followed by the addition of anhydrous magnesium sulfate (MgSO4) and anhydrous sodium acetate. Subsequently, the lipids in the livestock sample were extracted by freezing them at -20oC. The extracts were cleaned using MgSO4, primary secondary amine (PSA), and octadecyl (C18), which were then centrifuged to separate the supernatant. Nitrogen gas was used to evaporate the supernatant, which was then dissolved in methanol. The matrix-matched calibration curves were constructed using 8 levels (1, 2.5, 5, 10, 25, 50, 100, 150 ng/mL) and the coefficient of determination (R2) was above 0.9964. Average recoveries spiked at three levels (0.01, 0.1, and 0.5 mg/kg), and ranged from 79.5-105.1%, with relative standard deviations (RSDs) smaller than 14.2%, as required by the Codex guideline (CODEX CAC/GL 40). This study could be useful for residue safety management in livestock products.

Radioactive waste disposal facility in Korea, radioactive waste packaged in 200 L drums is placed in a concrete disposal container and disposed of at an underground silo type (cave) disposal facility. At this time, the disposal container cover is seated on the top of the disposal container, and if the disposal container and the cover are not completely combined, the container cover is raised up from the top of the disposal container, so safety problems may occur when stacking the disposal container. Therefore, various methods exist to secure a margin for the pure height inside the disposal container. The disposal container cover only covers the upper surface of the container to shield radiation, and structural performance is not required. Therefore, the method of processing the cover, such as a method of making the cover of the disposal container thin, is the easiest method to apply. In this study, a method to reduce the thickness of the cover of a concrete disposal container was devised, and structural performance under usability conditions such as lifting and seating was analyzed. In addition, the disposal container cover has a reinforced concrete form in which dissimilar materials (concrete and steel) are combined, an integrated analysis was performed to secure the reliability of the analysis results for this, and the analysis results were described. It was found that the proposed disposal container cover structure can improve usability by reducing the stress concentration phenomenon.

APro, developed by KAERI as a process-based total system performance assessment model, can simulate the radionuclide transport affected by thermal, hydraulic, mechanical and geochemical changes that may occurs in the engineering and natural barriers of a geological disposal system. APro targets a large-scale and heterogeneous 3D system that includes more than 10,000 boreholes located about 500 m underground and hundreds of fractures of different sizes distributed within an area of several km2. Simulating transport and reaction phenomena for such a system through the global implicit approach (GIA) may require considerable computational resources or be intractable in some cases. Therefore, APro adopts the sequential non-iterative approach (SNIA), one of the operator splitting (OS) methods, to separate the mass transport and reaction phenomena into independent problems. By using SNIA, the parallel computation performance in APro with multiple cores is expected to be improved. In this study, the effect of SNIA on the parallel computation performance was analyzed through a simple 1D reactive transport problem. Without SNIA, finite difference equations, discretized from the partial differential equations (PDEs) describing the reactive transport problem, have to be solved at once because all dependent variables are nonlinearly and spatially interconnected through reaction and mass transport terms. When the reaction and mass transport terms are separated through SNIA, the mass transport problem can be converted into independent linear equations for each chemical and the efficient linear system solver can be applied to each linear equation. In particular, since the reaction problem is changed to independent nonlinear equations for each node, the parallel computation performance can be greatly improved. To verify this, the 1D reactive transport problem was implemented in MATLAB, and SNIA and GIA were applied to solve the problem. As a result, there was no significant difference in results between SNIA and GIA for proper spatial and temporal discretization, which verified the accuracy of SNIA. In order to see the parallel computation performance, the calculation times for SNIA and GIA with increasing number of cores were measured and compared. As the number of cores increased, the SNIA calculation speed became faster than that of GIA, which verified that SNIA could improve parallel computation performance in APro. In the future, the effect of SNIA on the parallel computation performance will be verified for the numerical analysis of large-scale geological disposal systems.

Bentonite is considered as buffer of engineered barrier for retardation of radionuclide migration. Bentonite has low permeability, high swelling and high sorption capacity for radioactive nuclides. Properties have been widely investigated under various geochemical conditions simulating deep geological environments. The chemical stability of bentonite is an important factor in evaluating the long-term stability of the bentonite buffer. However, the presence of impurities in bentonite clays can reduce the retention capacity for retardation of radionuclide migration value of bentonite. Therefore, the bentonite purification is necessary. In the present study, grade improvement of montmorillonite was conducted using ultrasonic and froth flotation methods. As a result of confirming the grade of montmorillonite according to the optimal ultrasonic intensity for ultrasonic irradiation is 1.0 kHz of bentonite in Gyeongju (KJ-II) increased from 60% to 78%. In case of froth flotation method using PSS (0.1 mM) as a reagent, the grade of montmorillonite increased up to 90%.

최근에는 경량화 문제에 대한 합리적인 솔루션을 제공하고 유용한 개념설계를 제공할 수 있는 다중 재료 구조 위상최적화가 더욱 중요해지고 있다. 기존의 MMTO(Multi-Material Topology Optimization)의 경우 후보 물질의 수가 증가할수록 설계변수의 수도 증가 하고, 결과적으로 계산 시간이 크게 증가한다. 따라서 PSM(Phase Section Method)과 같은 단일 설계변수를 갖는 MMTO가 제안되었 다. 본 연구는 조성비가 면적이나 부피비를 나타내지 못하고, 설계변수가 목표치에 충분히 집중되지 않고, 특정 재료가 요구량보다 적 게 생성되는 PSM의 세 가지 주요 제한점을 고려하여 이를 개선하는데 중점을 둔다. 이러한 한계를 극복하기 위해 재정의된 조성비와 더 나은 수렴을 위한 조정된 매개변수를 제안한다. 제안된 수정 사항의 유효성을 2차원 및 3차원 수치 예제를 통해 검증한다.

This study aimed to investigate the validation and modify the analytical method to determine quercetin- 3-o-gentiobioside and isoquercitrin in Abelmoschus esculentus L. Moench for the standardization of ingredients in development of functional health products. The analytical method was validated based on the ICH (International Conference for Harmonization) guidelines to verify the reliability and validity there of on the specificity, linearity, accuracy, precision, detection limit and quantification limit. For the HPLC analysis method, the peak retention time of the index component of the standard solution and the peak retention time of the index component of A. esculentus L. Moench powder sample were consistent with the spectra thereof, confirming the specificity. The calibration curves of quercetin-3-o-gentiobioside and isoquercitrin showed a linearity with a near-one correlation coefficient (0.9999 and 0.9999), indicating the high suitability thereof for the analysis. A. esculentus L. Moench powder sample of a known concentration were prepared with low, medium, and high concentrations of standard substances and were calculated for the precision and accuracy. The precision of quercetin-3-o-gentiobioside and isoquercitrin was confirmed for intraday and daily. As a result, the intra-day precision was found to be 0.50-1.48% and 0.77-2.87%, and the daily precision to be 0.07-3.37% and 0.58-1.37%, implying an excellent precision at level below 5%. As a result of accuracy measurement, the intra-day accuracy of quercetin-3-o-gentiobioside and isoquercitrin was found to be 104.87-109.64% and the daily accuracy thereof was found to be 106.85-109.06%, reflecting high level of accuracy. The detection limits of quercetin-3-o-gentiobioside and isoquercitrin were 0.24 μg/mL and 0.16 μg/mL, respectively, whereas the quantitation limits were 0.71 μg/mL and 0.49 μg/mL, confirming that detection was valid at the low concentrations as well. From the analysis, the established analytical method was proven to be excellent with high level of results from the verification on the specificity, linearity, precision, accuracy, detection limit and quantitation limit thereof. In addition, as a result of analyzing the content of A. esculentus L. Moench powder samples using a validated analytical method, quercetin-3-o-gentiobioside was analyzed to contain 1.49±0.01 mg/dry weight g, while isoquercitrin contained 1.39±0.01 mg/dry weight g. The study was conducted to verify that the simultaneous analysis on quercetin-3-o-gentiobioside and isoquercitrin, the indicators of A. esculentus L. Moench, is a scientifically reliable and suitable analytical method.

증기운 폭발의 폭압을 예측하거나 위험성 분석을 위하여 다양한 폭압 산정법이 존재하지만 대표적으로 경험적 방법인 TNT 등가량 환산법과 멀티에너지법을 주로 사용한다. 멀티에너지법은 환경적 요인을 고려한 폭발강도계수를 사용한다. 본 연구에서는 문헌 분석 을 통하여 점화원 강도를 세분하고 강도분류를 확장하여 개선한 폭발강도계수 가이드라인을 제안하였다. 개선한 폭발강도계수 가이 드라인의 합리성 검증과 기존 Kinsella 가이드라인과의 비교를 위하여 실제 추정 폭압과 대조가 가능한 4가지의 증기운 폭발 사례를 적용하였다. 결과적으로 기존 Kinsella 가이드라인은 실제 추정 폭압에 비하여 광범위하거나 부정확한 폭압 산정 결과를 나타내는 것 으로 확인하였다. 반면, 개선한 폭발강도계수 가이드라인은 명확한 점화원의 강도 선정이 가능하고 분류의 확장을 통하여 더욱 세분 화된 계수 값의 선정이 가능함에 따라 실제 사례와 비교적 유사한 폭압 산정이 가능하다.

Fluoroimide는 감과 감자의 둥근무늬낙엽병과 역병을 억제하는데 효과가있는 살진균제로서, 이전 사용되었던 fluoroimide의 시험법은 전처리시 발암물질인 benzene을 사 용하는 문제가 있었으며, 복잡한 시험법으로 인해 시간이 오래걸리고 효율이 떨어지는 단점이 있었다. 또한, fluoroimide 의 특성상 산성에서 안정한 편이므로 전처리 시 이를 고려해야 하는 문제가 있었으며, PLS시행에 따라 기존의 정량한계인 0.05 mg/kg보다 낮은 정량한계 요구로 인해 fluoroimide에 대한 새로운 전처리방법이 필요하였다. Fluoroimide가 산성에서 안정한 특성을 고려하여, 추출 시 4N의 염산을 사용하였고 용매는 acetic acid가 포함된 acetonitrile을 사용하였으며, MgSO4와 NaCl을 통해 추출하였다. 정제는 C18 (Octadecylsilane)과 GCB (graphitized carbon black)를 첨가하여 정제하였으며, 기기분석은 LCMS/ MS로 분석하였다. 대표농산물 5종(현미, 감자, 대두, 감귤, 고추)을 대상으로 정량한계(0.01 mg/kg), 정량한계 10배(0.1 mg/kg), 정량한계 50배(0.5 mg/kg)의 수준으로 회수율 실험을 5반복 실시하였으며, 그 결과는 농산물 5종에 서 85.7-106.9%의 회수율을 확인하였으며, 분석오차는 15.6% 이하의 결과를 보여, 국제식품 규격위원회 가이드 라인의 잔류농약 분석 기준 및 ‘식품등 시험법 마련 표준 절차에 관한 가이드라인(2016)’에 부합하였다. 상기의 결과를 통해 개선한 fluoroimide의 시험법은 benzene을 대체 해 실험자의 안전성을 확보하였고, QuEChERS법을 적용하여 효율을 높여, 안전관리에 대한 공정시험법으로서 활용가능할 것으로 사료된다.

The railroad facilities are intended for long-term operation as the initial acquisition costs necessary for infrastructure construction are high. Therefore, regular maintenance of railroad facilities is essential, and furthermore, system reliability through systematic performance evaluation is required. In this study, the signal control system of railroad electrical equipment was selected as the subject of research and the performance evaluation target facility selection study was conducted using AHP. The results of the study can contribute to the reliability of the signal control system as well as to the reliability of the railroad system, which is a higher system.

To cope with automobile exhaust gas regulations, ISG (Idling Stop & Go) and charging control systems are applied to HEVs (Hybrid Electric Vehicle) for the purpose of improving fuel economy. These systems require quick charge/discharge performance at high current. To satisfy this characteristic, improvement of the positive electrode plate is studied to improve the charge/discharge process and performance of AGM(Absorbent Glass Mat) lead-acid batteries applied to ISG automotive systems. The bonding between grid and A.M (Active Material) can be improved by applying the Sand-Blasting method to provide roughness to the surface of the positive grid. When the Sand-Blasting method is applied with conditions of ball speed 1,000 rpm and conveyor speed 5 M/min, ideal bonding is achieved between grid and A.M. The positive plate of each condition is applied to the AGM LAB (Absorbent Glass Mat Lead Acid Battery); then, the performance and ISG life characteristics are tested by the vehicle battery test method. In CCA, which evaluates the starting performance at -18 oC and 30 oC with high current, the advanced AGM LAB improves about 25 %. At 0 oC CA (Charge Acceptance), the initial charging current of the advanced AGM LAB increases about 25 %. Improving the bonding between the grid and A.M. by roughening the grid surface improves the flow of current and lowers the resistance, which is considered to have a significant effect on the high current charging/discharging area. In a Standard of Battery Association of Japan (SBA) S0101 test, after 300 A discharge, the voltage of the advanced AGM LAB with the Sand-Blasting method grid was 0.059 V higher than that of untreated grid. As the cycle progresses, the gap widens to 0.13 V at the point of 10,800 cycles. As the bonding between grid and A.M. increases through the Sand Blasting method, the slope of the discharge voltage declines gradually as the cycle progresses, showing excellent battery life characteristics. It is believed that system will exhibit excellent characteristics in the vehicle environment of the ISG system, in which charge/discharge occurs over a short time.

본 연구에서는 점근해석 및 논로컬 이론에서 요구하는 4차 이상의 고차 미분근사를 수행하기 위하여 계방정식에 혼합변분이론을 적용하여 MLS 차분법으로부터 구해지는 고차 미분근사의 정확도를 큰 폭으로 향상시킨다. 또한, MLS 차분법에 존재하는 세 가지 조건변수에 따른 고차미분근사의 정확도를 비교·분석한다. 혼합변분이론의 합응력을 후처리하여 변위의 미분을 근사할 경우 기존의 변위장 기반 계방정식의 차분 결과에 비해 미분 차수가 2차 낮아진다. 해석 범위내 절점 수가 과도하게 많거나 기저 차수가 클 경우 MLS 차분법의 영향영역 내에서 과적합(overfitting)이 발생한다. 또한 영향영역이 최적 범위 이상으로 넓어질 경우 근사의 정확도가 떨어진다. 위 내용을 사인 하중을 받는 단순지지보 수치예제로부터 확인하였다.

Recognition that R&D (Research and Development) project is important for national competitiveness and sustainable economic growth has been extended all over the world, and the government financial support for R&D projects has increased. Therefore, government needs to make a decision about whether it invests in any project or not, and this decision-making complies with evaluation of the relevant experts. In this study, we improve project selection methods and procedures based on outranking methods which have mainly focused on general project environmental analysis in order to apply to the government support R&D project selection, and suggest R&D project selection methods and procedures that meet the purpose of government support. Therefore, it demonstrates that improved methods organize more profitable project groups to the purpose of the selecting government support R&D project than existing methods. Also, it illustrates that it is possible for decision makers to analyze variously by changing composition of selecting project group with variation of α.