In this study, we investigated the suppression of the corrosion of cast iron in a copper–cast iron double-layered canister under local corrosion of the copper layer. The cold spray coating technique was used to insert metals with lower galvanic activity than that of copper, such as silver, nickel, and titanium, between the copper and cast iron layers. Electrochemically accelerated corrosion tests were performed on the galvanic specimens in KURT groundwater at a voltage of 1.0 V for a week. The results revealed that copper corrosion was evident in all galvanic specimens of Cu–Ag, Cu–Ni, and Cu–Ti. By contrast, the copper was barely corroded in the Cu–Fe specimens. Therefore, it was concluded that if an inactive galvanic metal is applied to the areas where local corrosion is concerned, such as welding parts, the disposal canister can overcome local or non-uniform corrosion of the copper canister for long periods.
토석 채취 후 식생복구지의 토양 특성은 복구 식생의 생육에 중요하다. 본 연구는 토석 채취 후 식생복구지와 인접 소나무 및 굴참나무 임분을 대상으로 0∼10cm, 10∼20cm, 20∼30cm 깊이에 토양의 물리·화학적 특성을 조사하였다. 토양용적밀도와 토양 pH는 식생복구지가 소나무나 굴참나무 임분에 비해 유의적으로 높았으나(P<0.05), 유기탄소와 전질소농도는 인접 산림지에 비해 낮았다. 유효 인은 0~10cm 깊이에서 식생복구지 와 산림지 간 유의적인 차이가 없었으나, 교환성 칼슘은 식생복구지가 인접 산림지에 비해 유의적으로 높게 나타났다. 토양 유기 탄소저장량은 식생복구지가 9,896 kg C ha-1로 소나무 임분 131,368 kg C ha-1나 굴참나무 임분 154,381 kg C ha-1에 비해 유의적으로 낮았으며 질소저장량도(식 생복구지: 2,406 kg N ha-1; 소나무: 10,496 kg N ha-1; 굴참나무: 8,081 kg N ha-1) 유사한 경향을 보였다. 그러나 인, 포타슘, 마그네슘 저장량은 식생복구지와 인접 산림 간 유의적인 차이는 없었다. 한편, 칼슘저장량은 식생복구지가 8,998 kg Ca ha-1로 소나무 임분 697 kg Ca ha-1나 굴참나무 임분 660 kg Ca ha-1에 비해 유의적으로 크게 나타났다. 본 연구 결과에 따르면 토석 채취 후 식생복구지는 토양용적밀도와 토양 pH를 낮추고 유기물의 증가와 질소 시비 같은 양분관리가 필요한 것으로 나타났다.
In this study, a third metal layer with a higher corrosion potential than copper was introduced between the copper and cast iron layer to strengthen the corrosion resistance of the copper layer which is considered as a corrosion resistant barrier in the disposal container for spent nuclear fuel. Three types of corrosion-resistant metals, silver, nickel, and titanium, were selected as the intermediate insertion layer, and the galvanic specimens of two bonded metals were exposed to KURT (KAERI Underground Research Tunnel) groundwater and a high voltage of 1.0 V was applied to corrode the specimens at electrochemically accelerated condition. Corrosion of copper part was confirmed in Cu-Ti, Cu-Ni, and Cu-Ag galvanic specimens, but copper part was not corroded in Cu-Fe galvanic specimen. If the corrosion-resistant intermediate layer proposed in this study works properly, the local corrosion problem of copper disposal canister is expected to be some degree solved, which can apply to a welding part or a stress concentrated part.
The purpose of this study was to examine whether galvanic corrosion of copper occurs by inserting a third barrier layer with a higher corrosion potential than copper between copper and cast iron when the copper layer is locally perforated by pitting or partial corrosion. A triple layer composed of copper, inserted metal, and carbon steel was manufactured by cold spray coating of inserting metal powders such as Ag, Ni, and Ti on carbon steel plate followed by Cu coating on it. First, the corrosion properties were evaluated electrochemically for each metal coating. As a result of Tafel plot anaylsis in KURT groundwater condition, the corrosion potential of Fe (-567 mV) was much lower than that of Cu (-91 mV), and the corrosion potential of Ni (-150 mV) was also lower than that of Cu. Therefore, Ni was likely to corrode before Cu. However, the corrosion current of Ni was lower than that of the Cu. In the galvanic specimen where the copper and inserting metal were exposed together, Cu-Fe was much lower corrosion potential of -446 mV, and the corrosion potential of Cu-Ti, Cu-Ni, and Cu-Ag were slightly higher than that of Cu. Therefore, it seemed that Ag, Ni, and Ti all might promote galvanic corrosion of surrounding copper when the copper layer was perforated to the inserted metal layer. If the metal insertion presented in this study operates properly, the disposal container does not need to worry about the partial corrosion or non-uniform corrosion of external copper layer.
Monitoring a state that intentionally hides its nuclear activity via open-source information is akin to looking through a black box. Direct information on the state’s nuclear activity remains in the dark, leaving scholars to speculate how much nuclear material or warheads are being produced. Nevertheless, a state’s nuclear program consists of a complex network that ranges from producing weapon-grade nuclear materials by operating its nuclear facilities to securing resources to fund these activities. These indirect activities allow a narrow window of opportunity for researchers to map a state’s activity that sometimes may not be directly linked to nuclear activity per se but is significant to maintaining and operating its nuclear program. These may include malicious cyberattacks to steal or launder cryptocurrency and facilitating cooperation with fellow rogue states that do not comply with the NPT and nuclear nonproliferation regime. The problem lies in how researchers can map this network. Much of the literature that uses text analysis uses data from either (1) formal statement, reports, and documents or (2) journal articles to extract relations between topics that is otherwise difficult to surmise. This study, however, analyzes news articles containing keywords related to a states’ nuclear activity such as international sanctions, trade activities, other states’ policy etc. While news articles fail to live up to the academic rigor of journal articles and unlike formal documents may sometime contain misinformation or incorrect facts, they are a valuable medium to show the day-to-day activity of a state. Although bias may exist as particular news articles may or may not be chosen for text analysis, by using articles collected from 2021 to 2022, this study argues it is enough data to show a short-term trend in nuclear activity.
For countering nuclear proliferation, satellite imagery is being used to monitor suspicious nuclear activities in inaccessible countries or regions. Monitoring such activities involves detecting changes over time in nuclear facilities and their surroundings, and interpreting them based on prior knowledge in terms of nuclear proliferation or weaponisation. Therefore, analysts need to acquire and analyze satellite images periodically and have an understanding of nuclear fuel cycle as well as expertise in remote sensing. Meanwhile, as accessibility of satellite information has been increasing and accordingly a large amount of high-resolution satellite images is available, a lack of experts with expertise in both fields to perform satellite imagery analysis is being concerned. In this regard, the Institute of Korea Nonproliferation and Control (KINAC) has developed a prototype of semi-automatic satellite imagery analysis system that can support monitoring of potential nuclear activities to overcome the limitations of professionals and increase analysis efficiency. The system provides a satellite imagery database that can manage acquired images, and the users can load images from the database and analyze them in stages. The system includes a preprocessing module capable of resizing, correcting and matching images, a change detection module equipped with a pixel-object-based change detection algorithm for multi-temporal images, and a module that automatically generates reports with relevant information. In particular, this system continuously updates open-source information database related to potential nuclear activities and provides users with an integrated analytics platform that can support their interpretation by linking related images and textual information together. As such, the system could save time and cost in processing and interpreting satellite images by providing semi-automated analytic workflows for monitoring potential nuclear activities.
Corrosion cells that simulates engineering barrier system have been stored in an aerobic KURT environment for 10 years, which were recovered and dismantled in 2021. The test specimens were compressed copper (Com. Cu), Cold spray copper (CSC Cu), Ti Gr.2, STS 304, and Cast nodular iron. The specimens were buffered by compact Ca-type Gyeongju bentonite (KJ-I) and compact Na-type Wyoming bentonite. And the corrosion cells were exposed to KURT groundwater at 30°C for about 10 years (3,675 days). As a result of the long-term experiment in aerobic environment, it was confirmed that Na-bentonite is more advantageous for inhibiting corrosion than Ca-bentonite. The corrosion thickness of the most specimens in Ca bentonite was slightly lower than in Na bentonite until the initial 500 days, but after 10 years, the corrosion thickness of copper and cast iron specimens in Na bentonite was clearly lower. The corrosion thickness of the copper specimen in Na bentonite was very low about 0.5 um in both Com. Cu and CSC Cu. Moreover, the corrosion thickness in Ca bentonite was very high about 4 um for Com. Cu and 6 um for CSC Cu. In the case of cast iron, the corrosion thickness in Na bentonite was about 13 um, and 15 um in Ca bentonite. The common feature of copper and cast iron specimens in Ca bentonite, which showed a high corrosion thickness, is the forming of a white mineral deposition layer on the specimen surface, which was presumed to be some kind of feldspar. On the other hand, it was found that the STS304 and Ti specimens were hardly corroded even after 10 years. In conclusion, when a white mineral deposition layer was formed on the specimen surface, the corrosion thickness always increased sharply than before, and thus it was estimated that the generation of the mineral deposition layer cause the increase of bentonite permeability, and rather the weakening of existing passive corrosion film.
With the enhancement of the spatial resolution of satellite imagery (1 m or less), the satellite image analysis has been considered as the indispensable means for remote sensing of nuclear proliferation activities in the restricted access areas such as North Korea. Notably, in the case of an open-pit uranium mine, e.g. the Pyongsan uranium mine, the mining activity can be presumed if detecting the location and extent uranium tailing piles near shafts within temporal images. Several studies have researched on the target detection for minerals of interest such as limestone and coal to evaluate the economic activities by utilizing similarity measures, e.g., a spectral angle mapper and a spectral information divergence (SID). Thus, this paper presented a systematic change detection methodology for monitoring the uranium mining activity in the Pyongsan uranium mine with a similarity measure of SID. The proposed methodology using the target detection results consists of the following five steps. The first step is to acquire stereo images of areas of interest for change detection. The second step is to preprocess the stereo images as following measures: (i) the QUick Atmospheric Correction and the image-to-image registration with ENVI and (ii) the Gram-Schmidt pansharpening. The third step is to extract spectral information for minerals of interest, i.e., uranium tailing piles, by sampling pixels within the reference image. It is based on the satellite analysis report for the Pyongsan uranium mine by CSIS, which specified the location of the uranium tailing piles. As the fourth step, the target detection for uranium tailing piles was performed through the similarity measure of SID between the extracted spectral information and the spectral reflectance of the image. In the fifth step, the change detection was processed using the multivariate alteration detection algorithm, which compares the target detection results by canonical correlation analysis. Furthermore, this paper evaluated the performance of the proposed methodology with the change detection accuracy assessment index, i.e., the area under a receiver operating characteristic curve. In conclusion, this paper suggests the systematic change detection methodology utilizing time series analysis of target detection for uranium tailing piles, which can save time and cost for humans to interpret large amounts of satellite information at the restricted access areas. As future works, the feasibility of the proposed methodology would be investigated by analyzing distribution of minerals of interest regarding nuclear proliferation at Yongbyon, which has the historical events of suspicious nuclear activities.
Dishwashing tools such as sponges, scourers, and dishcloths are known to harbor dense and diverse microbial communities, including pathogenic bacteria. In this study, the potential of corona discharge plasma jet (CDPJ) as a disinfectant was tested to improve the hygienic quality of dishwashing tools. For the simulation of microbial contamination, selective pathogenic bacteria (Escherichia coli O157:H7, Staphylococcus aureus, and Pseudomonas putida) were inoculated on selected dishwashing tools (dishcloth, sponge, and scourer) at concentrations of 6.55 to 8.77 log CFU/cm 2 . CDPJ generated at 20 kV voltage and 1.5A current was used for decontamination, whereas a sample-to-electrode distance of 25 mm was maintained during the treatment. Following CDPJ treatment for 5 min, the viable counts of E. coli O157:H7, S. aureus, and P. putida were reduced by 4.30-4.56, 3.71-4.78, and 3.50-3.83 log, respectively. The rates of inactivation were varied among the pathogens, decreasing in the order E. coli O157:H7 > S. aureus > P. putida. Among tested kinetic models, namely log-linear, log-linear with shoulder, and Weibull models, the log-linear with shoulder model was found to be the most suitable model to explain the CDPJ inactivation of the pathogens. In conclusion, CDPJ can be used as a potential sanitizing agent for dishwashing tools.
Until now, there were no records of fossil ants both types of amber or impression in Korea, despite many fossil ants were known from Japan and China. Majorities of extinct fossil ants were mainly distributed from the Eocene to Miocene strata in worldwide. In Korea, the ant fossils were discovered only from a single site, the Pohang basin which is the typical Neogene sedimentary basin. Duho Formation, which new fossil species was found, belongs to Pohang basin and ranges from about 150m to 200m in thickness. More than 10 unidentified species of ant fossils excavated from Duho Formation were recognized as Formicidae by the authors. Hence, we provided short descriptions of one new fossil species, Aphaenogaster koreana sp, nov. and introduced current status of Cenozoic fossil ants excavated from Duho Formation, Republic of Korea.