Within the framework of a project entitled “Development of Advanced Sweet Potato Cultivation Technology for Smallholder Farmers in Paraguay” implemented by KOPIA Paraguay Center (Korea Partnership for Innovation of Agriculture) in collaboration with Paraguayan Institute of Agricultural T echnology (I PTA) d uring the period 2021-2024, r esults o f four m ain e xperiments are described in this research: selection of suitable varieties, optimal planting and harvesting times, the use of ridges, and optimal chemical fertilization doses. In the selection of suitable varieties for Paraguay, 11 sweet potato varieties were evaluated in departments of San Pedro and Misiones. As a result, varieties Andaí, Jety Paraguay, and Chaco I showed the highest productivity in San Pedro, while varieties Jety Uruguayo, Chaco I, and Taiwanés showed higher productivity in Misiones. The other three experiments were carried out in San Pedro only. Optimal planting and harvesting times were determined with three varieties: Andaí, Pyta Guasu, and Jety Paraguay. For Andaí and Jety Paraguay varieties, they should be planted in December and harvested at 122 days post planting (DPP). For Pyta Guasu, it should be planted in October and harvested at 124 DPP. Regarding productivity response with soil preparation methods, the use of ridges showed higher yields in all planting methods, with the curved method planting being the most productive. Finally, optimal chemical fertilization doses were established in order to improve the total yield. The optimal nitrogen fertilizer dose (urea 45% N) was 40 kg/ha. The optimal phosphorus fertilizer dose (triple superphosphate 45% P2O5) was 80 kg/ha and the optimal potassium fertilizer dose (potassium chloride 60% K2O) was 120 kg/ha.
실시간 온라인 게임 서버에서의 게임 상태 동기화는 중요한 문제이며, 기존 동기화 방식은 상황 에 따라 성능이 변동하는 한계가 있다. 본 연구에서는 이를 해결하기 위해 하이브리드 동기화 방 식을 제안한다. 클라이언트 간 거리가 가까울 때는 Lockstep 방식을, 멀 때는 서버 동기화 방식 을 사용하여 일관성과 가용성을 모두 만족시킨다. 술래잡기 게임에서 하이브리드 방식을 적용한 결과, 기존 방식보다 최대 74.6% 향상된 위치 일관성과 23.6% 감소된 응답시간을 달성했다.
Copper, silver, and gold-reduced graphene oxide nanocomposite (Cu-rGO, Ag-rGO, and Au-rGO) were fabricated via the hydrothermal method, which shows unique physiochemical properties. Environment friendly electromagnetic radiation was employed to synthesize rGO from GO. The nonlinear optical phenomenon of noble metal decorated rGO is predominantly due to excited state absorption, which arises from surface plasmon resonance and increases in defects at the surface due to Cu, Ag, and Au incorporation. It is found that the third-order nonlinear absorption coefficient was in the order of 10− 10 m/W, with notable enhancements in the third-order properties of Au-rGO compared to other nanocomposites and their respective counterparts. Functionalizing rGO induces defect states ( sp3), increasing NLO response. Cu, Ag, and Au exhibit higher Surface-Enhanced Raman Scattering (SERS) activity due to rGO-induced structural modifications. SERS signals are influenced by dominant signals from Au nanorods. The electronic structures for pure and doped rGO were investigated through Density Functional Theory (DFT). The computed partial density of states (PDOS) confirms the enhancement of the state in Au-doped rGO is due to the charge transference from Au to C 2p orbital. The optical absorption spectra and PDOS reveal the possibility of free carrier absorption enhancement in Au which validates experimentally observed higher two-photon absorption (β) value of Au-doped rGO. The tuning of nonlinear optical and SERS behaviour with variation in the noble metal upon rGO provides an easy way to attain tuneable properties which are exceedingly required in both optoelectronics and photonics applications.
Flexible electrodes, particularly paper electrodes modified with polypyrrole, have shown promise in energy-related applications. We have earlier demonstrated the usage of paper electrodes modified with polypyrrole as a flexible and suitable photoanode for photoelectrochemical water splitting (PEC). Further, modification of this electrode system with an appropriate tandem absorber system for solar fuel production is interesting in developing efficient photoanodes. In this study, we study the PEC performance of flexible polypyrrole-based paper photoanodes (PPy-PAs) by decorating them with rGO@Cu2Zn- SnS4 chalcopyrites (rGO@CZTS/PPy-PAs). The lower bandgap (~ 1.5 eV) of the rGO@CZTS/PPy-PAs system allows for efficient visible light absorption, substantially improving PEC water-splitting reactions. The rGO@CZTS/PPy-PAs exhibited an enhanced current density of ~ 13.2 mA/cm2 at 1.23 V vs RHE, ABPE of ~ 1.5%, and a hydrogen evolution rate of 177 μmoles/min/cm2. Overall, rGO@CZTS/PPy-PAs showed 2.1-fold, 1.1-fold, and 1.4-fold enhancement in photocurrent activity over PPy-PAs, CZTS/PPy-PAs, and rGO/PPy-PAs, respectively. The usability of rGO@CZTS/PPy-PAs is established in the form of stable photocurrent for more than 200 min. These findings open new possibilities for developing modified PPy PAs as flexible PEs for efficient solar-driven PEC devices and give directions on improving flexible PEs for flexible and efficient solar-driven PEC systems.
Carbon dots (C-dots) are a developing subclass of nanomaterials which are characterized by a typical diameter of less than 10 nm. C-dots are a type of core–shell composites that feature a surface passivation with various functional groups, including amine, carboxyl, hydroxyl group, and a carbon core. Green C-dots, which have drawn a lot of interest from researchers due to their superior water solubility, excellent biocompatibility, and environmental-friendly behavior when compared to chemically generated C-dots, can be made from a variety of low-cost and renewable materials. Since green C-dots have heteroatoms on their surface in the form of carboxyl, amine, hydroxyl, or other functional groups, which can enhance their physicochemical characteristics, quantum yield (QY), and likelihood of visible light absorption, further surface passivation is not necessary. Green C-dots may find use in the areas of biosensing, catalysis, bioimaging, and gene and drug delivery. In this paper, the creation of C-dots was outlined, and its fluorescence process examined. This review represents the summary of synthesis, mechanism, properties, characterization, and applications of C-dots. This article aims at the green chemistry strategies for C-dot synthesis. Furthermore, a discussion on the applications of C-dots produced with green approaches is presented. The paper may help the researchers in the field to develop new C-dots with potential features to attract the attention of new applications.