This study, changes in raw water quality is to indicate on the efficiency of ozone treatment of each pollutant as compared to derive the appropriate operating measures. The appropriate selection for injection rate of pre-ozone and did not inject pre-ozone assess changes in the water. When good water quality, you not injected of pre-ozone to evaluate the economic efficiency of electricity and put the most cost-effective ozone concentration were evaluated. Evaluation remove organic matter and chlorophyll-a concentration level in experiments with each factor of the water DOC> 2.5 ㎎ / L, THMFP> 70 ㎍ / L, Chl-a> 30 ㎎/ ㎥or less constant process, if you do not need to put pre-ozone showed little impact. It also does not put you in pre-ozone appropriate produce enough power rate savings was calculated as approximately 90 million won. Ability to remove organic materials and the ability to produce disinfection byproducts, and cost-effective decisions by considering the concentration of injection if pre-ozone 1 mg/L was investigated by the appropriate concentration of ozone injection.

This study utilized atomic force microscopy (AFM) and nanoindentation methods to evaluate epoxy water-resistance and anti-corrosiveness. This study considered two different epoxy formulations to assess typical degradation characteristics of epoxy surfaces with regard to water-resistance and anti-corrosiveness. As a result, this study was able to clearly confirm changes in physical characteristics and performance tendencies regarding ozone oxidizing reactions.

The main objectives of this research are to investigate characteristics of ozone solubility due to low solubility of conventional bubbles-ozone generators, evaluate the treatment characteristics of reclaiming textile wastewater for industrial water by means of micro/nano bubbles-dissolved ozone flotation(MNB-DOF) process. The textile wastewater used in this research was obtained from final effluent of the textile wastewater in B city. There is a 400L reactor which consists of a micro-nano bubble system and a ozone generator for experiments. As a result of generating micro-nano bubbles (below 0.5 ㎛) by using of MNB-DOF process, it improved ozone solubility due to higher ozone transfer rates. Consequently, the shorter ozonation time clearly indicates the lower power costs. The reported results clearly indicated that MNB-DOF process can be effectively and inexpensively. Results of the experiments through MNB-DOF process in this study satisfy all reclaiming standards as industrial water: pH 6.5～8.5, SS 10 mg/L or below, BOD_5 6 mg/L or below, turbidity 10 NTU or below, Coliforms 1,000/100 mL or below. Therefore there is a possibility of the reclaiming of the textile wastewater as industrial water.

밸러스트수 처리를 위한 Plasma Gun의 전기적 특성과 오존 생성에 미치는 주요 운전변수들의 영향에 관해 실험실 규모 연구를 수행하였다. 방전개시전압보다 높은 전압이 인가되면 방전이 시작되고 오존이 생성되었으며 전압이 증가함에 따라 기체로 전달되는 에너지 및 오존 농도가 거의 선형적으로 증가하였다. 오존 생성 측면에서 최적의 에너지 효율성을 얻을 수 있는 전극간 거리가 존재하였으며 실험된 장치에서는 1.95 mm의 전극간 거리에서 최적 효율이 얻어졌다. 전기에너지 특성에 미치는 내부전극 재질의 영향은 무시할만한 수준이었으나 내부전극의 전기전도도와 열전도도 차이가 오존 생성에 큰 영향을 미치는 것으로 나타났다. 일정한 Plasma Gun 구조에서 오존 생성은 기체로 전달되는 에너지밀도에 의해 중요한 영향을 받는 것으로 나타났으며 유입되는 기체의 산소함량이 증가할수록 오존 생성이 증가하는 것으로 나타났다.

The performance of ozone contactor in ozone-BAC advanced water treatment process was evaluated by the degree of decomposition of organic matters. The degree was measured by the analyses of UV254 absorbance and the concentrations of DOC and BDOC for the sand filtered water and the ozone treated water, respectively. In addition, the ozone concentration in the contactor, required for the maximum BDOC concentration, was selected as the optimum concentration, and the appropriate residential time of ozone treated water in a reservoir was recommended based on the residual ozone concentration in the treated water. The following results were obtained from the pilot scale experiments. By ozonation UV254 absorbance was decreased, and BDOC concentration was increased. The change of DOC concentration by ozonation was negligible, but the excess input of ozone resulted in the removal of the small amount of BDOC by complete oxidation. The optimum ozone concentration was 0.58 mg O3/mg DOC. In order to remove residual ozone, 20 minutes of the residential time were enough after ozonation.

The objective of this study was to investigate the effects of pH and temperature on the formation of bromate, which is ozonation by-products, during ozonation. In this experiment, the operating parameters including pH 3～10 and temperature 15～30℃ were studied. Through the study for the bromate formation, reaction rate constant, and ozonation effect index on pH and temperature, the results obtained are as follows. At the same initial pH condition, the increase of pH shown similar trends even if the reaction variables such as temperature and reaction time of ozonation were exchanged. As pH and temperature were increasing, the bromate concentration was increased but bromine(HOBr+OBr-) was decreased with increasing pH from 3 to 10. The activation energy(J/mol) for bromate formation decreased with increasing pH. The rate constants of bromate formation for the reaction of ozone and bromide, and ozone dosage coefficient(Ko) increased with temperature and pH. Ozonation effect index(OI) decreased with increasing temperature and pH.

The effect of ozone on the formation and the removal of disinfection byproducts(DBPs) of chlorination process was studied to elucidate the performance of water treatment process. The samples of raw water, prechlorination process, and preozonation process were analyzed quantitatively according to the Standard Methods for the Examination of drinking water. As a result, most of total trihalomethanes(THMs) which were formed in prechlorine treatment process was not removed in the preozonation process. Most of haloacetic acids(HAAs), haloacetonitriles(HANs), and chloral hydrate(CH) was removed in sedimentation and biological activated carbon(BAC) filtration processes. However, DBPs were increased more or less by postchlorine step. In particular, the formation of THMs and HAAs depends on ozone more than chlorine, but, the formation of HANs and CH depends on chlorine more than ozone. The seasonal variation of DBPs concentration for the year needs to be investigated to study the temperature effect because DBPs strongly depend on temperature among various efficient factors.

경북지방에서 많이 생산되고 있는 생과용 복숭아를 이용하여 수확후 오존수 침지처리가 복숭아 품질신선도에 미치는 영향에 대하여 분석한 결과 가용성고형물은 처리후 일수가 경과할수록 조금씩 증가하는 경향을 보였으며, 처리후 15일째는 무처리구와 오존수처리구에서 유의적으로 차이가 나타나지 않았으며, 산도의 변화에서는 무처리구에 비해 오존수 침지처리가 저장기간이 경과할수록 낮아지는 경향을 보였는데, 오존수처리후 10일째와 15일깨 모두 처리구보다 낮게 나타

This study was carried out to evaluate the pollutant removal efficiencies of the advanced drinking water treatment using ozonation process. For raw water, Nakdong River was used. By conducting batch test of ozonation, the following results were obtained. When ozone dosage of 5 mg/ℓ was used, ozone transfer and utilization efficiencies of the ozonation were 94 to 92%, respectively. Removal efficiencies of single VOC compound or mixed VOC compounds in the raw water were 80% to 90% by the ozonation with 2 mg/ℓ dosage and 10 minutes contact time. Removal efficiencies of ABS by the ozonation with 1 mg/ℓ, 3 mg/ℓ dosage and 20 minutes contact time were 83% to 96% , respectively. Almost 67% of chlorophyll-a at the concentration of 38.4㎍/ℓ was removed by ozonation at ozone dosage of 1 ㎎/ℓ for 20 min. Considering the efficiency of ozone utilization and water treatment, the most effective ozonation could be obtained with high ozone dosage and short contact time.

This study was carried out to evaluate the pollutant removal efficiencies of the advanced drinking water treatment using ozonation. For raw water, Nakdong River was used. By conducting batch ozonation test, the following results were obtained. When ozone dosage of 5㎎/ℓ was used, preozonation of raw water reduced turbidity, KMnO4 consumption, DOC(dissolved organic carbon), UV254 absorbance, THMFP(trihalomethane formation potential) as much as 3.9 NTU, 5.5㎎/ℓ, 1.15㎎/ℓ, 0.112 and 0.065㎎/ℓ, respectively. In case of postozonation of sand filtered water, water quality was also improved with decrease in turbidity, KMnO4 consumption, DOC, UV254 absorbance and THMFP at the amount of 0.08NTU, 2.6㎎/ℓ, 0.88㎎/ℓ, 0.042 and 0.018㎎/ℓ, respectively. On the other hand, contents of dissolved oxygen increased at the level of 1.3㎎/ℓ after preozonation process' and 1.0㎎/ℓ after postozonation process. The effect of ozone dosage was higher than that of its contact time for the removal of the pollutants.