이 연구에서는 계면활성제에 작용기를 첨가하여 유화제 뿐만 아니라 합성에서의 모노머로 작 용할 수 있는 반응성 계면활성제를 합성하였다. 반응성 계면 활성제는 메타아크릴 산, 아크릴산과 비이 온성 계면 활성제인 폴리 옥시 에틸렌 라우릴 에테르 (POE 23)를 사용하여 합성되었으며 벤젠을 용매 로서 사용하였고, P-TsOH를 촉매로서 사용 하였다. 합성된 계면 활성제는 FT-IR, 1H-NMR 스펙트 럼, 원소 분석을 하였다. 물성 평가는 HLB, Cloud point, 표면 장력, 임계 미셀 농도를 측정 하였다. HLB 값은 11.62∼12.09 범위로 평가 하였다. cmc 값은 표면 장력 법으로 측정하였을 때 1×10-4~5×10-4 의 값을 가졌다. 실험을 통해 측정된 Cloud point은 35, 39℃ 이었다. 합성 계면 활성 제의 유화 특성은 polyoxyethylene lauryl ether보다 낮았다. 또한, 유화력은 벤젠에서 보다 대두유에서 더 좋았다. 실험결과 합성 수율은 93.27 ∼ 94.49%로 확인되었다.

For a decade, solution-processed functional materials and various printing technologies have attracted increasingly the significant interest in realizing low-cost flexible electronics. In this study, Cu nanoparticles are synthesized via the chemical reduction of Cu ions under inert atmosphere. To prevent interparticle agglomeration and surface oxidation, oleic acid is incorporated as a surface capping molecule and hydrazine is used as a reducing agent. To endow water-compatibility, the surface of synthesized Cu nanoparticles is modified by a mixture of carboxyl-terminated anionic polyelectrolyte and polyoxylethylene oleylamine ether. For reducing the surface tension and the evaporation rate of aqueous Cu nanoparticle inks, the solvent composition of Cu nanoparticle ink is designed as DI water:2-methoxy ethanol:glycerol:ethylene glycol = 50:20:5:25 wt%. The effects of poly(styrene-co-maleic acid) as an adhesion promoter(AP) on rheology of aqueous Cu nanoparticle inks and adhesion of Cu pattern printed on polyimid films are investigated. The 40 wt% aqueous Cu nanoparticle inks with 0.5 wt% of Poly(styrene-co-maleic acid) show the “Newtonian flow” and has a low viscosity under 10 mPa·S, which is applicable to inkjet printing. The Cu patterns with a linewidth of 50~60 μm are successfully fabricated. With the addition of Poly(styrene-co-maleic acid), the adhesion of printed Cu patterns on polyimid films is superior to those of patterns prepared from Poly(styrene-comaleic acid)-free inks. The resistivities of Cu films are measured to be 10~15 μΩ·cm at annealing temperature of 300 ˚C.

Nowadays, the study of CFRP reinforced with carbon fiber is focused on improving the the mechanical property. The study on the fracture data of CFRP are not properly made out than that of the general mechanical joint. In this study, the fracture property of mode 1 at the same condition of tensile experiment is investigated by applying the layer angle to laminated CFRP with the thickness of 15 mm. When the reaction forces until dropping out the bonded surface are compared with the cases of the layer angles of 0°, 45° and 60°, the reaction force is shown to be most and the elapsed time until dropping out the bonded surface is longest at that of 45°. The deformation energy is also shown to have the highest value by dropping out the adhesive interface. As the basis of the analysis result of this study, the most safety with fracture resistance is shown in the case of 45°. the bonded structure applying the appropriate layer angle is thought to have the structural safety.

태양광 발전시스템은 태양복사에너지를 반도체의 광전효과를 이용하여 전기에너지로 직접 전환시키는 에너지변환 시스템이다. 태양전지의 내구성과 에너지변환율에 영향을 미치는 핵심소재로는 다층형 필름구조를 갖는 백시트를 들 수 있다. 대표적인 상용 백시트는 고내구성 poly(vinyl fluoride) (PVF) 필름이 중심축에 위치하고 가격저감을 위해 도입된 poly(ethylene terephthalate) (PET) 필름이 그 양쪽에 접합된 삼층구조로 구성된다. 하지만, PVF 필름의 높은 가격은 저렴한 고내구성 백시트 를 요구하는 시장상황을 반영하기 어렵게 한다. 이를 위한 해결책으로는 PVF 필름을 결정성 PET 필름으로 대체한 탄화수소계 백시트가 될 수 있다. 하지만, PET 필름의 본질적인 가수분해에 대한 취약성으로 인해, 추가적인 수분에 대한 배리어성 부여 는 필수적이다. 이를 위해 본 연구에서는 소수성 실리카 나노입자 분산기술을 활용한 수분차단성 폴리우레탄 접착제를 개발 코자 하였다. 개발된 접착제는 내부에 위치한 PET 필름으로의 수분침투를 약화시켜, 가수분해속도를 지연시킬 것이라 기대 되었다. 본 개념의 효용성을 확인하기 위해, 표준화된 온습도조건에 노출된 이후의 일반접착제와 수분차단성 접착제가 도입 된 백시트의 기계적 강도 및 시간당 태양전지성능 변화가 비교평가되었다.

유기 포도재배가 늘어남에 따라 이마점애매미충(Arboridia maculifrons), 이슬애매미충(A. maculifrons), 검은볼애매미충(A. nigrigena)의 발생이 늘어나고, 농가에서 방제의 어려움을 격고 있다. 애매미충류는 포도잎을 가해하는 노린재목 흡즙성 해충으로 약충과 성충 모두 엽록소를 파괴하기 때문에 광합성효율을 떨어뜨리고, 당·산도 함량 및 착색 등에 영향을 미치는 대표적 미소해충 중의 하나이다. 애매미충류의 친환경적인 방제를 위해 완전 비가림하우스에서 접착트랩 색에 대한 유인효과를 검정하였다. 검정결과 yellow>blue,purple,white>red 순으로 유인반응을 보였다 실내에서 모니터링 상자를 이용한 LED(Light emitting diode) 반응은 white> green>blue>yellow>red 순으로 유인 반응을 보였으며, 포장시험에서도 white의 효과가 인정되어 일몰후 1시간, 일몰후 2시간, 19~21시로 나누어 야간 시간대별 LED 유인효과를 분석해 본 결과 야간온도가 25℃이상에서 유인효과가 인정되었으며, 20℃이하에서는 유인효과가 없었다. 이는 미소해충이 운동을 위해 필요한 에너지가 기온과 관련이 있기 때문으로 생각된다.

PCB 제조에서 photoresist와 Copper Clad Laminate(CCL)의 구리표면과의 부착력을 항상시 키기 위하여 사용되는 soft etching제를 제조하기 위하여 과산화수소 사용을 배제하고, 유기산과 유기과 산화물을 이용하여 산의 종류, 농도, 에칭시간 등에 따른 구리표면의 에칭속도, 표면 조도, 및 오염도 등 을 조사하였다. 또한 에칭 후의 표면의 얼룩을 제거하기 위한 안정제의 최적 배합 및 농도도 확립하였 다. 본 연구 결과 유기산의 종류 중에서는 아세트산이 초기 구리 에칭속도가 가장 빨랐으며, 농도가 0.04 M이었을 때 0.4 μm/min이였다. 유기과산화물인 APS의 농도는 높을수록 에칭속도가 가장 빨랐으나, 표면 오염이 심각하였다. 안정제 용액의 조성도 표면 오염도에 큰 영향을 주었다. 결과적 0.04 M 아세 트산, 0.1M APS에 4 g/L의 안정제(ST-1)를 첨가한 에칭액의 경우 0.37 μm/min의 에칭속도와 표면 오염이 전혀 없으며, 표면 조도도 가장 우수하였다. 즉, CCL과 photoresist와 접착력을 향상시킬 수 있 을 것으로 판단된다.

PURPOSES : Recently, bonded concrete overlay has been used as an alternative solution in concrete pavement rehabilitation since its material properties are similar to those of the existing concrete pavements. Deteriorated concrete pavements need rapid rehabilitation in order to prevent traffic jams on Korean expressways. Moreover, speedy and effective repair methods are required. Therefore, the use of bonded concrete overlay with ultra-rapid hardening cement has increased in an effort to reopen promptly the expressways in Korea. However, mobile mixer is required for ultra-rapid hardening cement concrete mixing in the construction site. The use of mobile mixer causes various disadvantages aforementioned such as limitation of the construction supply, open-air storage of mixing materials, increase in construction cost, and etc. In this study, therefore, hydration accelerator in-situ mixing on polymer modified concrete produced in concrete plant is attempted in order to avoid the disadvantages of existing bonded concrete overlay method using ultra-rapid hardening cement. METHODS: Bonded concrete overlay materials using ultra-rapid hardening cement should be meet all the requirements including structural characteristics, compatibility, durability for field application. Therefore, This study aimed to evaluate the application of hydration accelerator in-situ mixing on polymer modified concrete by evaluating structural characteristics, compatibility, durability and economic efficiency for bonded concrete overlay. RESULTS : Test results of structural characteristics showed that the compressive, flexural strength and bond strength were exceed 21MPa, 3.15MPa and 1.4MPa, respectively, which are the target strengths of four hours age for the purpose of prompt traffic reopening. In addition, tests of compatibility, such as drying shrinkage, coefficient of thermal expansion and modulus of elasticity, and durability (chloride ions penetration resistance, freezing-thawing resistance, scaling resistance, abrasion resistance and crack resistance), showed that the hydration accelerator in-situ mixing on polymer modified concrete were satisfied the required criteria. CONCLUSIONS: It was known that the hydration accelerator in-situ mixing on polymer modified concrete overlay method was applicable for bonded concrete overlay and was a good alternative method to substitute the existing bonded concrete overlay method since structural characteristics, compatibility, durability were satisfied the criteria and its economic efficiency was excellent compare to the existing bonded concrete overlay methods.

PURPOSES: A tack coat has been utilized to increase the bond performance between the surface layer and base course (intermediate course) at various road pavement sites. This is similarly true in other nations. Based on this connection, the objective of the present study is to evaluate the properties of hot mix asphalt (HMA) mixtures with an RSC-4 or BD-Coat and determine the application rate of the tack coat. METHODS: The HMA specimens were manufactured using superpave gyratory compaction. The HMA mixtures were composed of a 5-cm thick surface layer and a 10-cm thick base course. An impact hammer resonance test (IHRT) and a static load shear test were conducted to evaluate the performance of the HMA mixtures with a tack coat. From these tests, the dynamic moduli related to the high-frequency resistance and interlayer shear strength (ISS) of HMA could be obtained. RESULTS: The results of the dynamic moduli of HMA are discussed based on the resonance frequency (RF). To check the accuracy of the IHRT, we conducted a coherence analysis. A direct shear test using the application of a static load test was carried out to evaluate the interlayer shear strength (ISS) of HMA. CONCLUSIONS: The maximum ISS was demonstrated at an RSC-4 application rate of 462 gsm, and the maximum dynamic modulus was demonstrated at an RSC-4 application rate of 306 gsm. By averaging the results of the ISS, the maximum ISS values were obtained when a BD-Coat application rate of 602 gsm was applied.

Adhensively bonded joints in dissimilar materials have been widely applied in various engineering fields such as automobiles, space vehicle, semiconductor, vessel. To establish a fracture criterion and a reasonable strength evaluation method on adhensively interfaces in dissimilar materials, it is necessary to assess fracture parameters with various bonding conditions. In this paper, through stress analysis by using the 2-dimensional elastic boundary element method(BEM), the stress singularity factors on adhensively bonded joint in dissimilar materials were investigated quantitatively, and suggested the strength evaluation method by using fracture parameters

The porous metallic material has the most superior physical property and the best mechanical capability. This study is investigated with the simulation analysis by compressing three kinds of specimens. Three aluminum foams with the thickness of 10 mm are bonded at Case 1. Two aluminum foams with the thicknesses of 10 mm and 20 mm are bonded at Case 2. It is one aluminum foam with the thickness of 30 mm at Case 3. The two dimensional model is done by ANSYS design modeler and the finite element analysis is performed by ANSYS structural analysis. As the forced displacement of 1 mm during the elapsed time of 60 sec is applied, the forced displacement of 10 mm during the total elapsed time of 600 sec is applied. As the analysis result, the most reaction force is shown at case 2 among three cases. Case 2 is estimated as the best structure. The analysis result of this study is thought to be the data necessary for the safe design about mechanical structure and the development of composite material.

For the last decade many bridges and buildings have experienced flexural strengthening with the fiber reinforced polymer(FRP) bonding system, demands for increasing heavy traffic loads and the changing of the code application. Of the many strengthening systems, NSM(near surface mounted) system with FRP has become attractive and popular way of strengthening for the existed RC structures and many studies and applications of this technique have significantly increased all over the world. Meanwhile, polymer mortar that contains much of the same ingredients as cement but includes the addition of certain polymer resins for enhancing desired physical properties, has been used as an alternative adhesive. This paper focuses on flexural behaviour of CFRP-bar NSM system with variables such as kinds of adhesive, anchorage, sectional aspect ratio. Based on the test results and test-to -predicted ratio, this paper provides researchers and practical engineers a fundamental knowledge and intuition.

PURPOSES : The objective of this study is to evaluate the bond strength of asphalt emulsions including polymer-modified emulsions for chip seals and fog seals using the bitumen bond strength (BBS) test. METHODS : For the laboratory testing, the Pneumatic Adhesion tensile Testing Instrument(PATTI) device is used to measure the bond strength between the asphalt emulsion and aggregate substrate based on the AASHTO TP-91. In order to conduct all the tests in controled condition, all test procedures are performed in the environmental chamber. The CRS-2L and the SBS CRS-2P emulsions are used as a polymermodified emulsion, and then unmodified emulsion, the CRS-2, is compared for the evaluation of chip seal performance. For the fog seal performance evaluation, two types of polymer-modified emulsions and one of unmodified emulsion, the CSS-1H, are employed. For chip seal study, the BBS tests are performed at 30, 60, 120, and 240 minutes of curing times with curing and testing temperatures of 15℃, 25℃, and 35℃. The fog seal tests are conducted at 30, 60, 90, 120, 180 minutes, and 24 hours with curing and testing temperatures of 25℃, 30℃, and 35℃. RESULTS AND CONCLUSIONS : Overall, chip seal emulsions and fog seal emulsions show the similar bond strength trend. At the same testing condition, polymer-modified emulsions show better bond strength than unmodified emulsions. Also, there is no significant difference between polymer-modified emulsions. One of important findings is that the most bond strength reaches their final bond strength within one hour of curing time. Therefore, the early curing time plays a vital role in the performance of chip seals and fog seals.

In this study, the specimen of tapered double cantilever beam(TDCB) with aluminum foam is designed and shearing fatigue strength is based on the investigation of static behaviour analysis under the condition of mode Ⅱ. These specimen models have length and width of 200 mm and 25 mm. The inclined angles of adhesive face at the specimens are 6°, 8 °and 10°. As the inclined angle becomes higher, the time for which the model can not be broken during fatigue load becomes longer. The shearing strength of TDCB bonded structure with aluminum foam applied by shearing fatigue load can be evaluated through finite element method.

In this study, tapered double cantilever beam bonded with aluminum foam composite is modelled and analyzed by finite element analysis. The bonding strength on Mode II of this structure is evaluated and investigated. In cases of inclined angles of 6°, 8° and 10°, maximum equivalent stresses occur 1.29, 1.59 and 2.6 MPa respectively at the range of forced displacement of 5 to 6 mm. And maximum reaction forces become 186, 208 and 235 N individually at this range of displacement in these cases. By the analysis result on 3 kinds of models, the maximum reaction load increases as angle of inclination of model increases. And the elapsed time to approach the maximum load and the time to disappear away become shorter. This study result can be applied into the real composite structure with aluminum foam in case that the surface bonded with adhesive is inclined. This fracture behavior can also be investigated and the impact property can be examined

It has been more than twenty years since the application of GFRP bridge decks in construction fields. Recently, a few studies by governments and individual researchers have investigated in-use GFRP bridge decks. Areas of trouble include the problems of cracking, spalling and the de-bonding of the pavement or the wearing surface on GFRP bridge decks, all of which affect the long-term durability and serviceability of these new construction materials. Related to these problems, reflective cracks on asphalt pavement are directly related to pultruded GFRP bridge decks. This study investigates the behavior of an adhesive joint under weak-axis bending by tests and FE analyses to identify the causes of pavement cracks in in-use pultruded GFRP bridge decks. In detail, the flexural stiffness and the load-carrying capacities in strong and weak axes are measured during bending tests on pultruded GFRP decks. Next, tensile local failures of an epoxy adhesive due to the concentration of deformations at adhesive joints are identified via a weak-axis bending test. Finally, the tensile failure of an epoxy adhesive due to the local concentration of deformation at an adhesive joint under weak-axis bending is verified through a finite element analysis.

PURPOSES: The objective of this study is to investigate the effect of asphalt and geotextile interlayer on the fracture behavior of unbonded concrete overlay through a laboratory composite beam test. METHODS: In order to evaluate the effect of interlayer materials on the fracture behavior of unbonded concrete overlay, a laboratory test of composite beam was conducted with different types of interlayer. The test results of the composite beam using two types of geotextile interlayer with different thicknesses were compared to the test results of the composite beam using the tradition type of asphalt interlayer. The unbonded concrete overlay on the existing concrete pavement without interlayer was set for the control condition. RESULTS AND CONCLUSION : Overall, the laboratory composite beam test results did show the effect of asphalt and geotextile interlayer on the fracture behavior of composite concrete beams. The three-layer geotextile interlayer and HMA layer both increase the peak load when the first macrocrack occurs in the top concrete beam, while the HMA interlayer causes the smallest load drop percentage after the first macrocrack. The three-layer geotextile did show better performance than the single-layer geotextile through the greater peak load and smaller load drop percentage. It indicates that the thickness of geotextile interlayer will affect the fracture behavior of unbonded concrete overlay and the thicker geotextile interlayer is recommended.

본 연구에서는 유변물성측정기를 이용하여 HPMC 첨가량, 물 양, HPMC 분자량, 셀룰로오스 에테르 치환체 및 치환도가 쌀 반죽의 압축 및 접착 특성에 미치는 영향에 대해 살펴보았다. HPMC 첨가량이 증가함에 따라 접착강도는 꾸준히 증가하였으나, 압축강도는 2% HPMC 첨가량에서 최대 강도를 보였다. HPMC의 분자량이 증가하거나, 물 양이 감소할수록 쌀 반죽의 압축강도 및 접착강도가 증가하는 결과를 보였다. 이들 인자 외에도, 셀룰로오스 에테르의 치환체 및 치환도도 쌀 반죽의 압축강도 및 접착 강도를 결정하는 중요한 인자임을 확인하였다.

The natures of fatigue crack growth under Mode Ⅱ loading are studied. End notched flexure beam specimens were used. The effects of adherend thickness, rubber modification and adhesive thickness on fatigue crack growth were examined. The experimental results show that some of these parameters apparently do affect fatigue crack growth. Resistance to ModeⅡ fatigue crack growth are increased by rubber modification. The effects of adhesive thickness and rubber content on fatigue crack growth were explained by von Mises's equivalent stress using BEM analysis. For unmodified epoxy adhesives, the fatigue crack growth properties under Mode Ⅱ loadings were significantly different in all regions. For rubber-modified epoxy adhesives, they were also different in the first and second regions, but in the third region, they were similar

PURPOSES : This study aimed to evaluate the long-term performance of bonded concrete overlay in Korean Highway, and factors influencing the performances. METHODS: The evaluation for long-term performance of bonded concrete overlay is investigated based on the following study : i) The pavement distress of number of bonded concrete overlay sections in Korean highway are collected through field measurement, and PCI for each section is calculated. ii) Performance of LTPP data of bonded concrete overlay sections in U.S.A is analysed. And it is compared with bonded concrete overlay of Korean highway. iii) An analysis of the factors influencing to long-term performance of bonded concrete overlay is investigated. RESULTS: Performance analysis was confirmed that the overlay thickness was affecting significantly on the Bonded Concrete Overlay life. The comparison of LTPP data(U.S.A) and field measurement data(Korean) was showed. CONCLUSIONS : It was showed that the performance of Korean bonded concrete overlay is relatively lower than that of the bonded concrete overlay in U.S.A. The cause of lower performance can be explained by the lack of overlay thickness.