PURPOSES : This study compared the performance evaluation of a hot mix asphalt (HMA) and asphalt mixture of a warm-antistrip agent. METHODS : A mix design applying Korean standards was conducted to evaluate the performance evaluation. Thereafter, the quality standard evaluation of the asphalt mixture produced was conducted, and if all quality standards were satisfied, a performance evaluation was conducted. Types of performance evaluation included the Hamburg wheel tracking test and dynamic modulus test. RESULTS : As a result of the Hamburg wheel tracking test, the asphalt mixture with a warm-antistrip agent obtained a lower sedimentation value at 10000 times and 20000 times. This result is considered to have higher plastic deformation resistance of the asphalt mixture with a Warm-antistrip agent than HMA. The U.S. Department of Transportation stipulates that plastic deformation resistance is excellent if the asphalt mixture does not exceed 20,000 times the precipitate of 20 mm. Therefore, we confirmed that the plastic deformation resistance of the asphalt mixture with a warm-antistrip agent was excellent. Additionally, the master curve was analyzed by synthesizing the results of the dynamic modulus test. When analyzing the low load cycle at the bottom left of the master curve, the dynamic modulus value of the master curve was higher in the asphalt mixture with a warm-antistrip agent than in the HMA. In addition, when analyzing the high load cycle part, the dynamic modulus of the HMA was measured to be higher than that of the asphalt mixture with a warm-antistrip agent. Accordingly, the resistance to fatigue cracking of the asphalt mixture with a warm-antistrip agent was considered superior to that of the HMA. CONCLUSIONS : As a result, we confirmed that the asphalt mixture with a warm-antistrip agent that satisfies the Korean quality standards had better plastic deformation and fatigue resistance for all performance evaluation tests conducted in this study than the HMA. However, since the Hamburg wheel tracking test did not significantly differ in the amount of sedimentation in the performance evaluation tests and the mixture using one additive was compared with HMA, studies on the effects of various additives containing warm-antistrip agents are required.

Metal halide perovskite nanocrystals, due to their high absorption coefficient, high diffusion length, and photoluminescence quantum yield, have received significant attention in the fields of optoelectronic applications such as highly efficient photovoltaic cells and narrow-line-width light emitting diodes. Their energy band structure can be controlled via chemical exchange of the halide anion or monovalent cations in the perovskite nanocrystals. Recently, it has been demonstrated that chemical exfoliation of the halide perovskite crystal structure can be achieved by addition of organic ligands such as noctylamine during the synthetic process. In this study, we systematically investigated the quantum confinement effect of methylammonium lead bromide (CH3NH3PbBr3, MAPbBr3) nanocrystals by precise control of the crystal thickness via chemical exfoliation using n-octylammonium bromide (OABr). We found that the crystalline thickness consistently decreases with increasing amounts of OABr, which has a larger ionic radius than that of CH3NH3 + ions. In particular, a significant quantum confinement effect is observed when the amounts of OABr are higher than 60 %, which exhibited a blue-shifted PL emission (~ 100 nm) as well as an increase of energy bandgap (~ 1.53 eV).

PURPOSES : The use of hydrated lime or other liquid anti-stripping agents (ASA) is the most common method of improving the moisture susceptibility of asphalt mixes. ASAs are also known to have an anti-aging effect, according to several researchers. Therefore, the use of ASAs is expected to enhance the stability of asphalt pavements. The purpose of this study is to investigate the anti-aging effect of ASAs that are found in the domestic market. METHODS : In this study, an asphalt binder and a mixture mixed with typical domestic solid and liquid ASAs were prepared and aged to evaluate the physicochemical changes. A liquid additive developed by a Korean oil refinery was used as the liquid ASA, and hydrated lime was utilized as the solid ASA. The aging process of the asphalt was determined in the laboratroy based on previous studies to simulate the aging process inh te field. RESULTS : The result of the laboratory experiment indicates that both the solid and liquid ASAs have an anti-aging effect. Moreover, the liquid additive performed relatively better than the hydrated lime. CONCLUSIONS : If ASAs have an anti-aging effect in addition to the anti-stripping function, it is expected to improve the stability of the asphalt pavement significantly. However, few studies have been carried out on the anti-aging effect of ASAs found in the domestic market. In this study, we conducted a fundamental study on the anti-aging effect to help in the selection and use of ASAs in the domestic asphalt-paving industry.

In this study, we investigate the relationship between the peeling behavior of the backsheet of a photovoltaic(PV) module and its surface temperature in order facilitate removal of the backsheet from the PV module. At low temperatures, the backsheet does not peel off whereas, at high temperatures, part of the backsheet remains on the surface of the PV module after the peeling process. The backsheet material remaining on the surface of the PV module is confirmed by X-ray diffraction(XRD) analysis to be poly-ethylene(PE). Differential scanning calorimetry(DSC) is also performed to investigate the interfacial characteristics of the layers of the PV module. In particular, DSC provides the melting temperature(Tm) of laminated ethylene vinyl acetate(EVA) and of the backsheet on the PV module. It is found that the backsheet does not peel off below the Tm of ethylene of EVA, while the PE layer of the backsheet remains on the surface of the PV module above the Tm of the PE. Thus, the backsheet is best removed at a temperature between the Tm of ethylene and that of PE layer.

In this paper, optical infrared thermography simulation using thermal wave imaging technique is performed to analyze the thermal characteristics of delamination defects. In this study, lock-in thermography(LIT) and pulsed thermography(PT) simulation was performed to analyze the samples of european traditional tiles with delamination defects, and the analytical modeler was developed through the ANSYS 19.2 transient thermal analysis tool. Applied sinusoidal heating with modulation frequency according to pulse heating and phase locking technique. The thermal response of the sample surface by heating was recorded and then data analysis was performed. The temperature gradient characteristics of each technique were compared, and phase angle was calculated for the LIT to analyze the parameters for the experiment setting. The simulation model was developed as a useful data for practical optical infrared thermography tests.

A 57 years old female complained of severe pain on the right temporomandibular joint (TMJ) area. Her right condyle had been partly resected under surgical operation 13 years ago due to condyle hypertrophy, thereafter she felt dull pain on TMJ area and recently the lesion became severely swelled and painful leading to cancer phobia. The present radiological views showed slightly enlarged and sclerosed condyle with increased radiopacity, but its articular sliding function was almost disable during mouth opening. The patient’s TMJ lesion was carefully managed with conservative physiotherapy and pain treatment. The microsection of condyle head obtained from the previous operation was re-evaluated histologically, and it was finally diagnosed as osteochondrosis dissecans (OCD), exhibiting hyperplastic proliferation of cartilage in condyle head and marked vascular dilatation in epiphyseal zone. This abnormal cartilage tissue was distinguishable from normal cartilage tissue found in the peripheral cartilaginous cap of the same microsection. The involved cartilage cap showed thick hypertrophic chondrocyte zone with horizontal and vertical clefts accompanying diffuse hyaline degeneration. The superficial fibrous zone of cartilage cap was thickened and frequently peeled off, while lower hypertrophic zone of cartilage cap was highly cellular and proliferative. Consequently, the endochondral ossification became aberrant and resulted pre-mature apoptosis of many hypertrophic chondrocytes, followed by diffuse and mild inflammatory reaction in the underlying marrow tissue. Therefore, it was suggested that this hypertrophic condyle lesion, OCD, be differentiated depending on radiological and histological features from ordinary condyle hyperplasia, osteochondroma, and osteoarthritis, and that the pathological confirmation of OCD may provide a reliable modality for dental and medical treatment of chronic and painful TMJ lesion.

In this study, tensile stresses of partially delaminated CFRP sheets were analytically evaluated. The analytical model is a 15-m long concrete beam with a rectangular cross-section of 2×3 m and uses 480 2D-plate elements and 5760 3D-solid elements for mesh construction. The elastic modulus of concrete and CFRP sheet used in the analysis are 27,536 MPa and 200,000 MPa, respectively, and the compressive strength of concrete and tensile strength of CFRP sheet are 30.0 MPa and 4,000 MPa, respectively. In order to evaluate the change of the tensile stress due to the delamination of the CFRP sheet, the whole attached model and the partially delaminated model according to the position of delamination were considered. As a result of the finite element analysis, the tensile stress of the entire attached CFRP sheet showed a constant tensile stress on the whole cross section, and the tensile stress of the partially delaminated CFRP sheet showed the maximum tensile stress on the position of delamination. Based on the results of this study, future research will be carried out to optimize the layout and shape of CFRP sheets embedded with optical fiber sensors.

난류경계층이 유지되기 위한 에너지 공급은 경계층 내 구조물인 와류들의 상호작용으로 끊임없이 이루어진다. 이러한 난류 유동은 수송분야의 마찰저항 및 해양구조물의 침식 및 진동을 유발하기 때문에 유동 제어를 위한 연구가 활발히 진행되고 있다. 이러한 제어의 극대화를 위해서는 난류 에너지 전달이 어떻게 이루어지는지에 대한 메카니즘 규명이 필수적이고, 이를 위해서는 층류경계층 내 유동현상으로 파악하는 것이 명확하고 용이하다는 장점이 있다. 따라서, 본 연구에서는 층류경계층 내 평판에 반구를 설치하여 역압력구배을 발생시킴으로써 교란된 유동현상의 상호작용을 분석하였다. 즉, 반구를 둘러싼 목걸이 와류와 반구 표면의 유동 박리에 의한 후류영역에서 머리핀 와류가 생성되어 상호 유기적으로 영향을 주고받는다. 이 과정에서 목걸이 와류는 후류영역으로 높은 운동량의 유체를 유입시켜 머리핀 와류의 발생 주파수를 증가시킨다. 반구 전방에 구멍을 뚫어 국부적인 흡입제어로 목걸이 와류의 와도를 감소시킴으로써 그 영향이 완화되는 과정을 유동 가시화 및 열선유속계로 측정하여 정성 및 정량적으로 분석하였다.

현재 국내 콘크리트 포장은 고속도로에서 약 40%, 일반 도로에서는 2% 정도를 차지하고 있다. 콘크리트 포장은 중차량에 대한 뛰어난 적용성과 20년 이상의 장기 공용연수를 가진다는 장점을 가지고 있다. 최근 국내 고속도로의 콘크리트는 장기간 사용으로 인해 노후화 되어있으며, 개통한지 오래되지 않은 콘크리트포장에서도 줄눈부 파손 및 표면박리, 표면마모 등으로 인한 보수비가 증가하고 있는 추세이다. 특히 강원 및 전북지역은 매년 겨울 많은 눈으로 인해 많은 양의 제설제를 사용하고 있어 표면박리상태가 심각 상태이다. 따라서 본 논문에서는 실리카퓸과 폴리머분말을 사용한 포장용 콘크리트의 표면박리저항성을 평가하고자 한다. 기배합된 콘크리트에 실리카퓸과 폴리머 분말을 후 첨가하였으며, 혼화재료의 혼입으로 부족한 단위수량은 혼화재료 혼입 시 추가하여 W/C를 42%로 보정해주었다. 표 1은 실험에 사용한 배합표이다. 압축강도 시험결과 재령 28일에 모든 변수에서 30 MPa 이상을 발도를 발현하였고, 실리카퓸 사용량이 증가할수록 강도가 증진되었지만 폴리머에 따른 영향은 거의 없는 것으로 나타났다. 휨강도 시험결과 실리카퓸과 폴리머 분말을 사용한 배합의 휨강도가 OPC 배합에 비해 큰 폭으로 증가하였으며, 폴리머 분말의 혼입량이 증가할수록 그러한 경향이 더 뚜렷하게 나타났다. 실리카퓸도 휨강도가 증가하는 경향을 보였지만 그 영향은 크지 않았다. 표면박리저항성 시험결과 실리카퓸이 혼입된 변수에서 실리카퓸에 의한 수밀성 증가로 인해 저항성이 상당히 증가하는 경향을 보였으며, 혼입률의 증가에 따라 그러한 경향은 더 뚜렷하게 나타났다. 하지만 폴리머 분말의 혼입량이 증가할수록 박리량이 증가하여 폴리머 분말이 표면박리 저항성에 악영향을 미치는 것으로 판단된다.

아스팔트 혼합물이 운반·대기 중에 단기노화(short-term aging: STA)되는 것은 잘 알려진 사실이며 노화정도는 혼합물의 온도가 높음에 따라 그리고 시간이 길어짐에 따라 지수 함수적으로 증가되는 것으로 알려져 있다. 또한 같은 온도와 시간에 같은 바인더, 골재 및 입도를 사용한 같은 혼합물이라도 사용되는 첨가제의 종류에 따라 노화도에 차이가 난다. 그리고 혼합물의 종류에 따라서도 노화도에 차이가 큰 것으로 알려져 있다. 따라서 본 연구에서는 박리방지제(anti-stripping agent: ASA)의 종류와 혼합물의 종류에 따른 노화도의 차이를 비교분석 하였다. ASA로는 박리방지효과가 우수한 분말의 소석회와 액상 ASA를 비교하였다. 혼합물은 밀입도 아스팔트 (dense-graded asphalt: DGA) 표층용 혼합물과 쇄석 매스틱 아스팔트 (stone mastic asphalt: SMA) 혼합물을 비교하였다. 노화도는 아스팔트 노화의 척도로는 가장 많이 쓰이는 절대점도(absolute viscosity: AV)를 이용하였다. STA 온도와 시간에 따른 AV의 차이를 STA 처리된 혼합물로부터 추출·회수하여 60℃에서 측정하였다. 시험결과 같은 온도와 시간으로 STA 처리된 혼합물에서 소석회가 사용된 혼합물의 노화도가 월등히 낮았으며, 혼합물의 종류로는 SMA 혼합물의 노화도가 DGA 혼합물보다 낮게 나타났다. 이는 소석회가 박리방지효과 뿐만 아니라 노화억제 효과가 크기 때문이며, SMA는 바인더 함량이 높아 골재를 피복한 아스팔트 필름의 두께가 두꺼워 노화도가 적게 나타난 것으로 판단되었다.

PURPOSES:The objective of this study is to evaluate the effect of anti-stripping on asphalt mixtures constituting anti-stripping agents.METHODS:Based on the literature review, asphalt mixture added with anti-stripping agents was prepared, and these asphalt mixtures were evaluated for anti-stripping properties for each anti-stripping agent through various lab tests, namely, tensile strength ratio (TSR), dynamic immersion test, uniaxial compression test, and indirect tensile strength test (IDT). The liquid anti-stripping agents used in the lab test were premixed with each asphalt binder (PG 64-22, PG 76-22) before being mixed with the aggregate.RESULTS:The result of the TSR test revealed that the effect of anti-stripping was highest when hydrated lime and liquid anti-stripping agent W were added. The correlation coefficient R2 between the TSR result and cohesion ratio is 0.99, which indicates that the sensitivity of the TSR to moisture damage is reliable from the mechanical point of view. The covering ratio of the asphalt binder to the liquid anti-stripping agent W was determined to be higher than that to the other liquid anti-stripping agents.CONCLUSIONS:It is considered that the improved moisture resistance of asphalt mixture as a result of the use of anti-stripping agents can reduce the incidence of various pavement damages such as portholes caused by stripping, and the performance life of the asphalt road pavement can be prolonged.

OBJECTIVES : The objective of this research is to determine the moisture resistance of the freeze-thaw process occurring in low-noise porous pavement using either hydrated-lime or anti-freezing agent. Various additives were applied to low-noise porous asphalt, which is actively paved in South Korea, to overcome its disadvantages. Moreover, the optimum contents of hydrated-lime and anti-freezing agent and behavior properties of low-noise porous asphalt layer are determined using dynamic moduli via the freeze-thaw test. METHODS: The low-noise porous asphalt mixtures were made using gyratory compacters to investigate its properties with either hydratedlime or anti-freezing agent. To determine the dynamic moduli of each mixture, impact resonance test was conducted. The applied standard for the freeze-thaw test of asphalt mixture is ASTM D 6857. The freeze-thaw and impact resonance tests were performed twice at each stage. The behavior properties were defined using finite element method, which was performed using the dynamic modulus data obtained from the freezethaw test and resonance frequencies obtained from non-destructive impact test. RESULTS: The results show that the coherence and strength of the low-noise porous asphalt mixture decreased continuously with the increase in the temperature of the mixture. The dynamic modulus of the normal low-noise porous asphalt mixture dramatically decreased after one cycle of freezing and thawing stages, which is more than that of other mixtures containing additives. The damage rate was higher when the freeze-thaw test was repeated. CONCLUSIONS : From the root mean squared error (RMSE) and mean percentage error (MPE) analyses, the addition rates of 1.5% hydrated-lime and 0.5% anti-freezing agent resulted in the strongest mixture having the highest moisture resistance compared to other specimens with each additive in 1 cycle freeze-thaw test. Moreover, the freeze-thaw resistance significantly improved when a hydrated-lime content of 0.5% was applied for the two cycles of the freeze-thaw test. Hence, the optimum contents of both hydrated-lime and anti-freezing agent are 0.5%.