Korea is a country where the population is concentrated in metropolitan areas that have undergone rapid industrial development. As of 2020, more than 43% of the total population lives in large cities, and about 18.5% of the total population lives in Seoul. A basic human need living in such a metropolis is a pleasant environment. In this study, complex odors and designated odors were evaluated at the boundary areas and at the outlets for 15 public environmental facilities selected from among odor sources in Seoul. As a result of measuring the complex odor intensity was 3 ~ 6 times at the boundary areas and 100 ~ 4,481 times at the outlets. In food waste treatment facilities, incineration facilities, and waste transfer station facilities, the compound making the largest contribution to odor is acetaldehyde, which was recorded at 46%, 25%, and 32% respectively. At a sewage treatment facility and agro-fisheries wholesale market, hydrogen sulfide was the largest contributing compound at 71% and 29% respectively.
In this study, swine and cattle farms located in Jeollanam-do were selected to analyze and evaluate the components of odorants in livestock facilities. In addition, a preliminary survey of the literature was conducted to establish a sampling and analysis method for phenol and indoles which are major components of odor emissions from livestock facilities, yet are not regulated by the laws. To establish a sampling and analysis method for phenol and indoles, Tedlar bag and Tenax-TA sorbent tube was used as background concentration of blank sample and samples according to the elapsed time. The results obtained indicate the GC/MS analysis with Tenax-TA sorbent tube sampling was an effective method for measuring the compounds of phenol and indoles. In the swine facility, the rankings of the odorants in order, from highest to lowest, were ammonia, sulfuric compounds, phenol/indoles, volatile fatty acids. The main odorants were hydrogen sulfide (41.3%) and 4-methylphenol (p-cresol, 13.9%). In the swine slurry storage, hydrogen sulfide (33.7%), ammonia (18.8%), and 3-methylindole (skatole, 15.7%) were the main odorants, and hydrogen sulfide (31%) and i-valeric acid (32.4%) were the main odorants in the cattle farms.
The correlation analysis between odor sensor and air dilution olfactometry method with odor emission facilities was performed for the real-time evaluation of odor emitted from the 13 facilities. The total correlation was less significant for all facilities due to various emission characteristics of odor. The correlation for the individual facility, however, showed a higher correlation coefficient (R=0.7371~0.9897). Especially, the strong correlation (above 0.9) was observed for the industry type with the odor characteristics like tobacco, styrofoam, acetic acid, and burning smell. The repeated odor measurements using the odor sensor showed good reproducibility with the mean relative standard deviation of 5.06%. The odor sensor could be useful tools for identifying and evaluating odor with an olfactometry in field, if the use and proofreading of the odor sensor are improved by a standardized method.
This research is carried out to investigate the odor emission characteristics in a sewage treatment plant. The plantwas divided into four areas (boundary areas, sewage treatment processes, sludge treatment processes and odortreatment plants), and measured around 27 sampling points. Odor characteristics from each areas were evaluatedby air dilution olfactory method and NH₃/SO₂/VOCs passive sampler, mainly in terms of spatial distribution. Themain odor emission sources were found out to be dewatering plant (S-4) of sludge, sludge transshipment place(S-5), and the outlet of odor treatment plant (B-2, B-3). The correlation between dilution number (OU) and ammoniaconcentration of passive sampler appeared to be low; correlation coefficient 0.49, but correlation coefficient for theresults of sulfur dioxide and toluene were very high, 0.95 and 0.93, respectively. These results indicate that odorcompounds form sewage treatment facility are mainly due to sulfur compounds and volatile organic compounds.
본 연구에서는 공공하수처리시설의 효율적인 관리방안 제시를 위하여 2008년~2010년까지 28개소의 공공하수처리시설에 대하여 복합악취와 지정악취물질(22종)을 대상으로 악취실태조사 및 원인분석을 실시하였다. 조사결과 전처리 공정과 슬러지 처리공정에서 주로 고농도의 악취가 발생되고 있었으며, 황화수소와 메틸머캅탄 등의 황화합물류가 주요 악취원인물질로 조사되었다. 공공하수처리시설에서 발생되는 악취는 유입수의 성상에 따라 차이가 있으며, 유입수에서의 복합악취는 67배~66,943배, 황화수소는 ND~66.87 ppm으로 조사되었다. A 하수처리시설 유량 조정조에서의 복합악취와 황화수소는 교반시 각각 3,000배, 6.23 ppm, 비교반시 각각 300배, 0.20 ppm으로 조사되었다. 유입 분배조와 생슬러지 분배조는 하수와 슬러지 이송 파이프 라인의 낙차에 의해 내부에 양(+)압이 형성되므로 파이프 라인의 연장과 악취포집설비를 정상적으로 설치․운영하여 내부를 음(-)압 상태로 유지할 필요가 있다.
The present study investigated the concentration of gaseous odor emitted from paint manufacturing facilities and the cases of improvement for odor emission reduction. It was found that the companies located in odor management district observed the odor emission standard more than the companies located in other local industrial complex. We ascribed the reason to the continuous crackdown by local government and voluntary efforts of each companies. Finally, we described the improvement cases of process for odor emission reduction.
This study was conducted to show the odor emission characteristics between the well maintained environment fundamental facility and the poorly maintained environmental facility. It also draws major components of odor emission based on facilities, stages, and suggest the proper way to reduce the level of odor for insufficient facilities. Insufficient facilities" air direct sensory and air dilution value levels are following: foodwaste > livestock > wastewater > night-soil > sewage. For the sewage and waste water facilities, the common characteristic of odor emission on each fundamental facility showed higher air dilution value in depositing reservoir and concentrator. And sulfur and aldehyde compounds came out to be the major odor causing components. In the case of night-soil and livestock facilities, the air dilution value was high in flow equalization tank and liquid erosion tank. And sulfur as well as ammonia component was the major malodorous substance. Foodwaste facility showed higher air dilution value than other facility, which sulfur and acetaldehyde compounds were acting as major malodorous substances.
This study was performed to obtain the emission characteristics of odor compounds generated from a livestock wastewater treatment process. The sampling of odor compounds was performed twice, on May 9th and June 14th 2006, at 4 and 5 sites in the boundary and source areas, respectively. The odor concentrations obtained from the air dilution sensory test ranged from 10 to 100 in the boundary area. Of the 5 source sites, the odor concentrations found at the pre-treatment building had the highest values, which were 14422 and 20800 for the first and second dates, respectively. To estimate the major odor compounds produced during a live wastewater process, the contributions of 12 odor compounds to the total odor were calculated from the concentration and odor threshold values of each compound. At the pre-treatment building and outlet of the activated carbon tower of the source sites, the contribution of sulfur compounds to the odor was 97%, and at the outlet of the biofilter that of NH₃ was 90%. The order of the contribution to the odor in the boundary area sites was; from highest to lowest: H₂S, C₂H₆S, i-C₅H10O, C₃H₉N, NH₃. The correlation coefficient between the theoretical odor concentration from the odor threshold of 12 odor compounds and that obtained from the air dilution sensory test was 0.73. This result indicated a limit to the correct analysis of the odor concentration obtained from the air dilution sensory test when only 12 odorous compounds at a livestock wastewater treatment process are used. The odor removal efficiency of the deodorization facilities showed that for the activation carbon tower, the odor concentration was reduced to 4% and the contributions of H₂S, C₂H₆S and NH₃, which were estimated to be the major odor compounds, were reduced to 20, 26 and 11%, respectively. With respect to the bio-filter, the removal efficiency of the odor compounds revealed an odor concentration of 0% because the major odor compounds were calculated as negative percentages.
The odor emission characteristics in a food waste treatment plant, in terms of odor active compounds and odor unit concentration, were evaluated using an air dilution method and instrumental analysis method, respectively. A GC/MS analysis of the emission source was also carried out to investigate the effect of waste polymer incineration on the formation of organic materials. The result, as evaluated using the instrumental analysis method, showed that ammonia, acetaldehyde, dimethylsulfide and propionaldehyde were detected in high amounts from the outlet at "A" food waste treatment plant. The major odorous compounds, however, were acetaldehyde and metylmercaptan, which were derived using an odor quotient method. Limonene, benzene and toluene were also detected from the GC/MS analysis of the emission source. The criteria were 500 at the final outlet, 15 at the site boundary line, but the observed results were 10000 and 30, respectively.
Emission characteristics of gaseous odor compounds emitted from the charcoal manufacturing process were investigated, and evaluated the odor removal efficiency of odor control devices. It was found that the measured odor dilution ratio of emission gases ranged from 10,000 to 44,814, which exceed largely the emission standard in the stack. Methylmercaptan, trimethylamine, hydrogen sulfide, acetaldehyde were turned out as major odor compounds of the charcoal manufacturing process. It was revealed that the odor removal ratio of odor control devices were very low due to the its improper maintenance and wrong design.