Fluorine-doped tin oxide (FTO) has been used as a representative transparent conductive oxide (TCO) in various optoelectronic applications, including light emitting diodes, solar cells, photo-detectors, and electrochromic devices. The FTO plays an important role in providing electron transfer between active layers and external circuits while maintaining high transmittance in the devices. Herein, we report the effects of substrate rotation speed on the electrical and optical properties of FTO films during ultrasonic spray pyrolysis deposition (USPD). The substrate rotation speeds were adjusted to 2, 6, 10, and 14 rpm. As the substrate rotation speed increased from 2 to 14 rpm, the FTO films exhibited different film morphologies, including crystallite size, surface roughness, crystal texture, and film thickness. This FTO film engineering can be attributed to the variable nucleation and growth behaviors of FTO crystallites according to substrate rotation speeds during USPD. Among the FTO films with different substrate rotation speeds, the FTO film fabricated at 6 rpm showed the best optimized TCO characteristics when considering both electrical (sheet resistance of 13.73 Ω/□) and optical (average transmittance of 86.76 % at 400~700 nm) properties with a figure of merit (0.018 Ω-1).

High-Manganese (Mn) austenitic steel, with over 24 wt% Mn content, offers outstanding mechanical properties in cryogenic settings, making it a potential replacement for existing cryogenic materials. This high manganese steel exhibits high strength, ductility, and wear resistance, making it promising for applications like LNG tanks, flanges, and valves. To operate in cryogenic environments, hot forging and heat treatment processes are vital, especially in flange production. The cooling rate during high-temperature cooling after hot forging plays a critical role in influencing the microstructure and mechanical properties of high manganese steel. The rate at which cooling occurs during this process influences the size of the grains and the distribution of manganese and consequently has an impact on mechanical properties. This study assessed the microstructure and mechanical properties based on different cooling rates during the hot forging of High-Mn steel flanges. Comparing air and water cooling after hot forging, followed by heat treatment, revealed notable differences in grain size. These differences directly impacted mechanical properties such as tensile strength, hardness, and Charpy impact property. Understanding these effects is crucial for optimizing the performance and reliability of High-Mn steel in cryogenic applications.

The heat transfer characteristics of double-pipe spiral heat exchanger were investigated by various curvature sizes, experimentally. The three different sizes of heat exchanger were made and tested with water as a working fluid to analyze the heat transfer characteristics. The heat transfer rates, overall heat transfer coefficient and pressure drop were analyzed with various heat exchanger sizes (i.e., curvature ratios). As result, the heat transfer rate increased with increasing the size of the heat exchanger as the flow rate increased due to increasing the area size of heat transfer. However, the overall heat transfer coefficient and pressure drop increased with decreasing the heat exchanger size (i.e., increased curvature ratio) due to the enhanced centrifugal force and inertia.

Decarbonization plays an important role in future energy systems for establishing a zero-carbon society. Hydrogen is believed to be a promising energy source that can be converted, stored, and utilized efficiently, leading to a broad range of possibilities for future applications. Hydrogen can be stored in various forms, including compressed gas, liquid hydrogen, hydrides, adsorbed hydrogen. Among these, liquid hydrogen has high gravimetric and volumetric hydrogen densities. There are a lot of previous studies on thermal behavior of MLI and VCS and optimization insulation system, but research on the insulation performance by varying the head shape of the tank has not been conducted. In this study, thermal-structural coupled analysis was conducted on the insulation system with VCS positioned between two layers of MLI for a liquid hydrogen storage tank. The analysis considered dome shapes (torispherical, circle, ellipses), and heat flux and temperature were derived from thermal analysis to predict insulation performance. Maximum equivalent stress and deformation were calculated from the structural analysis, and the optimal dome shape was proposed.

High-entropy alloys (HEAs) are characterized by having five or more main elements and forming simple solids without forming intermetallic compounds, owing to the high entropy effect. HEAs with these characteristics are being researched as structural materials for extreme environments. Conventional refractory alloys have excellent hightemperature strength and stability; however, problems occur when they are used extensively in a high-temperature environment, leading to reduced fatigue properties due to oxidation or a limited service life. In contrast, refractory entropy alloys, which provide refractory properties to entropy alloys, can address these issues and improve the hightemperature stability of the alloy through phase control when designed based on existing refractory alloy elements. Refractory high-entropy alloys require sufficient milling time while in the process of mechanical alloying because of the brittleness of the added elements. Consequently, the high-energy milling process must be optimized because of the possibility of contamination of the alloyed powder during prolonged milling. In this study, we investigated the hightemperature oxidation behavior of refractory high-entropy alloys while optimizing the milling time.

UV and O3 are materials used in the water treatment process, and many studies have been reported to remove organic matters, contaminants, and microorganisms. In this study, we were investigated effects of Chirnomidae (Chironomus flaviplumus, Chironomus riparius), which are contamination indicator species to exposure UV and O3 for the survival rate, body color change and gene expression response. The survival rate of C. flaviplumus exposed to UV decreased to about 70% after 24 hours, and C. riparius about 50%. There was no change in the survival rate of C. flaviplumus exposed to O3, and C. riparius decreased to 95% after 10 minutes of exposure, but there was no change during the subsequent exposure time. In addition, UV and O3 exposure to the two species in body color faded in a time-dependent. In the HSP70 gene expression, C. riparius showed an increase in expression after UV exposure compared to the control group, and a significant difference was shown 12 hours after exposure (P<0.05). C. flaviplumus exposed to O3 showed a relatively low expression compared to the control group, and showed a significant difference at 10 minutes and 1 hour after exposure (P<0.05). These results reported the ecotoxicological effects on Chironomidae according to UV and O3 exposure. Therefore, the results of this study can be used as basic data to understand the effects of UV and O3, which are disinfectants used in water treatment plants, on Chirnomidae entering plants. Key words: Chironomus flaviplumus, Chironomus riparius, UV, O3, acute toxicity, survival

Numerous factors contribute to the deterioration of reinforced concrete structures. Elevated temperatures significantly alter the composition of the concrete ingredients, consequently diminishing the concrete's strength properties. With the escalation of global CO2 levels, the carbonation of concrete structures has emerged as a critical challenge, substantially affecting concrete durability research. Assessing and predicting concrete degradation due to thermal effects and carbonation are crucial yet intricate tasks. To address this, multiple prediction models for concrete carbonation and compressive strength under thermal impact have been developed. This study employs seven machine learning algorithms—specifically, multiple linear regression, decision trees, random forest, support vector machines, k-nearest neighbors, artificial neural networks, and extreme gradient boosting algorithms—to formulate predictive models for concrete carbonation and thermal impact. Two distinct datasets, derived from reported experimental studies, were utilized for training these predictive models. Performance evaluation relied on metrics like root mean square error, mean square error, mean absolute error, and coefficient of determination. The optimization of hyperparameters was achieved through k-fold cross-validation and grid search techniques. The analytical outcomes demonstrate that neural networks and extreme gradient boosting algorithms outshine the remaining five machine learning approaches, showcasing outstanding predictive performance for concrete carbonation and thermal effect modeling.

This study focuses on heat-induced gelation of pea (Pisum sativum L.) proteins to assess the potential of pea protein aggregates (PPA) as novel plant-based meat alternatives. The microstructural (SEM, CLSM), mechanical (TPA analysis), and rheological properties (G', G'') of heat-induced gels at pH 2 were systematically investigated as a function of a different pea protein concentration (7.5, 10, 12.5%) and a varying heating time (1, 3, 6, 16 h). The result showed that PPA formation at higher protein concentration and heating time contributed to a homogenous and compact heat-induced gel formation. Such gel network strengthened mechanical properties in terms of high gel hardness (40 g) and elastic texture (2.7 mm springiness). For the rheological studies, the storage modulus (G') showed an increase during both the heating and cooling phases and then stabilized during the cooled-holding phase. This suggested that the formation of durable and stable gel was induced due to the decreased mobility of protein aggregates at low temperatures. Therefore, the PPA is indicated as a potential additive for enhancing the food texture quality in the plant-based meat food industry.

In electric vehicles, the core is a secondary cell battery. Raw material is pulverized by the grinding disc in the Classifier Separator Mill (CSM) and rises through the Classifier Wheel. Both require characteristics to withstand high-speed rotation, including abrasion, corrosion, and shock. Our study analyzes the impact of RPM and heat source on temperature, convergence, and durability. In conclusion, high heat increases flow, while high RPM reduces the maximum temperature but may harm durability. Proper RPM settings enhance durability.

High-strength low-alloy steel is one of the widely used materials in onshore and offshore plant engineering. We investigated the alloying effect of solute atoms in α-Fe based alloy using ab initio calculations. Empirical equations were used to establish the effect of alloying on the Vicker’s hardness, screw energy coefficient, and edge dislocation energy coefficient of the steel. Screw and edge energy coefficients were improved by the addition of V and Cr solute atoms. In addition, the addition of trace quantities of V, Cr, and Mn enhanced abrasion resistance. Solute atoms and contents with excellent mechanical properties were selected and their thermal conductivity and thermal expansion behavior were investigated. The addition of Cr atom is expected to form alloys with low thermal conductivity and thermal expansion coefficient. This study provides a better understanding of the state-of-the-art research in low-alloy steel and can be used to guide researchers to explore and develop α-Fe based alloys with improved properties, that can be fabricated in smart and cost-effective manners.

본 연구에서는 강한 내열성을 가지는 비병원성 Bacillus atrophaeus, Bacillus subtilis, Geobacillus stearothermophilus 포자의 열 저항성을 분석하여 레토르트 식품 제조 시 직 접적인 멸균 여부 판정에 사용 가능성을 평가하고자 하였 다. B. subtilis 포자의 D121-value는 2.9±0.1분이었으며, Zvalue는 43.0±1.4oC로 나타났다. G. stearothermophilus 포 자의 D121-value는 4.3±0.1분이었으며, Z-value는 25.0±1.6oC 로 나타났다. B. atrophaeus 포자의 D121-value는 3.7±0.1분 이었으며, Z-value는 35.8±1.4oC로 나타났다. B. subtilis, G stearothermophilus와 B. atrophaeus 포자의 D121-value는 모 두 레토르트 식품 멸균 확인에 사용되는 C. botulinum 포 자의 D121-value 보다 높은 값을 나타내었다. 이러한 결과 를 종합하여 볼 때 레토르트 식품 멸균 시 병원성 포자형 성균인 C. botulinum 대신 B. subtilis, G. stearothermophilus, B. atrophaeus 포자를 사용할 수 있을 것으로 판단된다. 또 한 기존 세균발육 실험에 소요되는 13일보다 단시간인 2- 3일에 멸균 여부를 확인할 수 있을 것으로 판단된다.

With the increasing number of aging buildings across Korea, emerging maintenance technologies have surged. One such technology is the non-contact detection of concrete cracks via thermal images. This study aims to develop a technique that can accurately predict the depth of a crack by analyzing the temperature difference between the crack part and the normal part in the thermal image of the concrete. The research obtained temperature data through thermal imaging experiments and constructed a big data set including outdoor variables such as air temperature, illumination, and humidity that can influence temperature differences. Based on the collected data, the team designed an algorithm for learning and predicting the crack depth using machine learning. Initially, standardized crack specimens were used in experiments, and the big data was updated by specimens similar to actual cracks. Finally, a crack depth prediction technology was implemented using five regression analysis algorithms for approximately 24,000 data points. To confirm the practicality of the development technique, crack simulators with various shapes were added to the study.

Radiant tubes heat exchangers are critical components that facilitate the heat transfer process to steel in an annealing furnace, and it addresses several engineering problems, such as thermal stress and mechanical failure due to long-term thermal cycling, which can significantly affect the longevity of the tubes and maintenance requirements. In this study, we used commercial software (ANSYS) to simulate the thermal stress and deformation of radiant tubes subjected to extreme thermal conditions and pressure loads. We evaluated both thermally induced deformation and creep deformation, which is a time-dependent deformation under constant stress over the long term. The results showed that uneven temperature conditions and pressure loads lead to significant deformation and potential failures. To mitigate these engineering challenges, we also tested several designs that include supporting brackets. This study provides valuable insights for designing radiant tube heat exchangers in annealing furnaces to extend their lifespan and ensure system safety.

Hydrogen is considered as one of the most promising future energy carriers due to its noteworthy advantages of renewable and high calorific value. The long-term storage of liquid hydrogen with low heat leakage is essential for future deep space exploration. Because of low critical temperature and volatility, liquid hydrogen tank poses severe requirements to multi-layer insulation (MLI). In order to reduce heat leak into tank, vapor cooled shield (VCS) was set up to cool MLI by retrieving the heat of discharged cryogenic gas hydrogen. This paper presents an parametric study on insulation system in liquid hydrogen storage vessel with MLI and VCS. Thermal model was developed, and heat transfer analysis by varying VCS position was conducted. Temperature and heat flux distributions along time passing were derived, and effect of VCS position on insulation performance was investigated.

Cesium lead iodide (CsPbI3) with a bandgap of ~1.7 eV is an attractive material for use as a wide-gap perovskite in tandem perovskite solar cells due to its single halide component, which is capable of inhibiting halide segregation. However, phase transition into a photo inactive δ-CsPbI3 at room temperature significantly hinders performance and stability. Thus, maintaining the photo-active phase is a key challenge because it determines the reliability of the tandem device. The dimethylammonium (DMA)-facilitated CsPbI3, widely used to fabricate CsPbI3, exhibits different phase transition behaviors than pure CsPbI3. Here, we experimentally investigated the phase behavior of DMA-facilitated CsPbI3 when exposed to external factors, such as heat and moisture. In DMA-facilitated CsPbI3 films, the phase transition involving degradation was observed to begin at a temperature of 150 °C and a relative humidity of 65 %, which is presumed to be related to the sublimation of DMA. Forming a closed system to inhibit the sublimation of DMA significantly improved the phase transition under the same conditions. These results indicate that management of DMA is a crucial factor in maintaining the photo-active phase and implies that when employing DMA designs are necessary to ensure phase stability in DMA-facilitated CsPbI3 devices.

먼지 필터 막은 인간의 건강, 안전 및 환경 보호의 몇 가지 중요한 측면에 기여하기 때문에 인간의 삶과 다양한 산업에서 중요한 역할을 한다. 이 연구는 고온 조건에 대한 우수한 열안정성과 접착 특성을 가진 polysulfone@polyphenylene sulfide/polytetrafluoroethylene (PSf@PPS/ePTFE) 복합 먼지 필터 막의 개발을 제시한다. FT-IR 분석은 PSF 접착제가 PPS 직 물에 성공적으로 함침되고 ePTFE 지지체와의 상호 작용을 확인한다. FE-SEM 이미지는 향상된 섬유 상호 연결 및 PSf 농도 와 함께 접착력을 보여준다. PSf@PPS/ePTFE-5는 가장 적합한 다공성 구조를 보여준다. 복합 막은 400°C까지 예외적인 열 안정성을 보여준다. 박리 저항 테스트는 먼지 여과에 대한 충분한 접착력을 보여 공기 투과성을 희생시키지 않고 힘든 고온 조건에서 신뢰할 수 있는 성능을 보장한다. 이 막은 산업 응용 분야에서 유망한 잠재력을 제공한다. 더 나아가 최적화 및 응 용 가능성을 탐구할 수 있다.

One-dimensional MgO nanostructures with various morphologies were synthesized by a thermal evaporation method. The synthesis process was carried out in air at atmospheric pressure, which made the process very simple. A mixed powder of magnesium and active carbon was used as the source powder. The morphologies of the MgO nanostructures were changed by varying the growth temperature. When the growth temperature was 700 °C, untapered nanowires with smooth surfaces were grown. As the temperature increased to 850 °C, 1,000 °C and 1,100 °C, tapered nanobelts, tapered nanowires and then knotted nanowires were sequentially observed. X-ray diffraction analysis revealed that the MgO nanostructures had a cubic crystallographic structure. Energy dispersive X-ray analysis showed that the nanostructures were composed of Mg and O elements, indicating high purity MgO nanostructures. Fourier transform infrared spectra peaks showed the characteristic absorption of MgO. No catalyst particles were observed at the tips of the one-dimensional nanostructures, which suggested that the one-dimensional nanostructures were grown in a vapor-solid growth mechanism.

본 연구에서는 육계사에 차열 페인트와 히트펌프의 적용에 따른 내부 온도 변화를 분석 하였다. 이를 위하여 환기율, 환기 방법, 시간별 환기 변화에 따른 실험 조건을 설정하였으며 육 계사 외부 및 내부 기온을 측정하였다. 그 결과, 차열 페인트를 도포한 육계사에서는 최대 1－2°C 실내 기온 상승을 억제하 는 효과가 나타났으며 히트펌프를 가동한 육계사에서는 외기 온도의 영향을 제일 적게 받는 환기율 0%일 때 내부 기온 감소 가 제일 크게 나타났다. 계사 내부의 온도가 외기 온도보다 높 을 경우에는 환기율을 높게 설정하여 환기팬을 이용한 냉방이 더욱 효과적이나 계사 내부 온도가 외기 온도와 유사하거나 낮을 경우에는 히트펌프를 이용하는 것이 가장 효과적일 것으 로 판단된다. 히트펌프 가동 시 외기 온도의 영향이 적은 환기 율을 0%로 설정하였을 때 내부 기온이 가장 큰 폭으로 감소하 였으나 실제 육계사에서는 분진, 이물질, 암모니아 등을 고려 하여 최소환기율 정도로 환기율을 설정한 후 히트펌프를 가동 하는 것이 가장 효율적일 것으로 판단된다. 본 연구는 실험 기 간이 짧아 데이터가 많지 않으며 실제 육계가 사육되고 있는 환경에서 실험을 진행한 것이 아니라는 한계가 있다. 향후 후 속 연구로 실제 닭이 사육되고 있는 환경에서의 히트펌프 효 과 분석과 히트펌프의 전력사용량, 냉방부하, 환기팬 가동시 간 등 다양한 환경인자를 포함한 연구가 진행되어야 할 것으 로 판단된다.