원자력 발전소에 설치되는 안전관련 기기의 손상은 심각한 사고로 이어질 수 있으므로 반듯이 지진안전성을 확보하여야 한 다. MCC, Switchgear, Inverter, Battery charger 등의 전기캐비닛은 대표적인 안전관련 기기이다. 대부분의 실험적 연구는 실험대 상기기의 크기와 실험장비의 성능한계 등으로 인하여 주요부품을 대상으로 하며, 실제 원자력발전소에 납품하는 전기캐비닛을 이용하 여 3축 동시가진에 의한 진동대 실험을 수행한 연구는 많지 않다. 따라서 실제기기를 대상으로 3축 진동대 실험을 통하여 내진성능과 한계상태를 직접적으로 평가하기 위한 연구가 필요하다. 이러한 한계상태평가의 주요 목적은 다양한 부품으로 구성된 캐비닛 단위 실 제기기의 임계 가속도 및 고장 모드를 조사하는 것이다. 본 논문에서는 3축 진동대 실험으로 한계상태 내진성능실험을 수행하여 원자 력발전소에 납품되는 것과 동일한 4종의 전기캐비닛들의 한계상태를 분석하였다.
Alluvial beds are intimately associated with electrical properties related to soil types, including clay mineral content, porosity, and water content. The hydraulic property governs water movement and storage in alluvial beds. This study revealed electrical resistivity and hydraulic properties in space and time in relation to the hydrogeological data, groundwater pumping, and rainfall infiltration into the alluvial bed located in Daesan-myeon, Changwon City. An electrical resistivity survey with electrode spacings of 2 and 4m using a dipole-dipole array indicates that electrical resistivity changes in the alluvial bed depend on groundwater pumping and rainfall events. Additionally, rainfall infiltration varies with hydraulic conductivity in the shallow zone of the alluvial bed. The 2 m electrode spacing survey confirms that electrical resistivity values decrease at shallow depths, corresponding with rainfall and increased water content in the soil, indicating rainfall infiltration approximately 1-2 m below the land surface. The 4m electrode spacing survey reveals that hydraulic conductivity (K) values and electrical resistivity (ρ) values display an inverse relationship from the surface to the water table (approximately 9 m) and at deeper levels than the water table. Notably, ρ values are impacted by pumping around the depth of the water table at 9 m. This study suggests that time-lapsed electrical resistivity surveys in space and time could be effective tools for detecting the impact of rainfall and pumping, as well as hydraulic conductivity in shallow alluvial beds.
Carbon fibers of polyacrylonitrile (PAN) type were coated with nickel nanoparticles using a chemical reduction method in alkaline hydrazine bath. The carbon fibers were firstly heated at 400 °C and then chemically treated in hydrochloric acid followed by nitric acid to clean, remove any foreign particles and functionalized its graphitic surfaces by introducing some functional groups. The functionalized carbon fibers were coated with nickel to produce 10 wt% Cf/Ni nanocomposites. The uncoated heat treated and the nickel coated carbon fibers were investigated by SEM, EDS, FTIR and XRD to characterize the particle size, morphology, chemical composition and the crystal structure of the investigated materials. The nickel nanoparticles were successfully deposited as homogeneous layer on the surface of the functionalized carbon fibers. Also, the deposited nickel nanoparticles have quazi-spherical shape and 128–225 nm median particle size. The untreated and the heat treated as well as the 10 wt% Cf/Ni nanocomposite particles were further reinforced in ethylene vinyl acetate (EVA) polymer separately by melt blending technique to prepare 0.5 wt% Cf-EVA polymer matrix stretchable conductive composites. The microstructures of the prepared polymer composites were investigated using optical microscope. The carbon fibers as well as the nickel coated one were homogenously distributed in the polymer matrix. The obtained samples were analyzed by TGA. The addition of the nickel coated carbon fibers to the EVA was improved the thermal stability by increasing the thermal decomposition temperature Tmax1 and Tmax2. The electrical and the mechanical properties of the obtained 10 wt% Cf/Ni nanocomposites as well as the 0.5 wt% Cf-EVA stretchable conductive composites were evaluated by measuring its thermal stability by thermogravimetric analysis (TGA), electrical resistivity by four probe method and tensile properties. The electrical resistivity of the fibers was decreased by coating with nickel and the 10 wt% Cf/Ni nanocomposites has lower resistivity than the carbon fibers itself. Also, the electrical resistivity of the neat EVA is decreased from 3.2 × 1010 to 1.4 × 104 Ω cm in case of the reinforced 0.5 wt% Cf/Ni-EVA polymer composite. However, the ultimate elongation and the Young’s modulus of the neat EVA polymer was increased by reinforcing with carbon fibers and its nickel composite.
In this study, four different samples of Se60Ge40-xBix chalcogenides glasses were synthesized by heating the melt for 18 h in vacuum Pyrex ampoules (under a 10-4 Torre vacuum), each with a different concentration (x = 0, 10, 15, and 20) of high purity starting materials. The results of direct current (DC) electrical conductivity measurements against a 1,000/T plot for all chalcogenide samples revealed two linear areas at medium and high temperatures, each with a different slope and with different activation energies (E1 and E2). In other words, these samples contain two electrical conduction mechanisms: a localized conduction at middle temperatures and extended conduction at high temperatures. The results showed the local and extended state parameters changed due to the effective partial substitution of germanium by bismuth. The density of extended states N(Eext) and localized states N(Eloc) as a function of bismuth concentration was used to gauge this effect. While the density of the localized states decreased from 1.6 × 1014 to 4.2 × 1012 (ev-1 cm-3) as the bismuth concentration increased from 0 to 15, the density of the extended states generally increased from 3.552 × 1021 to 5.86 × 1021 (ev-1 cm-3), indicating a reduction in the mullet’s randomness. This makes these alloys more widely useful in electronic applications due to the decrease in the cost of manufacturing.
The development of thermoelectric (TE) materials to replace Bi2Te3 alloys is emerging as a hot issue with the potential for wider practical applications. In particular, layered Zintl-phase materials, which can appropriately control carrier and phonon transport behaviors, are being considered as promising candidates. However, limited data have been reported on the thermoelectric properties of metal-Sb materials that can be transformed into layered materials through the insertion of cations. In this study, we synthesized FeSb and MnSb, which are used as base materials for advanced thermoelectric materials. They were confirmed as single-phase materials by analyzing X-ray diffraction patterns. Based on electrical conductivity, the Seebeck coefficient, and thermal conductivity of both materials characterized as a function of temperature, the zT values of MnSb and FeSb were calculated to be 0.00119 and 0.00026, respectively. These properties provide a fundamental data for developing layered Zintl-phase materials with alkali/alkaline earth metal insertions.
본 연구에서는 경피신경전기자극(TENS)을 이용하여 다양한 자극 강도에 따른 뇌혈관에 미치는 영향을 확인하고 자 한다. 특히 비지각적 감각의 전기자극을 통해 총경동맥(CCA)에서의 혈류 변화 및 혈관의 구조적인 변화를 확인 해 보고자 한다. 본 연구에는 20대의 건강한 성인 24명이 참여하였다. 자극 강도는 감각 역치 미만, 감각 역치, 그리 고 감각 역치 초과 세 가지를 각각 랜덤 순서로 적용하였다. 측정위치는 CCA 분기점의 1cm 하단에서 측정하였고, 혈류속도는 C-mode 도플러, 혈관의 구조는 B-mode 영상을 통해 측정하였다. 측정은 각각의 자극별로 중재 전, 중재 중, 그리고 중재 후에 수행하였고 각 세션마다 혈압의 변화를 측정하였다. 그 결과 최고 수축기 속도(PSV)는 역치 미만의 비지각적 감각자극에서 중재 후 유의하게 감소함이 확인되었다(p = .008). 역치 미만의 자극 후 PSV는 자극 전보다 평균 3.04% 유의하게 감소한 것으로 나타났다(p = .011). 반면 CCA의 혈관 직경의 변화는 모든 강도에서 자극 전후 유의한 변화가 나타나지 않았다. 본 연구에서 적용한 단시간의 비지각적 전기자극이 혈관의 직경이나 혈 압의 유의한 변화를 주지 않으면서 즉각적인 혈류속도 감소에 효과가 있음을 발견했다. 따라서 본 연구는 경동맥 부위에 환자의 불편함과 부작용이 없는 전기자극을 통해 뇌혈류의 조절이 가능하다는 것을 보여주는 중요한 시도로 평가될 수 있다.
In this study, the aromatic carbon content of epoxy resin (EP) increased via carbon tar pitch (CTP) modification, and the CTP occurred self-polymerization reaction. The carboxyl and hydroxyl groups of CTP and the hydroxyl and carboxyl groups of EP occurred chemical cross-linking reaction. CTP and graphitization treatment promoted EP CF carbon crystal growth. The graphitization degree of pure EP CF and 40 wt% CTP modified EP CF are 8.42% and 44.21%, respectively. With the increase CTP content, the cell size, ligament junction and density of graphitization modified EP CF gradually increased, while the number of pores and cells gradually decreased. The cell size, ligament junction size and density of 40 wt% CTP modified graphitization EP CF increased to 1200 μm, 280 μm and 0.5033 g/cm3, respectively. EP CF exhibits entangling carbon ribbon and isotropic amorphous carbon. The 40 wt% CTP modified EP CF is composed of evenly distributed amorphous resin carbon and graphite domain CTP carbon. The graphitization modified EP CF improved electrical conductivity, and the electrical conductivity of 40 wt% CTP modified EP CF is 126.6 S/m. The compressive strength can be decided by EP carbon strength and its char yield, and graphitization 40 wt% CTP modified EP CF reached 4.9 MPa. This study provides some basis for preparation and application of CTP modified EP CF.
In the present study, the effects of electrodes type (copper, steel or CFRP) and design (plate or mesh) on electrical stability of conductive cement as exposed to various weathering conditions were investigated. To fabricate these composites, multiwalled carbon nanotube and carbon fiber were added to the cement composites by 0.6 and 0.4% by cement mass. Seven different types of electrodes were embedded to the samples, and their electrical stability was examined during the curing period. In addition, the fabricated samples were exposed to water ingress and cyclic heating conditions. Then, the compressive strength of the samples was evaluated to observe the interfacial bonding between the cement paste and electrodes. Based on the experimental results, it was found that the samples showed different electrical stability even their mix proportion was same. Thus, it can be concluded that the type and design of the electrodes are important in measuring the electrical properties of the conductive cement composites. Specifically, an improved electrical stability of electrodes is required when they are exposed to various weathering conditions.
전기 캐비닛은 병원 및 발전소와 같은 중요 시설물에서 운영과 관리를 위한 시스템 기기를 보관한 다. 지진과 같은 극한하중 하에서 중요 시설물은 지속적으로 운영 및 제어되어야 하기 때문에 전기 캐 비닛의 안전성은 평가되고 확보되어야 한다. 하지만 실험적 연구만으로 다양한 유형의 전기 캐비닛에 대한 내진성능 평가를 수행하는 것은 많은 제약이 있다. 따라서 다양한 연구자들은 전기 캐비닛의 유 한요소 모델을 구축하고 내진성능 평가를 수행하였다. 유한요소 모델은 beam-stick 요소를 기반으로 구축되거나 3차원 shell 요소를 기반으로 구축되어왔다. Beamk-stick 요소 기반 및 3차원 shell 요소 기반의 유한요소 모델에 대한 전체거동에 대한 비교를 수행한 사례는 있으나 국부거동에 대한 동적응 답을 비교한 연구사례는 없다. 전기 캐비닛은 내부에 시스템 기기가 보관되므로 내부의 국부거동 기반 의 내부응답을 포착할 수 있어야한다. 따라서 본 연구는 단문형 전기 캐비닛에 대한 beam-stick 요소 및 3차원 shell요소를 기반으로 유한요소 모델을 구축하고 동일한 높이에서 가속도 응답을 비교하였다. 결과적으로 beam-stick 요소 기반의 3차원 유한요소 모델은 전기 캐비닛 내부 응답 스펙트럼을 정확 히 예측할 수 없기 때문에 내부 응답 스펙트럼을 위해서는 3차원 shell요소 기반의 상세 유한요소 모 델을 사용해야 한다.
Ni-CNT nanocomposites were synthesized via the electrical explosion of wire (EEW) in acetone and deionized (DI) water liquid conditions with different CNT compositions. The change in the shape and properties of the Ni-CNT nanopowders were determined based on the type of fluids and CNT compositions. In every case, the Ni nanopowder had a spherical shape and the CNT powder had a tube shape. However, the Ni-CNT nanopowders obtained in DI water exhibited irregular shapes due to the oxidation of Ni. Phase analysis also revealed the existence of nickel oxide when using DI water, as well as some unknown peaks with acetone, which may form due to the metastable phase of Ni. Magnetic properties were investigated using a Vibrating Sample Magnetometer (VSM) for all cases. Nanopowders prepared in DI water conditions had better magnetic properties than those in acetone, as evidenced by the simultaneous formation of super paramagnetic NiO peaks and ferromagnetic Ni peaks. The DI water (Ni:CNT = 1:0.3) sample revealed better magnetic results than the DI water (Ni-CNT = 1:0.5) because it had less CNT contents.
Silicon carbide (SiC) has emerged as a promising material for next-generation power semiconductor materials, due to its high thermal conductivity and high critical electric field (~3 MV/cm) with a wide bandgap of 3.3 eV. This permits SiC devices to operate at lower on-resistance and higher breakdown voltage. However, to improve device performance, advanced research is still needed to reduce point defects in the SiC epitaxial layer. This work investigated the electrical characteristics and defect properties using DLTS analysis. Four deep level defects generated by the implantation process and during epitaxial layer growth were detected. Trap parameters such as energy level, capture-cross section, trap density were obtained from an Arrhenius plot. To investigate the impact of defects on the device, a 2D TCAD simulation was conducted using the same device structure, and the extracted defect parameters were added to confirm electrical characteristics. The degradation of device performance such as an increase in on-resistance by adding trap parameters was confirmed.
In this investigation, samples of the chemical (Hg1-xPbxBa2Ca1.8Mg0.2Cu3O8+δ) were prepared utilizing a solid-state reaction technique with a range of lead concentrations (x = 0.0, 0.05, 0.10, and 0.20). Specimens were pressed at 8 tons per square centimeter and then prepared at 1,138 K in the furnace. The crystalline structure and surface topography of all samples were examined using X-ray diffraction (XRD) and atomic force microscopy (AFM). X-ray diffraction results showed that all of the prepared samples had a tetragonal crystal structure. Also, the results showed that when lead was partially replaced with mercury, an increase in the lead value impacted the phase ratio, and lattice parameter values. The AFM results likewise showed excellent crystalline consistency and remarkable homogeneity during processing. The electrical resistivity was calculated as a function of temperature, and the results showed that all samples had a contagious behavior, as the resistivity decreased with decreasing temperature. The critical temperature was calculated and found to change, from 102, 96, 107, and 119 K, when increasing the lead values in the samples from 0.0 to 0.05, 0.10, and 0.20, respectively.
Fluorine-doped tin oxide (FTO) has been used as a representative transparent conductive oxide (TCO) in various optoelectronic applications, including light emitting diodes, solar cells, photo-detectors, and electrochromic devices. The FTO plays an important role in providing electron transfer between active layers and external circuits while maintaining high transmittance in the devices. Herein, we report the effects of substrate rotation speed on the electrical and optical properties of FTO films during ultrasonic spray pyrolysis deposition (USPD). The substrate rotation speeds were adjusted to 2, 6, 10, and 14 rpm. As the substrate rotation speed increased from 2 to 14 rpm, the FTO films exhibited different film morphologies, including crystallite size, surface roughness, crystal texture, and film thickness. This FTO film engineering can be attributed to the variable nucleation and growth behaviors of FTO crystallites according to substrate rotation speeds during USPD. Among the FTO films with different substrate rotation speeds, the FTO film fabricated at 6 rpm showed the best optimized TCO characteristics when considering both electrical (sheet resistance of 13.73 Ω/□) and optical (average transmittance of 86.76 % at 400~700 nm) properties with a figure of merit (0.018 Ω-1).
Metals are recognized as electromagnetic interference (EMI) shielding materials owing to their high electrical conductivity. However, the need for light and flexible EMI shielding materials has emerged, owing to the heavyweight and inflexible nature of metals. Carbon nanotube (CNT)/polymer composites have been studied as promising flexible EMI shielding materials because of their lightweight nature due to the low density of CNTs and their high electrical conductivity. CNTs evenly dispersed in the polymer form an electrically conductive network, and the aspect ratio of the CNTs, which are one-dimensional nanofillers, is an important factor affecting electrical conductivity. In this study, we prepared three types of multi-walled carbon nanotubes (MWNTs) with different aspect ratios and fabricated polydimethylsiloxane (PDMS)/MWNT composites. Subsequently, the electrical conductivities and electrical percolation thresholds of the three PDMS/MWNT composites with different MWNT aspect ratios were measured to analyze the behavior of electrically conducting network formation according to the aspect ratio. Furthermore, the total EMI shielding effectiveness of each composite was determined to evaluate the effect of the MWNT aspect ratio on the EMI shielding. Reflection and absorption of electromagnetic wave were measured for the PDMS/MWNT composite with the largest aspect ratio to analyze the EMI shielding mechanism of the composite. Additionally, the effects of the MWNT content on the conductivity and EMI shielding performance were examined. The results provide valuable guidance for designing polymer MWNT composites with good electrical conductivity and EMI shielding performance under different aspect ratios of MWNTs.
ZnO/Cu/ZnO (ZCZ) thin films were deposited at room temperature on a glass substrate using direct current (DC) and radio frequency (RF, 13.56 MHz) magnetron sputtering and then the effect of post-deposition electron irradiation on the structural, optical, electrical and transparent heater properties of the films were considered. ZCZ films that were electron beam irradiated at 500 eV showed an increase in the grain sizes of their ZnO(102) and (201) planes to 15.17 nm and 11.51 nm, respectively, from grain sizes of 13.50 nm and 10.60 nm observed in the as deposited films. In addition, the film’s optical and electrical properties also depended on the electron irradiation energies. The highest opto-electrical performance was observed in films electron irradiated at 500 eV. In a heat radiation test, when a bias voltage of 18 V was applied to the film that had been electron irradiated at 500 eV, its steady state temperature was about 90.5 °C. In a repetition test, it reached the steady state temperature within 60 s at all bias voltages.
The concept of deep geological disposal for high-level radioactive waste is based on an engineered barrier system (EBS), including a canister, bentonite buffer and backfill material. The bentonite buffer is key component of the EBS to prevent groundwater infiltration and radionuclide leakage. However, the bentonite buffer can become saturated due to groundwater flow through the excavation damaged zone in the adjacent rock, causing erosion of bentonite buffer and affecting the long-term performance of EBS. While the RH (relative humidity) sensor is commonly used to assess the degree of saturation in the bentonite buffer, it has a critical challenge due to its sensor size, which can disturb the overall integrity of the bentonite buffer during the initial installation process. In contrasts, the electrical resistivity test, widely known as a non-destructive method, is used to predict soil properties such as the degree of saturation and water contents. This method measures the electric resistance of materials using electric current induced by electric potential difference between two electrodes. Notably, there is no study that assess the integrity of bentonite buffer in a nuclear waste repository using electrical resistivity measurement. This study presents the electrical resistance numerical module under steady state using commercial finite element method (FEM), and quantitatively estimate the change of electrical resistance according to saturation and erosion of bentonite buffer. Furthermore, the electric potential and current density distribution formed between two electrodes are analyzed.
Tomatoes in greenhouse are a widely cultivated horticultural crop worldwide, accounting for high production and production value. When greenhouse ventilation is minimized during low temperature periods, CO2 enrichment is often used to increase tomato photosynthetic rate and yield. Plant-induced electrical signal (PIES) can be used as a technology to monitor changes in the biological response of crops due to environmental changes by using the principle of measuring the resistance value, or impedance, within the crop. This study was conducted to investigate the relationship between tomato growth data, vital response, and PIES resulting from CO2 enrichment in greenhouse tomatoes. The growth of tomato treated with CO2 enrichment in the morning was significantly better in all items except stem diameter compared to the control, and PIES values were also higher. The growth of tomato continuously applied with CO2 was better in the treatment groups than control, and there was no significant difference in chlorophyll fluorescence and photosynthesis. However, PIES and SPAD values were higher in the CO2 treatment group than control. CO2 enrichment have a direct relationship with PIES, growth increased, and transpiration increased due to the increased leaf area, resulting in increased water absorption, which appears to be reflected in PIES, which measures vascular impedance. Through this, this study suggests that PIES can be used to monitor crops due to environmental changes, and that PIES is a useful method for non-destructively and continuously monitoring changes of crops.
This study focuses on how the partial substitution of copper by nickel nanoparticles affects the electrical and structural properties of the Bi2Ba2Ca2Cu2.9Ni0.1O10+δ, Bi2Ba2Ca2Cu2.8Ni0.2O10+δ and Bi2Ba2Ca2Cu2.6Ni0.4O10+δ compounds. Approximate values of crystallization size and crystallization percentage for the three compounds were calculated using the Scherer, modified Scherer, and Williamson-Hall methods. A great similarity was observed in the crystal size values from the Scherer method, 243.442 nm, and the Williamson-Hall method, 243.794 nm for the second sample. At the same time this sample exhibited the highest crystal size value for the three methods. In the examination of electrical properties, the sample with 0.1 partial substitution, Bi2Ba2Ca2Cu2.9Ni0.1O10+δ was determined to be the best with a critical temperature of 100 K and an energy gap of 6.57639 × 10-21 MeV. Using the SEM technique to analyze the structural morphology of the three phases, it was discovered that the size of the granular forms exceeds 25 nm. It was determined that the samples’ shapes alter when nickel concentration rises. The patterns that reveal the distribution of the crystal structure also exhibit clear homogeneity.