Particulate matter is known to have adverse effects on health, making it crucial to accurately gauge its concentration levels. While the recent advent of low-cost air sensors has enabled real-time measurement of particulate matter, discrepancies in concentrations can arise depending on the sensor used, the measuring environment, and the manufacturer. In light of this, we aimed to propose a method to calibrate measurements between low-cost air sensor devices. In our study, we introduced decision tree techniques, commonly used in machine learning for classification and regression problems, to categorize particulate matter concentration intervals. For each interval, both univariate and multivariate multiple linear regression analyses were conducted to derive calibration equations. The concentrations of PM10 and PM2.5 measured indoors and outdoors with two types of LCS equipment and the GRIMM 11-A device were compared and analyzed, confirming the necessity for distinguishing between indoor and outdoor spaces and categorizing concentration intervals. Furthermore, the decision tree calibration method showed greater accuracy than traditional methods. On the other hand, during univariate regression analysis, the proportion exceeding a PM2.5/PM10 ratio of 1 was significantly high. However, using multivariate regression analysis, the exceedance rate decreased to 79.1% for IAQ-C7 and 89.3% for PMM-130, demonstrating that calibration through multivariate regression analysis considering both PM10 and PM2.5 is more effective. The results of this study are expected to contribute to the accurate calibration of particulate matter measurements and have showcased the potential for scientifically and rationally calibrating data using machine learning.
Low-cost particulate matter (PM) sensors based on the light scattering principle measure the concentration of particles by the change of scattering intensity after light is irradiated onto the particles. It has been reported that when the relative humidity is high, water vapor may cause the expansion of airborne particles and affect the accuracy of the light scattering method for PM measurement, but it has also been shown that the effect of humidity is not significant or even negligible. Therefore, to determine the effect of humidity on the Plantower PMS7003 light scattering sensor, in this study, a BAM1020 (Beta Attenuation Monitoring) was installed alongside to continuously monitor the ambient atmospheric PM concentration for approximately four weeks. The sensors collected data at 10-minute intervals, resulting in a 1-hour average for comparative analysis. To accurately measure humidity, the performance of the Arduino + DHT22 humidity sensor was also pre-evaluated using a series of saturated salt solutions. The humidity was grouped into five intervals and analyzed by visual analysis. The results confirmed that there was no significant correlation between PM2.5 differences and humidity, which were randomly and uniformly distributed around the mean. However, since in the very low and high concentration ranges based on the beta-ray monitor measurements, the difference between the light scattering sensor PM10 measurement and the reference value is much larger than the difference between the PM2.5 and the reference value., there is an additional need to investigate the appropriate correction method for dust season or PM10. The results show that the outcomes of the light scattering sensor are more influenced by particle size and concentration than by humidity.
Most of the white fumes from the tenter process of a textile plant in an industrial complex are generated by water vapor and oil mist. While general water vapor disappears when the humidity is lowered, the white fume generated in the tenter process does not disappear and is continuously maintained, resulting in environmental problems and complaints. Efforts to reduce white fume are being conducted, but it is vitally important to develop a performance index that quantitatively calculates and deduces the degree by which white fume has been reduced, so that a tangible and visible result can be obtained in the performance evaluation of prevention facilities. In this study, the removal efficiency or performance of a general wet scrubber and a wet electrostatic precipitator (electrical fume collector, EFC) installed in the actual textile tenter process was analyzed by the light scattering method that can measure the concentration of particles up to a high level. The white fume removal efficiency of the EFC was 92%, much higher than the 17% removal efficiency of the general scrubber. In addition, the EFC was more effective in removing toluene, 1,1'- [oxybis(methylene)]bis- Benzene, and benzothiazole, which are the major substances generated from the textile tenter process, as well as complex odors. From these results, it was found that the light scattering method is one of the useful tools to evaluate the performance of white fume prevention facilities in the industrial field in terms of satisfying the urgent need for measurement and the ability to obtain a clear and precise result on site. This approach is meaningful in that real-time quantification is applicable more intuitively than the gravimetric method in assessing the fume removal performance as it can be observed with the naked eye.
The purpose of this study is to analyze the effect of temperature and humidity on the measured Particulate Matter (PM) concentrations recorded by PMS5003T, a low-cost light scattering type measuring tool. A regression analysis was performed on the ratio of PM concentrations measured by the light scattering method and the beta-ray absorption method according to temperature and humidity in an outdoor environment. As the temperature decreased, the PM concentration ratio increased, and this tendency intensified below 0oC. As the humidity increased, the PM concentration ratio increased, but the effect was less than the temperature effect. The coefficients of determination for temperature and humidity were R2 = 0.325 and 0.003, respectively, and the effects of temperature and humidity on the measured values w ere formulated and compensated for. As a result of the compensation, R2, relative precision, accuracy and RMSE improved from 0.927 to 0.958, from 91.183% to 96.651%, from 31.383% to 74.058%, and from 13.517 μg/m³ to 6.690 μg/m³, respectively. Finally, results from this study indicate that the reliability of the low-cost light scattering type PM sensor can be improved by applying the temperature and humidity compensation method.
The purpose of this study is to develop correction formulas using the results of measurement by PMS 103, which is a weight method measuring device, and by Dusttrak (TSI, USA), DustMate (Turnkey Instrument Ltd., UK), and LD-5 (SIBATA, Japan), which are light scattering measuring devices. The objective is to evaluate and identify new standards (to develop a proposal) in order to complement the limitations of the existing measurement methods of public transportation vehicle indoor air quality by utilizing the three nephelometer type measuring devices. In the case of non-rush hours, the PMS values were estimated using an estimation regression equation. Statistically, the PMS values that were actually measured were not significantly different (p-value=0.4375, 0.4375, 1.000). With respect to the agreement between the two values, ICC was 0.99 in the case of the estimation regression equation using LD-5 values, 0.97 in the case of the estimation regression equation using Dusttrak values, and 0.84 in the case of the estimation regression equation using DustMate values to allow for the identification of agreement at greater levels. In the case of rush hours, the PMS values were estimated using an estimation regression equation. Statistically, the PMS values that were actually measured were not significantly different (p-value=0.3125, 0.6250, 0.8125). With respect to the agreement between the two values, ICC was 0.92 in the case of the estimation regression equation using LD-5 values, 0.91 in the case of the estimation regression equation using Dusttrak values, and 0.89 in the case of the estimation regression equation using DustMate values to allow for the identification of agreement at greater levels.
다양한 질량비의 SiO2, Hollow SiO2 나노 파티클들을 Poly(methylmethacrylate) (PMMA) 용액에 분산하여 OLED 내부 광추출용 산란층을 제작 하였다. 구형의 실리카 나노 파티클들은 약 300 nm의 평균 입자 사이즈를 나타내었다. 실리카 나노 파티클 고분자 분산액은 스핀코팅을 통하여 기판위에 코팅 되어 제작되었다. 내부가 비어 있지 앉은 SiO2 나노 파티클 산란층의 경우 높은 산란 특성을 나타내었으며 (30wt%, 588 nm, Haze 0.37) Hollow SiO2 나 노 파티클의 경우 상대적으로 낮은 산란 특성을 나타내는 것을 확인할 수 있었다 (30 wt%, 588 nm, Haze 0.16). 하 지만 Hollow SiO2 나노 입자의 경우 매우 낮은 back-scattering으로 인한 높은 투과 특성을 나타내었다 (30 wt%, 588 nm, 85%). 또한 입자의 함량 증가에 따른 투과도의 감소와 산란의 증가 비가 상대적으로 매우 높음을 확인할 수 있었다.
The surfaces of most atmosphereless solar system objects are referred to as regolith, layers of loosely connected fragmentary debris, produced by meteorite impacts. Measurements of light scattered from such surfaces provides information about the composition and structure of the surface. A suitable way to characterize the scattering properties is to consider how the intensity and polarization of scattered light depends on the particle size, composition, porosity, roughness, wavelength of incident light and the geometry of observation. In the present work, the effect of porosity on bidirectional re ectance as a function of phase angle is studied for alumina powder with grain size of 0.3 μm and olivine powder with grain size of 49 μm at 543.5 nm. The optical constants of the alumina sample for each porosity were calculated with Maxwell Garnett eective medium theory. On using each of the optical constants of alumina sample in Mie theory with the Hapke model the variation of bidirectional re ectance is obtained as a function of phase angle with porosity as a parameter. Experimental re ectance data are in good agreement the model. For the olivine sample the effect of porosity is studied using Hapke (2008).
Enhancement of light trapping in solar cells is becoming increasingly urgent for the development of next generation thin film solar cells. One of the possible candidates for increasing light trapping in thin film solar cells that has emerged recently is the use of scattering from metallic nanostructures. In this study, we have investigated the effects of the geometric parameters of Ag nanorings on the light scattering efficiency by using three dimensional Finite Different Time Domain (FDTD) calculations. We have found that the forward scattering of incident radiation from Ag nanorings strongly depends on the geometric parameters of the nanostructures such as diameter, height, etc. The forward scattering to substrate direction is increased as the outer diameter and height of the nanorings decrease. In particular, for nanorings larger than 200 nm, the inner diameter of Ag nanorings should be optimized to enhance the forward scattering efficiency. Light absorption and scattering efficiency calculations for the various nanoring arrays revealed that the periodicity of nanorings arrays also plays an important role in the absorption and the scattering efficiency enhancement. Light scattering efficiency calculations for nanoring arrays also revealed that enhancement of scattering efficiency could be utilized to enhance the light absorption through the forward scattering mechanism.
Highly textured Ag, Al and Al:Si back reflectors for flexible n-i-p silicon thin-film solar cells were prepared on 100-μm-thick stainless steel substrates by DC magnetron sputtering and the influence of their surface textures on the light-scattering properties were investigated. The surface texture of the metal back reflectors was influenced by the increased grain size and by the bimodal distribution that arose due to the abnormal grain growth at elevated deposition temperatures. This can be explained by the structure zone model (SZM). With an increase in the deposition temperatures from room temperature to 500˚C, the surface roughness of the Al:Si films increased from 11 nm to 95 nm, whereas that of the pure Ag films increased from 6 nm to 47 nm at the same deposition temperature. Although Al:Si back reflectors with larger surface feature dimensions than pure Ag can be fabricated at lower deposition temperatures due to the lower melting point and the Si impurity drag effect, they show poor total and diffuse reflectance, resulting from the low reflectivity and reflection loss on the textured surface. For a further improvement of the light-trapping efficiency in solar cells, a new type of back reflector consisting of Ag/Al:Si bilayer is suggested. The surface morphology and reflectance of this reflector are closely dependent on the Al:Si bottom layer and the Ag top layer. The relationship between the surface topography and the light-scattering properties of the bilayer back reflectors is also reported in this paper.
The study of wave propagation and scattering in biological media has become increasingly important in recent years. The propagation of light within tissues is an important problem that confronts the dosimetry of therapeutic laser delivery and the development of diagnostic spectroscopy. In the clinical application of photodynamic therapy(PDT) and in photobiology, the photon deposition within a tissue determines the spatial distribution of photochemical reactions. Scattered light is measured as a function of the distance (r) between the axis of the incident beam and the detection spot. Consequently, knowledge of the photosensitizer(Chlorophyll-a) function that characterizes a phantom is measured. To obtain the results of scattering coefficients(μs) of a turbid material from diffusion described by experimental approach. It was measured the energy fluency of photon radiation at the position of penetration depth. From fluorescence experimental method obtained the analytical expression for the scattered light as the values of (I/Io)wavelength vs the distance between the center of the incident beam and optical fiber in terms of the condition of "in situ spectroscopy(optically thick)" and real time by fluorometric measurements. The result was compromised with transport of intensities though a random distribution of scatters.
Changes in surface morphology and roughness of dc sputtered ZnO:Al/Ag back reflectors by varying the deposition temperature and their influence on the performance of flexible silicon thin film solar cells were systematically investigated. By increasing the deposition temperature from 25˚C to 500˚C, the grain size of Ag thin films increased from 100 nm to 1000 nm and the grain size distribution became irregular, which resulted in an increment of surface roughness from 6.6 nm to 46.6 nm. Even after the 100 nm thick ZnO:Al film deposition, the surface morphology and roughness of the ZnO:Al/Ag double structured back reflectors were the same as those of the Ag layers, meaning that the ZnO:Al films were deposited conformally on the Ag films without unnecessary changes in the surfacefeatures. The diffused reflectance of the back reflectors improved significantly with the increasing grain size and surface roughness of the Ag films, and in particular, an enhanced diffused reflectance in the long wavelength over 800 nm was observed in the Ag back reflectors deposited at 500˚C, which had an irregular grain size distribution of 200-1000 nm and large surface roughness. The improved light scattering properties on the rough ZnO:Al/Ag back reflector surfaces led to an increase of light trapping in the solar cells, and this resulted in a noticeable improvement in the Jsc values from 9.94 mA/cm2 for the flat Ag back reflector at 25˚C to 13.36 mA/cm2 for the rough one at 500˚C. A conversion efficiency of 7.60% (Voc = 0.93, Jsc = 13.36 mA/cm2, FF = 61%) was achieved in the flexible silicon thin film solar cells at this moment.
The effect of light scattering layers (400 nm, TiO particle) of 4 m thickness on the dye-sensitized solar cell has been investigated with a 12 m thickness of photo-anode (20 nm, TiO particle). Two different structures of scattering layers (separated and back) were applied to investigate the light transmitting behaviors and solar cell properties. The light transmittance and cell efficiency significantly improved with inserting scattering layers. The back scattering layer structure had more effective transmitting behavior, but separated scattering layer (center: 2 m, back: 2 m) structure (9.83% of efficiency) showing higher efficiency (0.6%), short circuit current density (0.26 mA/cm) and fill factor (0.02). The inserting separating two scattering layers improved the light harvesting, and relatively thin back scattering layer (2 m of thickness) minimized interruption of ion diffusion in liquid electrolyte.
Changes in the surface morphology and light scattering of textured Al doped ZnO thin films on glasssubstrates prepared by rf magnetron sputtering were investigated. As-deposited ZnO:Al films show a hightransmittance of above 80% in the visible range and a low electrical resistivity of 4.5×10-4Ω·cm. The surfacemorphology of textured ZnO:Al films are closely dependent on the deposition parameters of heater temperature,working pressure, and etching time in the etching process. The optimized surface morphology with a cratershape is obtained at a heater temperature of 350oC, working pressure of 0.5 mtorr, and etching time of 45seconds. The optical properties of light transmittance, haze, and angular distribution function (ADF) aresignificantly affected by the resulting surface morphologies of textured films. The film surfaces, havinguniformly size-distributed craters, represent good light scattering properties of high haze and ADF values.Compared with commercial Asahi U (SnO2:F) substrates, the suitability of textured ZnO:Al films as frontelectrode material for amorphous silicon thin film solar cells is also estimated with respect to electrical andoptical properties.
The influences of fluorophor, scatterer, absorber in turbid material by light scattering were interpreted for the scattered fluorescence intensity and wavelength, it has been studied the molecular properties by laser induced fluorescence spectroscopy. It has been found that the effects of optical properties in scattering media by the optical parameters(μs, μa, μt). The value of scattering coefficient μs is large by means of the increasing particles of scatterer, it has been found that the slope decays exponentially as a function of distance from laser source to detector. It may also aid in designing the best model for oil chemistry, laser medicine and application of medical engineering.