Polylactic acid (PLA) is often used in the preparation of environmentally friendly biodegradable polymer plastics, and how to improve the flame retardant performance of polylactic acid has been concerned by experts and scholars. Here, we provide a new idea, using bamboo activated carbon as the main material, and phytic acid, urea and Zn(NO3)2·6(H2O) as modifiers to produce a new type of carbon flame retardant. It has bamboo activated carbon as carbon source; second, it has P, N elements and metal oxides. The two synergistically play a flame retardant role on polylactic acid. The polylactic acid composite showed good thermal stability, from no grade optimization to V-0 in the UL-94 test, and the limiting oxygen index was also increased from 20.1 to 31.2%. The above tests show that bamboo activated carbon loaded with ZnO has a good flame retardant effect on polylactic acid.

In this study, we investigate the impact of Isophorone diisocyanate functionalized graphene oxide (IPDI-GO) on the flame retardancy of rigid polyurethane foam (RPUF). IPDI-GO was synthesized and introduced into the RPUF matrix. The flame retardancy of RPUF was significantly enhanced by the incorporation of IPDI-GO, as evidenced by a reduction in peak heat release rate (PHRR) by 25% and total smoke production (TSP) by 15% in comparison to pure RPUF when IPDI-GO was incorporated at 3 wt%. Scanning electron microscopy (SEM) revealed that IPDI-GO contributed to the formation of a compact, continuous char layer on the RPUF surface. This study underscores the potential of IPDI-GO as a promising flame retardant additive for RPUF.

The conventional multi-scale modelling approach that predicts carbon nanotube (CNT) growth region in heterogeneous flame environment is computationally exhaustive. Thus, the present study is the first attempt to develop a zero-dimensional model based on existing multi-scale model where mixture fraction z and the stoichiometric mixture fraction zst are employed to correlate burner operating conditions and CNT growth region for diffusion flames. Baseline flame models for inverse and normal diffusion flames are first established with satisfactory validation of the flame temperature and growth region prediction at various operating conditions. Prior to developing the correlation, investigation on the effects of zst on CNT growth region is carried out for 17 flame conditions with zst of 0.05 to 0.31. The developed correlation indicates linear ( zlb=1.54zst +0.11) and quadratic ( zhb=zst(7-13zst )) models for the zlb and zhb corresponding to the low and high boundaries of mixture fraction, respectively, where both parameters dictate the range of CNT growth rate (GR) in the mixture fraction space. Based on the developed correlations, the CNT growth in mixture fraction space is optimum in the flame with medium-range zst conditions between 0.15 and 0.25. The stronger relationship between growth-region mixture-fraction (GRMF) and zst at the near field region close to the flame sheet compared to that of the far field region away from the flame sheet is due to the higher temperature gradient at the former region compared to that of the latter region. The developed models also reveal three distinct regions that are early expansion, optimum, and reduction of GRMF at varying zst.

Epoxy resin (EP) is a thermosetting resin with excellent properties, but its application is limited due to its high brittleness and poor flame retardancy. Therefore, to solve this problem, a dispersion system of imidazole-containing ionic liquid ([Dmim]Es) and graphene in epoxy resin is designed based on the π–π stacking effect between imidazole and graphite layers. The study on the thermal and flame-retardant properties of the composites show that the modified [Dmim]Es–graphene nanosheets improved the flame retardancy, smoke suppression and thermal stability of epoxy resin. With the addition of 5wt% [Dmim]Es and 1% Gra, the exothermic rate (HRR) and total exothermic (THR) of the composites decrease by 35% and 30.2% compared with the untreated epoxy cross-linking, respectively. The limiting oxygen index reaches 33.4%, the UL-94 test rating reaches V-0. The characterization of mechanical properties shows that the tensile properties and impact properties increased by 13% and 30%, respectively. Through SEM observation, the addition of [Dmim]Es improves the dispersion of graphene in the EP collective and changes the mechanical fracture behavior. The results show that ionic liquid [Dmim]Es-modified graphene nanosheets are well dispersed in the matrix, which not only improves the mechanical properties of epoxy resin (EP), but also has a synergistic effect on flame retardancy. This work provides novel flame-retardant and graphene dispersion methods that broaden the range of applications of epoxy resins.

The purpose of this study is to compare and analyze the flame retardant performance of Japanese cypress(Chamaecyparis obtusa) plywood, commonly used in indoor decoration, furniture, and tableware, by treating it with three different fire retardants with different primary ingredients. The experiment was conducted in compliance with Article 31, Paragraph 2 of the Enforcement Decree of the Fire Facilities Installation and Management Act and Articles 4 and 7-2 of the Flame Retardant Performance Standards. After flame time, after glow time, char length, and char area were measured. As a result, first, after flame time was measured at 0 seconds regardless of whether the flame retardant treatment was applied. Second, after glow time was relatively long, measuring 22.7 seconds without treatment, which is likely due to the weak fire resistance and high concentration of carbon monoxide generated by the chemical characteristics of the Japanese cypress itself. Third, it was confirmed that the effects of the primary ingredient, phosphorus, in the flame retardant treatment varied depending on the technological development of the manufacturers of the same species of Japanese cypress plywood. In the future, it is expected that the results of this study will provide fundamental data to select flame retardant treatments that show high flame retardant performance according to the botanical characteristics of the wood.

In this work, the ablation behavior of monolith ZrB2-30 vol%SiC (Z30S) composites were studied under various oxy-acetylene flame angles. Typical oxidized microstructures (SiO2/SiC-depleted/ZrB2-SiC) were observed when the flame to Z30S was arranged vertically. However, formation of the outmost glassy SiO2 layer was hindered when the Z30S was tilted. The SiC-depleted region was fully exposed to air with reduced thickness when highly tilted. Traces of the ablated and island type SiO2 were observed at intermediate flame angles, which clearly verified the effect of flame angle on the ablation of the SiO2 layer. Furthermore, the observed maximum surface temperature of the Z30S gradually increased up to 2,200 °C proving that surface amorphous silica was continuously removed while monoclinic ZrO2 phase began to be exposed. A proposed ablation mechanism with respect to flame angles is discussed. This observation is expected to contribute to the design of complex-shaped UHTC applications for hypersonic vehicles and re-entry projectiles.

선박의 건조공정 중 강재의 절단과 곡 가공, 용접에 있어 화염의 사용은 필수적이다. 현재 조선소의 강재 절단과 가공 과정에서 는 아세틸렌이 화염 연료로 가장 많이 사용되고 있지만, 폭발 사고의 위험성과 상대적으로 적은 발열량의 한계로 최근에는 프로판 연료의 활용이 증가하고 있다. 하지만 프로판 연료는 상대적으로 가공 속도가 느리고, 가공 시 슬래그의 발생빈도가 높아 품질이 저하된다. 대체 연료로써 프로필렌이 주목받으며 가공 속도와 품질향상에 대한 기대가 증가하고 있다. 프로필렌은 발열량이 우수한 연료로 강재 가공 간 생산성과 가공 품질의 우수성을 갖추고 있다. 이에 본 논문에서는 프로판, 프로필렌 화염을 이용한 철판 가공 시 각 연료의 연소 특성을 분 석 및 비교하였다. 프로필렌 화염을 이용한 철판 가공 시 배출되는 온실가스와 유해가스를 프로판 연료의 배출량과 비교하여 저감효과를 실험적으로 확인하였다. 또한, 가공 연료에 따른 입열량이 선박용 강재의 기계적 강도 변화에 미치는 영향을 알아보기 위해 열 분포실험과 인장시험을 수행하였다. 실험 결과로, 대체 연료인 프로필렌을 사용할 때 프로판 연료에 비해 온도분포가 고르게 나타났다. 기계적 강도 실 험 결과로 인장강도의 저하는 관찰되지 않았으나, 변형률은 감소하는 경향을 보였다. 본 연구의 결과를 바탕으로 향후 실제 조선소의 강재 가공 및 절단과정에 적용하였을 때, 발생하는 문제점에 대한 분석 및 보완연구를 수행할 예정이다.

The purpose of this study is to improve the mechanical properties and develop manufacturing technology through self-soluble alloy powder flame spray coating on the surface of a run-out table roller for hot rolling. The roller surface of the run-out table should maintain high hardness at high temperatures and possess high wear, corrosion, and heat resistances. In addition, sufficient bonding strength between the thermal spray coating layer and base material, which would prevent the peel-off of the coating layer, is also an important factor. In this study, the most suitable powder and process for roll manufacturing technology are determined through the initial selection of commercial alloy powder for roll manufacturing, hardness, component analysis, and bond strength analysis of the powder and thermal spray coating layer according to the powder.

본 연구에서는 가교제인 붕산과 아크릴 수지 바인더에 삼인산(3 인산), 피트산(6 인산) 또는 폴 리인산암모늄(10 인산)을 혼합하여 인계 난연 코팅액을 제조하였다. 제조된 인계 난연 코팅액을 부직포에 각각 코팅하여 높은 난연 효과를 얻었다. 이렇게 제조된 난연성 부직포를 연기밀도기준시험(ASTM E662), 산소한계지수기준시험(ISO E622), 수직연소기준시험(UL 94)을 이용하여 평가하였다. 그들의 난연 효과는 phosphate 그룹의 수에 의해 영향을 받았으며, 천연 또는 합성 바인더 수지에 관계없이 그 효과는 ammonium polyphosphate > phytic acid > triphosphate의 순서로 나타났다. 천연 탄화수소 화합물도 바인더 수지의 난연성을 결정하기 위해 조사되었다. 그 결과 천연 탄화수소 바인 더 수지가 난연성 부직포 제조에 사용될 수 있음을 보여주었다.

Oil spills into ocean or coastal waters can result in significant damage to the environment via pollution of aquatic ecosystems. Absorbents based on reduced graphene oxide (rGO) foams have the capacity to remove minor or major oil spills. However, conventional chemical synthesis of rGO often uses petrochemical precursors, potentially harmful chemicals, and requires special processing conditions that are expensive to maintain. In this work, an alternative cost-effective and environmentally friendly approach suitable for large-scale production of high-quality rGO directly from used cooking sunflower oil is discussed. Thus, produced flaky graphene structures are effective in absorbing used commercial sunflower oil and engine oil, via monolayer physisorption in the case of used sunflower and engine oils facilitated by van der Waals forces, π–π stacking and hydrophobic interactions, π-cation ( H+) stacking and radical scavenging activities. From adsorption kinetic models, first-order kinetics provides a better fit for used sunflower oil adsorption (R2 = 0.9919) and second-order kinetics provides a better fit for engine oil adsorption (R2 = 0.9823). From intra-particle diffusion model, R2 for USO is 0.9788 and EO is 0.9851, which indicates that both used sunflower and engine oils adsorption processes follow an intra-particle diffusion mechanism. This study confirms that waste-derived rGO could be used for environmental remediation.

아산화질소(Nitrous oxide, N2O)는 지구온난화 물질의 하나로 이산화탄소에 비해 지구온난화효과가 310배 강하고 분해하는데 120년이 소요되기 때문에 오존층 파괴에 주범으로 알려져 있다. 따라서 본 연구에서는 N2O를 저감하기 위해 고온 열분해 기술을 적용하여 N2O 저감 공정에서 발생하는 NOx 배출 특성에 대해 조사하였다. 고온 유동장을 형성하기 위해 동축 분젠 예혼합 화염을 열원으로 채택하였으며 실험 변수로는 노즐출구속도, 동축류 속도 및 N2O 희석률로 설정하였다. 실험 결과, NO 생성률은 노즐출구속도 및 동축류 유량에 관계없이 N2O 희석률이 증가함에 따라 증가하였다. NO2의 경우에는 연소 불안정성(Kelvin Helmholtz 불안정)이 억제된 안정된 예혼합 화염에서 다량으로 배출되었는데, 이는 화염 면 부근에서 감소된 N2O의 체류시간으로 인해 열분해 시간이 충분하지 않기 때문인 것으로 사료 된다. 따라서 N2O의 저감 효율을 증진시키기 위해서는 K-H 불안정성이 발생되는 노즐출구속도를 선정하여 화염 면 부근에서 발생되는 와류(toroidal vortex) 형태의 유동 구조를 형성하는 것이 N2O의 체류시간을 증가시키는데 효과적인 것으로 판단된다.

This study developed a flame-retardant fiber-reinforced composite material that satisfies the required regulations of railway vehicle interior parts for the purpose of reducing weight and simplifying the production process using SMC(sheet molding compounds) composite materials. It is essential to secure flame-retardant performance that minimizes flames and smoke for the safe evacuation of passengers in case of fire for interior parts of railway vehicles. In this study, the resin for SMC was developed by adding various flame retardant materials such as vinyl ester (halogen-based and phosphorus-based) and antimony trioxide, and chopped glass fibers were used as the reinforcing material. As a result of preparing specimens for phosphorus-based and halogen-based SMC materials, and comparing the flame retardant performance, the phosphorus-based SMC material had an oxygen index of 36.1, smoke density (1minute 30 seconds, 4minutes, 10minutes) of 1.7, 51.5, 195.1. It was measured with a toxicity index of 0.05 R and average heat for sustained burning of 4.5MJ/m, which satisfies all the flame retardant standards required for interior parts of railway vehicles, and it was found that most of the performance was better than that of halogen-based SMC.

본 연구는 조제유류 중 지방산에 대해 최신 분석법을 마련하고자 수행하였다. 조제유류 중 지방산 함량 분석을 위해 GC를 이용한 분석법을 확립하고 시중에 유통 중인 제품을 대상으로 적용성을 검토하였다. 분석법 검증은 특이성, 직선성, 검출한계 및 정량한계, 정확성, 정밀성에 대해 수행되었다. Linoleic acid 및 α-linolenic acid의 0.1-5 mg/ mL 농도범위에서 R2=0.999 이상의 우수한 직선성을 확인할 수 있었다. Linoleic acid 및 α-linolenic acid의 LOD는 각각 0.06 mg/mL, 0.01 mg/mL, LOQ는 각각 0.16 mg/mL, 0.03 mg/mL였다. 표준인증물질 분석을 통해 정확성을 검토 하였으며, linoleic acid 및 α-linolenic acid의 회수율은 각각 100.8%와 101.1%로 확인하였다. 정밀성을 검토한 결과 시료 채취량에 따른 반복성은 linoleic acid 1.4-2.9%, α- linolenic acid 1.1-2.7%이었고, 실험실간 재현성은 각각 2.8%, 1.5%임을 확인하였다. 본 연구에서 확립된 분석법을 적용하여 국내 유통 중인 조제유류 및 조제식 제품 12건에 대해 적용성 검토를 실시한 결과 전체 시료에서 분석이 용이 하였으며, 모두 기준·규격에 적합함을 확인하였다. 본 결과로부터 확립된 GC를 이용한 분석법은 조제유류 중 지방산 함량을 확인하기에 적합함을 확인하였으며 국내 식품 영양 성분의 관리 기반을 강화하는데 기여할 것으로 사료된다.

연소실 내 공조현상으로 인해 발생되는 열음향 불안정성은 안정적인 연소시스템을 구현하기 위해 해결해야 하는 고질적인 문제로 제기되어 왔다. 열음향 불안정성은 크게 1차 2차 열음향 불안정성으로 나뉘며, 본 연구에서는 열음향 불안정성 중 2차 열음향 불안 정성의 천이에 관해 열손실이 미치는 영향에 대한 실험적 연구를 진행하였다. 2차 열음향 불안정성을 발생시키기 위해 한쪽 끝이 열린 1/4 파장 공명기를 채택하여 수직으로 설치하였고, 공명기 내부에는 예혼합 가스를 주입하였다. 또한 공명기 상단으로 발생하는 열손실 효과를 비교하기 위해 추가적으로 외부 동축류 관을 설치하였다. 연료 농후조건의 예혼합 가스만을 채택하여 주입하였기 때문에 동축관 에 주입되는 기체에 따라 공명기 상부에 추가적인 확산화염이 형성될 수 있다. 그 결과 확산화염이 발생되었을 경우 공명기 상단으로의 열손실이 감소하며 2차 열음향 불안정성이 발현되었으며, 확산화염이 억제되어 공명기 상단으로의 열손실이 증가하였을 경우 2차 열음향 불안정성의 발현이 억제되는 결과를 도출하였다.

Although flame synthesis promises economic benefit and rapid synthesis of carbon nanotube (CNT), the lack of control and understanding of the effects of flame parameters (e.g., temperature and precursor composition) impose some challenges in modelling and identifying CNT growth region for obtaining better throughput. The present study presents an investigation on the types of carbon precursor that affect CNT growth region on nickel catalyst particles in an ethylene inverse diffusion flame. An established CNT growth rate model that describes physical growth of CNT is utilised to predict CNT length and growth region using empirical inputs of flame temperature and species composition from the literature. Two variations of the model are employed to determine the dominant precursor for CNT growth which are the constant adsorption activation energy (CAAE) model and the varying adsorption activation energy (VAAE) model. The carbon precursors investigated include ethylene, acetylene, and carbon monoxide as base precursors and all possible combinations of the base precursors. In the CAAE model, the activation energy for adsorption of carbon precursor species on catalyst surface E a,1 is held constant whereas in the VAAE model, E a,1 is varied based on the investigated precursor. The sensitivity of the growth rate model is demonstrated by comparing the shifting of predicted growth regions between the CAAE model and the VAAE model where the CAAE model serves as a control case. Midpoint-based and threshold-based techniques are employed within each model to quantify the predicted CNT growth region. Growth region prediction based on the midpoint-VAAE approach demonstrates the importance of acetylene and carbon monoxide to some extent towards CNT growth. Ultimately, the threshold-VAAE model shows that the dominant precursor for CNT growth is the mixture of acetylene and carbon monoxide. A simplified reaction mechanism is proposed to describe the surface chemistry for precursor reactions with nickel catalyst where decomposition of the ethylene fuel source into acetylene and carbon monoxide is accounted for by chemisorption.