Although many attempts have been made to solve the atmospheric diffusion equation, there are many limits that prevent both solving it and its application. The causes of these impediments are primarily due to both the partial differentiation term and the turbulence diffusion coefficient. In consideration of this dilemma, this study aims to discuss the methodology and cases of utilizing a passive air sampler to increase the applicability of atmospheric dispersion modeling. Passive air samplers do not require pumps or electric power, allowing us to achieve a high resolution of spatial distribution data at a low cost and with minimal effort. They are also used to validate and calibrate the results of dispersion modeling. Currently, passive air samplers are able to measure air pollutants, including SO2, NO2, O3, dust, asbestos, heavy metals, indoor HCHO, and CO2. Additionally, they can measure odorous substances such as NH3, H2S, and VOCs. In this paper, many cases for application were introduced for several purposes, such as classifying the VOCs’ emission characteristics, surveying spatial distribution, identifying sources of airborne or odorous pollutants, and so on. In conclusion, the validation and calibration cases for modeling results were discussed, which will be very beneficial for increasing the accuracy and reliability of modeling results.

해양레저활동 인구증가 및 관련 산업의 급성장으로 인해 레저 선박을 접안하는 계류시설과 부유체를 기반으로 하는 해상부유 식 펜션 등 레저시설 수요가 증가하고 있으며, 이러한 연안에서 사용되는 부유체는 대부분 경량 부유체로서 중량이 상대적으로 경량이므 로 연안으로 유입되는 파(Wave)와 상재 하중에 의해 쉽게 경사가 발생하여 안정성이 낮아 안전사고가 빈번히 발생하고 있다. 이런 문제점 에 대한 해결방안으로 부유체의 운동저감장치를 연구하여 알리고자 한다. 본 연구논문에서는 부유체에 운동저감장치(기압차를 이용한 운 동저감장치)를 부착하여 운동저감효과를 부착하지 않은 부유체와 비교하는 방식으로 효과를 분석하였다. 효과분석은 전산해석시험으로 분석하여 부유체의 안정성 증가방법을 연구하고 그 효과를 검증해 보았다. 시험결과 분석결과 기압차를 이용한 운동저감장치를 부착한 부유체가 운동저감장치를 부착하지 않은 부유체보다 파랑에 대한 운동량이 저감되어 부유체의 안정성이 증가된 것으로 분석되었다. 이러 한 부유체의 운동저감 장치는 무동력 선박뿐만 아니라 동력선, 반잠수식 선박에서도 유용하게 사용될 것으로 판단되어 다양한 분야에 적 용하여 연구를 진행할 계획이다.

Low-cost particulate matter (PM) sensors based on the light scattering principle measure the concentration of particles by the change of scattering intensity after light is irradiated onto the particles. It has been reported that when the relative humidity is high, water vapor may cause the expansion of airborne particles and affect the accuracy of the light scattering method for PM measurement, but it has also been shown that the effect of humidity is not significant or even negligible. Therefore, to determine the effect of humidity on the Plantower PMS7003 light scattering sensor, in this study, a BAM1020 (Beta Attenuation Monitoring) was installed alongside to continuously monitor the ambient atmospheric PM concentration for approximately four weeks. The sensors collected data at 10-minute intervals, resulting in a 1-hour average for comparative analysis. To accurately measure humidity, the performance of the Arduino + DHT22 humidity sensor was also pre-evaluated using a series of saturated salt solutions. The humidity was grouped into five intervals and analyzed by visual analysis. The results confirmed that there was no significant correlation between PM2.5 differences and humidity, which were randomly and uniformly distributed around the mean. However, since in the very low and high concentration ranges based on the beta-ray monitor measurements, the difference between the light scattering sensor PM10 measurement and the reference value is much larger than the difference between the PM2.5 and the reference value., there is an additional need to investigate the appropriate correction method for dust season or PM10. The results show that the outcomes of the light scattering sensor are more influenced by particle size and concentration than by humidity.

In this study, the removal performance of high-concentration H2S and complex odors was evaluated for bio-filters installed in sewage treatment plants and manure treatment plants. The amount of odor generation according to temperature was found to be higher in summer than in spring. It was found that the longer the empty bed retention time of the bio-filter, the higher the odor removal efficiency. Therefore, in order to effectively remove odors, it is necessary to maintain a sufficiently long residence time when designing a bio-filter. In addition, a case in which a bio-filter and a wet pre-treatment system were combined to remove high-concentration odors was studied. The result showed that the wet pre-treatment was effective in removing high-concentration odors. In particular, most of the hydrogen sulfide could be adequately removed by wet pre-treatment.

Cr thin films with O added are deposited on sapphire substrate by DC sputtering and are nitrided in NH3 atmosphere between 300 and 900 oC for various times. X-ray diffraction results show that nitridation begins at 500 oC, forming CrN and Cr2N. Cr oxides of Cr2O3 are formed at 600 oC. And, at temperatures higher than 900 oC, the intermediate materials of Cr2N and Cr2O3 disappear and CrN is dominant. The atomic concentration ratios of Cr and O are 77% and 23%, respectively, over the entire thickness of as-deposited Cr thin film. In the sample nitrided at 600 oC, a CrN layer in which O is substituted with N is formed from the surface to 90 nm, and the concentrations of Cr and N in the layer are 60% and 40%, respectively. For this reason, CrN and Cr2N are distributed in the CrN region, where O is substituted with N by nitridation, and Cr oxynitrides are formed in the region below this. The nitridation process is controlled by inter-diffusion of O and N and the parabolic growth law, with activation energy of 0.69 eV.

Four types of metal oxide semiconductor gas sensor arrays were used to observe the aroma and spoilage odor emitted during the ripening process of plum & banana fruits. All gas sensors showed a high correlation (R=0.82~0.90) with the olfactory. The TGS 2603 sensor showed a high correlation of 0.90 between the odor generated and sensory perception of smell in the process of ripening and decaying fruits. In addition, it showed a very high correlation of 0.91 with the decay rate of the plum sample, and the significance probability through one-way ANOVA was also less than 0.05, which confirmed it as an optimal gas sensor (TGS 2603). Principal component analysis was performed using all the data. The cumulative variability was 99.54%, which could be explained only by two principal components, and the first principal component was 95.11%, which was related to the freshness of the fruit. It was analyzed as fresh fruit in the negative(-) direction and decayed fruit in the positive(+) direction.

This study was carried out in order to help establish a continuous efficiency test method to evaluate the performance of chemical odorants. We designed a continuous efficiency test device, and conducted several experiments during 240 mins with D.W. and two chemical deodorants for several specified substances, and a complex odor compound. Based on the results, it was confirmed that the deocorant test only for ammonia and amine could yield no useful outcome because the solubility of the two compounds was very high. Henceforth, simultaneous tests for sulfides, mercaptans, aldehydes, and so on, shoud be conducted in order to ascertain the accurate deodorant performance results. It is also clear that the concentration of target compounds and reaction time are very important for the purposes of accurate deodorant tests. In addition, information about the absorption efficiency with regard to complex odor compound such as DMS+DMDS may be important and the results based on air dilution olfactory method should be provided. It is believed that this study can make a contribution to formulating the correct standards regarding the testing of deodorants and the application of such tests.

AZO thin films are grown on a p-Si(111) substrate by RF magnetron sputtering. The characteristics of various thicknesses and heat treatment conditions are investigated by X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Hall effect and room-temperature photoluminescence (PL) measurements. The substrate temperature and the RF power during growth are kept constant at 400 ℃ and 200 W, respectively. AZO films are grown with a preferred orientation along the c-axis. As the thickness and the heat treatment temperature increases, the length of the c-axis decreases as Al3+ ions of relatively small ion radius are substituted for Zn2+ ions. At room temperature, the PL spectrum is separated into an NBE emission peak around 3.2 eV and a violet regions peak around 2.95 eV with increasing thickness, and the PL emission peak of 300 nm is red-shifted with increasing annealing temperature. In the XPS measurement, the peak intensity of Al2p and Oll increases with increasing annealing temperature. The AZO thin film of 100 nm thickness shows values of 6.5 × 1019 cm−3 of carrier concentration, 8.4 cm−2/V·s of mobility and 1.2 × 10−2 Ω·cm electrical resistivity. As the thickness of the thin film increases, the carrier concentration and the mobility increase, resulting in the decrease of resistivity. With the carrier concentration, mobility decreases when the heat treatment temperature increases more than 500 ℃.

n-Butanol is used to assess how odor intensity correction affects judges’ evaluation of the odor intensity based on the concentration. The odor intensity correction effect is verified by using three types of test solutions which are used for the selection of judges based on their concentration levels. The correction effect is statistically analyzed according to gender, odorant type, and concentration on the group and individual level. The result shows that n- Butanol correction affects the odor intensity evaluation for three odorants in different ways. In most cases, n- Butanol correction increases the panelists' sensitivity to the odor intensity change, and results to be close to the theoretical value. The female panelists can more accurately evaluate the sourness intensity of acetic acid after n- Butanol correction. All panelists regardless of gender can more accurately evaluate the fishiness intensity of trimethylamine after n-Butanol correction. For evaluating the caramel smell intensity of methylcyclopentenolone, a full panel without n-Butanol correction is recommended. Therefore, n-Butanol correction should be included in the process of judge selection and the odor intensity assessment.

Since the implementation of the Odor Prevention Act in 2005, the number of odor complaints has continuously increased due to the increased interest in the living environment. The current odor control means is a concentrationbased method for the source of odor. That is why there is a difference between the odor sensitivity and the result of the odor measurement in the odor damage area. The government is considering the introduction of the grid method, which is the odor management method of Germany, as the method of odor investigation in the odor damage area in the second comprehensive Odor Prevention Policy (2019-2028). The grid method is receptor-based odor measurement method that investigators use to judge odors in the field, task that expensive and requires substantial manpower and time. To study an odor measurement method that is suitable for domestic conditions, this study compared the correlation between results based on the odor frequency concept grid method around the livestock facilities and the result of ammonia concentration measured by passive air sampler. The correlation coefficient (R) that is between the frequency of odor per spot for the entire odor and the ammonia concentration that was measured by passive air sampler was 0.65 which is relatively good. Among the entire odor detected by the grid method, the correlation coefficient (R) between the odor frequency selected only for livestock odor and the ammonia concentration was significantly increased to 0.80. In addition, the correlation between odor exposure (ECPexist) and the ammonia concentration for the overall odor was 0.81 (linear) and 0.86 (index). If only the livestock odors were selected, the correlation between odor exposure and the ammonia concentration was very high at 0.96 (linear) and 0.95 (index).

ZnO thin-films are grown on a p-Si(111) substrate by RF sputtering. The effects of growth temperature and O2 mixture ratio on the ZnO films are investigated by scanning electron microscopy (SEM), X-ray diffraction (XRD), and roomtemperature photoluminescence (PL) measurements. All the grown ZnO thin films show a strong preferred orientation along the c-axis, with an intense ultraviolet emission centered at 377 nm. However, when O2 is mixed with the sputtering gas, the half width at half maximum (FWHM) of the XRD peak increases and the deep-level defect-related emission PL band becomes pronounced. In addition, an n-ZnO/p-Si heterojunction diode is fabricated by photolithographic processes and characterized using its current-voltage (I-V) characteristic curve and photoresponsivity. The fabricated n-ZnO/p-Si heterojunction diode exhibits typical rectifying I-V characteristics, with turn-on voltage of about 1.1 V and ideality factor of 1.7. The ratio of current density at ± 3 V of the reverse and forward bias voltage is about 5.8 × 103, which demonstrates the switching performance of the fabricated diode. The photoresponse of the diode under illumination of chopped with 40 Hz white light source shows fast response time and recovery time of 0.5 msec and 0.4 msec, respectively.

The stench of various sources has become a complex issue that all governments must face and solve. n-Butanol is often used as an odor intensity reference for daily air quality monitoring and evaluation. However, its odor space, including odor sensation and odor effect, is still not fully understood, especially in wide concentration ranges. This study described n-butanol odor character profiles with objective descriptors. They are mostly presented as “odorless” or “offensive” at low concentrations, and frequently characterized as “chemical” or “medicinal” at high concentrations. The semantic differential shows that n-butanol odor is a negative emotional odor rather than a positive one. The principal component analysis shows that the representative factors of the n-butanol sensibility structure according to the sensibility evaluation are expressed with diverse sensibility vocabulary, and ‘esthetics’ represent its characterless nature. The good linearity between intensity and concentration, the near absence of gender difference, diverse odor types rather than a specific type, and ease with which to make a wide range of concentrations, makes n-butanol a candidate to be considered as a suitable standard odorant.

This study is a summary of the complex odor proficiency testing method using the air dilution sensory method conducted for the last 7 years. Results of the homogeneity and stability test were obtained from the measurement of the standard sample for identifying the range of measurable concentration so that the complex odor proficiency testing method was established through processing the manufactured standard sample and distribution method. Standard samples were prepared using a large Teflon bag after being homogeneously mixed inside a Teflon bag. Also, a distributing container was selected with a polyester aluminum bag in order to avoid samples of the best condition from being contaminated during transport as well as being exposed to invasive odor from a sampling bag. Test results revealed that the mixture of toluene and m-Xylene was most appropriate for this proficiency testing method to the homogeneity and stability of the testing method. In addition, DMS and DMDS were the optimized samples at the outlet area. As a result, the standard method was established to address the analysis quality management to the mixed odor inspection agencies in Korea.

본 연구에서는 현행 악취공정시험방법에 나타나있는 공기희석 관능법을 사용하여 물질농도와 희석배수와의 관계를 살펴보기 위해 프로피온산, 뷰틸산, 발레르산, i-발레르산 및 i-뷰틸알코올에 대한 물질농도와 희석배수를 측정하였다. 또한 상관관계식을 이용하여 지정악취물질의 농도 규제치의 적정성을 검토하였다. 1. 판정인에 의해 측정된 대상물질의 물질농도와 희석배수의 상관관계는 식 Log C = Af·Log D + 0.5에 의해 적절하게 나타났으며, 총 22종의 지정 악취물질별 상관관계식의 기울기 값의 범위는 0.9023~1.2012으로 이소발레르알데하이드가 가장 작고, 뷰틸알데하이드가 가장 큰 것으로 나타났다. 2. 물질별 관계식으로부터 산출된 희석배수 15와 20에 해당되는 물질농도와 최소감지농도와의 비를 구한 결과, 각 물질의 농도비가 희석배수 15 및 20과 유사한 수치를 나타내 물질별 관계식이 의미가 있는 것으로 추정되었다. 3. 물질별 관계식으로부터 산출된 희석배수 15와 20에 해당되는 물질농도와 현행 물질농도 기준치와 의 비교를 통하여 기준치의 적정 수준 여부를 검토 해본 결과, 프로피온산과 뷰틸산의 경우는 기준치가 상대적으로 낮게 설정된 것으로 판단되며, 발레르산, 이소발레르산과 뷰틸알코올의 경우 물질농도 기준치가 적정 수준인 것으로 추정된다. 본 연구결과는 현행 악취방지법의 부지경계선에서 복합악취 농도 규제기준에 대한 개선방안 및 지정악취 물질들의 물질농도와 악취강도, 희석배수간의 상관관계 및 특성연구 등의 기반 자료로 사용될 수 있을 것이다.

To analyze the synergistic effects of applying lavender aroma to a footbath, we analyzed the EEG and emotional responses of footbath, lavender inhalation, and lavender footbath in women in their 30s. Foot baths reduced wave activation, wave and wave inactivation, and SEF50 and SEF90. The foot bath activated waves by about 66% compared to the background EEG, and reduced SEF50 and SEF90 by 0.43 Hz-0.68 Hz and 3.7 Hz, respectively. Lavender inhalation activated α, β, and γ waves at a concentration of 1% or more, and inactivated θ waves. As the concentration of lavender inhalation increased, α waves increased and β and γ waves decreased. Lavender foot bath activates θ waves and α waves, and inactivates β waves and γ waves. Compared with the background EEG, the lavender foot baths reduced SEF50 and SEF90, which are the median frequencies of EEG power, 0.5 Hz and 3.4 Hz, respectively. Lavender showed a positive emotional response when applied to inhalation and foot bath. Lavender showed a positive emotional response when applied to inhalation and foot bath. When the lavender was inhaled at the concentration of 1~10% and the lavender foot bath was applied, the average preference index (API) showed 0.64~0.66 and 3.6 ± 0.6, respectively. Lavender oil has a greater synergistic effect on emotional reactions when applied to an aromatherapy bath than by inhalation. Lavender decreased SEF50 and SEF90 as the API increased. A lavender footbath was superior to lavender inhalation in both emotional and EEG responses, and was more relaxed and calming than a footbath. These results suggest that the aroma foot bath method, in which lavender is applied to a footbath, is more effective in terms of providing relaxation and calming than a footbath or lavender inhalation aromatherapy.