Behaviors of saturated fatty acid halides (CI4, C16, C18) were measured by LB method when the molecules were stimulated by pressure. The saturated fatty acid halides were deposited on the indium tin oxide(lTO) glass by the LB method. The average organic ultra thin film size and the surface roughness of the fatty acid halides thin films were investigated using AFM. It was found that AFM images show small surface roughness (2.5~5.0 nm) and the organic ultra thin film size of 2.5~12 nm. Both aggregations and pin-holes were also seen on the AFM images. However we found that the surface roughness. These effects seem to be reasonable to be related to the increase of the organic ultra thin film size of fatty acid halides.

The inorganic-organic composite particles with core-shell structure were polymerized by using styrene and potassium persulfate (KPS) as a shell monomer and an initiator, respectively. We studied the effect of surfactants on the core-shell structure of silicone dioxide/styrene composite particles polymerized in the presence of sodium dodecyl sulfate(SDS), polyoxyethylene alkylether sulfate (EU-S133D), and at none surfactant condition. We found that SiO2 core / polystyrene(PS) shell structure was formed when polymerization of styrene was conducted on the surface of SiO2 particles, and the concentration SDS and EU-Sl33D was 8.34×10-2mole/L. The core-shell structure was confirmed by measuring the thermal decomposition of the polymer composite using thermogravimetric analyzer (TGA), and the morphology of the composite particles was characterized by transmission electron microscope (TEM).

The acrylic coating emulsions were prepared by the emulsion polymerization to protect the surface of steel plate from the corrosion chemicals like acid, base and salt water. MMA(methyl methacrylate), styrene, BA(butyl acrylate), and 2-HEMA(2-hydroxyethyl methacrylate) were used as monomer. KPS(potassium persulfate) and SBS(sodium bisulfite) as redox initiator and SDBS(sodium dodecylbenzene sulfonate) as emulsifier were used on the emulsion polymerization reaction. The most stable in-situ coating was obtained when 10% of MMA was added. Both particle size and quantity in emulsion were decreased as increasing the mount of SDBS. the most stable prepared coating emulsion with polyisocyanate crosslinker showed very high anticorrosion properties on the coated steel layer to salt water, whereas no significant improvement of anticorrosion property to acdic and basic condition it showed.

The core-shell composite particles of inorganic/organic were polymerized by using styrene(St) as a shell monomer and potassium persulfate (KPS) as an initiator. We studied the effect of core-shell structure of silicone dioxide/styrene in the presence of an anionic surfactant sodium lauryl sulfate (SLS) and polyoxyethylene alky lether sulfate (EU-S133D). We found that when SiO2 core/PSt shell polymerization was prepared on the surface SiO2 particle, to minimize the coagulation during the shell polymerization, the optimum conditions were at concentration of 2.56×10-2mole/L SLS. The structure of core-shell polymer was confirmed by measuring the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of core-shell polymer particles by transmission electron microscope (TEM).

The effects of the applied stretch and MgADP binding on the structure of the actin and myosin cross-bridges in rabbit fibers in the rigor state have been investigatedwith improved resolution by x-ray diffraction using synchrotron radiation. To clarify the structure of the ATP hydrolysis intermediates formed by actin and myosin cross-bridges,the effects of various phosphate analogs in the of MgADP on the structure of the thin and thick filaments in glycerinated rabbit muscle fibers in the rigor state investigated by x-ray diffraction with a short exposure time using synchrotron radiation. These results strongly suggest that when MgADP and phosphate analogs such as metallofluorides(BeF3 and AlF4)and vanadate(VO4(Vi)) were added the rigor fibers in the presence of the ATP-depletion backup system, the intensities of the actin-based layer lines were markedly weakened. We found that the intensity of the 14.5 nm-based meridional reflections increase by 20-50% when phosphate analogs such as metallofluorides(BeF3 and AlF4) and vanadate(VO4(Vi)) was added to the rigor muscle.

This study is focused on the antimicrobial activity of cyanobacteria Microcystis aeruginosa by the reduction and oxidation reaction of copper and zinc alloy metal fiber filter. Cu/Zn ion is easily makes radicals with molecular hydroperoxide. Especially, hydroperoxide radical shows strong toxicity to the strains. Plasma membrane causes conformational change when hydroperoxide radical binds to plasma membrane. Elution of copper ion from copper and zinc alloy metal fiber is detected in the cyanobacteria solution as 0.5 ppm, and that of zinc ion is 0 ppm respectively. Zinc ion is figured to form a hydroxide in the cyanobacteria solution and precipitated to form a sludge. The concentration of chlorophyll-a in the cyanobacteria solution was proved to be the index of antimicrobial level of Microcystis aeruginosa.

2004년 8월경 경기도 성남시와 광주시 일원에서 처음으로 피해가 확인된 참나무시들음병의 매개충 확산억제를 위한 방제방법으로 고사목 벌채훈증법을 적용하여 왔으나, 험난한 산악지역에서 방제작업이 어렵기 때문에 이러한 점을 보완하기 위하여 고사목을 벌채하지 않고 입목상태에서 매개충의 밀도를 억제하기 위한 훈증제 입목천공주입법의 효과를 조사하였다. 고사목의 경우 4～5m이상 높은 부위까지 매개충의 칩입공이 분포하지만 주로 2m이하에서 약 90%정도의 침입공이 분포하는 것으로 조사되어 천공이 가능한 1.5m높이까지 지름 10㎜, 길이 10㎝인 목공용 드릴날과 동력천공기를 이용하여 지상에서 1m까지는 10×10㎝간격으로, 1～1.5m높이까지는 20×20㎝ 간격으로 천공하고 천공당 3㎖의 메탐소디움 훈증제를 주입한 후 살충효과를 조사한 결과 10×10㎝간격으로 천공하였을 경우 100%의 살충율을 보였으며, 20×20㎝간격으로 천공하였을 경우 60～80%의 저조한 살충율을 보였다. 이러한 결과로 입목천공훈증법은 지형이 험난하여 벌채훈증법을 적용하기 힘든 고사목에 대한 처리방법의 하나로 적용가능한 방법이라 판단되었다.

The core-shell latex particles were prepared by sequential emulsion polymerization using alkyl methacrylate as a shell monomer and potassium persulfate (KPS) as an initiator. We study the effects of core-shell structure of calcium carbonate/alkyl methacrlyate in the presence of an anionic surfactant sodium lauryl sulfate (SLS) and polyoxyethylene alkyl ether sulfate (EU-S133D)). The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of latex by transmission electron microscope (TEM).

We investigated heat stability of epoxy resin products and epoxy resin according to the influence hardener. The heat flow which shows the degree of thermal decomposition of the epoxy resin product and epoxy resin measured by using the differential scanning calorimeter (DSC). As a result, we found that in the case of heat stability for epoxy resin as hardener was added, the ratio of one to one (epoxy resin : hardener) was the most suitable in air condition and nitrogen atmosphere.

This paper is studied on the efficient purification process of dimethyl carbonate (DMC) from the melt layer crystallization combining crystallization process, sweating process and distillation recovery process. Purity and yield of DMC crystal depended mainly on the crystallization temperature, cooling rate, sweating termperature sweating rate. Through the optimization of crystallization and sweating operation, DMC crystal can be upgraded to very high purity over 99.9% and high yield over 85%.

To find out the affection of the sampling techniques to the result of a faunistic study, we surveyed the insect fauna of the Chungbuk National University (four different sites) for a year, from spring to fall. For each site, four different collecting methods: light trap, net sweeping, pitfall trap, and window trap, were applied and the collecting was done every other week for a total of 16 times. A total of 14 orders and 672 species were collected. 501 species were collected by the light trap, which covers about 75% of the total number of species, turn out to be the most effective, while other methods could only cover 18% or less. On average, only about 30% of the species collected at a given time of collecting were re-collected at the next collecting, which means about 70% of the species collected from the first collecting remains not collected in the next collecting if you collect insects every other week. The result suggests that, in addition to applying diverse collecting methods, frequent sampling, or narrow sample window, is another very important factor for a good representation of species diversity in an insect faunistic study.

This study is focused on the possibility of copper alloy metal fiber for an antimicrobial activity in the water soluble metal working fluids. Electrochemical potential of Cu/Zn ion is -268mV, and easily makes radicals with molecular oxygen. Especially, hydroperoxide radical shows strong toxicity to the strains. Plasma membrane causes conformational change when hydroperoxide radical binds to plasma membrane. Elution of copper ion from copper alloy metal fiber is detected in metal working fluid. As a result antimicrobial activity of copper alloy metal fiber in metal working fluid is superior to that of copper fiber.

In T-mixer crystallization, supersaturation is generated by mixing of another solvent or non-solvent in order to reduce the solubility of the compound. Also, T-mixer is a type of continuous crystallization. In order to induce micro-mixing, two solutions were mixed rapidly by T-mixer, which formed high supersaturation. As the results, mean size of HMX crystals decreased with increasing de-supersaturation rate (Rs). Eventually, HMX particles ranging from 0.5 to 5μm can be obtained by T-mixer crystallization. Mixing efficiency in T-mixer increased with increasing Rs values. In T-mixer crystallization without surfactants, homogeneous nucleation was formed when S and Rs was over 54 and 1.6×103/sec. In T-mixer crystallization with surfactants, homogeneous nucleation was formed when S and Rs was over 26 and 7.4/sec.

As an additional high purification method of p-dioxanone monomer for a high molecular weight polymer, the sweating operation of crystalline layer obtained by layered melt crystallization from p-dioxanone-diethylene glycol system was studied. Purity and yield of p-dioxanone crystal depended mainly on the sweating temperature and sweating time. Increasing sweating time and sweating temperature, the purity of p-dioxanone crystal increase, whereas the yield of that decrease, respectively. Through the optimization of sweating operation, p-dioxanone crystal can be upgraded to very high purity over 99.9 % suited to monomer for polymerization.

This paper describes the experiments for investigating the effects of thermal stability of several commercial carpet mate materials. The melting point and thermal decomposition temperature was measured by means of a differential scanning calorimeter(DSC) in air condition. The DSC data and burning test results of nylon bulked continuous filament(N-BCF) yarn 100%, nylon(NY), polypropylene(PP), and a new material named polytrimethyleneterephthalate(PTT) were analysed to obtain the effect on their thermal stability. Conclusively, we observed that PTT and PP were approximately 380℃ and 240℃ to start the thermal decomposition, respectively. In other words, PTT is thermally the most stable material for carpet manufacturing.

To provide an aqueous rust inhibitor for metalworking lubricant having low toxicity and excellent rust resistance, we synthesized diester of malonic acid by three consecutive esterifications with over 98% of conversion. This substituted malonic diester could be used as an additive to mineral oil based metalworking lubricant. These metalworking lubricant compositions were showed excellent rust resistance and suitable for various metals and different metalworking processes including hot rolling and cold rolling of aluminum and aluminum alloys.

The accidents occurred by unstable material which is easily exploded or burnt up were caused by heat and collision under the condition of relatively low temperature without oxygen, have been reported frequently. However, the amount of the unstable material is getting higher by development of fine ceramic research area even though its dangerous characteristic is disregarded. This research studied a heat stability and measured boiling point of various carpet material. Carpet has been used in home as well as general indoor usage. Now a day, carpet material which is hardly burnt has been on commercial, but its detailed unstable conditions is not mentioned. This research reports the measurement of the initial temperature of generation heat and heat-radiation change on differential scanning calorimeter (DSC). The DSC data of nylon bulked continuous filament (N-BCF) yam 100%, nylon (NY), poly propylene (PP), and a new material named polytrimethylene terephthalate (PTT) are studied and researched about the effect of them using TGA, furnace, and direct-burning experiment.

We investigated the electrochemical properties for Langmuir-Blodgett (LB) films mixed with fatty acid (8A5H) and phospholipid (DLPE, DMPC, and DPPA). LB films of 8A5H monolayer and 8A5H-phospholipid mixture were deposited using the Langmuir-Blodgett method on the indium tin oxide(ITO) glass. The electrochemical properties measured using cyclic voltammetry with three-electrode system, an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode at various concentrations(0.1, 0.5, and 1.0 mol/L) of NaClO4 solution. A measuring range was reduced from initial potential to -1350 mV, continuously oxidized to 1650 mV and measured to the initial point. The scan rate was 50, 100, 150 and 200 mV/s, respectively. As a result, LB films of fatty acid and phospholipid (8A5H/DLPE and DPPA) appeared irreversible process were caused by only the reduction current from the cyclic voltammogram and LB film of 8A5H-DMPC mixture was found to be caused by a reversible oxidation-reduction process.

We investigated the electrochemical properties for Langmuir-Blodgett (LB) films mixed with 4-octyl-4'-(5-carboxylpentamethyleneoxy)azobenzene (denoted as 8A5H) and phospholipid(L-α-dimyristoylphosphatidylcholine, denoted as DMPC). LB films of 8A5H monolayer and 8A5H-DMPC were deposited by using the Langmuir-Blodgett method on the indium tin oxide(ITO) glass. The electrochemical properties measured by using cyclic voltammetry with a threeelectrode system, an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode at various concentrations(0.1, 0.5, and 1.0mol/L) of NaClO4 solution. A measuring range was reduced from initial potential to -1350mV, continuously oxidized to 1650mV and measured to the initial point. The scan rates were 50, 100, 150 and 200mV/s, respectively. As a result, LB films of 8A5H monolayer appeared irreversible process caused by only the oxidation current from the cyclic voltammogram and LB films of 8A5H-DMPC mixture were found to be caused by a reversible oxidation-reduction process.

Core-shell polymers of methyl methacrylate-styrene system were prepared by sequential emulsion polymerization in the presence of sodium dodecyl benzene sulfonate(SDBS) as an emulsifier using ammonium persulfate(APS) in an initiator and the characteristics of these core-shell polymers were evaluated. Core-shell composite latex has the both properties of core and shell components in a particle, whereas polymer blends or copolymers show a combined physical properties of two homopolymers. This unique behavior of core-shell composite latex can be used in various industrial fields. However, in preparation of core-shell composite latex, several unexpected matters are observed, for examples, particle coagulation, low degree of polymerization, and formation of new particles during shell polymerization. To solve this matters, we study the effects of surfactant concentrations, initiator concentrations, and reaction temperature on the core-shell structure of PMMA-PSt and PSt-PMMA. Particle size and particles distribution were measured by using particle size analyzer, and the morphology of the core-shell composite latex was observed by using transmission electron microscope. Glass temperature was also measured by using differential scanning calorimeter. To identify the core-shell structure, pH of the composite latex solutions was measured.