In this study, the characteristic of offensive major odorous compound from the Bon-San industrial complex in Gimhae were determined by analytical methods of Gas Chromatography, High Performance Liquid Chromatography and UV/VIS Spectrophotometer. The kind of major odorous compounds examined acetaldehyde, sulfur compounds, ammonia and styrene. The concentration of all odorous compounds at 3 sampling points of industrial complex were lower than those of regulation standard levels of the industrial complex in Korea. The mean concentration of hydrogen sulfide was 0.0235 ppm at sampling point 2, it was higher than other sampling point. Complex odors was lower than regulation standard levels of the industrial complex in Korea.

In this study, we measured volatile organic compounds in Gimhae city, South Korea. We selected twenty site and measured volatile organic compounds in ambient air by passive sampler when at sampling intervals of two month from April to December 2005. Passive sampler was exposed for fifteen day in ambient air. And samples were analyzed by GC/FID for volatile organic compounds. The results of each measured functional zone, mean concentration of each compound measured were generally higher the industrial complex area and traffic pollution area than residental area. Each area showed similar pattern for the observation period. concentration of measured each compound were the following order: winter > fall > spring > summer.

This study assessed the characteristics of emission and cell toxicology of Methylethylketone(MEK) in ambient air of industrial area. MEK is produced by the oxidation of sec-butyl alcohol and used as the solvent for making ink, printing, coating of film, bonding material and drug extraction. The MEK concentrations in the ambient-air of industrial area in Gimhae City was detected in the range of 25.4～1,580 ㎍/㎥ with an average 297.4 ㎍/㎥. The concentration of MEK showed a descending tendency from April to August followed by its increased tendency since then. The effects of MEK on the human lung cancer A549 cells was examined by the generation of Reactive Oxygen Species(ROS) and cytotoxicity. The range of MEK concentration detected in the area induced ROS generation affecting the oxidation state with a little effects on the viability of the cells.

In this study, we evaluated the property change and relationship between hematological and biochemical parameters in exposure group and control group by multiple inhalation exposure, of NO2. In case of leukocyte, change of hematological property increased significantly in statistics (p<0.05) in mice experiment. in case of hematocrit of exposure group, it was of decreased significantly in statistics. the tendency of hemoglobin and hematocrit was similar to all for three case. in case of methmoglobin that of the exposure group in mice experiment was meaning increased(p<0.05). For the NO2 influence in biochemical property, total protein and triglyceride was decreased but not significant in statistics, albumin was decreased in the exposure group in the animal experiments. blood urea nitrogen and creatinine increased significantly in statistics in the animal experiments. uric acid and lactate dehydrogenase in serum increased significantly in the exposure group. We have to evaluate risk assessment for the NO2 of indoor air pollutant in low concentration and long time.

We were carried out to monitor pesticide residues in herbal medicine. In Korea Pharmacy, these are no critics for pesticides except 5 kinds of organic chlorines (BHC, DDT, Aldrin, Endrin, Dieldrin) and heavy metals. We analysed 53 kinds of pesticides consisted of 14 kinds of organochlorines, 20 kinds of organophosphoruses, and 19 kinds of pesticides estimated endocrine disruptor on 373 samples consisted with 30kinds of herbal medicine. In this study, Domestic, Chinese and Japanese herbal medicines were tested with GC/ECD, GC/NPD and then confirmed with GC/MSD. Recoveries were 75～110% in ECD detector and 76～97% in NPD detector. Detection limits were 0.004～0.064ppm in ECD detector and 0.006～0.094ppm in NPD detector. Organochlorines and others were not detected in samples.

The simultaneous analysis of multi-residual pesticides was developed using a gas chromatography (GC) method. In this study, a simple and reliable methodology was improved to detect 154 kinds of pesticides in ginseng extract sample by using a liquid-liquid extraction procedure, open column chromagraphy and chromatographic analysis by GC electron capture detector (ECD) and GC nitrogen-phosphorus detector (NPD). The 154 kinds of pesticides were classified in 4 groups according to the chemical structure. The extraction of pesticides was experimented with 70% acetone and dichloromethane/petroleum ether in order, and cleaned up via open column chromatography (3×30㎝) packed with florisil (30g, 130℃, 12hrs). The final extract was concentrated in a rotator evaporator at 40℃ until dryness. Then the residue was redissolved to 2㎖ with acetone, and analyzed by GC-ECD and GC-NPD. The applied concentration of pesticides was over 1~10㎍/㎖. The recovery tests were ranged from 70.7% to 115.2% with standard deviations between 0.3 and 5.7% of the standard spiked to the ginseng extract sample (Group Ⅰ~Ⅳ). The limit of detection (LOD) ranged from 0.001 to 0.099㎍/㎖ (Group Ⅰ~Ⅳ). The 9 kinds of pesticides were not detected. The developed method was applied satisfactory to the determination of the 154 kinds of pesticides in the ginseng extract with good reproducibility and accuracy.

Quinclorac, bentazone, 2,4-D, bensulfuron-methyl, dymuron, capropamide, pencycuron 및 ethofenprox를 동시에 분석할 수 있는 전처리 방법과 0.1% 인산 및 아세토니트릴을 이동상으로하고 225 nm를 측정파장으로 사용한 RP-HPLC(reverse phase-high performance liquid chromatography)법을 개발하였다. 동 농약성분들의 검출 및 정량한계는 각각 0.12〜0.84 ppm 및 0.34〜1.20 ppm이었고, 회수율은 78〜96%이었다. 본 방법을 통하여 시료 전처리에서 분석까지 기존 13시간이 소요된 총 분석시간을 3시간 이내로 줄일 수 있었다.

This study was carried out to investigate the correlation between toluene in air and hippuric acid in human urine, which is based in the results of the health check-in and measure of working environment, was investigated for five years. Toluene in air and hippuric acid in urine were checked 116 workers who exposed to toluene in five type of industry. The Mean concentration of toluene in air by type of industry and every year and sex distinction, had positive correlation.(p<0.01) The Mean concentration of hippuric acid in urine by type of industry, every year, sex distinction, disparity of age and term of duty had positive correlation.(p<0.01)

Pesticides were extracted from samples with 70% acetone and methylene chloride in order, and then cleaned up via open-column chromatography apparatus packed with florisil, and finally analyzed simultaneously the organophosphorus pesticides using GC/NPD. Ultra-2 and Ultra-1 fused silica capillary columns were used to separate and identify the products. Recovery of most analytes from soybean sample, taken from pesticide residues well, was greater than(80%) for all except(6) analytes. This method can simultaneously determine multiple pesticides with a high degree of accuracy and precision.

Pesticides were extracted from samples with 70% acetone and methylene chloride in order, and then cleaned up via open-column chromatography apparatus packed with florisil, and finally analyzed simultaneously the organochlorine and pyrethroid pesticides using GC(ECD). An ultra-2 fused silica capillary column was used to separate and identify the products. The resolution between the last isomeric peak of cypermethrin(59.987min) and the first isomeric peak of flucythrinate(60.043min) was not satisfactory. The last isomeric peak of fenvalerate(62.344min) and the first isomeric peak of fluvalinate(62.397min) were overlapped. Recoveries of soybean sample for the most pesticides were 73.3% to 102.4%. Detection limits were between 0.004 and 0.063㎍/㎎ when this method was used.

Activated carbon is amorphous and its intraparticle pores are well developed. Thus it has high adsorption capabilities and catalytic effect, and is utilized in many areas of industries such as food processing. In recent years, the demand of activated carbon has been increased to solve the environmental problems-waste treatment and removal of poisonous gas. Therefore, in this study an activated carbon was made using the waste and then the industrial characteristics of the produced activated carbon were investigated. The result showed that the carbonization yield was decreased when carbonization temperature was increased from 400 to 600℃ and that the optimal carbonization temperature was 500℃. The optimal concentration of NaOH for removing ash in the raw sample was 1～2N. The iodine adsorption of activated carbon using waste sample at 500℃ carbonization was 1204.28mg/g. The activation result of carbonization sample showed that the optimal activation condition was the carbonization at 500℃ and the activation at 800℃. So the production of activated carbon was thought to be possible, reused as resource, and decreased the environmental pollution.

The growth and heavy metal experiments revealed oppositive interactions between toxic metals(Zn and Cd) and Mn when the coastal diatom T. pseudonana were used. Cd and Zn inhibited the algal growth rate only at low Mn ion concentrations and this effect could be accounted for an inhibition of cellular Mn take by the toxic metals. Mn and Zn inhibited cellular Cd take and this indicated a reciprocal effects among the metals with respect to metal take. Saturation kinetics modeling of the take data was consistent with two metals competing with each other for binding to the Mn take system and with both Cd and Mn being transported into the cell by that system. Mathematical modeling of Mn and Cd take data revealed evidence for a Cd efflux system.

For the purpose of developing a new process for the elimination of oil components from oily waste water, experimental researches using oil gelling agent were performed. The process is composed of three units, that is, decantator, gelling column and adsorption column. l0g of gelling agent in the gelling column could effectively absorb 15.65g of oil from ship washing waste water and 16.93g of oil from steel industry waste water. COD in waste waters dramatically diminished not in the gelling column but in the adsorption column. The gelling is hindered by other organic components in waste water, and the optimum space time for the gelling column is 20min. lg of gelling agent absorbed 3.7-4.0g of oil from waste waters with 25 min in the batch operation.

The well-mixed room model has been traditionally used to predict the concentrations of contaminants in indoor environments. However, this is inappropriate because the flow fields in many indoor environments distribute contaminants non-uniformly, due to imperfect air mixing. Thus, some means used to describe an imperfectly mixed room are needed. The simplest model that accounts for imperfect air mixing is a two-zone model. Therefore, this study on development of computer program for the two-zone model is carried out to propose techniques of estimating the concentration of contaminants in the room. To do this, an important consideration is to divide a room into two-zone, i.e. the lower and upper zone assuming that the air and contaminants are well mixed within each zone. And between the zones the air recirculation is characterized through the air exchange parameter. By this basic assumption, the equations for the conservation of mass are derived for each zone. These equations are solved by using the computational technique. The language used to develope the program is a VISUAL BASIC. The value of air exchange coefficient(f_12) is the most difficult to forecast when the concentrations of contaminants in an imperfectly mixed room are estimated by the two-zone model. But, as the value of f_12 increases, the air exchange between each zone increases. When the value of f_l2, is approximately 15, the concentrations in both zone approach each other, and the entire room may be approximately treated as a single well-mixed room. Therefore, this study is available for designing of the ventilation to improve the air quality of indoor environments. Also, the two-zone model produces the theoretical base which may be extended to the theory for the multi-zone model, that will be contributed to estimate the air pollution in large enclosures, such as shopping malls, atria buildings, airport terminals, and covered sports stadia.

This study was performed to investigate the riverbed structure and the pollution type in Nakdong River, Western Nakdong River, and Suyoung Stream. Sediment and water samples were collected at 15 in Nakdong River, 7 in Western Nakdong River, and 8 sites in Suyoung Stream from February 20, 1997 to June 15, 1997. The depth distributions of sampling sites in the three streams were measured and heavy metals(Cd, Pb, Cr, Cu) and pesticides in sediments and COD, BOD, and total nitrogen(T-N) in water samples were analyzed. The deepest and the shallowest sites were site 11(11.58m) and 9(3.35m) in Nakdong River, site 7(6.25m) and 4(2.06m) in Western Nakdong River, and site 8(2.89m) and 1(0.61m) in Suyoung Stream, respectively. The mean concentration of Cd(45.79ppm) was higher in the sediment of Western Nakdong River than in other two streams and those of Pb(76.25ppm), Cr(48.13ppm), and Cu(77.50ppm) were higher in the sediment of Suyoung Stream than in other two streams. Pesticides(1 kind of organophosphonis and 3 kinds of organochlorine pesticide) were detected only in the sediment of Western Nakdong River. The mean concentrations of COD(20.26ppm), BOD(25.36ppm), and T-N(18.05ppm) were higher in the water sample of Suyoung Stream than in other two streams.

The sediment in the highly contaminated Gamjeon brook was collected, mixed with the raw material of the tile, and then the commercial tile was produced using the mixture. The concentrations of the heavy metals in the mixture-before and after the tile was produced-were analyzed and the effects of the acid solution on the produced file were examined. The production of the tiles was successful and the result of heavy metal analysis showed that the concentration of Fe was the highest and that of Cd was the lowest The amount of heavy metal in the sediment - the raw material of the tile mixture was more than that of the produced tile. The elution concentration of the heavy metal by the acid solution(pH = 4 - 7) was low and the quality of the produced tile was better than the commercial tile. The result of this study suggested that the contaminated sediment was removed to produce good tiles, therefore the water pollution and soil pollution were reduced.