Moso bamboo, as a kind of renewable functional material, exhibits outstanding development potential. It is promising to prepare activated carbon with good mechanical strength and high specific surface area using moso bamboo as raw material. In this work, we employed a hydraulic extruder to extrude the bamboo charcoal and the adhesive to obtain the moso bamboo activated carbon, and improved the specific surface area of the columnar activated carbon through high-temperature water vapor activation. Through the catalytic role of the water vapor activation process, the formation and expansion of the pores were promoted and the internal pores were greatly increased. The obtained columnar activated carbon shows excellent mechanical strength (93%) and high specific surface area (791.54 m2/ g). Polyacrylamide@asphalt is one of the most effective adhesives in the high-temperature water vapor activation. The average pore size (22.99 nm) and pore volume (0.36 cm3/ g) of the prepared columnar activated carbon showed a high mesoporous ratio (83%). Based on the excellent pore structure brought by the activation process, the adsorption capacity of iodine (1135.75 mg/g), methylene blue (230 mg/g) and carbon tetrachloride (64.03 mg/g) were greatly improved. The resultant moso bamboo columnar activated carbon with high specific surface area, excellent mechanical properties, and outstanding adsorption capacity possesses a wide range of industrial applications and environmental protection potential.
이 연구는 20세기 말 이후 중국과 남한의 올림픽 포스터 디자인에서 두드러진 특징과 미묘함을 분석하고 비교합니다. 시각적 표현, 문화적 함 의, 그리고 그들의 사회-역사적 맥락 내의 의사소통 전략을 탐구합니다. 이 연구는 양국이 어떻게 전통적 요소와 현대적 디자인을 독특하게 혼합 하여 국가 정신과 문화적 정체성을 표현하며, 대중의 인식과 감정에 영 향을 주는지를 밝혀냅니다. 또한, 이러한 디자인 뒤에 있는 사회-정치적 동기를 논의하며 미래의 추세를 예상합니다. 이 분석은 중국과 한국의 포스터 디자인의 독특한 가치와 문화 간 의사소통에서의 역할에 대한 새 로운 통찰을 제공합니다.
In recent years, the efficient and clean utilization of coal has been widely concerned by scholars at home and abroad. Despite the abundance of global coal resources, the deep utilization rate of coal is still insufficient. To address this challenge, it has been explored the development and preparation of coal-based high value-added carbonaceous materials. In the present study, a novel process was developed for the preparation of graphene using biphenyl sourced from low-rank coal. Using chemical vapor deposition (CVD) technology, it was successfully implemented for us to grow high-quality graphene on copper foils. The prepared graphene products were observed and characterized using Raman spectroscopy, optical microscopy and scanning electron microscopy techniques. The results of this research provide a new perspective for the utilization of low-rank coal resources.
In response to the growing demand for high-performance lithium-ion batteries, this study investigates the crucial role of different carbon sources in enhancing the electrochemical performance of lithium iron phosphate ( LiFePO4) cathode materials. Lithium iron phosphate ( LiFePO4) suffers from drawbacks, such as low electronic conductivity and low lithium-ion diffusion coefficient, which hinder its industrial development. Carbon is a common surface coating material for LiFePO4, and the source, coating method, coating amount, and incorporation method of carbon have a significant impact on the performance of LiFePO4 materials. In this work, iron phosphate was used as the iron and phosphorus source, and lithium carbonate was used as the lithium source. Glucose, phenolic resin, ascorbic acid, and starch were employed as carbon sources. Ethanol was utilized as a dispersing agent, and ball milling was employed to obtain the LiFePO4 precursor. Carbon-coated LiFePO4 cathode materials were synthesized using the carbothermal reduction method, and the effects of different carbon sources on the structure and electrochemical performance of LiFePO4 materials were systematically investigated. The results showed that, compared to other carbon sources, LiFePO4 prepared with glucose as the carbon source not only had a higher discharge specific capacity but also better rate cycle performance. Within a voltage range of 2.5–4.2 V, the initial discharge specific capacities at 0.1, 0.5, and 1 C rates were 154.6, 145.6, and 137.6 mAh/g, respectively. After 20 cycles at a 1 C rate, the capacity retention rate was 98.7%, demonstrating excellent electrochemical performance.
The presence of tetracycline (TC) has been detected in the human living environment, and its complex structure makes it difficult to degrade. The green and efficient utilization of electroactivated persulfate advanced oxidation technology for the degradation of tetracycline remains a challenge. In this study, N-doped reduced graphene oxide (N-rGO) was prepared using a hydrothermal treatment method with urea as the nitrogen source. Four different mass ratios of graphene oxide (GO) to urea were synthesized, and the optimal mass ratio was determined through degradation experiments of tetracycline. The N-rGO/EC/PMS three-dimensional electrocatalytic system was constructed, and the influence of the experimental data on TC degradation, such as initial pH, PMS dosage and voltage, was determined. Characterization analysis using scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS), and other methods was conducted. The efficient catalytic ability of N-rGO was demonstrated through the generation of hydrogen peroxide ( H2O2) and consumption of peroxymonosulfate (PMS). The superiority of the three-dimensional (3D) electrochemical advanced oxidation process was proposed by combining different systems. Furthermore, the presence of hydroxyl radicals (.OH), persulfate radicals ( SO4 ·−), and singlet oxygen (1O2) was identified using electron spin resonance (ESR) technology. The utilization of N-rGO as a three-dimensional electrode, coupled with the advantages of PMS activation and electrochemical oxidation processes, is a promising method for treating organic pollutants in wastewater.
The challenge of incorporating photothermal conversion function into chitosan (CS) hybrid fibers lies in balancing functionality and mechanical properties. In this study, we successfully prepared a chitosan/graphene oxide/gelatin (CS/GA/GO) hybrid fiber using the wet spinning process, achieving improved mechanical properties and efficient photothermal conversion capabilities. When compared with pure CS fiber with a breaking strength of 1.07 cN/dtex, the breaking strength of the CS/ GA composite fiber increased by 46.73%, while the CS/GA/GO hybrid fiber showed an even greater increase of 85.98%. In addition, the introduction of gelatin (GA) led to secondary scattering of near-infrared light, enhancing the photothermal conversion efficiency. As a result, the CS/GA/GO hybrid fiber exhibited a faster temperature rise rate and higher maximum temperatures (94.3 °C, 103.0 °C, and 111.3 °C) as compared to the CS/GO hybrid fiber. The successful incorporation of GA not only improved the mechanical properties but also enhanced the photothermal performance of the hybrid fiber.
Polylactic acid (PLA) is often used in the preparation of environmentally friendly biodegradable polymer plastics, and how to improve the flame retardant performance of polylactic acid has been concerned by experts and scholars. Here, we provide a new idea, using bamboo activated carbon as the main material, and phytic acid, urea and Zn(NO3)2·6(H2O) as modifiers to produce a new type of carbon flame retardant. It has bamboo activated carbon as carbon source; second, it has P, N elements and metal oxides. The two synergistically play a flame retardant role on polylactic acid. The polylactic acid composite showed good thermal stability, from no grade optimization to V-0 in the UL-94 test, and the limiting oxygen index was also increased from 20.1 to 31.2%. The above tests show that bamboo activated carbon loaded with ZnO has a good flame retardant effect on polylactic acid.
This study successfully prepared high-porosity aluminosilicate fibrous porous ceramics through vacuum suction filtration using aluminosilicate fiber as the primary raw material and glass powder as binder, with the appropriate incorporation of glass fiber. The effects of the composition of raw materials and sintering process on the structure and properties of the material were studied. The results show that when the content of glass powder reached 20 wt% and the samples were sintered at the temperature of 1,000 °C, strong bonds were formed between the binder phase and fibers, resulting in a compressive strength of 0.63 MPa. When the sintering temperatures were increased from 1,000 °C to 1,200, the open porosity of the samples decreased from 89.08 % to 82.38 %, while the linear shrinkage increased from 1.13 % to 10.17 %. Meanwhile, during the sintering process, a large amount of cristobalite and mullite were precipitated from the aluminosilicate fibers, which reduced the performance of the aluminosilicate fibers and hindered the comprehensive improvement in sample performance. Based on these conditions, after adding 30 wt% glass fiber and being sintered at 1,000 °C, the sample exhibited higher compressive strength (1.34 MPa), higher open porosity (89.13 %), and lower linear shrinkage (5.26 %). The aluminosilicate fibrous porous ceramic samples exhibited excellent permeability performance due to their high porosity and interconnected three-dimensional pore structures. When the samples were filtered at a flow rate of 150 mL/min, the measured pressure drop and permeability were 0.56 KPa and 0.77 × 10-6 m2 respectively.
In this work, the trend in the performance of carbon fiber (CF) and its composite during self-polymerization of polydopamine (PDA) at carbon fiber surface was investigated by varying the self-polymerization time of dopamine in an aqueous solution. Research has shown that the PDA coating elevated the surface roughness and polarity of the inert fiber. The tensile strength of single carbon fiber was significantly improved, especially after 9 h of polydopamine self-polymerization, increasing by 18.64% compared with that of desized carbon fiber. Moreover, the interlaminar shear strength (ILSS) of CF-PDA9-based composites was 35.06% higher than that of desized CF-based composites. This research will provide a deep insight into the thickness and activated ingredients of dopamine oxidation and self-polymerization on interfacial compatibility of carbon fiber/epoxy resin composites.
In the present study, an innovative electrochemical sensing platform was established for sensitive detection of NO2 —. This sensor was developed using CoFe alloy encapsulated in nitrogen-doped carbon nanocubes (named as CoFe@NC-NCS), synthesized through the calcination of polydopamine-coated CoFe Prussian-blue analogues (CoFe-PBA@PDA). The morphological and electrochemical characterization reveals that the CoFe@NC-NCS possesses high electrocatalytic activity for electrochemical quantitation of NO2 —, ascribed to the huge surface area and plentiful active positions, benefiting from the porous, hollow, and core–shell structure of CoFe@NC-NCS. Under the optimal conditions, CoFe@NC-NCS/GCE possessed remarkable sensing performance for NO2 — with wide liner ranges and a detection limit of 0.015 μM. NO2 — recovery experiments in real samples exhibited recoveries in the range of 98.8–103.5%. Hence, the CoFe@NC-NCS shows great promise for the construction of electrochemical sensor with more potential application.
High-quality diamond films have attracted extensive attentions due to their excellent optical and electrical properties. However, several issues, such as random orientation, stress accumulation, and slow growth rate, severely limit its applications. In this paper, high-quality polycrystalline diamond films with highly ordered (100) orientation were prepared by microwave plasma chemical vapor deposition. The effects of growth parameters on the microstructure, quality and residual stress of diamond films were investigated. Experimental results indicate that relatively high temperature at low methane concentration will promote the formation of (100) oriented grains with a low compressive stress. Optimized growth parameters, a methane concentration of 2% along with a pressure of 250 Torr and temperature at 1050 ℃, were used to acquire high growth rate of 7.9 μm/h and narrow full width at half maximum of Raman peak of 5.5 cm− 1 revealing a high crystal quality. It demonstrates a promising method for rapid growth of high-quality polycrystalline diamond films with (100) orientation, which is vital for improving the diamond related applications at low cost.
Modification of the surface of raw activated carbon using chemical solvents can significantly improve the adsorption performance of activated carbon. Triethylenetetramine is one of the most important chemical solvents used to modify raw activated carbon for formaldehyde removal indoor. We conducted the liquid impregnation experiments at different initial concentrations, temperatures, adsorbent dosage and time ranges to fully investigate the adsorption of triethylenetetramine on the surface of raw activated carbon for modification. We found that the Langmuir isotherm model and pseudo-first-order kinetic model fit quite well with the experimental data and the R2 are 0.9883 and 0.9954, respectively. The theoretical maximum adsorption capacity is 166.67 mg/g. The change in Gibbs free energy (ΔG0), enthalpy change (ΔH0) and entropy change (ΔS0) were also calculated to study the direction and driving force of the liquid adsorption process. In order to understand the adsorption process at the molecular level, a new activated carbon model based on the actual physical and chemical properties of activated carbon was carefully established in the Materials Studio to simulate the liquid-phase adsorption. The pore structure, elemental composition, functional group content, density, pore volume, and porosity of the activated carbon model converge close to the actual activated carbon and the adsorption isotherms obtained from the simulation agree well with the experimental results. The results show that the adsorption of triethylenetetramine on activated carbon is a spontaneous, endothermic and monolayer physical adsorption process.
According to traditional philological materials such as Shuowen Jiezi and oracle bone inscriptions, the original meaning of the character 得 is “get”. This article takes the Book of Mencius as closed materials, exhaustively categorizing all entries of 得 in Mencius, totaling 114 examples. Then we analyze semantic content and grammatical features references to the four commentaries from Zhao Qi , Sun Shi, Zhu Xi, Jiao Xun. We find that all examples of 得 are used as verbs, but there are 12 examples where it is used as a delexical verb, exemplifies the gradual trend of semantic attenuation of 得. After conducting linguistic analysis of the character 得, we explore its manifestation of the philosophical ideas in Mencius, including aspects of personal cultivation, interpersonal relationships, and governance wisdom. Through the interaction of language and cultural analysis, we further deepen our study of the language theory and ancient classics culture.
Natural enemy insects, including predators and parasitoids, are beneficial organisms that feed upon other agricultural pests. Using natural enemy insects to suppress or prevent outbreak of pests is a key component of integrated pest management strategy. It is safe, effective, and environmentally friendly and can be applied easily to the greenhouses, filed crops and orchards. Rearing and application of natural enemy insects in biocontrol in China have a long history. As early as 1700 years ago, the predator Oecophylla smaragdina has been used for controlling many kinds of citrus pests. Up to now, more than 30 species of natural enemies that can be artificially mass produced and widely used for biological control of many kinds of pests, including caterpillars, aphids, whiteflies, thrips, leaf mites and scales in China. The annual average application area of natural enemies is over 11.34 million hectares. However, with the increasing demand of using natural enemies in biological control programs, the development of natural enemy insect industrialization still face many challenges. It is urgent to explore more effective candidate natural enemies, improve the production efficiency, increase the shelf life of products and enhance the colonization of natural enemy insects after release, and thus facilitate the commercially production and application of natural enemies. This is of great significance for comprehensively promoting the use of green prevention and control techniques for crop diseases and pests, reducing the use of chemical pesticides, ensuing the quality and safety of food and agricultural products, and ultimately promoting sustainable agricultural development.
This paper tests firms’ strategic response to negative consumer sentiment. We use sentiment analysis on social media posts to detect and proxy for negative consumer sentiments toward the firms and operationalize the number of ESG positive news about the firms as the strategic response to the sentiment. We document a surprising phenomenon that negative sentiment toward a firm is positively associated with future ESG news announcements by the firm. The effect is stronger for B2B firms than for B2C ones. We argue this is the firm’s strategic reaction rather than being a true change in the firm’s ESG policy, because (1) The ESG effect only lasts for a short period, and (2) the negative sentiment toward the firm decreases after the ESG news. Using former US president Trump’s tweets as external shocks, we show the causal relationship in a DID framework.
Some digital platforms introduced a novel positive-framing design in the multi-dimensional rating system, which framed the attribute with positive words for consumers to rate. The results from a cross-platform quasi-natural experiment show that the positive-framing design can increase the rating scores compared with the traditional non-positive framing design.
In recent years, the trend of customer demand and personalization has become more and more obvious. The previous innovation model can no longer meet the diversified needs of consumers. Therefore, firms vigorously develop open innovation to promote internal and external innovation (von Hippel, 1988). With the rapid development of AI technology, open innovation communities have more interactions with the users. Organizations continue to rely on their open innovation community to collect innovative ideas from non-professional customers and then integrate them into their new product development process to produce innovative products that are more in line with customer preferences (Bayus, 2013). At present, the research on user design focuses on how to increase user design implementation and the idea popularity (Yang et al., 2022; Zhang et al., 2022). Few studies discussed how to motivate consumers to participate in innovative content output from the source. In addition, academic research on user design is mostly limited to management comments, lacking in-depth empirical research (Franke et al. 2008). Previous studies have proved that the number of leading users in the open innovation community is far less than that of non-leading users (Hofstetter et al., 2018), so it is very necessary to improve the willingness of users to participate in community creative activities. With the vigorous development of the new technology, it is an urgent problem to be solved to encourage users to participate in innovation activities and improve the innovation performance of firms (Chesbrough, 2012). Today, firms pay more and more attention on the implementation of AI technology. With AI and user design as the research background, “AI recommendation” and “willingness to design” as the key variables, and the “S-O-R model” and “Self-determination Theory” as the basis, this paper deeply explores whether AI recommendation can be used as a factor affecting user’s participation in design activities from the perspective of users, focusing on the intermediary role of user’s inspiration, competency and self-expression. It also puts forward that product involvement and aesthetic experience openness (Donghwy and Youn, 2018) are the boundary conditions that affect user’s willingness to participate in design. The results show that user’s willingness to participate in design is higher when providing AI recommedation, and the sense of inspiration, competence and self-expression play a mediating role in it. Furthermore, the results show that when product involvement is high, users are more willing to participate in design. Similarly, users with a high degree of aesthetic experience openness are more willing to participate in design activities. This study enriches the theory of enterprise community management, promote the internal information flow of the open innovation community, and provide theoretical guidance and reference for firms to optimize the new product design process.
중국의 고령화 사회가 도래함에 따라 가족의 노후는 사회의 주 요 노후 방법 중 하나가 되었으며 중국인들은 음식, 특히 노인을 좋아하고 스스로 요리하는 것을 선호하며 음식 생산 장소, 주방 은 노인의 생활 공간의 일부로써 주택에서 자주 사용되고 가사 노동이 가장 집중되는 곳이며 노인에게도 사고가 발생하기 쉬운 곳입니다.무장애 장비와 시설이 완비된 무장애 주방은 노인의 능 력 부족을 극복하고 보상하며 노인에게 안전하고 편안하며 자립 적인 주방 생활 환경을 제공하고 노인의 생활과 정신의 요구를 충족시켜 삶의 질을 향상시킬 수 있다.본문은 자기관리 능력이 있는 노인을 연구대상으로 하여 노인의 생리적 특징과 심리적 특 징을 두 가지 차원에서 분석하고, 무장애 주방설계의 이념과 원 칙을 결합하여 주방공간의 평면배치와 조작과정, 주방입면의 설 계원칙을 설명하고, 노인의 주방작업의 행동패턴과 생리적 특징 을 통해 노인의 주방작업시 실제 수요를 분석하여 노인의 무장애 주방공간의 설계원칙과 주방설계를 제안한다.노인의 주방 업무에 대한 장벽을 줄이고 노동 강도를 줄이며 작업 효율성을 높이고 노인의 신체적, 정신적 편안함을 높다.동시에 관련 디자인 분야에 대한 참고 자료를 제공 한다.
지능형 컴퓨팅의 등장으로 빅데이터를 활용한 패션 브랜드 의미 마이닝과 가치 홍보에 초점을 맞춘 새로운 연구 트렌드가 등장하였다. 본 연구의 목적은 인기 여성복 브랜드 5개를 대상으로 다양한 종류의 의류에 대한 소비자 감성 트렌드를 조사하는 것이다. 유니클로, 에이치스타일, 베로모다, 피스버드, 온리. 이를 위해 총 93,550건의 소비자 평가를 수집하고, 키스멧 감성 분석 엔진을 활용하여 의류 유형별 감성 극성도를 분석하였 다. 그 결과, 브랜드에 따라 감정 극성이 크게 다르다는 것을 알 수 있었으며, HSTYLE 후드티, ONLY 니트웨 어, 피스버드 순면, 유니클로 니트가 각각 소비자들에게 가장 강한 긍정적 감정을 불러일으켰다. 또한 이번 연 구에서는 각 브랜드에서 가장 인기 있는 의류 유형과 착용 효과를 밝혀 패션 기업이 효과적인 마케팅 전략을 수립하고 제품 제공을 강화하는 데 중요한 인사이트를 제공했다. 이러한 연구 결과를 바탕으로 게임 업계에서 는 감성 분석을 적용하여 다양한 게임 브랜드, 장르, 게임 플레이에 대한 플레이어의 감정 반응을 이해하고 게임 프로모션 전략과 제품 디자인 개발에 도움을 줄 수 있다. 전반적으로 이 연구 결과는 디자인 분야에서 빅데이터의 잠재력을 입증하고 업계에서 경쟁 우위를 확보하기 위해 빅데이터를 활용하는 것이 중요하다는 점을 강조할 수 있다.