In this study, volatile organic compounds (VOCs) emitted from printing industries were analyzed, and an inorganic adsorbent, γ-alumina, was selected for the effective control of the VOC emissions. Printing processes commonly require inks, thinners, and cleaners, and they were mixed organic solvents containing aromatic compounds, ketones, and alcohols. Therefore, toluene, methyl ethyl ketone (MEK), and isopropyl alcohol (IPA) were selected as model compounds for this study. The adsorptive properties using γ-alumina were determined for the model compounds. Both batch isotherm and continuous flow column tests demonstrated that the adsorption capacity of MEK and IPA was 3~4 times higher than that of toluene. The column test performed at an inlet toluene concentration of 100 ppm showed that an 80% breakthrough for toluene was observed after 3 hours, but both MEK and IPA were continuously adsorbed during the same time period. A numerical model simulated that the γ-alumina could remove toluene at a loading rate of 0.4 mg/min only for a 4-hour period, which might be too short of a duration for real applications. Consequently, lifetime enhancement for γ-alumina must be implemented, and ozone oxidation and regeneration would be feasible options.

Fossil fuel combustion during fishing activities is a major contributor to climate changes in the fishing industry. The Tier1 methodology calculation and on-site continuous measurements of the greenhouse gas were carried out through the use of fuel by the coastal and offshore gillnet (blue crabs and yellow croaker) and trap (small octopus and red snow crab) fishing boats in Korea. The emission comparison results showed that the field measurements are similar to or slightly higher than the Tier1 estimates for coastal gillnet and trap. In offshore gillnet and trap fisheries, Tier1 estimate of greenhouse gases was about 1,644-13,875 kg CO2/L, which was more than the field measurement value. The CO2 emissions factor based on the fuel usage was 2.49-3.2 kg CO2/L for coastal fisheries and 1.46-2.24 kg CO2/L for offshore fisheries. Furthermore, GHG emissions per unit catch and the ratio of field measurement and Tier1 emission estimate were investigated. Since the total catch of coastal fish was relatively small, the emission per unit catch in coastal fisheries was four to eight times larger. The results of this study could be used to determine the baseline data for responding to changes in fisheries environment and reducing greenhouse gas emission.

A membrane contactor technique is proposed to selectively remove the SO2 gas from the ship exhaust gas. Membrane contactor system operates with two independent streams of liquid and gaseous phase, with a large contact area between the streams, resulting in high mass transfer coefficient values. In this study, hydrophobic polypropylene substrate was used to greatly minimize the wetting of the membranes. The performance of three absorbents -distilled water, NaOH, and Na2SO3 aqueous solution- was investigated in terms of SO2 removal efficiency within a specific range of different parameters (gas flow rate, absorbent molarities, liquid flow rate, L/G ratio). Finally, optimum operating parameters for a high SO2 removal efficiency were suggested; and the overall mass transfer coefficient and HTU values were examined.

본 연구에서는 선박용 엔진을 활용하여 E2, E3 사이클 시험 결과로부터 연료 내 황 함유량 변화에 따른 대기오염물질 배출 특성을 조사하였다. 테스트를 위해 사용된 엔진은 360 PS의 엔진(Doosan L126TIH engine)을 활용하였고, 동력계로는 Horiba-Schenck사의 400㎾급 동력계인 W400을 사용하였다. 엔진에서 발생되는 대기오염물질 계측을 위해서는 오스트리아 AVL사의 FTIR과 SPC 장비를 배기라인 후단에 장착해서 사용하였다. 실험 결과로는 E2, E3 사이클 모두에서 연료 내 황 함유량이 증가할수록 THC와 CO의 단위 출력 당 배출량은 감소하고 입자상물질은 증가하였다. 연료의 황 함유량이 증가할수록 동점도가 증가되어 엔진의 연료소모율이 좋아지는 것을 확인하였다. 이는 본 연구에 사용된 엔진의 경우 연료 분사압력이 일정한 상태에서 동점도 증가에 따른 분무입자의 평균입경이 커짐에 따른 연소 상태가 개선되었기 때문이라 생각되어진다. 질소산화물의 경우 이번 연구에서는 황함유량의 변화에도 배출량에서는 큰 변화를 보이지 않았다.

As the issue of microplastics (MPs) detection in tap water was raised in other countries in 2017, monitoring of MPs in drinking and source water, and sewage treatment plant (STP) effluents was initiated. This study intends to look into other studies on MPs in STPs at home and abroad, and review the characteristics of MPs and their removal efficiencies in the STPs, the risk and effect of MPs on watersheds, and management practices in order to help better understand MPs in STPs. To manage MPs effectively in STPs, it is necessary to investigate the detection of MPs discharged from STPs, do research on human health risk and control measures, and build a monitoring system including standardized analytical methods.

Two sewage treatment facilities were selected to identify odor emission characteristics, focusing on volatile organic compounds (VOCs) and sulfur compounds. The complex odor, 5 kinds of sulfur compounds and 23 kinds of VOCs were analyzed from gas and sludge storages. Hydrogen sulfide was detected in the highest concentration and had the highest odor quotient among the odorous compounds monitored in this study, demonstrating that the contribution of hydrogen sulfide to the complex odor reached up to 90%. For VOCs, the overall contribution to the complex odor was not critical but VOCs can sufficiently trigger an odorous sensation because the sum of the odor quotient reached up to 2.89.

The role played by reservoirs in the biogeochemical cycles of elements is a subject of ongoing debate. Recent research has revealed that reservoirs emit significant levels of greenhouse gases. To assess the importance of reservoirs in monsoon climate areas as a source of methane gas into the atmosphere, we investigated variations in organic carbon (OC) input into the reservoir, oxic state changes, and finally the amount of methane emitted (focusing on the ebullition pathway) in Lake Soyang, which is the largest reservoir in South Korea. Total organic carbon (TOC) concentrations were higher during summer after two years of heavy rainfall. The sedimentation rates of particulate organic carbon (POC) and particulate organic nitrogen (PON) were higher in the epilimnion and hypolimnion than the metalimnioin, indicating that autochthonous and allochthonous carbon made separate contributions to the TOC. During stratification, oxygen depletion occurred in the hypolimnion due to the decomposition of organic matter. Under these conditions, H2S and CH4 can be released from sediment. The methane emissions from the reservoir were much higher than from other natural lakes. However, the temporal and spatial variations of methane ebullition were huge, and were clearly dependent on many factors. Therefore, more research via a well-organized field campaign is needed to investigate methane emissions.

The O2 and CO2 concentrations in controlled atmosphere (CA) rooms are determined by the respiration of produce like apples and the airtightness of the CA room, with gas in the CA room controlled by O2 and CO2 removal as well as respiration (CO2 increase and O2 decrease). The purpose of this study was to evaluate the validity of the gas exchange model for O2 removal, CO2 removal, the rate of O2 decrease and CO2 increase by respiration of apples, and airtightness of the CA room. It took 17.5 hours to reduce O2 concentration from 20.9% to 2.0% after loading 4.3 tons of Fuji apples into the CA room, which was 4.2 hours longer than the 13.3 hours of the model formula. After the CO2 concentration rose to 0.5% due to respiration, it took 4.7 hours to lower the CO2 concentration to 0.2%, which was 0.6 hours longer than that of the model equation. The rate of CO2 increase by respiration was 0.021%/ h, which was similar to the model equation (0.017%/h). Also after 4.7 hours, the O2 concentration decreased by 0.1% which was also in line with the model equation (0.13%/h).

In this study, the loading rates (or emission rate) and concentrations of air pollutants (ammonia, hydrogen sulfide, carbon dioxide, methane, nitrous oxide, and particulate matter (PM2.5, PM10 and TSP)) emitted from a naturally ventilated dairy facility were analyzed and compared to enable a better understanding that are in close proximity to each other, air pollution status. In general, the pollution patterns should be similar in measurement sites that are in close proximity to each other, and this hypothesis was fundamental to our approach in this study. For the comparison in nearby different sites, monitoring points were located at inside (source site) and outside the dairy building (ambient site), and concentrations and wind velocity were simultaneously monitored in real time. The patterns of PM2.5 emission rate and loading rate were similar in the source site and the ambient site which was consist with the hypothesis, while the PM2.5 mass concentration were not similar in both sites. As well as PM2.5, the emission rates (source site) of gaseous carbon dioxide (CO2) and nitrous oxide (N2O) were highly correlated to their loading rates (ambient site), while the concentrations of CO2 and N2O were not similar. Therefore, wind velocity, which is included in the emission or loading rate, should be simultaneously monitored with the concentration at the same measurement points for better understanding of the air pollution status.

This study was conducted to propose the conditions of controlled atmosphere (CA) storage suitable for the storage of winter Chinese cabbage and to investigate the maximum storage period of Chinese cabbage based on the results of the quality analysis for CA storage. The weight loss rate of Chinese cabbage stored at 194 days in low temperature storage was about 2 times higher than that in CA storage. The trimming loss rate of Chinese cabbage stored at low temperature was 1.5 times higher than that of CA storage after 83 days of storage. Bolting of Chinese cabbage was observed in only low temperature storage. The Chinese cabbage firmness of CA storage was not different in the range of 5.7-6.2 N, while low temperature storage gradually increased after 83 days of storage and was 7.5 N at 194 days. The incidence of mold occurred after 83 days in low temperature storage, while in CA storage it occurred after 153 days. In the quality evaluation, CA storage for Chinese cabbage was rated 1.5-1.9 points higher than the low temperature storage. The maximum storage period of Chinese cabbage at low temperature storage was 83 days and that at CA storage 153 days.