In this study, we report significant improvements in lithium-ion battery anodes cost and performance, by fabricating nano porous silicon (Si) particles from Si wafer sludge using the metal-assisted chemical etching (MACE) process. To solve the problem of volume expansion of Si during alloying/de-alloying with lithium ions, a layer was formed through nitric acid treatment, and Ag particles were removed at the same time. This layer acts as a core-shell structure that suppresses Si volume expansion. Additionally, the specific surface area of Si increased by controlling the etching time, which corresponds to the volume expansion of Si, showing a synergistic effect with the core-shell. This development not only contributes to the development of high-capacity anode materials, but also highlights the possibility of reducing manufacturing costs by utilizing waste Si wafer sludge. In addition, this method enhances the capacity retention rate of lithium-ion batteries by up to 38 %, marking a significant step forward in performance improvements.
For low-rise piloti-type buildings that suffered significant damage in the Pohang earthquake, the seismic performance of those designed by codes issued before and after the earthquake has been recently revised. This study started with the expectation that many of the requirements presented in the current codes may be excessive, and among them, the spacing of column stirrup could be relaxed. In particular, the recently revised design code of concrete structures for buildings, KDS 41 20 00, suggests that the column stirrup spacing is 1/2 of the minimum cross-sectional size or 200 mm, which is strengthened compared to KBC 2016, but relaxed than the current KDS, 41 17 00, which is 1/4 of the minimum size or 150 mm. As a result of the study, it was found that the target performance level was sufficiently satisfied by following the current standards and that it could be satisfied even if the relaxed spacing was followed. Therefore, the strict column stirrup spacing of KDS 41 17 00 could be relaxed if a wall other than core walls is recommended in the current guideline for the structural design of piloti-type buildings.
Piloti-type structures with vertical irregularity are vulnerable to earthquakes due to the soft structure of the first story. Structural characteristics of buildings can significantly affect the seismic loss function, calculated based on seismic fragility, and therefore need to be considered. This study investigated the effects of the number of stories and core locations on the seismic loss function of piloti-type buildings in Korea. Twelve analytical models were developed considering two variations: three stories (4-story, 5-story, and 6-story) and four core locations (center core, x-eccentric core, y-eccentric core, and xy-eccentric core). The interstory drift ratio and peak floor acceleration were assessed through incremental dynamic analysis using 44 earthquake records, and seismic fragility was derived. Seismic loss functions were calculated and compared using the derived seismic fragility and repair cost ratio of each component. The results indicate that the seismic loss function increases with more stories and when the core is eccentrically located in the piloti-type structure model. Therefore, the uncertainty due to the number of stories and core location should be considered when deriving the seismic loss function of piloti-type structures.
In this study, a core-shell powder and sintered specimens using a mechanically alloyed (MAed) Ti-Mo powder fabricated through high-energy ball-milling are prepared. Analysis of sintering, microstructure, and mechanical properties confirms the applicability of the powder as a sputtering target material. To optimize the MAed Ti-Mo powder milling process, phase and elemental analyses of the powders are performed according to milling time. The results reveal that 20 h of milling time is the most suitable for the manufacturing process. Subsequently, the MAed Ti-Mo powder and MoO3 powder are milled using a 3-D mixer and heat-treated for hydrogen reduction to manufacture the core-shell powder. The reduced core-shell powder is transformed to sintered specimens through molding and sintering at 1300 and 1400oC. The sintering properties are analyzed through X-ray diffraction and scanning electron microscopy for phase and porosity analyses. Moreover, the microstructure of the powder is investigated through optical microscopy and electron probe microstructure analysis. The Ti-Mo core-shell sintered specimen is found to possess high density, uniform microstructure, and excellent hardness properties. These results indicate that the Ti-Mo core-shell sintered specimen has excellent sintering properties and is suitable as a sputtering target material.
MCCI, one of the ex-vessel phenomena during a severe accident, is generally caused by mutual reactions between molten core and reactor building basemat concrete, but occurs between sacrificial materials made by concrete and corium in APR nuclear power plant with PECS applied. In this paper, MCCI analysis was performed to design and apply a device to block the core melt at the junction connected to the ICI cavity sump from the core catcher installed in the reactor cavity of the APR. Unlike the sacrificial material, which has a cooling effect by inducing erosion of the ex-vessel core melt, the device is composed of concrete applied as a barrier to protect the ICI cavity sump. The decent thickness of the barrier wall of the device was calculated.
PURPOSES : The purpose of this study is to provide basic data to improve the service life of asphalt pavement using basalt aggregate in Jeju Island by evaluating the performance of asphalt pavement through analysis of material and structural aspects. METHODS : To evaluate the performance of Jeju Island's asphalt pavement, cracks, permanent deformation, and longitudinal roughness were analyzed for the Aejo-ro road, which has high traffic and frequent premature damage. Cores were collected from Aejo-ro sections in good condition and damaged condition, and the physical properties of each layer were compared and analyzed. In addition, plate cores were collected from two sections with severe damage and the cause of pavement damage was analyzed in detail. RESULTS : About 45% of the collected cores suffered damage such as layer separation and damage to the lower layer. The asphalt content of surface layer in the damaged section was found to be 1.1% lower on average than that in the good condition section, and the mix gradations generally satisfied the standards. The density difference between the cores of each layer was found to be quite large, and the air voids was found to be at a high level. CONCLUSIONS : Test results on the cores showed that, considering the high absorption ratio of basalt aggregate, the asphalt content was generally low, and the high air voids of the pavement was believed to have had a significant impact on damage. High air voids in asphalt pavement can be caused by poor mixture itself, poor construction management, or a combination of the two factors. Additionally, the separation of each layer is believed to be the cause of premature failure of asphalt pavement.
The EV electric vehicle market is growing rapidly worldwide. Magnet fixing technology is important for mass production of driving motors, a key part of electric vehicles. The magnet fixing method was carried out by the PAM (Polyamide molding) method. This study conducted the injection of rotor core magnet PA of EV traction motor and is a study on the amount of rotor core deformation. In this study, the change in the outer diameter of the product after injection and the non-molding phenomenon were tested. An injection mold was made and the results and phenomena of product deformation types are discussed.
대한해협 대륙붕 해저사퇴의 형성과정을 이해하기 위해 77m 심도 심부 SSDP-101 코어를 연구하였다. 이 심부 코어는 WGS 측지계 기준으로 북위 128도 16.335분, 동경 34도 19.666분에 위치한 수심 60m의 사퇴 정상부에서 시추 하였다. SSDP-101 코어 시료의 해양지질학적 분석은 제4기 후기 상대 해수면 변화에 의해 야기된 대한해협 대륙붕 퇴 적환경의 변화를 밝혔다. 하부 코어 퇴적층은 간헐적 하천 범람이 일어나는 염하구 환경에서 형성된 것으로 해석되었다. 연구 지역의 사퇴는 상대해수면이 현재보다 더 낮은 시기에 형성되었고, 사퇴 퇴적물은 상대해수면이 상승함에 따라 키 질작용을 받았다. 현재 대륙붕의 해저사퇴는 해수면이 낮았던 시기의 해저사퇴가 현재 해수면 환경까지 잔존된 결과로 해석된다.
Recently, Free-Form and Irregular Shape high-rise buildings are constructed by IT technology development. Tilted shaped high-rise building which is one of Irregular shape high-rise buildings can cause lateral displacement by gravity load and lateral load due to tilted elevation shape. Therefore, it is necessary to review the behavior and structural aspects of the Tilted shape high-rise building by gravity load. In this paper, the dynamic characteristics of a tilted structure with a dual-core were analyzed with the core location as a design variable, and response behavior, vulnerable members, and vulnerable layers to earthquake loads were analyzed. As a result of the analysis, as the location of the core moved in an tilted direction, the eccentric distance and eccentric load decreased, reducing the axial force of the vertical members. However, the location of the core had little effect on the response.
BNKT Ceramics, one of the representative Pb free based piezoelectric ceramics, constitutes a perovskite(ABO3) structure. At this time, the perovskite structure (ABO3) is in the form where the corners of the octahedrons are connected, and in the unit cell, two ions, A and B, are cations, A ion is located at the body center, B ion is located at each corner, and an anion O is located at the center of each side. Since Bi, Na, and K sources constituting the A site are highly volatile at a sintering temperature of 1100℃ or higher, it is difficult to maintain uniformity of the composition. In order to solve this problem, there should be suppression of volatilization of the A site material or additional compensation of the volatilized. In this study, the basic composition of BNKT Ceramics was set to Bi0.5(Na0.78K0.22)0.5TiO3 (= BNKT), and volatile site (Bi, Na, and K sources) were coated in the form of a shell to compensate additionally for the A site ions. In addition, the physical and electrical properties of BNKT and its coated with shell additives(= @BNK) were compared and analyzed, respectively. As a result of analyzing the crystal structure through XRD, both BNKT(Core) and @BNK(Shell) had perovskite phases, and the crystallinity was almost similar. Although the Curie temperature of the two sintered bodies was almost the same (TC = 290 ~ 300 ℃), it was confirmed that the d33 (piezoelectric coefficient) and Pr (residual polarization) values were different. The experimental results indicated that the additional compensation for a shell additive causes the coarsening, resulting in a decrease in sintering density and Pr(remanent polarization). However, coating shell additives to compensate for A site ion is an effective way to suppress volatilization. Based on these experimental results, it would be the biggest advantage to develop an eco-friendly material (Lead-free) that replaced lead (Pb), which is harmful to the human body. This lead-free piezoelectric material can be applied to a biomedical device or products(ex. earphones (hearing aids), heart rate monitors, ultrasonic vibrators, etc.) and skin beauty improvement products (mask packs for whitening and wrinkle improvement).
This study proposes an RCS composite damping device that can achieve seismic reinforcement of existing buildings by dissipating energy by inelastic deformation. A series of experiments assessing the performances of the rubber core pad, hysteretic steel slit damping device, and hybrid RCS damping device were conducted. The results showed that the ratios of the deviations to the mean values satisfied the domestic damping-device conformity condition for the load at maximum device displacement in each direction, at the maximum force and minimum force at zero displacement, as well as the hysteresis curve area. In addition, three analysis models based on load-displacement characteristics were proposed for application to seismic reinforcement design. In addition, the validity of the three proposed models was confirmed, as they simulated the experimental results well. Meanwhile, as the shear deformation of the rubber-core pad increased, the hysteretic behavior of super-elasticity greatly increased the horizontal force of the damping device. Therefore, limiting the allowable displacement during design is deemed to be necessary.
본 연구에서는 양생물주기 및 보양을 하지 않은 구조체의 압축강도와 표준 양생 공시체의 압축강도를 비교 평가하였 다. 코어채취를 위해서 980x2090x200mm3 철근콘크리트 슬래브를 준비하였으며, 콘크리트 공시체 25개를 KS F 2405에 따라서 표준 양생, 20개를 구조체와 동일한 환경에서 대기중 양생을 하였다. 실험 결과, 28일 표준공시체 압축강도 대비 코어 채취 압 축강도는 약 4MPa 낮게, 대기중 양생 공시체의 압축강도는 약 7.6MPa 낮게 측정되었다. KCS에서는 양생기간의 온도가 낮을 경 우 온도보정강도를 제시하고 있으며, 실험결과로부터 제시된 값이 적정함을 확인하였다. 7일, 14일에 측정된 대기중 공시체의 압축강도는 코어채취 공시체의 압축강도와 유사하였지만, 28일 압축강도는 현저하게 차이가 나타났다. 초기 구조체의 초기 압축 강도 예측에 대기양생 공시체를 이용하는 것은 가능하지만, 28일 압축강도를 추측하는데 대기중 양생 공시체를 사용하는 것은 무리가 있다고 판단된다.
The capacity of high nickel Li(NixCoyMn1-x-y)O2 (NCM, x ≥ 0.8) cathodes is known to rapidly decline, a serious problem that needs to be solved in a timely manner. It was reported that cathode materials with the {010} plane exposed toward the outside, i.e., a radial structure, can provide facile Li+ diffusion paths and stress buffer during repeated cycles. In addition, cathodes with a core-shell composition gradient are of great interest. For example, a stable surface structure can be achieved using relatively low nickel content on the surface. In this study, precursors of the high-nickel NCM were synthesized by coprecipitation in ambient atmosphere. Then, a transition metal solution for coprecipitation was replaced with a low nickel content and the coprecipitation reaction proceeded for the desired time. The electrochemical analysis of the core-shell cathode showed a capacity retention of 94 % after 100 cycles, compared to the initial discharge capacity of 184.74 mA h/g. The rate capability test also confirmed that the core-shell cathode had enhanced kinetics during charging and discharging at 1 A/g.
When the center of stiffness and the center of mass of the structure differ under the seismic load, torsion is caused by eccentricity. In this study, an analysis model was modeled in which the positions of the core and the plane rotation axis of a 60-story torsional atypical structure with a plane rotation angle of 1 degree per floor were different. The structural behavior of the analysis model was analyzed, and the earthquake response behavior of the structure was analyzed based on the time history analysis results. As a result, as the eccentricity of the structure increased, the eccentricity response was amplified in the high-rise part, and the bending and torsional behavior responses were complex in the low-order vibration mode. As a result of the analysis, the maximum displacement and story drift ratio increased due to the torsional behavior. The maximum story shear force and the story absolute maximum acceleration showed similarities for each analysis model according to the shape of the vibration mode of the analysis model.
Currently, the construction trend of high-rise structures is changing from a cube-shaped box to a free-form. In the case of free-form structures, it is difficult to predict the behavior of the structure because it induces torsional deformation due to inclined columns and the eccentricity of the structure by the horizontal load. For this reason, it is essential to review the stability by considering the design variables at the design stage. In this paper, the position of the weak vertical member was analyzed by analyzing the behavior of the structure according to the change in the core position of the twisted high-rise structures. In the case of the shear wall, the shear force was found to be high in the order of proximity to the center of gravity of each floor of the structure. In the case of the column, the component force was generated by the axial force of the outermost beam, so the bending moment was concentrated on the inner column with no inclination.
최근 비구조요소의 피해사례가 증가하면서 비구조요소 내진설계에 관한 많은 연구가 진행되고 있다. 하지만 대부분의 연구는 평면 적 요소보다는 수직적 요소나 시스템적 요소를 변수로 층가속도를 평가하고 있다. 때문에 본 논문에서는 횡력저항에 많은 부분을 차 지하는 코어를 평면적 변수로 사용하여 비구조요소 내진설계를 위한 층가속도에 대해 평가하였다. 정사각형의 2축대칭의 평면에서 코어의 형태(위치 및 비중)변화에 따라 서로 다른 5개의 평면과 각 평면마다 5층, 10층, 15층, 20층의 층수를 가진 총 20개의 모델로 선 형시간이력해석을 수행하였다. 분석 결과 코어 위치에 따라 편심을 받는 평면에서는 층가속도가 최대 1.7배의 비틀림 증폭이 발생하 였고 구조물의 중층부에서 비틀림의 영향이 가장 큰 것을 확인할 수 있었다. 편심이 없이 코어의 비중만 변화한 평면에서는 주기 0.4694초를 기준으로 이하일 때는 주기가 증가할수록 층가속도가 저층부에서는 감소하고 고층부에는 증가하며, 반대로 주기 0.4694 초 이상일 때는 주기가 증가할수록 층가속도가 저층부에서는 증가하고 고층부에는 감소한다는 것을 확인할 수 있었다. 또한, 구조물 의 층수는 최대층가속도에 영향을 주지 못하는 것을 확인하였다. 핵심용어 :
이 연구의 목적은 8주간의 코어 훈련이 프리스타일 스키 선수들의 배근력, 서전트 점프, Y- 자 검사 및 평형감각 조절 능력에 미치는 영향을 보고자 하였다. 14명의 프리스타일 선수를 무작위로 운동군 7명과 통제군 7명으로 분류하였다. 훈련군은 8주간의 코어 훈련을 하였고, 통제군은 일반적인 훈 련을 하였다. 연구 결과 배근력과 서전트 점프에서 효과를 보였고, 집단 간 유의한 차이는 보이지 않았다. Y-자 검사의 경우 좌측 앞쪽에서 효과를 보였고, 좌·우측 좌측 후방 안쪽에서 집단 간 차이를 보였다. 종합점수의 경우 운동군은 사전의 좌·우 차이 7.5cm, 사후에서 1.66cm로 감소하였으나 통제군은 사전 3.73cm에서 사후 7.01cm로 증가한 것으로 나타났다. 평형감각 조절 능력에서는 조건 2, 5, 6에서 유의한 효과를 보였으나 집단 간의 차이는 없었다. 결론적으로, 8주간의 코어 훈련은 프리스타일 스키 선수들의 자세 조절 능력에서 유익한 효과를 미치는 것으로 나타났다.