본 논문에서는 다양한 기상 조건에서 시인성과 내구성을 향상시키도록 설계된 도로 표시용 UV 경화 코팅 시스템 개발을 위해 수행한 연구의 결과를 나타내었다. 제조된 UV 코팅을 사용해 차선 표시의 재귀반사도와 내마모성을 강화하고 포장가속시험(APT), 휠 트래킹 내구성 테스트 등 다양한 테스트를 통해 성능을 평가하였다. 이 결과를 바탕으로 도로 안전을 위한 야간 시인성 및 미끄럼을 개선하 고자 한다.

Corrosion-related challenges remain a significant research topic in developing next-generation Molten Salt Reactors (MSRs). To gain a deeper understanding of preventing corrosion in MSRs, previous studies have attempted to improve the corrosion resistance of structural alloys by coating surfaces such as alumina coating. To conduct a corrosion test of coating alloys fully immersed in molten salt, it’s important to ensure that the coating application process is carefully carried out. Ideally, coating all sides of the alloy is necessary to avoid gaps like corners of the alloy, while only applying a one-sided coating alloy can lead to galvanic corrosion with the base metals. Using the droplet shape of eutectic salt applied to only one side of the coating alloy would avoid these problems in conventional corrosion immersion tests, as corrosion would occur solely on the coating surface. Although the droplet method for corrosion tests cannot fully replicate corrosion in the MSRs environment, it offers a valuable tool for comparing and evaluating the corrosion resistance of different coating surfaces of alloys. However, the surface area is important due to the effect of diffusion in the corrosion of alloy in molten salt environments, but it is difficult to unify in the case of droplet tests. Therefore, understanding the droplet-alloy properties and corrosion mechanism is needed to accurately predict and analyze these test systems’ behavior highlighting unity for corrosion tests of different coating surfaces of alloys. To analyze the molten salt droplet behavior on various samples, pelletized eutectic NaCl-MgCl2 was prepared as salt and W-, Mo-coating, and base SS316 as samples. At room temperature, the same mass of pelletized eutectic NaCl-MgCl2 was placed on different samples under an argon atmosphere and heated to a eutectic point of 500°C in a furnace. After every hour, the molten droplets were hardened by rapid cooling at room temperature outside the furnace. The mass loss of salts and the contact area of the samples were measured by mass balance and SEM. The shape, surface area to volume ratio, and evaporation of the droplets of NaCl-MgCl2 per each coating sample and hour were analyzed to identify the optimal mass to equalize the contact coating surface of alloys with salts. Furthermore, We also analyzed whether their results reached saturation of corrosion products through ICP-MS. This will be significant research for the uniformity of the liquid-drop shape corrosion test of the coating sample in molten eutectic salts.

The paint removal of fighter jets is just as important as the painting, because perfect paint removal ensures the quality of the exterior painting on the aircraft. However, the current conditions for paint removal work of the ROKAF’s are poor. It is identified that the painting process currently implemented by the ROKAF is not only exposed to harmful compounds such as harmful dust and hexavalent chromium, but also consumes a lot of water. Thus, the introduction of advanced facility is considered. This study compares the fighter jets painting removal process currently applied by the Korean Air Force with the improved laser coating removal process of the US Air Force, and conducts an incremental analysis to perform economic analysis for the introduction of advanced facility. Four scenarios were envisioned on the premise of an increase in the number of fighters in the future, incremental analysis shows that laser coating removal method is advantageous in all scenarios. In addition, it is recommended that paint removal cycle keeps the current 12-year and the outsourcing amount to civilian depot is reduced.

Deicing agent refers to the substance that melts snow by exothermic or endothermic chemical reaction after spraying on snow. It also has the function of reducing the freezing point to prevent freezing. However, the long-term use of deicing agent can cause some negative problems, such as pot hole, concrete corrosion, vehicle and steel bridge parts corrosion. At present, wet salt spray deicing is a cost-effective deicing method that is being widely used. Typical deicing agents are calcium chloride and sodium chloride. Deicing equipment is placed to similar or higher corrosive environment than coastal or marine environment due to direct contact to chloride in deicing operation. Therefore, the anti-corrosion control is very important for the maintenance of deicing equipment. In this study, corrosion resistance, blistering and repairability of the deicing equipment were tested by using test standard (salt water production and spraying- KS D 9502 , evaluating degree of rusting- ASTM D 610, evaluating degree of blistering- ASTM D 714, pull-off strangth of coatings- ASTM D 4541). And an economical coating system with long-term antirust performance was constructed. The results show that the performance of the coating system has been improved than with the original coating.

The first aim of the study is to improve the productivity by uniformizing the thickness of coating and reducing quality-inspection time. The second aim is to cut down on the raw materials for coating by prevent the waste of spraying in the air during a painting process through a real-time coating-sizerecognition monitering to fit the target components. To achieve the two aims, a simplified version of automatic coating control system for recognition of coating for vessels and Spray. With the sytem, following effects are expected: First, quality improvement will be achieved by uniformizing the film-thickness. Second, it will reduce the waste of coating paint by constructing the speed of the coating, the spray gun robot transfer time, and the number of DBs according to the size of the vessel. Third, as a 3D industry, it will be able to solve the difficulty of supply of labors and save up the labor costs. Therefore, in the future, further research will be needed to be applied to various products with DB design that designates the variable value, which is added for each type of pieces by comparing the difference between various types of workpieces and linear ones.

최근 우수한 유연성과 화학적 안정성 등을 가진 고분자 수지와 우수한 기계적 성질 등을 나타내는 무기 재료로 이루어진 나노 복합 시스템으로써 유-무기 하이브리드 코팅 필름에 관한 연구가 활발히 진행되고 있다. 아크릴레이트 단량체로써 사용된 o-phenylphenoxyethyl acrylate (OPPEA)는 1.576의 높은 굴절률을 나타내고, Bisphenol A ethoxylate diacrylate (BAEDA)는 굴절률은 낮지만 경화된 고분자의 경도를 향상시킨다. 또한, 무기 소재로써 사용된 지르코니아는 산화지르코늄으로써 우수한 내구성과 광학특성 등을 나타낸다. 본 연구에서는 광학 특성을 향상시키기 위한 목적으로 아크릴레이트 단량체 중 BAEDA의 함량을 조절하여 필름을 제조한 뒤 연필 경도계와 아베굴절계를 이용하여 광학 특성 변화를 확인하였고, UV-vis spectrophotometer을 이용해 투과도를 비교하여 최적의 조건을 확립하였다. 그리고 실란 커플링제인 γ-methacryloxypropyltrimethoxysilane (MPS)를 사용하여 지르코니아를 소수화 처리하여 아크릴레이트 단량체에 대한 분산성을 향상시키고, 개질 전후의 물에 대한 분산성 변화를 조사하여 물에 대한 친화력이 감소하였음을 확인하였고, FT-IR ATR spectrophotometer를 통해 MPS에 의해 도입된 1716 cm-1에서의 에스터 C=O 결합 peak의 존재를 통해 MPS에 의한 지르코니아 표면의 개질 반응이 진행되었음을 확인하였다. 또한, 지르코니아의 표면에 도입된 규소 원자의 존재는 X 선 형광법을 이용하여 확인하였다. 그리고 화학적으로 개질된 지르코니아를 아크릴레이트 단량체에 도입하여 광경화 필름을 제조하였을 때, 굴절률은 아크릴레이트 자체 필름보다 1.2% 향상되었음을 확인하였고, SEM/EDS mapping 분석을 통해 PET 필름에 코팅된 개질 후 지르코니아가 아크릴레이트 코팅층에 균일하게 분포되어 있음을 알 수 있었다.

In this study, we investigated to the heat transfer performance of coating nano-structure with various shapes and patterns on the heat transfer surface. As a result of the measurement of the 3D nano shape, it was confirmed that the roughness generally increases when the adhesive is sprayed on the coating surface and finished durability experiment. In the case of TEOS adhesive, the roughness increased by 0.074 ㎛, 0.012 ㎛ and 0.015 ㎛, and the contact angle decreased 12.64°, 1.31°, 9.84° at the coating time of 120 seconds, 180 seconds and 240 seconds, respectively. In the case of PVA adhesive, the roughness increased by 0.069 ㎛, 0.056 ㎛ and 0.03 ㎛, and the contact angle decreased 2.85°, 4.82°, 6.96° at the coating time of 120 seconds, 180 seconds and 240 seconds, respectively. In the case of DGEBF adhesive, the roughness increased by 0.042 ㎛, 0.053 ㎛ and 0 ㎛, and the contact angle decreased 0.81° at the coating time of 120 seconds, increased 4.82°, 6.96° at the coating time of 180 seconds and 240 seconds, respectively. As a result, the durability tends to decrease as more nano-structures are deposited, and 3D nano shapes, contact angles and SEM photographs showed that the performance of the PVA adhesive was superior among the three adhesives.

There is a growing concern on the improvement of water distribution pipeline for multi-regional water supply system in Korea along with its aging infrastructure. Rehabilitation of large diameter pipeline is more efficient in cost and time compared to replacement with trenching. The procedure for rehabilitation are diagnosis, cleaning, spraying coating material, and final inspection. The internal state of pipeline was carefully diagnosed and got C grade, which required rehabilitation. We found that 17,274,787,000 Korean won could be saved after pipe surface coating because of increased C coefficient of Hazen-Williams equation. Optimal coating material was D polyurea. We also found optimal distance between spraying nozzle and pipe wall to be 70 - 80 cm, which were critical factors for coating quality. This study also illustrated the time for spray drying to be more than 30 min. These results could be used in the quality control process during rehabilitation of aged pipelines.

A microencapsulated cinnamon oil (CO)-coated film was developed using a pilot-plant scale film coating system. CO microencapsulated with polyvinyl alcohol was incorporated with a printing ink and the ink mixture was applied to the surface of a polypropylene (PP) film as an ink coating using a gravure printing press at a speed of 20-200 m/min. The tensile strength, percentage elongation at break, elastic modulus, and water vapor permeability of the PP films with and without coating with the microcapsules were not significantly different (p > 0.05), which indicates that the coating did not alter those properties of the films. Microencapsulation effectively prevented the volatilization of CO in the films. The microencapsulated system may be extended to other food-packaging films for which the same ink-printing platform is used. The results from this study imply that the oil-microencapsulated films could be potentially produced by a modern film manufacturing system.

In this study, we have prepared three kinds of enteric tablet coating formulations for prevention the crack incidence and enhanced process improvement of enteric tablet using aqueous system. we determined the mechanical strength of three formulatons on the enteric film-coating process. The compared experiment of one-layer and two-layer (A), (B) coating treated having placebo tablets without breakline and logo. In result, the breaking force time of two-layer (B) film strength was found to increase 0.8min than two-layer (A). We confirmed the half reduction of working hour and the simplification in the one-layer coating process, and the coating troubles was solved as setting up a dehumidifier in inlet of coater. In result, we recovered that optimum running capacity(g/kg) of dehumidifier is 10g/kg and below.

보일러 시스템에서의 부식 현상은 다양한 산업 분야에서 중대한 문제 중 하나로 인식되어왔다. 부식에 주된 원인으로는 높은 온도와 염소 가스와 같은 부식을 촉진시키는 특정한 가스인자들을 꼽을 수 있다. 많은 연구자들은 부식 현상을 억제하기 위한 재료 개발과 방법들에 대해 주목해서 연구해왔지만 각각의 내부식방법들을 비교 분석한 연구 사례는 흔치 않다. 이번 연구에서 우리는 보일러 시스템 고유의 온도 및 가스 조건을 구현할 수 있는 장치를 고안하여 각각의 내부식 방법들을 평가해보았다. 대부분의 보일러 시스템에서는 보일러 관의 외부(~800℃)와 내부(~500℃)가 내부의 스팀생성으로 인해 온도가 다르게 구현되는 독특한 특징이 있다. 우리가 새롭게 고안된 장치를 이용하면 내부식 방법들(ceramic coating, silica taping, plasma coating, high velocity oxygen fuel coating and overlay Inconel welding)에 대한 평가뿐만 아니라 부식을 유발시키는 염소 가스에 대한 영향도 구분해서 분석할 수 있다. 본 연구를 통해 보일러 튜브 표면에서 발생하는 고온 부식의 메커니즘에 대한 분석 및 고찰을 비롯해 각각의 내부식 방법들에 대한 보일러 튜브의 수명연장효과(잔여 수명 분석)을 FE-SEM, EDS, 무게감량법들을 통해 비교･평가할 수 있었다.

콘크리트 표면에 존재하는 균열은 염소이온의 침투에 대한 빠른 침투 통로가 되어 내구성능을 저하시킬 수 있다. 균열을 제어하기 위하여 설계적 측면에서 높은 철근비로 균열폭을 감소시킬 수는 있으나, 이러한 균열이 실질적으로 내구성을 저하시키는데에 따른 검토 및 내구성 향상을 유도할 수 있는 방법이 필요하다. 표면도막공법은 균열폭이 작은 경우에 균열을 실링하여 염소이온 침투를 차단하는데 가장 간단한 방법중의 하나이며, 경제성 대비 성능도 만족할 만 하다. 그래서 표면도막공법이 콘크리트와 균열을 함침하여 유해물질의 침투로 인한 철근의 부식을 제어하기 위한 유효성을 검토하는 연구가 필요하다. 본 연구는 표면도막공법으로 압축응력 인가로 인한 미세균열을 통한 염소이온 침투의 제어 가능성을 검토하고자 하였다. 실험결과는 염소이온은 압축응력 인가율 50~70%, 탄산화는 70~80%의 범위에서 임계응력이 존재하는 것으로 나타났는데, 이 임계치 이상을 초과하게 되면 상대적으로 심각한 열화가 진전되는 것을 확인할 수 있었다. 또한, 표면도막공법은 균열치료효과를 얻는데 유효한 것으로 판단되었다.

파우더 파운데이션은 사용이 간편하고 수정화장이 용이하여 고객들이 많이 사용하고 있으며, 파우더 파운데이션을 만드는 방법은 건식방식, 소성방식, 그리고 습식방법으로 크게 분류할 수가 있다. 이중 습식방법은 이미 잘 알려진 바와 같이 back injection 방법과 front injection 방법이 있으며, 본 논문에서는 front injection 방법을 사용해 실험을 진행하였다. 실험결과 용매의 종류에 따른 경도 변화를 살펴보면 휘발성 실리콘이나 탄화수소계 휘발성 물질을 이용할 때 보다 정제수를 이용할 때 경도가 높게 나타났으며, 사용감 측면에서는 물보다는 탄화수소계 휘발성 물질과 휘발성 실리콘 등을 사용했을 때, 고객 선호도가 높게 나타났다. 또한 코팅물질 변화에 따른 경도 변화로는 아미노산계 코팅물질을 사용하였을 대 경도가 상승하는 효과를 나타냈으며, 실리콘 코팅 물질을 사용했을 때 경도 상승효과가 미비한 것으로 나타났다. 이러한 결과를 토대로 각 대상 고객에 맞는 처방을 개발하고자 할 때 사용감과 경도의 상관관계를 알고, 처방설계에 이용한다면 고객이 원하는 사용감에 한발 더 접근할 수 있으리라 생각된다.