The Moving Particle Semi-implicit (MPS) method is one of most famous method in the particle-based computational fluid dynamics field. The MPS, the state-of-art method, is simple but intuitive methodology including multi-phase and complex structure interactions problems. However, the concept of particle method may contain the physical weakness. In order to avoid physical violence, the particle number density and kernel function were employed. Despite all the efforts, the microscopic problems were not easily resolved yet. In this study, the surface tension model was developed and added into the MPS method to strengthen physical phenomena and physics laws. The simulation result with new MPS method including surface tension model was compared with corresponding theoretical results and they show good-agreement.
This paper presents the theoretical analysis for the flow driven by surface tension and gravity force in an inclined circular tube. The previously developing equation for Power-Law model is a simple ordinary differential type. A governing equation is developed for describing the displacement of a non-Newtonian fluid(Casson model) that continuously flows into a circular tube by surface tension, which represents a second-order, nonlinear, non-homogeneous, and ordinary differential form. It was found that the theoretical predictions of the governing equation were in good agreement with the results for considering the Newtonian model.
This paper presents the theoretical analysis for the flow driven by surface tension and gravity force in an inclined circular tube. The present study introduces detailed mathematical procedures for Casson viscosity model. The equations of velocity distribution and flow rate are developed to describe the displacement of a non-Newtonian fluid that continuously flew into a circular tube by surface tension. The equation of modified volumetric flow shows the complicated form of (10) due to yield stress term, and the equation of velocity distribution which includes the yield stress and inclination angle of circular tube is composed of terms of r and rc as form of (14).
This paper presents the theoretical analysis for the flow driven by surface tension and gravity force in an inclined circular tube. The governing equation is developed to describe the displacement of a Newtonian fluid that continuously flew into a circular tube by surface tension, which represents a second-order, nonlinear, nonhomogeneous and ordinary differencial form. It was found that the theoretical predictions of the governing equation were excellent agreement with the unsteady state solutions for horizontal tube and the results of force balance equation for steady state.
A new model and resultant equation for the coagulation of acrylonitrile monomers in precipitation polymerization are suggested in consideration of the surface tension (γ) and cohesive energy density (ECED). The equation was proven to be quite favorable by considering figure fittings from known surface tensions and cohesive energy densities of certain organic solvents. The relationship between scale value of surface tension (γ/M) and cohesive energy density of monomers can be obtained by changing the coagulation bath component for effective precipitation polymerization of acrylonitrile in wet spinning.
For the fabrication of core-shell structure bimetallic lead-free solder balls, both the critical temperature (Tcr) for the phase separation of two immiscible liquid phases and the temperature coefficient of the interfacial tension between the two separated liquid phases are required. In order to obtain this information, the temperature dependence of the surface tension of 60%Bi-24%Cu-16%Sn(-REM) alloys was measured using the constrained drop method. The slope of the temperature dependence of the surface tension changed clearly at a critical temperature for the separation of two immiscible liquid phases. The critical temperature of the 60%Bi-24%Cu-16%Sn alloy was estimated to be 1097K. An addition of 0.05% Ce decreased the critical temperature to 1085K, whereas that of 0.05% La increased it to 1117K. It was found that the surface tension and its temperature coefficient of the 60%Bi-24%Cu-16%Sn alloy were slightly increased by the addition of 0.05% Ce and 0.05% La. In addition, additions of Ce and La increased the temperature coefficient of the interfacial tension.
A semi-empirical method to estimate the surface tension of molten alloys at different oxygen partialpressures is suggested in this study. The surface tension of molten Ag-Sn and Ag-Cu alloys were calculatedusing the Butler equation with the surface tension value of pure substance at a given oxygen partialpressure. The oxygen partial pressure ranges were 2.86×10-12-1.24×10-9Pa for the Ag-Sn system and2.27×10-11-5.68×10-4 Pa for the Ag-Cu system. In this calculation, the interactions of the adsorbed oxygenwith other metallic constituents were ignored. The calculated results of the Ag-Sn alloys were in reasonableaccordance with the experimental data within a difference of 8%. For the Ag-Cu alloy system at a higheroxygen partial pressure, the surface tension initially decreased but showed a minimum at XAg = 0.05 to increaseas the silver content increased. This behavior appears to be related to the oxygen adsorption and thecorresponding surface segregation of the constituent with a lower surface tension. Nevertheless, the calculatedresults of the Ag-Cu alloys with the present model were in good agreement with the experimental data withina difference of 10%.
The rheological properties and surface tensions of polymer solutions and polymer-surfactant mixed solutions were investigated. The polymers used in this study were a homopolymer of acrylic acid crosslinked with an allyl ether of pentaerythritol, an allyl ether of sucrose, or an allyl ether of propylene (CARBOMER), acylate/C10-30 alkyl acylate crosspolymer (AAAC), and ammonium acryloydimethyltaurate/VP copolymer (ADTV). A solubilizing agent PEG-40 hydrogenated castor oil (HCO-40) and an emulsifying agent polyoxyethylene (20) sorbitan monostearate (POLYSORBATE 60) made the micelles intervening between AAAC polymers, resulting in the increase of viscosity. However, HCO-40 made this behavior over the wider range of surfactant concentration than POLYSORBATE 60. From the view point of surface tensions in the same range of surfactant concentration, AAAC/HCO-40 solution showed the area of increasing surface tension with surfactant concentration in contrast to the AAAC/POLYSORBATE 60 solution showing no increasing area.
The conductances of trimethyltetradecylammonium bromide (TTAB) plus triphenyltetradecyl phosphonium bromide (TTPB) and TTAB plus trimethylhexadecylammonium bromide (HTAB) over the entire mole fraction range of TTAB were measured in water and in cyclodextrin plus water mixtures at fixed 4 and 8 mM of cyclodextrin at 30℃. The conductivity plot for both binary mixtures shows a single break from which the mixed critical micelle concentration and degree of micelle ionization were computed. From the slope of the conductivity curve, the equivalent ionic conductivities of the monomeric, associated, and the micelle states were calculated and discussed with respect to the surfactant-cyclodextrin complexation in the whole mole fraction range of both surfactant binary mixtures. The association constant K between the respective monomeric surfactant and cyclodextrin cavity of fixed 4 mM cyclodextrin was computed by considering 1:1 association from the surface tension measurement. A comparison among the K values for HTAB-cyclodetrin, TTAB-cyclodextrin, and TTPB-cyclodextrin shows that the former complexation is significantly stronger in comparison to the other ones due to the longer hydrophobic tail.
본 연구에서는 경사와 위사의 장력에 기인되는 감성 봉제용 직물의 마찰특성을 KES-FB 계측기를 이용하여 분석하였다. 직물의 마찰특성은 직물표면의 마찰계수, 마찰계수의 평균편차, 그리고 표면요철도를 측정하였다. 이들 표면특성치를 분석하기 위해서 75d/36f PET 필라멘트를 경사로 사용하고 100d/192f PET 필라멘트를 위사로 사용하여 5매 주자직 직물을 Omega와 Picanol 직기에서 각각 제직하고 이들을 같이 연결하여 염색가공 공정을 진행시켰다. 이들 가공된 직물의 직물표면특성은 제직시 측정된 경사와 위사의 장력특성과 함께 분석되어 졌으며 직물의 중앙부위와 양 셀베지 부분의 직물 위치에 따른 표면특성의 차이가 분석되어졌다.
테오스(TEOS)를 출발물질로 사용하여 건조조절제(DCCA;Dying Control Chemical Additives)를 첨가하지 않고, 솔-젤 법을 이용하여 Si(001) 단결정 기판 위에 실리카 박막을 제조하였다. 박막은 스핀 코팅 방법으로 테오스 =1 몰, 염산=0.05몰의 조건하에 메탄올, 증류수의 첨가량을 변화시키면서 젤화 완료시간, 박막의 두께, 균열 발생 여부, 박막의 결정성 등을 조사하였다. 그 결과 솔의 제화 완료시간은 메탄올 첨가량이 8몰일 때 가장 긴 640시간이었다. 코팅된 박막의 두께는 메탄올 첨가량이 많아질수록 감소하였다. 소결은 승온 속도0.6˚C/min으로 500˚C에서 1시간 행하였으며, 메탄올 첨가량이 0.8몰, 2몰일 때는 표면에서 균열이 발생하여 worm-like grain 구조를 가졌고, 메탄올 4몰인 경우에는 국부적으로 균열이 발생하였으나, 메탄올 양이 8몰 이상에서는 균열이 발생하지 않았다. 즉, 솔-젤 공정에서 균열 방지를 위해 첨가되는 건조조절제(DMF)를 첨가하지 않고도 용매인 메탄올과 증류수 혼합비를 조절, 표면장력을 제어함으로써 균열없는 박막을 제조하였다.
This study investigated the effect of surface water on concrete substrate on adhesive strength in tension of very high flowable SBR-modified cement mortar. Polymer cement ratio(P/C) were 10, 20, 30, 50 and 75% and the weight ratio of fine aggregate to cement were 1:1 and 1:3. The specimens obtained with different P/C and C:F were characterized by unit weight, flow test, crack resistance and adhesion test. Three selected specimens among these tested specimens were studied about the effect of surface water evenly sprayed on concrete substrate on adhesive strength.