Within the air purification system of a nuclear power plant, specific radioactive isotopes are extracted from gases through adsorption onto activated carbon. To properly dispose of used activated carbon, it is essential to determine the concentration of radioactive nuclides within it. This study discusses the application of the pyrolysis method for analyzing the concentrations of 3H and 14C in spent activated carbon. The pyrolysis was conducted using Raddec’s Pyrolyser, with adjustments made to parameters such as temperature profiles, airflow rates, sample quantities, and trapping solution volumes. The evaluation method for the pyrolysis of activated carbon to analyze 3H and 14C involved adding 3H and 14C sources to the activated carbon before use and subsequently assessing the recovery rates of the added sources in comparison to the analysis results.

A comprehensive understanding of actinide coordination chemistry and its structure is essential in many aspects of the nuclear fuel cycle, such as fuel reprocessing, waste management, reactor safety, and non-proliferation efforts. Managing radioactive waste generated during the nuclear fuel cycle has recently become more important, accordingly increasing the importance of designing appropriate waste forms and storage solutions for long-term waste disposal. Compared to the increase in the need for understanding the chemistry of major radioactive elements, the information on the local structure of the radioactive elements, especially actinides, remains unknown. To probe this issue, X-ray absorption fine structure (XAFS) can be applied. By analyzing the EXAFS (extended X-ray absorption fine structure) and XANES (X-ray absorption near edge structure), the local structure around atoms can be determined. However, the radioactive properties of the nuclides hindered the measurement of EXAFS and XANES, due to the difficulties of preparation, containment, and transfer of the sample. To measure the EXAFS of various compounds regarding the back-end nuclear fuel cycle, laboratory-based EXAFS (hiXAS, HP spectroscopy) has been introduced which can measure the EXAFS and XANES at the energy range of 5-18 keV. Compounds of Copper (Cu foil, CuO samples), Zirconium (Zr foil), and Europium (Eu2O3) were used for the verification of the laboratory -based EXAFS at a given energy range. The measured EXAFS spectrum of various compounds exhibit good agreement with the theoretical data, showing an R-factor of less than 0.02. It was found that each graph has a first peak corresponding to 2.55Å for Cu foil (Cu-Cu), 1.93Å for CuO samples (Cu-O), 3.23Å for Zr foil (Zr-Zr), and from 2.32Å to 2.34Å for Eu2O3 (Eu-O), which agree well with other values from the literature. From the result, it can be implied that this equipment can be used especially in the back-end nuclear fuel cycle field to enhance the understanding of local structure in radiochemistry.

Thermal cutting processes that can be applied to dismantling nuclear power plants include oxygen cutting, plasma cutting, and laser cutting. According to the global trend, research projects are being carried out in various countries to upgrade laser cutting, and many studies are also being conducted in Korea with plans to apply laser cutting processes when dismantling nuclear power plants. However, with the current technology level of the laser cutting process, the maximum thickness that can be cut is limited to 250 mm. Therefore, in this study, a laser-oxygen hybrid cutting process was implemented by adding a laser heat source to the oxygen cutting process that can cut carbon steel with a thickness of 250 mm or more (RV, beam, column, beam, etc.) when dismantling the nuclear power plant. This has the advantage of improving the cutting speed and reducing the cutting width Kerf compared to conventional oxygen cutting. In this research, the laser-oxygen hybrid cutting process consisted of laser cutting to which Raycus’ 8 kW Fiber Laser power source was applied and oxygen cutting to which hydrogen was applied with Fuel Gas. The oxygen torch was placed perpendicular to the test piece, and the laser head was irradiated by tilting 35° to 70°. The effects of cutting directions on quality and performance were studied, and cutting paths were selected by comparing cutting results. Thereafter, it was confirmed that there is an optimal laser output power according to the cutting thickness by studying the effect on the cutting surface quality by changing only the laser output power under the same cutting conditions. The results of this study are expected to be helpful in the remote cutting process using laser-oxygen hybrid cutting when dismantling domestic nuclear power plants in the future.

Derived Concentration Guideline Levels (DCGLs), which represent the residual radioactivity concentration limits, serve as the pivotal criteria for decontamination during decommissioning of nuclear power plants and are essential for license termination. The analysis of radionuclides in various media to check site-specific and radionuclide-specific DCGLs is a resource-intensive and time-consuming processes, and there are some radionuclides that are hard to analyze. In the decommissioning of the Rancho Seco nuclear power plant in the United States, a conservative approach was adopted. Potentially highly contaminated areas on the site were identified by collecting and analyzing soil samples, and radionuclides exceeding the Minimum Detectable Concentration (MDC) were selected as the potential Radionuclide of Concern (ROC), and surrogate DCGLs for hard-to-detect radionuclides were applied to soil samples. For soil samples in the Rancho Seco nuclear power plant, Cs-137 contributed more than 90% of the total radioactivity. DCGLs of the ROC were obtained using the scaling factors through analysis of Cs- 137 for a large amount of soil samples. In Korea, the scaling factor methodology has not been applied to the decommissioning of commercial nuclear power plants. An initial investigation was undertaken to assess the viability of implementing Surrogate Derived Concentration Guideline Levels (DCGLs) in the dismantling of Kori Unit 1, drawing insights from the U.S. nuclear power plant decommissioning experiences. To do this approach, the concentration ratio of radionuclides of interest to key radionuclide in contaminated soil should be known and consistent. But related information is not available at this time. So Surrogate DCGL for representative C-14, Fe-55, Ni-59, Ni-63, and Sr-90 was obtained using the scaling factors applied to radioactive waste data, specifically Decontaminated Aqueous Waste (DAW) and Spent Resin. In order to develop a reliable surrogate DCGLs the Kori Unit 1 site, it is important to analyze the radionuclides in the soil for the Kori Unit 1 decommissioning site to obtain consistent concentration ratio of the radionuclides of concern to the key radionuclides. When a the suitable DCGL is developed, it can be used for FSS planning and prior decision-making ensuring the safe and effective decommissioning of Kori Unit 1 and similar nuclear power plants.

The radioactive waste generated within radiation-controlled areas is classified and processed according to relevant laws and regulations based on contamination levels. In cases where such radioactive waste complies with the legally defined clearance concentration or dose criteria, it is disposed of as non-radioactive waste by means of incineration, reclamation, recycling, etc. Within radiation controlled areas, various consumables are periodically replaced to ensure the proper operation of the area. It is necessary to have appropriate disposal methods for these consumables. In particular, waste items such as fire extinguishers, fluorescent lamps, batteries, and pressure vessels (hereinafter referred to as “Special Waste Type”), which may contain hazardous substances within their internal components and contents, should be considered for appropriate disposal methods that comply with nuclear safety and environmental laws. In the present case, the specified special waste type do not come into direct contact with radiation sources, and they have impermeable surfaces, which significantly reduces the risk of external contamination infiltrating the interior. However, the current method of clearance is not suitable for these items (Typically, nuclear energy-related business operators are required to classify clearance target waste based on internal and external components and demonstrate compliance with the criteria. Nevertheless, for special waste type, it is difficult to separate and measure internal and external components within the radiation-controlled area). In this case, the Clearance Procedure for special waste type applied to Korea Atomic Energy Research Institute was introduced. Additionally, we have extracted considerations for future domestic clearance of the type.

To evaluate the inventory of radionuclides for the disposal of waste generated from nuclear power plants, indirect assessment methods such as the scaling factor method or average radioactivity concentration method can be applied. A scaling factor represents the average concentration ratio between key radionuclides and difficult-to-measure (DTM) radionuclides, while the average radioactivity concentration refers to the average concentration of DTM radionuclides, regardless of the concentration of key radionuclides or within specific ranges of key radionuclide concentrations. These indirect assessment methods can be statistically derived through the analysis of representative drums. This study will address how to apply these scaling factors and average radioactivity concentrations. Firstly, the concentration of gamma-emitting radionuclides will be analyzed using a drum radionuclide analyzer, and the concentration of DTM radionuclides will be determined by applying scaling factors specific to each DTM radionuclide. In the case of using the average radioactivity concentration method, the average concentration of DTM radionuclides will be applied independently of the concentration of gamma-emitting radionuclides. It is crucial to perform radioactive decay correction based on the date of generation or disposal when applying scaling factors or average radioactivity concentration. Additionally, for repackaged 320 L drums, determining which drum among the two 200 L drums inside should serve as the reference is of utmost importance

The radwaste repository consists of a multi-barrier, including natural and engineered barriers. The repository’s long-term safety is ensured by using the isolation and delay functions of the multi-barrier. Among them, natural barriers are difficult to artificially improve and have a long time scale. Therefore, in order to evaluate its performance, site characteristics should be investigated for a sufficient period using various analytical methods. Natural barriers are classified into lithological and structural characteristics and investigated. Structural factors such as fractures, faults, and joints are very important in a natural barrier because they can serve as a flow path for groundwater in performance evaluation. Considering the condition that the radioactive waste repository should be located in the deep part, the drill core is an important subject that can identify deep geological properties that could not be confirmed near the surface. However, in many previous studies, a unified method has not been used to define the boundaries of structural factors. Therefore, it is necessary to derive a method suitable for site characteristics by applying and comparing the boundary definition criteria of various structural factors to boreholes. This study utilized the 1,000 m deep AH-3 and DB-2 boreholes and the 500 m deep AH-1 and YS- 1 boreholes drilled around the KURT (KAERI Underground Research Tunnel) site. Methods applied to define the brittle structure boundary include comparing background levels of fracture and fracture density, excluding sections outside the zone of influence of deformation, and confining the zone to areas of concentrated deformation. All of these methods are analyzed along scanlines from the brittle structure. Deriving a site-specific method will contribute to reducing the uncertainties that may arise when analyzing the long-term evolution of brittle structures within natural barriers.