The binary oxide adsorbent using Fe and Mn (Fe-Mn) has been prepared by precipitation method to enhance the removal of phosphate. Different amounts of chitosan, a natural organic polymer, were used during preparation of Fe-Mn as a stabilizer to protect an aggregation of Fe-Mn particles. The optimal amount of chitosan has been determined considering the separation of the Fe-Mn particles by gravity from solution and highest removal efficiency of phosphate (Fe-Mn10). The application of Fe-Mn10 increased removal efficiency at least 15% compared to bare Fe-Mn. According to the Langmuir isotherm model, the maximum uptake (qm) and affinity coefficient (b) were calculated to be 184 and 240 mg/g, and 4.28 and 7.30 L/mg for Fe-Mn and Fe-Mn10, respectively, indicating 30% and 70% increase. The effect of pH showed that the removal efficiency of phosphate was decrease with increase of pH regardless of type of adsorbent. The enhanced removal efficiency for Fe-Mn10 was maintained in entire range of pH. In the kinetics, both adsorbents obtained 70% removal efficiency within 5 min and 90% removal efficiency was achieved at 1 h. Pseudo second order (PSO) kinetic model showed higher correlation of determination (R2), suggesting chemisorption was the primary phosphate adsorption for both Fe-Mn and Fe-Mn10.

PURPOSES : In this study, a method to use magnesium phosphate ceramic (MPC) concrete for the surface maintenance of airport pavements with jointed concrete is developed. METHODS : To investigate the application of a material incorporated with MPC for the surface maintenance of airport pavements with jointed concrete, structures with various cross-sections and thicknesses were constructed. The cross-section of the structure was modeled for the surface maintenance of four types of pavements and typical pavement construction processes, such as cutting, cleaning, production and casting, finishing, hardening, and joint reinstallation. Subsequently, the hours required for each process was determined. RESULTS : The MPC concrete used for the surface maintenance of airport pavements with jointed concrete demonstrate excellent performance. The MPC concrete indicates a compressive strength exceeding 25 MPa for 2 h, and its hydration heat is 52.9 ℃~61.2 ℃. Meanwhile, the crushing and cleaning performed during the production and casting of the MPC require a significant amount of time. Specifically, for a partial repair process, a total of 6 h is sufficient under traffic control, although this duration is inadequate for a complete repair process. CONCLUSIONS : MPC concrete is advantageous for the surface maintenance of airport pavements with jointed concrete. In fact, MPC concrete can be sufficiently constructed using existing concrete maintenance equipment, and partial repair works spanning a cross-sectional area of 11 m2 can be completed in 1 d. In addition, if the crushing and cleaning are performed separately from production and construction, then repair work using MPC concrete can be performed at a larger scale.

Phosphate coating is applied to the surface of the round bar material used in the multi-stage cold forging process for the purpose of lubrication. The film characteristics are determined according to the conditions of the phosphate film treatment process. In this study, the film properties according to the phosphate treatment conditions were defined as the coefficient of repeated friction and quantitative analysis was performed. Different friction behaviors were exhibited depending on the film properties, suggesting that optimization of the phosphate film treatment conditions is possible based on this. Finally, as a practical example, friction behavior according to the film characteristics was applied to the automotive engine bolt forming process. As a final conclusion, the need for linkage analysis with phosphating conditions for optimizing the forging process was raised. In addition, it can be seen that damage to the phosphate film should be considered in the process of predicting the limiting life of the die.

Spinach (Spinacia oleracea L.), a green leafy vegetable, is well known as a functional food due to its biological activities. Vascular calcification is associated with several disease conditions including atherosclerosis, diabetes, and chronic kidney disease (CKD), and is known to raise the risk of cardiovascular diseases related morbidity and mortality. However, there are no previous studies that have investigated the effects of fermented spinach exract (FSE) against aortic and its underlying mechanisms. Therefore, this study investigated the effects and action of possible mechanisms of FSE on inorganic phosphate (PI)-induced vascular calcification in ex vivo mouse aortic rings. PI increased vascular calcification through calcium deposition in ex vivo aortic rings. FSE inhibited calcium accumulation and osteogenic key marker, runt-related transcription factor 2 (Runx2), and bone Morphogenetic Protein 2 (BMP-2) protein expression in ex vivo aortic rings. And, FSE inhibited PI-induced extracellular signal-regulated kinase (ERK) and p38 phosphorylation in ex vivo aortic rings. These results show that FSE can prevent vascular calcification which may be a crucial way for the prevention and treatment of vascular disease association with vascular calcification.

A wire rod, a material for multistage cold forging, is subjected to spheroidization and low annealing heat treatment to secure formability, and a phosphate coating treatment on the material surface to secure lubricity. The film layer produced by the phosphate treatment process is involved in adhesion to the material surface, adhesion to the forging die surface, and lubricity. This results in the increase or decrease of the forming load and the increase or decrease of the die life in the cold forging process. In particular, as the cold forging process progresses, the phosphate film is damaged and the original performance is deteriorated, so there is a high possibility of process defects. In case of excessive damage, the film is completely lost and die soldering occurs. Therefore, in this study, quantitative criteria for phosphate film damage are presented and the effect on the cold forging process is analyzed based on this to improve process analysis prediction accuracy. Therefore, in this study, quantitative criteria for phosphate film damage are presented, and based on this, the friction coefficient in the multi-stage cold forging process is to be derived.

The adsorption process using GAC is one of the most secured methods to remove of phosphate from solution. This study was conducted by impregnating Cu(II) to GAC(GAC-Cu) to enhance phosphate adsorption for GAC. In the preparation of GAC-Cu, increasing the concentration of Cu(II) increased the phosphate uptake, confirming the effect of Cu(II) on phosphate uptake. A pH experiment was conducted at pH 4-8 to investigate the effect of the solution pH. Decrease of phosphate removal efficiency was found with increase of pH for both adsorbents, but the reduction rate of GAC-Cu slowed, indicating electrostatic interaction and coordinating bonding were simultaneously involved in phosphate removal. The adsorption was analyzed by Langmuir and Freundlich isotherm to determine the maximum phosphate uptake(qm) and adsorption mechanism. According to correlation of determination(R2), Freundlich isotherm model showed a better fit than Langmuir isotherm model. Based on the negative values of qm, Langmuir adsorption constant(b), and the value of 1/n, phosphate adsorption was shown to be unfavorable and favorable for GAC and GAC-Cu, respectively. The attempt of the linearization of each isotherm obtained very poor R2. Batch kinetic tests verified that ~30% and ~90 phosphate adsorptions were completed within 1 h and 24 h, respectively. Pseudo second order(PSO) model showed more suitable than pseudo first order(PFO) because of higher R2. Regardless of type of kinetic model, GAC-Cu obtained higher constant of reaction(K) than GAC.

Tin bis(monohydrogen orthophosphate) monohydrate 물질의 흡착 성질에 관하여 KCl 수용액을 통하여 조사하였다. 금속이온 농도와 pH를 변화시키면서 어떻게 달라지는지 화학평형에 바탕을 두고 data를 분석하였다. 금속이온들의 흡착 data는 Langmuir 흡착식에 넣어 Langmuir 수치들을 얻는데 사용되었다. Tin phosphate는 산성에서 이온교환 화합물로 작용하였으며, 2가의 전이금속이온에 대해 Cu+2 > Co+2 > Ni+2의 순서로 선택적 흡착성질을 나타내었다. 약한 산성 이온 교환체에서와 같이 금속이온의 교환은 tin phosphate의 선택성을 결정하는데 결정적 역할을 하였다. 모든 경우에서 흡착의 정도는 온도와 농도의 증가와 함께 증가하였다. Lnngmuir 수치들은 흡착과정 동안의 엔트로피, 엔탈피, 자유에너지 변화량같은 열역학적 함수들을 계산하는데 이용되었다.

This study investigated the substitution effect of phosphate and isolated soybean powder (ISP) by Allomyrina dichotoma larvae powder (AP) in emulsion sausage. The sausages were prepared for five treatments: 1) positive control (PC): sausages manufactured with sodium pyrophosphate (0.3%) and ISP (1%); 2) negative control (NC): sausages manufactured without sodium pyrophosphate, and ISP; 3) phosphate replacement (PR): sausages manufactured with ISP and AP (1%); 4) ISP replacement (IR): sausages manufactured with sodium pyrophosphate and AP; 5) phosphate and ISP replacement (PIR): sausages manufactured with AP. The 1% AP extract showed DPPH radical scavenging (45.65±2.468%) and metal chelating (22.46±3.559%) activity. The high pH value of AP (8.03) increased the pH of the meat batter of PR, IR, and PIR (p<0.05), but there was no inhibitory effect on cooking loss. Cooking loss of IR was not significantly different with PC due to phosphate. The addition of AP decreased the L* and a* values and increased the b* values, and decreased hardness, chewiness, and springiness of PR, IR, and PIR (p<0.05). AP did not inhibit lipid oxidation in sausages, in contrast to phosphate. In sensory evaluation, the addition of AP resulted in low scores for all sensory parameters of the sausages, although most panels had normal or positive awareness (p<0.05). Aroma was more influential on samples than color. Overall, AP did not replace phosphate and ISP in the sausages. Therefore, processes such as eliminating unique aroma and color and increasing solubility through particle size control are necessary to use AP as a protein source.

2 (Langmuir, Freundlich, Elovich, Temkin, and Dubinin-Radushkevich) and 3 (Sips and Redlich-Peterson)-parameter isotherm models were applied to evaluated for the applicability of adsorption of Cu(II) and/or phosphate isotherm using chitosan bead. Non-linear and linear isotherm adsorption were also compared on each parameter with coefficient of determination (R2). Among 2-parameter isotherms, non-linear Langmuir and Freundlich isotherm showed relatively higher R2 and appropriate maximum uptake (qm) than other isotherm equation although linear Dubinin-Radushkevich obtained highest R2. 3-parameter isotherm model demonstrated more reasonable and accuracy results than 2-parmeter isotherm in both non-linear and linear due to the addition of one parameter. The linearization for all of isotherm equation did not increase the applicability of adsorption models when error experiment data was included.

Phosphorus is a vital resource for sustaining agriculture and nutrition, but a limited non-renewable resource. Thus, the recovery of phosphorus from waste activated sludge(WAS) was attempted by microwave heating and magnesium ammonium phosphorus(MAP) crystallization. Polyphosphate-accumulating organisms(PAOs) in WAS release phosphate from the cell when they are exposed to high temperature environments. Microwave heating caused phosphorus and ammonia to release from WAS. The amount was increased with increasing temperature, showing that 88.5% of polyphosphate present in the cells were released in the form of phosphate at 80oC. A similar result was also observed in the release of ammonia. On the other hand, both phosphorus and ammonia were crystallized with magnesium, and then was harvested as MAP. Phosphorus recovery rate reached almost 97.8%, but the ammonia was about 13.4%. These results cleary indicate that phosphorus could be recovered from WAS using a physiological trait of PAOs. Heavy metal analyses also show that the MAP crystal is useful and safe as a phosphorus fertilizer.

인산염 농도 변화에 따른 Hizikia fusiforme의 무기비소 축적량 및 생장률을 분석하였다. 무기비소에 14일간 노출 하였을 때, 2 mg L-1의 높은 인산염 농도에서 무기비소 축적량이 증가하지 않았다. 하지만 인산염 농도가 0.02 mgL-1로 낮은 경우에 무기비소 축적량이 3배 이상 증가하였다. 또한 H. fusiforme는 인산염 농도가 낮은 경우 생장률이 14.5%, 무기비소 (10 μg L-1)에 노출되었을 경우 생장률이 대조구 대비 30% 감소하였다. H. fusiforme는 인산염과 무기비소를 구분하지 못하여 인산염의 농도가 낮은 경우 무기비소 축적량이 증가하게 되고, 축적된 무기비소는 광합성 저해 및 세포분열을 방해하여 생장률을 억제한다. 특히 우리나라의 대표적인 양식생물인 H. fusiforme는 다른 해조류에 비해 상대적으로 무기비소 축적량이 높다고 알려져 있기 때문에, H. fusiforme의 식품안전성을 확보하기 위해 다양한 연구가 필요하다.

본 연구는 담녹조강 Tetraselmis suecica와 T. tetrathele의 인산염 흡수에 미치는 발광다이오드의 파장의 영향을 조사하였다. 파장은 청색 발광다이오드(LED; 450 nm), 황색 LED(590 nm), 적색 LED(630 nm) 그리고 형광램프(control)이며, 조도는 100 μmol m-2 s-1로 주사하였 다. T. suecica와 T. tetrathele의 최대흡수속도(ρmax)는 적색 LED에서 6.35 pmol cell-1 hr-1와 9.85 pmol cell-1 hr-1로 나타났으며, 반포화농도(Ks)는 9.43 μM와 21.2 μM로 나타났다. 이는 적색 LED 아래에서 T. suecica와 T. tetrathele가 다른 파장보다 영양염에 대한 친화성이 높다는 것으로 의미한다. 따라서 경제성 및 생산성 향상을 위한 Tetraselmis 배양시스템(광배양기)의 최적 광원은 낮은 영양염 상태에서도 높은 생장속도를 보이는 적색 LED가 적합할 것으로 판단된다.

굴 패각과 같은 반응성 재료는 사용 목적에 적합한 전처리 조건을 선택할 필요가 있다. 본 연구에서는 인 농도 제어를 목적으로 효율적인 굴 패각 사용을 위한 전처리 조건을 제안하는데 목적을 둔다. 굴 패각의 전처리(소성 온도, 소성 시간, 입자 크기)에 따른 인산염 제거 효율을 조사하였다. 또한 XAFS 분석 및 등온 흡착 실험을 통해 굴 패각의 인산염 제거특성에 대해 조사하였다. 실험 결과 소성 온도는 600°C, 소성 시간은 6 h, 입자 크기는 0.355~0.075 mm에서 우수한 제거 효율을 확인하였다. 등온 흡착 실험 결과 Langmuir 모델이 굴 패각의 흡착에 적합한 것으로 나타났다. XAFS 분석 결과 600°C에서 소성시킨 굴 패각에는 인산칼슘이 생성된 것이 확인되었다. 즉 굴 패각의 칼슘 이온 용출에 의한 인산칼슘 형성이 인산염의 농도 감소에 기여하고 있음을 확인하였다.

친환경화소재 음이온 교환막을 제조하기 위하여 수용성 PVA에 (Formylmethyl) triphenyl-phosponium chloride의 모노머를 아세틸화 반응에 의해 고정시켰다. 제조한 막의 특성을 분석하기 위해 FTIR, TGA. SEM등의 기기분석장치 및 물리 화학적 기본 특성인 IEC, Transport number, MER등을 조사하였고 이에 대한 거동을 보고하고자한다.

본 연구는 우육 심장근의 수리미 유사물로의 활용 가능성 구명과 인삼염의 첨가가 우육 심장 수리미 유사물의 품질특성에 미치는 영향에 대해 알아보고자 실시하였다. 공시재료로 우육 심장근 수리미 유사 물을 사용하였으며 무처리구(C), 소금 2% 처리구(T1), 소금 1.95% + 인산염 0.05% 처리구(T2) 그리고 소금 1.90% + 인산염 0.10% 처리구(T3)로 나누어 실험을 하였다. 수분함량 결과 대조구에 비해 처리구 에서 낮게 나타났으며 T1에서 가장 낮은 수분함량 값을 나타내었다(P<0.05). 조단백질 함량은 T3가 가 장 높게 나타났으며 T1에서 가장 낮게 나타났다(P<0.05). pH는 대조구에 비해 T1에서 낮게 나타났으며 인산염 첨가수준에 따라 증가하였다(P<0.05). 가열감량은 대조구에서 가장 높게 나타났으며 T2에서 가 장 낮은 값을 나타내었다(P<0.05). 보수력 또한 대조구에서 가장 낮게 나타났으며 T2 처리구에서 가장 높게 나타났다(P<0.05). 명도의 경우 대조구에서 높게 나타나며 처리구에서 낮게 나타났다(P<0.05). 적 색도는 대조구에 비해 처리구에서 높게 나타났으며 T3에서 가장 높게 나타났다(P<0.05). 황색도는 T1 과 T2 처리구에서 낮게 나타났다(P<0.05). 또한 백색도는 대조구에서 높게 나타났으며 소금 및 인산염 첨가시 낮게 나타났다(P<0.05). 경도, 응집성, 검성 및 씹힘성은 T1에서 낮게 나타났으며 소금과 인산 염 0.1% 첨가구인 T3에서 높게 나타났다(P<0.05). 따라서 우육 심장 수리미 유사물에 인산염의 첨가는 단백질 함량을 높이고 보수력을 증가시켜 조직감을 개선시키는 것으로 판단된다. 그러나 명도 및 백색 도가 낮아 수세방법의 개선에 대한 연구가 요구된다.

The excessive concentration of phosphorus in the river and reservoir is a deteriorating factor for the eutrophication. The converter slag was used to remove the phosphate from the synthetic wastewater. Influencing factors were studied to remove soluble orthophosphate with the different particle sizes through the batch and the column experiments by continuous flow. Freundlich and Langmuir adsorption isotherm constants were obtained from batch experiments with PSA and PSB. Freundlich isotherm was fitted better than Langmuir isotherm. Regression coefficient of Freundlich isotherm was 0.95 for PSA and 0.92 for PSB, respectively. The adsorption kinetics from the batch experiment were revealed that bigger size of convert slag, PSA can be applied for the higher than 3.5 mg/L of phosphate concentration. The pilot plant of continuous flow was applied in order to evaluate the pH variation, breakthrough points and breakthrough adsorption capacity of phosphate. The variation of pH was decreased through the experimental hours. The breakthrough time was 1,432 and 312 hours to 10 mg/L and 50 mg/L for the influent concentration, respectively. The breakthrough adsorption capacity was 3.54 g/kg for 10 mg/L, and 1.72 g/kg for 50 mg/L as influent phosphate concentration.

본 연구는 염지공정에 사용되는 대표적인 염지제 종류를 각각 또는 혼합 처리한 돈육 등심의 품질 특성을 확인하고, 육제품 특성에 영향하는 각 염지제의 특성을 확인코자 실시하였다. 본 실험의 원료육은 돈육 등심을 이용하여 염지제를 첨가하지 않은 대조구(C)와 소금 5%(T1), 인산염 5%(T2), 탄산수소나트륨 3%(T3), 소금 5% + 인산염 5%(T4), 소금 5% + 탄산수소나트륨 3%(T5) 및 인산염 5% + 탄산수소나트륨 3%(T6) 등 원료육 중량의 10%를 기준으로 처리구를 설정하였다. 주입된 처리구들은 준비된 폴리백에 보관 후 24시간 동안 4℃에 냉장보관 하였다. pH 측정 결과, 5.44-6.04의 범위를 보였으며, 소금 염지 처리구(T1)을 제외한 모든 처리구에서 대조구보다 높게 나타났다(p<0.05). 육즙감량(%)은 대조구에서 다른 처리구들에 비해 높게 나타났으며(p<0.05), 보수력(%) 또한 처리구에서 대조구에 비해 높은 경향을 보이며 T1과 T3 처리구에서 가장 높은 보수력을 나타내었다(p<0.05). 단백질 용해성의 총단백질 및 근원 섬유단백질 농도는 모든 처리구에서 높은 용해성을 나타내었다(p<0.05). 결과적으로 염지제의 종류 및 이의 혼합 처리에 따른 돈육 등심의 이화학적 특성에 뚜렷한 차이를 보이지 않았으나, 염지제의 처리는 근육의 pH 상승과 육즙 손실의 감소, 보수력 및 단백질 용해성을 증가시켜 육제품의 품질특성에 기여할 것으로 판단된다.

질산염과 인산염의 농도가 다른 배지에서 Gymnodinium sanguineum과 Sketetonema costotum의 성장과 세포구성성분을 비교 분석하였다. 질산염은 0, 0.3, 0.6, 0.9, 1.2 mM, 인산염은 0, 15, 30, 45, 60μM을 각각 첨가한 배지에서 배양하였을 때, 저농도의 질산염 및 인산염 배지에서 G. sanguineum의 성장은 억제되었으나, S. costatum은 성장에 영향을 받지 않은 것으로 나타났다.