A study on the denitrification of reverse osmosis(RO) concentrated wastewater from sewage reuse treatment plant in P city was conducted using waste desulfurization agent obtained from desulfurization process. Sulfur-based autotrophic denitrifying carrier comprises the predetermined amount of waste iron sulfide (FeS, Fe2S3), mine drainage sludge and elemental sulfur showing mesoporisity with 9.9 nm (99 Å) of average pore size. Sulfur denitrifying bacteria and sulfur reducing bacteria were implanted into the pores of sulfur denitrifying carrier. Nitrate was not affected by empty bed contact time (EBCT). It is probably due to larger reducing capacity of the carrier than the concentration of nitrate in RO concentrated wastewater. Total nitrogen (T-N) removal efficiency exhibited about 90% after 4 days. Sulfate ion was surprisingly decreased with sulfur autotropic process due to the reduction of sulfate ion to HS- and S2- by sulfur reducing bacteria. Sulfide and hydrogen sulfide ions were then taken by Fe(OH)3, main component of mine drainage sludge, releasing OH-. Alkalinity was therefore maintained between 7.5 and 8.5 in pH by the released OH-. Also, it had the effect of suppressing the production of H2S, which causes bad odor.

해당 연구는 산업 폐수에서 염료를 효율적으로 제거하기 위한 고급 박막 나노복합체(TFN) 기반 나노여과막을 개 발하여 효과적인 폐수 처리 방법을 제시합니다. 최근 연구의 동향을 보면, 나노카본, 실리카 나노스피어, 금속-유기 프레임워 크(MOF) 및 MoS2와 같은 혁신적인 재료를 포함하는 TFN 막의 제조에 중점을 둡니다. 주요 목표는 염료 제거 효율을 향상 시키고 오염 방지 특성을 개선하며 염료/염 분리에 대한 높은 선택성을 유지하는 것입니다. 이 논문은 넓은 표면적, 기계적 견고성 및 특정 오염 물질 상호 작용 능력을 포함하여 이러한 나노 재료의 뚜렷한 이점을 활용하여 현재 나노여과 기술의 제 한을 극복하고 물 처리 문제에 대한 지속 가능한 솔루션을 제공하는 것을 목표로 합니다.

This paper aims to review the odor removal performance and operating parameters of pilot and full-scale chemical scrubbers, bioscrubbers, biofilters, and biotrickling filters for odor control in wastewater treatment plants. Based on the performance of full-scale facilities installed in wastewater treatment plants, empty-bed residence times were the shortest for bioscrubbers (7.5±2.5s), followed by chemical scrubbers (20±8.1s), biotrickling filters (22.2±26.2s), and biofilters (48±30s). The removal efficiencies of complex odors by biofilters, biotrickling filters, bioscrubbers, and chemical scrubbers were 97.7±1.9%, 87.7±15.6%, 89.0±9.0%, and 70.0%, respectively. The investment cost was the lowest for biofilters, followed by biotrickling filters, bioscrubbers, and chemical scrubbers. In addition, the operating costs of these deodorization technologies were in the following order: biofilters < bioscrubbers and biotrickling filters < chemical scrubbers. However, most studies on odor control for wastewater treatment processes have been conducted on a laboratory scale with model odors (single odorous compound or mixtures of 2-3 odorous compounds). Therefore, field research to develop deodorization technologies for wastewater treatment plants should be more actively conducted to accumulate data for the design and operation of full-scale deodorizing systems.

This study is to manufacture a titanium dioxide (TiO2) photocatalyst by recycling sludge generated using titanium tetrachloride (TiCl4) as a coagulant. Compared to general sewage, a TiCl4 coagulant was applied to dyeing wastewater containing a large amount of non-degradable organic compounds to evaluate its performance. Then the generated sludge was dried and fired to prepare a photocatalyst (TFS). Scanning electron microscope-energy dispersive X-ray spectroscopy (SEM-EDX), X-ray diffraction (XRD), and nitrogen oxide reduction experiments were conducted to analyze the surface properties and evaluate the photoactive ability of the prepared TFS. After using titanium tetrachloride (TiCl4) as a coagulant in the dyeing wastewater, the water quality characteristics were measured at 84 mg/L of chemical oxygen demand (COD), 10 mg/L of T-N, and 0.9 mg/L of T-P to satisfy the discharge water quality standards. The surface properties of the TFS were investigated and the anatase crystal structure was observed. It was confirmed that the ratio of Ti and O, the main components of TiO2, accounted for more than 90 %. As a result of the nitric oxide (NO) reduction experiment, 1.56 uMol of NO was reduced to confirm a removal rate of 20.60 %. This is judged to be a photocatalytic performance similar to that of the existing P-25. Therefore, by applying TiCl4 to the dyeing wastewater, it is possible to solve the problems of the existing coagulant and to reduce the amount of carbon dioxide generated, using an eco-friendly sludge treatment method. In addition, it is believed that environmental and economic advantages can be obtained by manufacturing TiO2 at an eco-friendly and lower cost than before.

항생제는 과도한 사용으로 인해 폐수뿐만 아니라 다양한 수원에서 발견되는 새로운 오염 물질 중 하나입니다. 수 중 항생제 오염 물질을 처리하기 위한 고도 산화 공정, 생물학적 처리 등 다양한 기술이 있습니다. 이 두 가지 공정은 비효율 적이며, 부산물의 생성은 이 공정을 더욱 복잡하게 만듭니다. 오염 물질을 제거하기 위한 또 다른 대안으로 막 기술이 있습니 다. 항생제와 내성 유전자의 제거를 개선하기 위해 막 생물 반응기는 NaClO와 탄소 물질로 변형됩니다. 풍부한 반응성 종의 생성은 항생제의 내성 유전자에 대해 활성입니다.

The odors emitted from wastewater treatment plants are not only a health and hygiene problem, but can also lead to complaints from residents and have wider social ramifications such as bringing about falling property values in the surrounding area. In this paper, based on the data measured at domestic and overseas wastewater treatment facilities, the concentrations of complex odors and odorous compounds were compared for each treatment/process: primary treatment, secondary treatment, and sludge treatment processes. Odor compounds that contribute greatly to complex odors were summarized for each process. In addition, the characteristics of odor wheels for each wastewater treatment process, which provide both chemical and olfactory information regarding odors, were reviewed. For domestic wastewater treatment facilities, the complex odor concentrations (unit, dilution factor) of the primary and secondary treatment processes were 4.5-100,000 (median, 32.1) and 2.5-30,000 (median, 10.7), respectively. However, the complex odor concentrations in the sludge treatment process were 3.0-100,000 (median, 118.7), which was more than three times higher than that in the wastewater treatment process. In the wastewater treatment process, those odor compounds making the greatest contributions to complex odors were sulfur-containing compounds such as hydrogen sulfide, dimethyl sulfide, and dimethyl disulfide DMS. In order to properly manage odors from wastewater treatment plants and minimize their impact, it is important to understand the status of odor emissions. Therefore, the compositions and concentrations of odors from wastewater treatment processes and odor wheel information, which are reviewed in this paper, are used to evaluate the potential risk of odor from wastewater treatment facilities in order to derive strategies to minimize odor emissions. Moreover, the information can be usefully used to introduce the best available technology to reduce odors emitted from wastewater treatment facilities.

본 연구에서는 분리막 생물반응기(membrane bioreactor, MBR)에서 발생되는 생물막오염 완화에 탁월한 효과를 가진 분리막을 개발할 목적으로, 친수성 산소 기능기가 많은 탄소나노구체(carbon nanosphere, CNS)를 합성한 뒤, 이를 첨가 제로 활용하여 친수성과 다공성 기공 구조를 갖는 고성능 한외여과막을 제조하였다. CNS는 막 표면에 초승달 모양의 기공을 형성하였고, CNS 함량을 4.6 wt%까지 증가시킴에 따라 최대기공 크기보다 큰 결함을 야기하지 않으면서 평균 표면 기공 크 기를 약 40% 증가시키는 것으로 나타났다. 또한, CNS 복합막의 다공성 기공 구조는 CNS의 등방성 형태와 상대적으로 낮은 입자 수밀도 덕분에 CNS 첨가에 따른 고분자 용액의 점도 급등이 방지됐기 때문이라고 판단된다. 그러나 너무 다공성이 커 지게 되면 기계적 물성이 저하되므로, 기공구조와 기계적 성질을 포함한 종합적인 고려를 했을 때 CNS2.3이 가장 우수하다 고 관측되었다. CNS2.3은 CNS0에 비해 수투과도가 2배 이상 높을 뿐만 아니라, MBR 공정에서 분리막 세정이 요구될 때까 지의 운전 시간도 5배 이상 연장시킨 것으로 확인되었다.

The production process of ultra-pure water (UPW) involves dozens of unit processes such as reverse osmosis (RO), pretreatments, membrane degasifier, and several ion exchange processes. Recently, continuous electrodeionization (CEDI) has replaced the 2-bed and 3-tower (2B3T) ion exchange process. As a result, the majority of wastewater in UPW production now comes from the RO concentrate. The important of RO in UPW production is to produce high-quality water with a low ion concentration (around 1 mg/L) for CEDI feed water. Minimizing RO concentrate is essential to reduce the wastewater produced in the UPW production process. This can be achieved by maximizing the recovery of the RO system. However, increasing the recovery is limited by the water quality of the RO permeate. To ensure high-quality permeate water, the RO system is designed with a two-pass configuration. The recovery of each pass in the RO system is limited (e.g., < 85%) due to the expected increase in permeate water concentration at higher RO feed water concentrations. Interestingly, tests using 4-inch RO modules with low concentration feed water (≤ 35 mg/L as NaCl) revealed that the permeate concentration remains almost constant regardless of the feed water concentration. This implies that the recovery of the first RO pass can be increased as long as the average feed/concentrate concentration of the second RO pass is less than 35 mg/L. According to this design criterion for the RO system, the recovery of the first and second RO pass, with a feed water concentration of 250 mg/L as NaCl, can be increased up to 94.8% and 96.0%, respectively. Compared to the conventional RO system design (e.g., 70% and 80% for the first and second RO pass) for UPW production, this maximum recovery design reduces the volume of RO feed and concentrate by up to 38.4% and 89.2%, respectively.

나노여과막(NF)은 식품가공, 제약 등 폐수는 물론 지자체 하수처리시설에서 배출되는 폐수 처리에 있어 훨씬 낮 은 압력으로 운용이 가능해 역삼투막(RO)보다 인기가 높다. NF막의 경우 분리 메커니즘은 투과확산 기작과 더불어 RO 박막 보다 낮은 가교밀도로 인한 체거름 메커니즘이다. 막 오염은 세라믹 막과 달리 고분자 막의 경우 나노 여과 공정의 고질적인 문제 중 하나이다. 이러한 문제를 해결하기 위해 차아염소산나트륨을 사용한 멤브레인 세척이 이루어진다. 폴리머 멤브레인 에 비해 세라믹 멤브레인은 이러한 화합물에 매우 안정적이다. 본 리뷰에서는 NF 프로세스에 의한 폐수 처리의 다양한 유형 의 세라믹 막 적용에 대해 논의한다.